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Reiner Botz Eckhard Faber Michael J. Whiticar James M. Brooks 《Earth and Planetary Science Letters》1988,88(3-4)
The carbon isotopic composition of diagenetic dolomite and calcite in some sediments of the Gulf of Mexico varies between “normal-marine” (δ13C ca. 0‰) and −14.6‰ which suggests that biogenic CO2 contributed to the carbonate formation. The δ13O values of dolomite and coexisting calcite are very similar but variable down-core.Dolomite and calcite precipitated early from pore water where SO42− was not reduced. However, during (and after?) SO42− reduction dolomite and calcite still formed and there are at least two generations of carbonate minerals present. 相似文献
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Microbial anaerobic oxidation of methane in sediments is a kinetic process associated with a carbon isotope effect which enriches the remaining methane in 13C. Three, models: % residual methane, higher hydrocarbon enrichment, and CO2-CH4 coexisting pairs are used to independently calculate fractionation factors (αc) in the range of 1.002–1.014, which overlap the range determined by culture studies, αc is smaller than that associated with methanogenesis by CO2 reduction or by acetate-type fermentation, and comparison of the coexisting CO2-CH4 pairs can distinguish between the formation and consumption processes. Methane oxidation in sediments continues to a threshold concentration of ca. 0.2 mM; the residual methane is either unavailable or unattractive to consumption. Minor amounts of methane may also be produced simultaneously in the methane consumption zone, influencing the apparent fractionation factor in this zone. 相似文献
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Falk H. Weinlich Eckhard Faber Alena Bou&#x;kov Josef Horlek Manfred Teschner Jürgen Poggenburg 《Tectonophysics》2006,421(1-2):89-110
A continuously operated gas monitoring station was emplaced within the epicentral area of the NW Bohemian swarm earthquakes overlying directly the active Mariánské Lázně fault. The recordings of 8-month continuous monitoring period are presented. The variations in radon concentrations are similarly to variations in CO2, i.e. CO2 is considered to be the carrier gas for radon. Very small diurnal variations in gas concentration are caused by the earth tides, as daily variations in meteorological conditions cannot explain a short daily minimum at midday times. Sudden changes in gas concentration, which clearly exceed these diurnal variations occur and are always linked with seismic activities. Decreased gas concentration may indicate compression resulting in reduced fault permeability as is implied by negative peaks following local earthquake swarms. A sudden increase in CO2 and Rn concentration may indicate an increased fault permeability caused by stress redistribution, giving rise to opening of migration pathways. This implies a repeatedly sudden rise in gas concentration before local earthquake swarms. Several variations in gas concentration were monitored linked with remote earthquakes of ground motion amplitudes >1 μm. These seismic events are accompanied by an interference of the diurnal gas concentration–stress-cycle along the Mariánské Lázně fault. However, if shocks of remote earthquake can alter properties of the migrating fluids or the fault properties it can be suggested that these are able to trigger local seismicity, as indicated in the case of the Slovenia earthquake on 12th July 2004. 相似文献
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Hakan Hogrmez M Nam&#x;k Yal&#x;n Bernhard Cramer Peter Gerling Eckhard Faber Rainer G Schaefer Ulrich Mann 《Organic Geochemistry》2002,33(12)
Previous studies on the coal-bed methane potential of the Zonguldak basin have indicated that the gases are thermogenic and sourced by the coal-bearing Carboniferous units. In this earlier work, the origin of coal-bed gas was only defined according to the molecular composition of gases and to organic geochemical properties of the respective source rocks, since data on isotopic composition of gases were not available. Furthermore, in the western Black Sea region there also exist other source rocks, which may have contributed to the coal-bed gas accumulations. The aim of this study is to determine the origin of coal-bed gas and to try a gas-source rock correlation. For this purpose, the molecular and isotopic compositions of 13 headspace gases from coals and adjacent sediments of two wells in the Amasra region have been analyzed. Total organic carbon (TOC) measurements and Rock-Eval pyrolysis were performed in order to characterize the respective source rocks. Coals and sediments are bearing humic type organic matter, which have hydrogen indices (HI) of up to 300 mgHC/gTOC, indicating a certain content of liptinitic material. The stable carbon isotope ratios (δ13C) of the kerogen vary from −23.1 to −27.7‰. Air-free calculated gases contain hydrocarbons up to C5, carbon dioxide (<1%) and a considerable amount of nitrogen (up to 38%). The gaseous hydrocarbons are dominated by methane (>98%). The stable carbon isotope ratios of methane, ethane and propane are defined as δ13C1: −51.1 to −48.3‰, δ13C2: −37.9 to −25.3‰, δ13C3: −26.0 to −19.2 ‰, respectively. The δD1 values of methane range from −190 to −178‰. According to its isotopic composition, methane is a mixture, partly generated bacterially, partly thermogenic. Molecular and isotopic composition of the gases and organic geochemical properties of possible source rocks indicate that the thermogenic gas generation took place in coals and organic rich shales of the Westphalian-A Kozlu formation. The bacterial input can be related to a primary bacterial methane generation during Carboniferous and/or to a recent secondary bacterial methane generation. However, some peculiarities of respective isotope values of headspace gases can also be related to the desorption process, which took place by sampling. 相似文献
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Dr. Klaus Huber Dr. Eckhard Kleine Dr. Hans-Ulrich Lass Dr. Wolfgang Matthäus 《Ocean Dynamics》1994,46(2):103-114
Summary Major Baltic inflows (from the Kattegat) represent the only possibility for deep water renewal in the Baltic Sea that is generally characterised by stable stratification. Such an inflow occurred in January 1993 for the first time in 16 years. Observations were made by a moored station at Darß Sill and, for the first time since investigations into major Baltic inflows began, by a research vessel. In addition, the event has been simulated in an operational model.
Der Salzwassereinbruch vom Januar 1993 in die Ostsee-Messungen und Modellergebnisse
Zusammenfassung Für die im allgemeinen stabil geschichtete Ostsee bilden Salzwassereinbrüche (aus dem Kattegat) die einzige Möglichkeit zur Erneuerung des Tiefenwassers. Ein solcher Salzwassereinbruch ereignete sich nach 16 Jahren Unterbrechung erst wieder im Januar 1993. Dieser Vorgang wurde durch Messungen von einer permanenten Station auf der Darßer Schwelle und — erstmals in der Geschichte der Erforschung von Salzwassereinbrüchen —einem Forschungsschiff registriert. Außerdem liegt eine numerische Simulation mit einem operationellen Modell vor.
Insertion d'eau salée dans la mer Baltique en janvier 1993. Mesures et exploitation d'un modèle numérique
Résumé L'apport d'eau salée en provenance du Kattegat reste la seule possibilité de renouvellement des eaux profondes des couches stables de la mer Baltique. Un telle insertion d'eau salée ne s'est produite qu'au mois de janvier 1993 après une interruption de 16 ans. Ce processus a été enregistré par des mesures d'une station permanente (Darßer Schwelle) et, pour la première fois dans l'histoire de l'étude des insertions d'eau salée, par un navire scientifique. En outre une simulation numérique à l'aide d'un modèle opérationnel est présentée.相似文献
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Eckhard Wehmeier 《Geoforum》1980,11(2):107-121
The influence of urbanization on the overall water consumption within an irrigation oasis is reviewed. The hypothesis that the overall water consumption would decrease because urban lands need only about half the amount of water per unit area as do irrigated agricultural lands, does not hold true for the Salt River Project. The reasons involved are water law, water use policy, specific traits of urban development, and mental attitude of the people toward water as a limited resource. 相似文献
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天然气中氮的地球化学特征 总被引：23，自引：0，他引：23
本文研究了天然气中氮的地球化学特征，并讨论了氮的成因。 相似文献
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Flow‐through column experiments were carried out to investigate the influence of pH on the sorption of three phenols (2‐methyl‐4, 6‐dinitrophenol, 2, 4, 6‐trichlorophenol, pentachlorophenol) onto a natural sandy aquifer material collected from a bank filtration site of River Elbe, Germany. For the phenols investigated, an increase in sorption (retardation) with decreasing pH is observed indicating a stronger sorption of the neutral species in comparison to that of the anions formed by dissociation. The anions of 2‐methyl‐4, 6‐dinitrophenol and 2, 4, 6‐trichlorophenol do not show significant sorption. On the contrary, pentachlorophenol showed sorption not only in neutral form but also in ionic form significantly which should be taken into account while assessing the fate and transport of such compound. A linear model based on the degree of protonation (calculated from pH and pKa) can be used to resolve the apparent (observed) sorption coefficient (Kd, app) into its neutral (Kd, n) and ionised (Kd, i) components. Knowing pKa, Kd, n, and Kd, i the apparent sorption coefficient for pH values other than experimentally investigated can be predicted. 相似文献