Fluxes of selected trace metals from the Seine estuary to the eastern English Channel during the period August 1994 to July 1995     

Jean-Franois Chiffoleau  Dominique Auger  Emmanuelle Chartier 《Continental Shelf Research》1999,19(15-16)

Two sampling cruises conducted in the Seine estuary (France) under low-water and flood conditions produced high resolution profiles for dissolved cadmium, lead, copper, zinc and nickel concentrations versus salinity. The distribution of dissolved trace metals differed depending on hydrologic conditions, partly because of the dilution of upstream inputs during flood periods. Daily fluxes of these dissolved trace metals were estimated for the two sampling periods (September 1994 and February 1995) by extrapolating the dilution lines observed in higher salinity waters to salinity=0 and then multiplying the effective freshwater concentrations thus obtained by the corresponding freshwater flow. Several procedures were subsequently applied to deduce each daily flux for the year studied from data for these two periods. A consensus was found among these procedures, allowing the determination of net fluxes of dissolved trace metals with a precision of 20–35%. The net fluxes thus estimated were 4 T yr⁻¹ for Cd, 4 T yr⁻¹ for Pb, 40 T yr⁻¹ for Cu, 130 T yr⁻¹ for Zn and 50 T yr⁻¹ for Ni.  相似文献   

Reconstructing fluvial incision rates based on palaeo-water tables in chalk karst networks along the Seine valley (Normandy,France)     

Carole Nehme  Andrew Farrant  Daniel Ballesteros  Dominique Todisco  Joel Rodet  Diana Sahy  J. Michael Grappone  Jean-Claude Staigre  Damase Mouralis 《地球表面变化过程与地形》2020,45(8):1860-1876

Quantifying rates of river incision and continental uplift over Quaternary timescales offer the potential for modelling landscape change due to tectonic and climatic forcing. In many areas, river terraces form datable archives that help constrain the timing and rate of valley incision. However, old river terraces, with high-level deposits, are prone to weathering and often lack datable material. Where valleys are incised through karst areas, caves and sediments can be used to reconstruct the landscape evolution because they can record the elevation of palaeo-water tables and contain preserved datable material. In Normandy (N. France), the Seine River is entrenched into an extensive karstic chalk plateau. Previous estimates of valley incision were hampered by the lack of preserved datable fluvial terraces. A stack of abandoned phreatic cave passages preserved in the sides of the Seine valley can be used to reconstruct the landscape evolution of the region. Combining geomorphological observations, palaeomagnetic and U/Th dating of speleothem and sediments in eight caves along the Lower Seine valley, we have constructed a new age model for cave development and valley incision. Six identified cave levels up to ∼100 m a.s.l. were formed during the last ~1 Ma, coeval with the incision of the Seine River. Passage morphologies indicate that the caves formed in a shallow phreatic/epiphreatic setting, modified by sediment influxes. The valley's maximum age is constrained by the occurrence of late Pliocene marine sand. Palaeomagnetic dating of cave infills indicates that the highest-level caves were being infilled prior to 1.1 Ma. The evidence from the studied caves, complemented by fluvial terrace sequences, indicates that rapid river incision occurred during marine isotope stage (MIS) 28 to 20 (0.8–1 Ma), with maximal rates of ~0.30 m ka⁻¹, dropping to ~0.08 m ka⁻¹ between MIS 20–11 (0.8–0.4 Ma) and 0.05 m ka⁻¹ from MIS 5 to the present time. © 2020 John Wiley & Sons, Ltd.  相似文献   

Depositional controls on a hypertidal barrier-spit system architecture and evolution,Pointe du Banc spit,north-western France     

Mikkel Fruergaard  Bernadette Tessier  Clément Poirier  Dominique Mouazé  Pierre Weill  Suzanne Noël 《Sedimentology》2020,67(1):502-533

Physical stratigraphy, architecture and evolution of barrier systems in hypertidal environments (tidal range above 6 m) are understudied, and depositional controls are poorly understood compared with wave-dominated barrier systems and barrier spits in microtidal, mesotidal and macrotidal settings. Based on vibracores, ground-penetrating radar, radiocarbon and optically stimulated luminescence age data, the formation and evolution of the hypertidal barrier system of Pointe du Banc, north-western France has been reconstructed. The study shows that the barrier spit has a complex composite sedimentary architecture consisting of wave-dominated and tide-dominated sedimentary bodies. A morpho-sedimentary model is presented that demonstrates how barrier-spit progradation resulting from littoral drift was the main manner of spit elongation, whereas sediment convergence caused by landward migration of swash bars and seaward migration of tidal dunes caused the spit terminus to grow in height and width. These results suggest that long-term accretion rates varied considerably in response to changes in sediment supply. Variations in storminess together with the large-scale topography of the coast controlled the sediment supply and thus the evolution of the barrier system during latest Holocene. Despite architectural complexity, hypertidal barrier systems preserve records of past climate changes.  相似文献   

Immobilization of Cr(VI) by sulphate green rust and sulphidized nanoscale zerovalent iron in sand media: batch and column studies     

Digiacomo  Flavia  Tobler  Dominique J.  Held  Thomas  Neumann  Thomas 《Geochemical transactions》2020,21(1):1-22

The study presented in this work emerged as a result of a multiyear regional geochemical survey based on low-density topsoil sampling and the ensuing geochemical atlas of Croatia. This study focuses on the Dinaric part of Croatia to expound the underlying mechanisms controlling the mobilities and variations in distribution of potentially harmful elements as observed from different environmental angles. Although serious environmental degradation of the vulnerable karst soil landscapes was expected to occur chiefly through the accumulation of various heavy metals, the most acute threat materialized through the soil acidification (Al-toxicity) affecting the entire Dinaric karst area. This picture surfaced from the analysis of all three investigated discriminant function models employing the abovementioned environmental criteria selected autonomously with respect to the evaluated soil geochemistry, namely, geologic setting, regional placement and land use. These models are presented by not only the characteristic discriminant-function diagrams but also a set of appropriate mathematically derived geochemical maps disclosing the allocations of potential threats to the karst soil landscapes posed by soil acidity.  相似文献   

Exploring the past through lynchet landscapes in the Vosges Mountains and the Lorraine Plateau (France)     

Benjamin Keller  Robin Vincent  Dominique Schwartz  Damien Ertlen 《Geoarchaeology》2024,39(3):300-319

Lynchets are ridges formed by erosion and sediment accumulation downstream of agricultural plots and offer valuable insights into past agricultural activity. These microtopographies cover vast areas and serve as indicators of historical changes in land use. As a result, their ubiquity across Europe makes them particularly interesting. In this study, we propose a geoarchaeological approach to analyze six lynchets, four in the Vosges Mountains and two on the Lorraine Plateau (France). The lynchets can be considered soil archives with no stratigraphic organization or chronological sequence from bottom to top, making it difficult to determine the age of the lynchets and identify changes in land use over time. To this end, we propose the analysis of historical and geo-historical archives combined with the “pedosedimentary” archives of lynchets through charcoal identification and dating combined with near-infrared spectroscopy to determine the age, vegetation, and past land use changes associated with lynchet landscapes. By combining these multiple data sources, we are better able to show the chronological development of these ancient agricultural systems and uncover valuable information on landscape history. Charcoal dating suggests a higher frequency of fires from the Middle Ages. The dating aligns with the regional dynamics of anthropogenic fires, indicating a potential use of fire for cultural purposes. We also demonstrate the difficulty of extrapolating the dating of a lynchet to the entire lynchet system. Our results highlight the difficulties of interpreting the formation and dating of lynchets and the lynchet system on the sole basis of charcoal analysis. However, we highlight the value of applying pedoanthracology to lynchets to determine the dynamics of land use change in former fields.  相似文献   

Sub-Micrometre Resolution FIB-SEM-based ToF-SIMS Used to Map Geochemical Zoning in Four Zircon Reference Materials     

Ryan North  Lloyd T. White  Mitchell Nancarrow  Anthony Dosseto  Dominique Tanner 《Geostandards and Geoanalytical Research》2023,47(1):125-142

Zircon geochemistry can vary over micrometre scales; therefore, natural reference materials need to be well characterised before being used to calculate trace element mass fractions in unmeasured samples. Moreover, reference material homogeneity needs to be ensured with the accelerating rate of geoanalytical developments to map mineral chemistry at increasingly finer scales. Here, we investigate trace element zoning in four widely used zircon reference materials: 91500, Mud Tank, Temora and Plešovice, as well as zircon crystals from the Mount Dromedary/Gulaga Igneous Complex, Australia. Sub-micrometre resolution focused ion beam scanning electron microscope (FIB-SEM) based time-of-flight secondary ion mass spectrometry (ToF-SIMS) and 5 μm resolution LA-ICP-MS mapping show that trace elements are zoned in all reference materials, though 91500 exhibited the least zonation. We demonstrate that FIB-SEM-based ToF-SIMS can rapidly resolve variations in trace elements (e.g., U, Th, Sc, Y, Gd, Dy, Yb and Li) at sensitivities down to the μg g^-1 level with a spatial resolution of 195 nm for areas 100 × 85 μm to 959 × 828 μm. Zircon 91500 is recommended for future quantitative analyses provided that (1) the spatial distribution of elements is imaged before analysis of unknown samples and (2) it is used in conjunction with a doped glass as the primary reference material.  相似文献