Structural evolution of zeolite levyne under hydrostatic and non-hydrostatic pressure: geometric modelling     

G. Diego Gatta  Stephen A. Wells 《Physics and Chemistry of Minerals》2006,33(4):243-255

This is an exploratory study on the high-pressure (HP) structural evolution of a zeolitic framework (with LEV topology) on the basis of geometric modelling and previously published accurate unit-cell constants measured by means of single-crystal X-ray diffraction. The geometric simulations for 11 P values from 0 to 5 GPa gives more insight into the HP-behaviour of levyne, showing that the anomalous elastic behaviour of this zeolite observed under hydrostatic conditions at low P (P<1 GPa) is due to a double change in the compressional mechanism. Since the geometric simulation is not restricted to using the experimentally determined cell parameters, simulations of uniaxial compression along the [001] direction and of compression in the (001) plane have been performed, shedding more light on the compression mechanisms under non-hydrostatic regimes, which are difficult to access experimentally. The mechanisms associated with compressions along different axes provide insight into the hydrostatic compression mechanisms leading to the anomalous elastic behaviour.Electronic Supplementary Material Supplementary material is available for this article at and is accessible for authorized users.  相似文献   

Observation of converted Moho reflections in the north-west of the Iberian Peninsula     

Julia Téllez  Diego Córdoba 《Geophysical Journal International》1996,124(1):7-17

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Early Paleozoic Structural and Metamorphic Evolution of Western Sierra de San Luis (Argentina), in Relation to Cuyania Accretion     

Pablo Diego GonzAlez  Ana Maria Sato  Eduardo Jorge Llambias  Miguel A.S. Basei  Silvio R.F. Vlach 《Gondwana Research》2004,7(4):1157-1170

Structural, metamorphic and isotopic data obtained from the Nogoli Metamorphic Complex of western Sierra de San Luis indicate that the Early Paleozoic Famatinian Orogeny overprinted an already structured and metamorphosed older basement. The older geological features are relict NW trending fabric associated with high-grade (amphibolite facies) regional metamorphism preserved within thin strips of schists and paragneisses and in the core of mafic to ultramafic lenses. Arc magmatism, medium P (Barrovian type)/high T (amphibolite to granulite facies) regional metamorphism and penetrative NNE to NE trending foliation are related to the building of the Famatinian orogenic belt. The P-T conditions of the Famatinian prograde metamorphism reached a pressure peak of ca. 8 kb, with a thermal peak from -750°C up to -820°C. U-Pb conventional and chemical dating and Ar-Ar plateau ages constrain the peak of the main orogenic phase related to the Famatinian belt to 470–457 Ma (Early to Mid-Ordovician). Greenschist facies retrograde metamorphism closely associated with shear zones and secondary Ar-Ar plateau and Sm-Nd ages suggest that a late to post-orogenic phase of the Famatinian belt was active at least since -445 Ma. This phase continued during the Silurian to Late Devonian times through multiple reactivation of early shear zones. The Famatinian Orogeny reset a previous thermal history and therefore, the timing of the relict fabric could not be constrained conclusively with radiometric dates. Despite this difficulty, a range of 520 to 490 Ma suggests some inheritance from Pampean events registered by the older NW-SE fabric. The Early to Mid-Ordovician regional metamorphism and ductile deformation of the western Sierra de San Luis is interpreted as the orogenic effects of the collision of the allochthonous Cuyania terrane with the autochthonous proto-Pacific margin of Gondwana during the Famatinian Orogeny.  相似文献   

Micro-Analytical Zircon and Monazite U-Pb Isotope Dating by Laser Ablation-Inductively Coupled Plasma-Quadrupole Mass Spectrometry     

Keegan E. Alagna  Maurizio Petrelli  Diego Perugini  Giampiero Poli 《Geostandards and Geoanalytical Research》2008,32(1):103-120

In this study we evaluated the capability of a 213 nm laser ablation system coupled to a quadrupole-based ICP-MS in delivering accurate and precise U-Pb ages on zircons and monazites. Four zircon samples ( ca. 50 Ma to ca. 600 Ma) and four monazite samples ( ca. 30 Ma to ca. 1390 Ma) of known ages were analysed utilising laser ablation pits with diameters of 20 μm and 60 μm. Instrument mass bias and laser induced time-dependent elemental fractionation were corrected for by calibration against a matrix-matched reference material. Tera-Wasserburg plots of the calculated U-Pb data were employed to assess, and correct for, common Pb contributions. The results indicated that the LA-ICP-MS technique employed in this study allowed precise and accurate U-Pb isotope dating of zircon and monazite on sample areas 20 μm in diameter. At this spot size, the precisions achieved for single spot ²⁰⁶Pb/²³⁸U ages, were better than 5% (2s) for monazites and zircons with ages down to 30 Ma and 50 Ma, respectively. The precisions reported are comparable to those generally reported in SIMS and LA-MC-ICP-MS U-Pb isotope determinations.  相似文献   

Satellite number density profiles of primary galaxies in the 2dFGRS     

Laura Sales  Diego G. Lambas 《Monthly notices of the Royal Astronomical Society》2005,356(3):1045-1052

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The role of Earth observation in improving water governance in Africa: ESA’s TIGER initiative     

Diego Fernandez-Prieto  Francesco Palazzo 《Hydrogeology Journal》2007,15(1):101-104

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Community structure and phenology of chironomids (Insecta: Chironomidae) in a Patagonian Andean stream     

Patricia Elizabeth García  Diego Alejandro An Surez 《Limnologica》2007,37(1):109-117

In this paper, we studied the assemblage of Chironomidae from headwaters of Ñireco stream by recording drifting pupal exuviae caught in the debris close to the shore. Samples were collected in three stations along 18 km of the stream every 2 weeks during spring–summer months and monthly during autumn–winter over a year. A total of 15949 exuviae were collected and 55 taxa were identified. The most abundant taxa were Cricotopus spp. with highest numbers of exuviae recorded in each station over the study period. Subfamily Orthocladiinae was the most abundant taxa, followed by Chironominae and Podonominae. The emergence period in the stream occurred between December 1998 and March 1999. Most of the dominant and frequent species were univoltine. The emergence peaks at each sampling station occurred at the highest temperature of the water recorded.  相似文献   

The power spectrum of flux-limited X-ray galaxy cluster surveys     

Ariel Zandivarez  Mario G. Abadi  Diego G. Lambas 《Monthly notices of the Royal Astronomical Society》2001,326(1):147-154

We compute the redshift space power spectrum of two X-ray cluster samples: the X-ray Brightest Abell Cluster Sample (XBACS) and the Brightest Cluster Sample (BCS) using the method developed by Feldman, Kaiser & Peacock. The power spectra derived for these samples are in agreement with determinations of other optical and X-ray cluster samples. For XBACS we find the largest power spectrum amplitude expected, given the high richness of this sample ( R ≥2) . In the range 0.05< k <0.4  h  Mpc⁻¹ the power spectrum shows a power-law behaviour P ( k )∝ k ⁿ with an index n ≃−1.2 . In a similar range, 0.04< k <0.3  h  Mpc⁻¹ , the BCS power spectrum has a smaller amplitude with index n ≃−1.0 . We do not find significant evidence for a peak at k ≃0.05  h  Mpc⁻¹ , suggesting that claims such of feature detections in some cluster samples could rely on artificial inhomogeneities of the data. We compare our results with power spectrum predictions derived by Moscardini et al. within current cosmological models (LCDM and OCDM). For XBACS we find that both models underestimate the amplitude of the power spectrum but for BCS there is reasonably good agreement at k ≳0.03  h  Mpc⁻¹ for both models.  相似文献   

Strange attractors in plagioclase oscillatory zoning: petrological implications   总被引：1，自引：0，他引：1  

Diego?PeruginiEmail author  Giampiero?Poli  Luca?Valentini 《Contributions to Mineralogy and Petrology》2005,149(4):482-497

Oscillatory zoning in plagioclase crystals from different mixed lava flows cropping out on the Island of Capraia (Italy) has been investigated. An-calibrated profiles from back-scattered-electron images are used as compositional time series of oscillatory zoning. They are analyzed by a qualitative visual method that allows to appreciate at first sight the global structure of the time series and by a quantitative method to reconstruct the attractors associated to the oscillatory patterns, and to calculate the fractal dimension of attractors. Results show that attractors have fractional dimensions, indicating that series are chaotic. In addition, it is evidenced that there is a wide variation in oscillatory zoning in crystals from the same lava flow and that plagioclase populations from the different lava flows differ in the shape of frequency histograms of attractor dimension. The development of oscillatory zoning is simulated by considering a chemically inhomogeneous magmatic mass governed by chaotic flow fields, coupled with chemical diffusion, in which plagioclase crystals grow according to the availability of nutrients in their neighborhoods. Results show that in such a dynamical system plagioclase crystals develop chaotic zoning patterns analogous to those observed in natural plagioclases. This approach allows us to explain the differences observed in plagioclase crystals from the same lava flow and the differences in the shape of frequency histograms of attractor dimensions in the four lava flows.  相似文献   

Landscape structure,groundwater dynamics,and soil water content influence soil respiration across riparian–hillslope transitions in the Tenderfoot Creek Experimental Forest,Montana     

Vincent J. Pacific  Brian L. McGlynn  Diego A. Riveros‐Iregui  Daniel L. Welsch  Howard E. Epstein 《水文研究》2011,25(5):811-827

Variability in soil respiration at various spatial and temporal scales has been the focus of much research over the last decade aimed to improve our understanding and parameterization of physical and environmental controls on this flux. However, few studies have assessed the control of landscape position and groundwater table dynamics on the spatiotemporal variability of soil respiration. We investigated growing season soil respiration in a ～393 ha subalpine watershed in Montana across eight riparian–hillslope transitions that differed in slope, upslope accumulated area (UAA), aspect, and groundwater table dynamics. We collected daily‐to‐weekly measurements of soil water content (SWC), soil temperature, soil CO₂ concentrations, surface CO₂ efflux, and groundwater table depth, as well as soil C and N concentrations at 32 locations from June to August 2005. Instantaneous soil surface CO₂ efflux was not significantly different within or among riparian and hillslope zones at monthly timescales. However, cumulative integration of CO₂ efflux during the 83‐day growing season showed that efflux in the wetter riparian zones was ～25% greater than in the adjacent drier hillslopes. Furthermore, greater cumulative growing season efflux occurred in areas with high UAA and gentle slopes, where groundwater tables were higher and more persistent. Our findings reveal the influence of landscape position and groundwater table dynamics on riparian versus hillslope soil CO₂ efflux and the importance of time integration for assessment of soil CO₂ dynamics, which is critical for landscape‐scale simulation and modelling of soil CO₂ efflux in complex landscapes. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献