The coupled δC-radiocarbon systematics of three Late Glacial/early Holocene speleothems; insights into soil and cave processes at climatic transitions     

D. Rudzka  F. McDermott  D. Fleitmann  H. Stoll 《Geochimica et cosmochimica acta》2011,75(15):4321-4339

The coupled δ¹³C-radiocarbon systematics of three European stalagmites deposited during the Late Glacial and early Holocene were investigated to understand better how the carbon isotope systematics of speleothems respond to climate transitions. The emphasis is on understanding how speleothems may record climate-driven changes in the proportions of biogenic (soil carbon) and limestone bedrock derived carbon. At two of the three sites, the combined δ¹³C and ¹⁴C data argue against greater inputs of limestone carbon as the sole cause of the observed shift to higher δ¹³C during the cold Younger Dryas. In these stalagmites (GAR-01 from La Garma cave, N. Spain and So-1 from Sofular cave, Turkey), the combined changes in δ¹³C and initial ¹⁴C activities suggest enhanced decomposition of old stored, more recalcitrant, soil carbon at the onset of the warmer early Holocene. Alternative explanations involving gradual temporal changes between open- and closed-system behaviour during the Late Glacial are difficult to reconcile with observed changes in speleothem δ¹³C and the growth rates. In contrast, a stalagmite from Pindal cave (N. Spain) indicates an abrupt change in carbon inputs linked to local hydrological and disequilibrium isotope fractionation effects, rather than climate change. For the first time, it is shown that while the initial ¹⁴C activities of all three stalagmites broadly follow the contemporaneous atmospheric ¹⁴C trends (the Younger Dryas atmospheric ¹⁴C anomaly can be clearly discerned), subtle changes in speleothem initial ¹⁴C activities are linked to climate-driven changes in soil carbon turnover at a climate transition.  相似文献   

Factors affecting the Nd3+ (REE3+) luminescence of minerals     

Christoph Lenz  Dominik Talla  Katja Ruschel  Radek Škoda  Jens Götze  Lutz Nasdala 《Mineralogy and Petrology》2013,107(3):415-428

In this paper, possibilities and limits of the application of REE³⁺ luminescence (especially the Nd^{3+ 4}F_3/2 → ⁴I_9/2 emission) as structural probe are evaluated. Important factors controlling the Nd³⁺ luminescence signal are discussed, including effects of the crystal-field, crystal orientation, structural state, and temperature. Particular attention was paid to the study of the accessory minerals zircon (ZrSiO₄), xenotime–(Y) (YPO₄), monazite–(Ce) (CePO₄) and their synthetic analogues. Based on these examples we review in short that (1) REE³⁺ luminescence can be used as non-destructive phase identification method, (2) the intensities of certain luminescence bands are strongly influenced by crystal orientation effects, and (3) increased widths of REE³⁺-related emission bands are a strong indicator for structural disorder. We discuss the potential of luminescence spectroscopy, complementary to Raman spectroscopy, for the quantitative estimation of chemical (and potentially also radiation-induced) disorder. For the latter, emissions of Nd³⁺-related centres are found to be promising candidates.  相似文献   

The use of tracers to assess drill-mud penetration depth into sandstone cores during deep drilling: method development and application     

Linda Pellizzari  Dominik Neumann  Mashal Alawi  Dieter Voigt  Ben Norden  Hilke Würdemann 《Environmental Earth Sciences》2013,70(8):3727-3738

For the utilization of deep saline aquifers in the frame of geotechnical use, such as geological sequestration of CO₂, H₂ or energy storage, a baseline characterization of pristine reservoir rock cores is required to monitor changes in the indigenous microbial communities and pore fluids, and to study alterations in rock characteristics resulting from interaction with geological storage technologies. However, drilling procedures and technical fluids, particularly drill mud, are sources of core contamination. To measure the penetration of drill mud into the cores, three tracers (fluorescein, microspheres, and 4′,6-diamidino-2-phenylindole stained bacteria) were tested under laboratory conditions. The flow of drill mud into core samples was induced by applying uniaxial pressure differentials to the core, and the penetration depth was microscopically determined for each tracer. Fluorescein was extracted from the rock samples and quantified fluorometrically. The results indicate that all tested tracers are suitable for tracking drill-mud penetration. The actual penetration depth seems to be related to differences in mineral composition and texture as well as microfractures. Among all tested tracers, fluorescein labelling is the simplest, cheapest and most accurate method for analyzing the contamination of rock cores by technical fluids. The application of this tracer was successfully applied during two deep drilling campaigns at the CO₂ storage pilot site in Ketzin, Germany. The results highlight that the use of tracers is indispensable to ensure the quality of core samples for microbiological and biogeochemical analysis.  相似文献   

Reionization and the Cosmic Dawn with the Square Kilometre Array     

Garrelt Mellema  Léon V. E. Koopmans  Filipe A. Abdalla  Gianni Bernardi  Benedetta Ciardi  Soobash Daiboo  A. G. de Bruyn  Kanan K. Datta  Heino Falcke  Andrea Ferrara  Ilian T. Iliev  Fabio Iocco  Vibor Jelić  Hannes Jensen  Ronniy Joseph  Panos Labroupoulos  Avery Meiksin  Andrei Mesinger  André R. Offringa  V. N. Pandey  Jonathan R. Pritchard  Mario G. Santos  Dominik J. Schwarz  Benoit Semelin  Harish Vedantham  Sarod Yatawatta  Saleem Zaroubi 《Experimental Astronomy》2013,36(1-2):235-318

The Square Kilometre Array (SKA) will have a low frequency component (SKA-low) which has as one of its main science goals the study of the redshifted 21 cm line from the earliest phases of star and galaxy formation in the Universe. This 21 cm signal provides a new and unique window both on the time of the formation of the first stars and accreting black holes and the subsequent period of substantial ionization of the intergalactic medium. The signal will teach us fundamental new things about the earliest phases of structure formation, cosmology and even has the potential to lead to the discovery of new physical phenomena. Here we present a white paper with an overview of the science questions that SKA-low can address, how we plan to tackle these questions and what this implies for the basic design of the telescope.  相似文献   

Geochemistry of rare earth elements in a marine influenced coal and its organic solvent extracts from the Antaibao mining district, Shanxi, China   总被引：2，自引：0，他引：2  

Wenfeng Wang  Yong Qin  Shuxun Sang  Yanming Zhu  Chaoyong Wang  Dominik J. Weiss 《International Journal of Coal Geology》2008,76(4):309-317

Twenty-six samples including roof, bottom and coal plies of a marine influenced coal bed were collected from the Antaibao mining district, Shanxi, China. The rare earth elements (REEs) were determined in solids and organic solvent extracts. The distribution pattern showed three distinct patterns: shale-like, LREE-rich and HREE-rich. This is attributed to the variable microenvironment of peat-forming swamp, the degree of marine influences and different REE sources. REEs in the coal are mainly controlled by detrital minerals but also affected by seawater. The chondrite-normalized REE patterns of the organic solvent extracts are distinctly different from those of corresponding original coal samples, which show a negative Eu anomaly, a depletion of middle REEs and an enrichment of HREEs. The LREEs in coal extracts are likely adsorbed by hydrogen-containing functional groups, and HREEs are likely bonded to carbon atoms.  相似文献   

Evolution of the trophic state of Lake Annecy (eastern France) since the last glaciation as indicated by iron, manganese and phosphorus speciation     

Jean-Luc Loizeau  Daniel Span  Véronique Coppee  Janusz Dominik 《Journal of Paleolimnology》2001,25(2):205-214

Lake Annecy sediments have been studied to provide an insight into the evolution of the lake trophic state in response to climate changes during the Holocene. Determination of the concentration of carbonate, Fe, Mn, and different forms of P in conjunction with total sediment fluxes derived from ¹⁴C ages allows an estimation of yearly fluxes of these sediment components. High fluxes of endogenic carbonate occur during the early to middle Holocene. Non apatitic inorganic phosphorus flux is variable but shows some higher-than-present values during this period. These observations are interpreted as being a result of enhanced productivity by favourable conditions for phytoplankton development. In addition, the low Mn/Fe ratio of the redox-sensitive forms of these elements recorded during this period suggests low oxygen concentrations in the bottom waters. Therefore it appears that the lake may have undergone oxygen depletion in the bottom water during the warmer-than-present periods, due to increased productivity and subsequent oxygen consumption from the decay of organic matter. With future climate changes, this suggests that lake water quality may likely degrade under global warming.  相似文献   

Holocene Climatic Optimum centennial-scale paleoceanography in the NE Aegean (Mediterranean Sea)     

Maria V. Triantaphyllou  Alexandra Gogou  Margarita D. Dimiza  Sofia Kostopoulou  Constantine Parinos  Grigoris Roussakis  Maria Geraga  Ioanna Bouloubassi  Dominik Fleitmann  Vassilis Zervakis  Dimitris Velaoras  Antonia Diamantopoulou  Angeliki Sampatakaki  Vassilis Lykousis 《Geo-Marine Letters》2016,36(1):51-66

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No large-angle correlations on the non-Galactic microwave sky     

Craig J. Copi  Dragan Huterer  Dominik J. Schwarz  Glenn D. Starkman 《Monthly notices of the Royal Astronomical Society》2009,399(1):295-303

We investigate the angular two-point correlation function of temperature in the Wilkinson Microwave Anisotropy Probe ( WMAP) maps. Updating and extending earlier results, we confirm the lack of correlations outside the Galaxy on angular scales greater than about 60° at a level that would occur in 0.025 per cent of realizations of the concordance model. This represents a dramatic increase in significance from the original observations by the Cosmic Background Explorer Differential Microwave Radiometer ( COBE-DMR) and a marked increase in significance from the first-year WMAP maps. Given the rest of the reported angular power spectrum   C _ℓ  , the lack of large-angle correlations that one infers outside the plane of the Galaxy requires covariance among the   C _ℓ  up to  ℓ= 5  . Alternately, it requires both the unusually small (5 per cent of realizations) full-sky large-angle correlations and an unusual coincidence of alignment of the Galaxy with the pattern of cosmological fluctuations (less than 2 per cent of those 5 per cent). We argue that unless there is some undiscovered systematic error in their collection or reduction, the data point towards a violation of statistical isotropy. The near-vanishing of the large-angle correlations in the cut-sky maps, together with their disagreement with results inferred from full-sky maps, remains open problems, and are very difficult to understand within the concordance model.  相似文献   

Process identification through rejection of model structures in a mid‐mountainous rural catchment: observations of rainfall–runoff response,geophysical conditions and model inter‐comparison     

Thomas Graeff  Erwin Zehe  Dominik Reusser  Erika Lück  Boris Schröder  Gerald Wenk  Hermann John  Axel Bronstert 《水文研究》2009,23(5):702-718

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An anomaly detector with immediate feedback to hunt for planets of Earth mass and below by microlensing     

M. Dominik †  N. J. Rattenbury  A. Allan  S. Mao  D. M. Bramich  M. J. Burgdorf  E. Kerins  Y. Tsapras  &#;. Wyrzykowski 《Monthly notices of the Royal Astronomical Society》2007,380(2):792-804

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