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Boron isotopes in marine carbonates are increasingly used to reconstruct seawater pH and atmospheric pCO2 through Earth’s history. While isotope ratio measurements from individual laboratories are often of high quality, it is important that records generated in different laboratories can equally be compared. Within this Boron Isotope Intercomparison Project (BIIP), we characterised the boron isotopic composition (commonly expressed in δ11B) of two marine carbonates: Geological Survey of Japan carbonate reference materials JCp‐1 (coral Porites) and JCt‐1 (giant clam Tridacna gigas). Our study has three foci: (a) to assess the extent to which oxidative pre‐treatment, aimed at removing organic material from carbonate, can influence the resulting δ11B; (b) to determine to what degree the chosen analytical approach may affect the resultant δ11B; and (c) to provide well‐constrained consensus δ11B values for JCp‐1 and JCt‐1. The resultant robust mean and associated robust standard deviation (s*) for un‐oxidised JCp‐1 is 24.36 ± 0.45‰ (2s*), compared with 24.25 ± 0.22‰ (2s*) for the same oxidised material. For un‐oxidised JCt‐1, respective compositions are 16.39 ± 0.60‰ (2s*; un‐oxidised) and 16.24 ± 0.38‰ (2s*; oxidised). The consistency between laboratories is generally better if carbonate powders were oxidatively cleaned prior to purification and measurement.  相似文献   
94.
This investigation aimed to examine the load carrying capacity of model piles embedded in sandy soil and to develop a predictive model to simulate pile settlement using a new artificial neural network (ANN) approach. A series of experimental pile load tests were carried out on model concrete piles, comprised of three piles with slenderness ratios of 12, 17 and 25. This was to provide an initial dataset to establish the ANN model, in attempt at making current, in situ pile-load test methods unnecessary. Evolutionary Levenberg–Marquardt (LM) MATLAB algorithms, enhanced by T-tests and F-tests, were developed and applied in this process. The model piles were embedded in a calibration chamber in three densities of sand; loose, medium and dense. According to the statistical analysis and the relative importance study, pile lengths, applied load, pile flexural rigidity, pile aspects ratio, and sand-pile friction angle were found to play a key role in pile settlement at different contribution levels, following the order: P?>?δ?>?lc/d?>?lc?>?EA. The results revealed that the optimum model of the LM training algorithm can be used to characterize pile settlement with good degree of accuracy. There was also close agreement between the experimental and predicted data with a root mean square error, (RMSE) and correlation coefficient (R) of 0.0025192 and 0.988, respectively.  相似文献   
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Management of coastal ecosystems necessitates the evaluation of pollutant loading based on adequate source discrimination. Monitoring of sediments and fish on the shelf off San Diego has shown that some areas on the shelf are contaminated with polychlorinated biphenyls (PCBs). Here, we present an analysis of PCB contamination in fish on the shelf off San Diego designed to discriminate possible sources. The analysis was complicated by the variability of species available for analysis across the shelf, variable affinities of PCBs among species, and non-detects in the data. We utilized survival regression analysis to account for these complications. We also examined spatial patterns of PCBs in bay and offshore sediments and reviewed more than 20 years of influent and effluent data for local wastewater treatment facilities. We conclude that most PCB contamination in shelf sediments and fish is due to the ongoing practice of dumping contaminated sediments dredged from San Diego Bay.  相似文献   
96.
The primary objective of the Origins, Spectral Interpretation, Resource Identification, and Security–Regolith Explorer (OSIRIS‐REx) mission is to return to Earth a pristine sample of carbonaceous material from the primitive asteroid (101955) Bennu. To support compositional mapping of Bennu as part of sample site selection and characterization, we tested 95 spectral indices on visible to near infrared laboratory reflectance data from minerals and carbonaceous meteorites. Our aim was to determine which indices reliably identify spectral features of interest. Most spectral indices had high positive detection rates when applied to spectra of pure, single‐component materials. The meteorite spectra have fewer and weaker absorption features and, as a result, fewer detections with the spectral indices. Indices targeting absorptions at 0.7 and 2.7–3 μm, which are attributable to hydrated minerals, were most successful for the meteorites. Based on these results, we identified a set of 17 indices that are most likely to be useful at Bennu. These indices detect olivines, pyroxenes, carbonates, water/OH‐bearing minerals, serpentines, ferric minerals, and organics. Particle size and albedo are known to affect band depth but had a negligible impact on interpretive success with spectral indices. Preliminary analysis of the disk‐integrated Bennu spectrum with these indices is consistent with expectations given the observed absorption near 3 μm. Our study prioritizes spectral indices to be used for OSIRIS‐REx spectral analysis and mapping and informs the reliability of all index‐derived data products, including a science value map for sample site selection.  相似文献   
97.
Residual displacement, as a significant measure of structural inelasticity, is effectively used in post-earthquake seismic assessment of structures. This demand can be considered for seismic evaluation of structures under multiple earthquakes. This study introduces a simple and novel index to predict the residual displacement of mainshock-damaged structures against subsequent aftershock. The proposed index is defined as a ratio between residual displacement of damaged structures against aftershock and peak inelastic displacement of intact structures under mainshock. In this study, constantstrength spectra based on the index are developed considering the effects of important structural characteristics and also significant seismic parameters. Moreover, analytical equations are presented to predict the proposed index for bi-linear single-degree-of-freedom(SDOF) systems considering both the effects of positive and negative polarities of aftershock. Furthermore, an equation is suggested to estimate the peak inelastic displacement of intact systems under mainshock, which is required to compute the index.  相似文献   
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Circular shaped density plumes of low turbidity, low fecal indicator (Escherichia coli and enterococci) concentrations, and high salinity have been observed near the Industrial Canal in Lake Pontchartrain, north of the City of New Orleans. A conceptual model in polar coordinates and a numerical model are developed, together with data analysis, to illustrate the dense plume. It is demonstrated that the northward expansion of the plume occurs under northerly winds. The northward expansion of the plume occurs under northerly winds that drive downwind flow at the surface and upwind radial flow at the bottom. Northerly wind-induced straining, similar to tidal straining, promotes vertical stratification. As a result, the water becomes stratified near a thin bottom layer (<1 m), within which density currents are facilitated. The stability of the stratified plume suppresses wind-induced turbulent mixing inside the plume. The bottom water outside of the plume is more effectively stirred by the wind, the result being that the suspended sediment concentration outside of the plume area is much higher than inside. This contrast in mixing makes the plume visible from the surface by satellites even though the stratification is at the bottom. Laterally, wind stress produces a torque (vorticity) in areas of non-uniform depth such that upwind flow is developed in deep water and downwind flow in shallow water. The continuity requirement produces an upwind flow along the axis of the Industrial Canal (IC). The upwind flow is balanced by the downwind flow over the shallower peripheral areas along the coast.  相似文献   
100.
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