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101.
Alexandra V. Turchyn Volker Brüchert Gregory S. Engel Daniel P. Schrag 《Geochimica et cosmochimica acta》2010,74(7):2011-6698
Kinetic isotope effects related to the breaking of chemical bonds drive sulfur isotope fractionation during dissimilatory sulfate reduction (DSR), whereas oxygen isotope fractionation during DSR is dominated by exchange between intercellular sulfur intermediates and water. We use a simplified biochemical model for DSR to explore how a kinetic oxygen isotope effect may be expressed. We then explore these relationships in light of evolving sulfur and oxygen isotope compositions (δ34SSO4 and δ18OSO4) during batch culture growth of twelve strains of sulfate-reducing bacteria. Cultured under conditions to optimize growth and with identical δ18OH2O and initial δ18OSO4, all strains show 34S enrichment, whereas only six strains show significant 18O enrichment. The remaining six show no (or minimal) change in δ18OSO4 over the growth of the bacteria. We use these experimental and theoretical results to address three questions: (i) which sulfur intermediates exchange oxygen isotopes with water, (ii) what is the kinetic oxygen isotope effect related to the reduction of adenosine phosphosulfate (APS) to sulfite (SO32−), (iii) does a kinetic oxygen isotope effect impact the apparent oxygen isotope equilibrium values? We conclude that oxygen isotope exchange between water and a sulfur intermediate likely occurs downstream of APS and that our data constrain the kinetic oxygen isotope fractionation for the reduction of APS to sulfite to be smaller than 4‰. This small oxygen isotope effect impacts the apparent oxygen isotope equilibrium as controlled by the extent to which APS reduction is rate-limiting. 相似文献
102.
John A. Izbicki Christen E. Petersen Kenneth J. Glotzbach Loren F. Metzger Allen H. Christensen Gregory A. Smith David O’Leary Miranda S. Fram Trevor Joseph Heather Shannon 《Applied Geochemistry》2010
About 1.02 × 106 m3 of chlorinated municipal drinking water was injected into a confined aquifer, 94–137 m below Roseville, California, between December 2005 and April 2006. The water was stored in the aquifer for 438 days, and 2.64 × 106 m3 of water were extracted between July 2007 and February 2008. On the basis of Cl− data, 35% of the injected water was recovered and 65% of the injected water and associated disinfection by-products (DBPs) remained in the aquifer at the end of extraction. About 46.3 kg of total trihalomethanes (TTHM) entered the aquifer with the injected water and 37.6 kg of TTHM were extracted. As much as 44 kg of TTHMs remained in the aquifer at the end of extraction because of incomplete recovery of injected water and formation of THMs within the aquifer by reactions with free-chlorine in the injected water. Well-bore velocity log data collected from the Aquifer Storage Recovery (ASR) well show as much as 60% of the injected water entered the aquifer through a 9 m thick, high-permeability layer within the confined aquifer near the top of the screened interval. Model simulations of ground-water flow near the ASR well indicate that (1) aquifer heterogeneity allowed injected water to move rapidly through the aquifer to nearby monitoring wells, (2) aquifer heterogeneity caused injected water to move further than expected assuming uniform aquifer properties, and (3) physical clogging of high-permeability layers is the probable cause for the observed change in the distribution of borehole flow. Aquifer heterogeneity also enhanced mixing of native anoxic ground water with oxic injected water, promoting removal of THMs primarily through sorption. A 3 to 4-fold reduction in TTHM concentrations was observed in the furthest monitoring well 427 m downgradient from the ASR well, and similar magnitude reductions were observed in depth-dependent water samples collected from the upper part of the screened interval in the ASR well near the end of the extraction phase. Haloacetic acids (HAAs) were completely sorbed or degraded within 10 months of injection. 相似文献
103.
Yu-Chen Song Hai-Dong Meng Michael J. O’Grady Gregory M. P. O’Hare 《Computational Geosciences》2010,14(2):263-271
A clustering algorithm that is based on density and is adaptive density-reachable is developed and presented for arbitrary data point distributions in some real-world applications, especially in geophysical data interpretation. Through comparisons of the new algorithm and other algorithms, it is shown that the new algorithm can reduce the dependency of domain knowledge and the sensitivity of abnormal data points, that it can improve the effectiveness of clustering results in which data are distributed in different shapes and different densities, and that it can get a better clustering efficiency. The application of the new clustering algorithm demonstrates that data mining techniques can be used in geophysical data interpretation and can get meaningful and useful results, and that the new clustering algorithm can be used in other real-world applications. 相似文献
104.
David L. Naftz Gregory T. Carling Cory Angeroth Michael Freeman Ryan Rowland Eddy Pazmiño 《Aquatic Geochemistry》2014,20(6):547-571
Density stratification in saline and hypersaline water bodies from throughout the world can have large impacts on the internal cycling and loading of salinity, nutrients, and trace elements. High temporal resolution hydroacoustic and physical/chemical data were collected at two sites in Great Salt Lake (GSL), a saline lake in the western USA, to understand how density stratification may influence salinity and mercury (Hg) distributions. The first study site was in a causeway breach where saline water from GSL exchanges with less saline water from a flow restricted bay. Near-surface-specific conductance values measured in water at the breach displayed a good relationship with both flow and wind direction. No diurnal variations in the concentration of dissolved (<0.45 μm) methylmercury (MeHg) were observed during the 24-h sampling period; however, the highest proportion of particulate Hgtotal and MeHg loadings was observed during periods of elevated salinity. The second study site was located on the bottom of GSL where movement of a high-salinity water layer, referred to as the deep brine layer (DBL), is restricted to a naturally occurring 1.5-km-wide “spillway” structure. During selected time periods in April/May, 2012, wind-induced flow reversals in a railroad causeway breach, separating Gunnison and Gilbert Bays, were coupled with high-velocity flow pulses (up to 55 cm/s) in the DBL at the spillway site. These flow pulses were likely driven by a pressure response of highly saline water from Gunnison Bay flowing into the north basin of Gilbert Bay. Short-term flow reversal events measured at the railroad causeway breach have the ability to move measurable amounts of salt and Hg from Gunnison Bay into the DBL. Future disturbance to the steady state conditions currently imposed by the railroad causeway infrastructure could result in changes to the existing chemical balance between Gunnison and Gilbert Bays. Monitoring instruments were installed at six additional sites in the DBL during October 2012 to assess impacts from any future modifications to the railroad causeway. 相似文献
105.
Avalanche and landslide simulation using the material point method: flow dynamics and force interaction with structures 总被引:3,自引:0,他引:3
Carter M. Mast Pedro Arduino Gregory R. Miller Peter Mackenzie-Helnwein 《Computational Geosciences》2014,18(5):817-830
In this paper, the material point method (MPM) is presented as a tool for simulating large deformation, gravity-driven landslides. The primary goal is to assess the interaction of these flow-like events with the built environment. This includes an evaluation of earthen mounds when energy dissipating devices are placed in the path of a snow avalanche. The effectiveness of the embankments is characterized using displacement, velocity, mass, and energy measures. A second example quantifies the force interaction between a landslide and a square rigid column. Multiple slide approach angles are considered, and various aspects of the impact force are discussed. 相似文献
106.
Scott H. Ensign Cliff R. Hupp Gregory B. Noe Ken W. Krauss Camille L. Stagg 《Estuaries and Coasts》2014,37(5):1107-1119
Sediment accretion was measured at four sites in varying stages of forest-to-marsh succession along a fresh-to-oligohaline gradient on the Waccamaw River and its tributary Turkey Creek (Coastal Plain watersheds, South Carolina) and the Savannah River (Piedmont watershed, South Carolina and Georgia). Sites included tidal freshwater forests, moderately salt-impacted forests at the freshwater–oligohaline transition, highly salt-impacted forests, and oligohaline marshes. Sediment accretion was measured by use of feldspar marker pads for 2.5 year; accessory information on wetland inundation, canopy litterfall, herbaceous production, and soil characteristics were also collected. Sediment accretion ranged from 4.5 mm year?1 at moderately salt-impacted forest on the Savannah River to 19.1 mm year?1 at its relict, highly salt-impacted forest downstream. Oligohaline marsh sediment accretion was 1.5–2.5 times greater than in tidal freshwater forests. Overall, there was no significant difference in accretion rate between rivers with contrasting sediment loads. Accretion was significantly higher in hollows than on hummocks in tidal freshwater forests. Organic sediment accretion was similar to autochthonous litter production at all sites, but inorganic sediment constituted the majority of accretion at both marshes and the Savannah River highly salt-impacted forest. A strong correlation between inorganic sediment accumulation and autochthonous litter production indicated a positive feedback between herbaceous plant production and allochthonous sediment deposition. The similarity in rates of sediment accretion and sea level rise in tidal freshwater forests indicates that these habitats may become permanently inundated if the rate of sea level rise increases. 相似文献
107.
Nathan D. Sheldon Ramananda Chakrabarti Gregory J. Retallack Roger M. H. Smith 《Sedimentology》2014,61(6):1812-1829
The end of the Palaeozoic is marked by two mass‐extinction events during the Middle Permian (Capitanian) and the Late Permian (Changhsingian). Given similarities between the two events in geochemical signatures, such as large magnitude negative δ13C anomalies, sedimentological signatures such as claystone breccias, and the approximate contemporaneous emplacement of large igneous provinces, many authors have sought a common causal mechanism. Here, a new high‐resolution continental record of the Capitanian event from Portal Mountain, Antarctica, is compared with previously published Changhsingian records of geochemical signatures of weathering intensity and palaeoclimatic change. Geochemical means of discriminating sedimentary provenance (Ti/Al, U/Th and La/Ce ratios) all indicate a common provenance for the Portal Mountain sediments and associated palaeosols, so changes spanning the Capitanian extinction represent changes in weathering intensity rather than sediment source. Proxies for weathering intensity chemical index of alteration, ?W and rare earth element accumulation all decline across the Capitanian extinction event at Portal Mountain, which is in contrast to the increased weathering recorded globally at the Late Permian extinction. Furthermore, palaeoclimatic proxies are consistent with unchanging or cooler climatic conditions throughout the Capitanian event, which contrasts with Changhsingian records that all indicate a significant syn‐extinction and post‐extinction series of greenhouse warming events. Although both the Capitanian and Changhsingian event records indicate significant redox shifts, palaeosol geochemistry of the Changhsingian event indicates more reducing conditions, whereas the new Capitanian record of reduced trace metal abundances (Cr, Cu, Ni and Ce) indicates more oxidizing conditions. Taken together, the differences in weathering intensity, redox and the lack of evidence for significant climatic change in the new record suggest that the Capitanian mass extinction was not triggered by dyke injection of coal‐beds, as in the Changhsingian extinction, and may instead have been triggered directly by the Emeishan large igneous province or by the interaction of Emeishan basalts with platform carbonates. 相似文献
108.
Arnold J. H. Reesink Philip J. Ashworth Gregory H. Sambrook Smith James L. Best Daniel R. Parsons Mario L. Amsler Richard J. Hardy Stuart N. Lane Andrew P. Nicholas Oscar Orfeo Steven D. Sandbach Christopher J. Simpson Ricardo N. Szupiany 《Sedimentology》2014,61(4):1055-1085
To date, published studies of alluvial bar architecture in large rivers have been restricted mostly to case studies of individual bars and single locations. Relatively little is known about how the depositional processes and sedimentary architecture of kilometre‐scale bars vary within a multi‐kilometre reach or over several hundreds of kilometres downstream. This study presents Ground Penetrating Radar and core data from 11, kilometre‐scale bars from the Río Paraná, Argentina. The investigated bars are located between 30 km upstream and 540 km downstream of the Río Paraná – Río Paraguay confluence, where a significant volume of fine‐grained suspended sediment is introduced into the network. Bar‐scale cross‐stratified sets, with lengths and widths up to 600 m and thicknesses up to 12 m, enable the distinction of large river deposits from stacked deposits of smaller rivers, but are only present in half the surface area of the bars. Up to 90% of bar‐scale sets are found on top of finer‐grained ripple‐laminated bar‐trough deposits. Bar‐scale sets make up as much as 58% of the volume of the deposits in small, incipient mid‐channel bars, but this proportion decreases significantly with increasing age and size of the bars. Contrary to what might be expected, a significant proportion of the sedimentary structures found in the Río Paraná is similar in scale to those found in much smaller rivers. In other words, large river deposits are not always characterized by big structures that allow a simple interpretation of river scale. However, the large scale of the depositional units in big rivers causes small‐scale structures, such as ripple sets, to be grouped into thicker cosets, which indicate river scale even when no obvious large‐scale sets are present. The results also show that the composition of bars differs between the studied reaches upstream and downstream of the confluence with the Río Paraguay. Relative to other controls on downstream fining, the tributary input of fine‐grained suspended material from the Río Paraguay causes a marked change in the composition of the bar deposits. Compared to the upstream reaches, the sedimentary architecture of the downstream reaches in the top ca 5 m of mid‐channel bars shows: (i) an increase in the abundance and thickness (up to metre‐scale) of laterally extensive (hundreds of metres) fine‐grained layers; (ii) an increase in the percentage of deposits comprised of ripple sets (to >40% in the upper bar deposits); and (iii) an increase in bar‐trough deposits and a corresponding decrease in bar‐scale cross‐strata (<10%). The thalweg deposits of the Río Paraná are composed of dune sets, even directly downstream from the Río Paraguay where the upper channel deposits are dominantly fine‐grained. Thus, the change in sedimentary facies due to a tributary point‐source of fine‐grained sediment is primarily expressed in the composition of the upper bar deposits. 相似文献
109.
The proportional contributions of stream bank and surface sources to fine sediment loads in watersheds in New York State were quantified with uncertainty analysis. Eroding streamside glacial drift, including glaciolacustrine deposits, were examined to help explain variations in the proportional contributions made by bank erosion. Sediment sources were quantified by comparing concentrations of the bomb‐derived radionuclide 137Cs in fluvial sediment with sediment from potential source areas such as agricultural soils, forest soils and stream banks. To compare sediment sources in streams containing abundant deposits of fine‐grained glacial drift with watersheds that lacked moderate or extensive streamside deposits, samples were taken from 15 watersheds in the region. The mean contribution of bank erosion to sediment loads in the six streams with glaciolacustrine deposits was 60% (range 46–76%). The proportional contribution of bank erosion was also important in one stream lacking glaciolacustrine deposits (57%) but was less important in the remainder, with contributions ranging from 0 to 46%. Data from this study on the varying contributions of bank erosion and data from past studies of sediment yield in 15 watersheds of New York State suggest that eroding streamside glacial deposits dominate sediment yield in many watersheds. In other watersheds, past impacts to streams, such as channelization, have also resulted in high levels of bank erosion. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
110.
The mobility, bioaccessibility and transfer pathways of metals and metalloids in estuarine sediments have been the focus of much detailed research. However, to date, few studies have examined the mineralogical siting of metals and metalloids in such sediments. This is despite the fact the mineralogy of sediments is an important factor that controls which and how much of a particular metal is released to pore waters and overlying water columns. This study reports on the mineralogical siting of metals in contaminated estuarine sediments, Hobart, Australia, and aims to evaluate the mobility of metals in the contaminated substrates. Mineralogical, mineral chemical and bulk chemical analyses demonstrate that the sediments contain very high levels of several metals and metalloids. The contaminated sediments have concentrations of zinc (Zn), lead (Pb), copper (Cu) and cadmium (Cd) ranging from 0.55 to 4.23 wt%, 0.16 to 0.70 wt%, 415 to 951 mg/kg and 23 to 300 mg/kg, respectively. Franklinite and lesser sphalerite are the main repositories of Zn, whereas much of the Pb and Cu is hosted by sulfides, organic matter and undetermined iron (Fe) oxides. While the release of contaminant loads from franklinite through dissolution is likely to be insignificant, even small releases of metals from the highly contaminated sediments can still cause the deterioration of local water quality. The contaminated sediments represent long-term sources of metal pollutants, particularly Zn, to local waters. This study demonstrates that mineralogical analyses are a vital tool to recognise the potential mobility of trace metals in estuarine environments. 相似文献