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991.
Mineralogy and geochemistry of El Dorado epithermal gold deposit, El Sauce district, central-northern Chile 总被引:1,自引:0,他引:1
J. Carrillo-Rosúa S. Morales-Ruano D. Morata A. J. Boyce M. Belmar A. E. Fallick P. Fenoll Hach-Alí 《Mineralogy and Petrology》2008,92(3-4):341-360
Summary The El Dorado Au-Cu deposit is located in an extensive intra-caldera zone of hydrothermal alteration affecting Upper Cretaceous
andesites of the Los Elquinos Formation at La Serena (≈ 29°47′S Lat., 70°43′W Long., Chile). Quartz-sulfide veins of economic potential are hosted by N25W and N20E
fault structures associated with quartz-illite alteration (+supergene kaolinite). The main ore minerals in the deposit are
pyrite, chalcopyrite ± fahlore (As/(As + Sb): 0.06−0.98), with electrum, sphalerite, galena, bournonite-seligmanite (As/(As
+ Sb): 0.21−0.31), marcasite, pyrrhotite being accessory phases. Electrum, with an Ag content between 32 and 37 at.%, occurs
interstitial to pyrite aggregates or along pyrite fractures. Pyrite commonly exhibits chemical zonation with some zones up
to 1.96 at.% As. Electron probe microanalyses of pyrite indicate that As-rich zones do not exhibit detectable Au values. Fluid
inclusion microthermometry shows homogenization temperatures between 130 and 352 °C and salinities between 1.6 and 6.9 wt.%
NaCl eq. Isotope data for quartz, ankerite and phyllosilicates and estimated temperatures show that δ18O and δD for the hydrothermal fluids were between 3 and 10‰ and between −95 and −75‰, respectively. These results suggest
the mineralizing fluids were a mixture of meteoric and magmatic waters. An epithermal intermediate-sulfidation model is proposed
for the formation of the El Dorado deposit.
Author’s present address: J. Carrillo-Rosúa, Dpto. de Didáctica de las Ciencias Experimentales, Universidad de Granada, Campus de Cartuja, 18071, Granada, Spain 相似文献
992.
Summary Boron-doped mullites were synthesized using aluminium nitrate-nonahydrate, tetraethoxysilane and boric acid in a sol–gel process
with subsequent annealing at 950 and 1300 °C for five hours. Two different bulk compositions with constant Al2O3 contents (60 and 70 mol%, respectively) and varying SiO2 plus B2O3 contents were investigated. X-ray powder diffraction analyses yielded a linear decrease of the lattice parameters with increasing
bulk B2O3 content, which was interpreted as to be due to boron incorporation. Related to the increasing boron content, corresponding
infrared spectra revealed a slight and continuous shift for most of the absorption bands. These data show that mullite is
able to incorporate large amounts of boron into its structure (up to about 20 mol% B2O3 depending on the bulk composition of the starting materials). Infrared analyses suggest that boron is incorporated into the
mullite structure in form of planar three-fold coordinated BO3 groups.
Author’s address: A. Beran, Institut für Mineralogie und Kristallographie, Universit?t Wien-Geozentrum, Althanstra?e 14, 1090 Wien, Austria 相似文献
993.
M. El Ghorfi F. Melcher T. Oberthür A. E. Boukhari L. Maacha A. Maddi M. Mhaili 《Mineralogy and Petrology》2008,92(1-2):59-80
Summary The Neoproterozoic Bou Azzer ophiolite complex hosts numerous, small lenticular bodies of massive and disseminated chromite.
Metallurgical-grade high-Mg and high-Cr spinels (cores with 48–62 wt% Cr2O3) reveal complex alteration patterns of successive Cr and Mn enrichment and loss of Al towards the rims, while the Mg# ratios
[(Mg/(Mg + Fe2+)] remain almost constant. Concentration patterns of platinum-group elements are typical for ophiolitic chromitite poor in
sulfides, with predominance of the IPGE, variable Rh, and low Pt and Pd. The most abundant platinum-group mineral is Rh-bearing
laurite that occurs either included in spinel or in silicate matrix, whereas Os-Ir-Ru alloy is always included in spinel.
Laurite inclusions reveal complex intergrowth textures with Rh-Ru-Pt rich alloy, and with Rh-rich sulfide. Most laurites display
trends to sulfur-poor compositions leading to local formation of very fine-grained Ru-Os-Ir alloy phases. Ni-Co-Fe sulfides,
arsenides and sulfarsenides devoid of PGE are associated with the alteration of chromite. Textural position and chemical composition
of the base metal inclusions, as well as comparison of alteration features between chromite and accessory chromian spinel
in the Co-Ni-As ores of the Bou Azzer ophiolite indicate a close connection. It is suggested that hydrothermal fluids percolated
through the marginal zones of the ophiolite belt during greenschist facies metamorphism and deposited Ni-Co-Fe arsenides,
sulfarsenides and minor sulfides as accessories within altered chromitites, and also in structurally favourable zones as Ni-Co-As
ores.
Author’s address: Dr. Frank Melcher, Federal Institute for Geosciences and Natural Resources, Stilleweg 2, 30655 Hannover, Germany 相似文献
994.
M. Mejías J. Garcia-Orellana J. L. Plata M. Marina E. Garcia-Solsona B. Ballesteros P. Masqué J. López C. Fernández-Arrojo 《Environmental Geology》2008,54(3):521-536
A methodology for the characterization of deep carbonate aquifers has been developed and applied to El Maestrazgo Jurassic
aquifer in Castellón, Spain. Characterization of these aquifer formations, located at more than 300 m deep, consisted of a
previous phase of compilation, analysis and synthesis of the existing information about the area, followed by a coordinated
combination of different speciality studies: geology, stratigraphy, structural analysis, hydrogeology, hydrochemistry, geophysics
and remote sensing. Geological studies included geological mapping, definition of stratigraphical units and facies and structural
analysis. The aim of the hydrogeology study was to define aquifer formations, recharge area, aquifer points inventory and
groundwater flow directions for the establishment of piezometric and water quality observation nets. Special techniques were
applied, like thermal infrared aerial images and the evaluation of submarine groundwater discharge by means of natural radium
isotopes. Hydrochemical techniques, including majority elements characterization and stable isotopes (18O, 2H and 3H) determination, allowed classifying hydrochemical facies and establishing a renewal pattern for water within the system.
Geophysics was useful in determining the aquifer geometry, the features of the basement and the petrophysical characteristics
of the geological formations. Preliminary results show an important tectonic complexity and the possibilities for groundwater
uses in the area of study. 相似文献
995.
The Cambrian-Vendian groundwater body plays an important role in drinking water supply of capital Tallinn and other settlements
in northern Estonia. Water quality in this deep-seated confined groundwater body is influenced by the intrusion of present-day
seawater and pumping-induced upward migration of deeper saline groundwater. The aim of this study is to evaluate the threshold
values applying the methodology worked out within the EU 6th FP project “Background criteria for the identification of groundwater
thresholds (BRIDGE)” and to compare the results with the values proposed by local authorities. A database containing 250 monitoring
points was completed and used for the calculation of natural background levels (as the 90 and 97.7 percentile) in groundwater.
The calculation of threshold values is based on natural background levels and reference values. In case of Cambrian-Vendian
groundwater body the receptor is drinking water, thus limit values set by Estonian drinking water standard were used as reference
values. The threshold values proposed by local authorities are more or less the same as calculated by BRIDGE methodology.
Exceptionally different values are derived in case of chloride and ammonium. 相似文献
996.
Two algorithms for in-situ detection and identification of vertical free convective and double-diffusive flows in groundwater
monitoring wells or boreholes are proposed. With one algorithm the causes (driving forces) and with the other one the effects
(convection or double-diffusion) of vertical transport processes can be detected based on geophysical borehole measurements
in the water column. Five density-driven flow processes are identified: thermal, solutal, and thermosolutal convection leading
to an equalization, as well as saltfingers and diffusive layering leading to an intensification of a vertical density gradient.
The occurrence of density-driven transport processes could be proven in many groundwater monitoring wells and boreholes; especially
shallow sections of boreholes or groundwater monitoring wells are affected dramatically by such vertical flows. Deep sections
are also impaired as the critical threshold for the onset of a density-driven flow is considerably low. In monitoring wells
or boreholes, several sections with different types of density-driven vertical flows may exist at the same time. Results from
experimental investigations in a medium-scale testing facility with high aspect ratio (height/radius = 19) and from numerical
modeling of a water column agree well with paramters of in-situ detected convection cells. 相似文献
997.
Implementation of reconstructed geomorphologic units in landslide susceptibility mapping: the Melen Gorge (NW Turkey) 总被引:6,自引:2,他引:4
In the international literature, although considerable amount of publications on the landslide susceptibility mapping exist,
geomorphology as a conditioning factor is still used in limited number of studies. Considering this factor, the purpose of
this article paper is to implement the geomorphologic parameters derived by reconstructed topography in landslide susceptibility
mapping. According to the method employed in this study, terrain is generalized by the contours passed through the convex
slopes of the valleys that were formed by fluvial erosion. Therefore, slope conditions before landsliding can be obtained.
The reconstructed morphometric and geomorphologic units are taken into account as a conditioning parameter when assessing
landslide susceptibility. Two different data, one of which is obtained from the reconstructed DEM, have been employed to produce
two landslide susceptibility maps. The binary logistic regression is used to develop landslide susceptibility maps for the
Melen Gorge in the Northwestern part of Turkey. Due to the high correct classification percentages and spatial effectiveness
of the maps, the landslide susceptibility map comprised the reconstructed morphometric parameters exhibits a better performance
than the other. Five different datasets are selected randomly to apply proper sampling strategy for training. As a consequence
of the analyses, the most proper outcomes are obtained from the dataset of the reconstructed topographical parameters and
geomorphologic units, and lithological variables that are implemented together. Correct classification percentage and root
mean square error (RMSE) values of the validation dataset are calculated as 86.28% and 0.35, respectively. Prediction capacity
of the different datasets reveal that the landslide susceptibility map obtained from the reconstructed parameters has a higher
prediction capacity than the other. Moreover, the landslide susceptibility map obtained from the reconstructed parameters
produces logical results. 相似文献
998.
Soil erosion susceptibility assessment and validation using a geostatistical multivariate approach: a test in Southern Sicily 总被引:2,自引:0,他引:2
A certain number of studies have been carried out in recent years that aim at developing and applying a model capable of assessing
water erosion of soil. Some of these have tried to quantitatively evaluate the volumes of soil loss, while others have focused
their efforts on the recognition of the areas most prone to water erosion processes. This article presents the results of
a research whose objective was that of evaluating water erosion susceptibility in a Sicilian watershed: the Naro river basin.
A geomorphological study was carried out to recognize the water erosion landforms and define a set of parameters expressing
both the intensity of hydraulic forces and the resistance of rocks/soils. The landforms were mapped and classified according
to the dominant process in landsurfaces affected by diffuse or linear water erosion. A GIS layer was obtained by combining
six determining factors (bedrock lithology, land use, soil texture, plan curvature, stream power index and slope-length factor)
in unique conditions units. A geostatistical multivariate approach was applied by analysing the relationships between the
spatial distributions of the erosion landforms and the unique condition units. Particularly, the density of eroded area for
each combination of determining factors has been calculated: such function corresponds, in fact, to the conditional probability
of erosion landforms to develop, under the same geoenvironmental conditions. In light of the obtained results, a general geomorphologic
model for water erosion in the Naro river basin can be depicted: cultivated areas in clayey slopes, having fine-medium soil
texture, are the most prone to be eroded; linear or diffuse water erosion processes dominate where the topography is favourable
to a convergent or divergent runoff, respectively. For each of the two erosion process types, a susceptibility map was produced
and submitted to a validation procedure based on a spatial random partition strategy. Both the success of the validation procedure
of the susceptibility models and the geomorphological coherence of the relationships between factors and process that such
models suggest, confirm the reliability of the method and the goodness of the predictions. 相似文献
999.
1000.
The Samborombon Bay wetland is located on the west margin of the Rio de la Plata estuary, in the Province of Buenos Aires,
Argentina. This paper analyses the geological, geomorphologic, soil and vegetation characteristics of the southernmost sector
of this wetland and their influence on surface water and groundwater. The study area presents three hydrologic units: coastal
dunes, sand sheets and coastal plain. Coastal dunes and sand sheets are recharge zones of high permeability with well-drained,
non-saline soils, and a few surface water flows. Changes in the water table are related to rainfall. Groundwater in coastal
dunes is Ca–Mg–HCO3 to Na–HCO3, and of low salinity (590 mg/l). Groundwater in sand sheets is mainly Na–HCO3 with a salinity of about 1,020 mg/l. The coastal plain exhibits medium to low permeability sediments, with submerged saline
soils poorly drained. Groundwater is Na–Cl with a mean salinity of 16,502 mg/l. A surface hydrological network develops in
the coastal plain. Surface water levels near the shoreline are affected by tidal fluctuations; far from the shoreline water
accumulates because of poor drainage. Both sectors have Na–Cl water, but the former is more saline. Human intervention and
sea level rise may affect the wetland severely. 相似文献