Sources and behavior of arsenic and trace elements in groundwater and surface water in the Poopó Lake Basin,Bolivian Altiplano     

Oswaldo Eduardo Ramos Ramos  Luis Fernando Cáceres  Mauricio Rodolfo Ormachea Muñoz  Prosun Bhattacharya  Israel Quino  Jorge Quintanilla  Ondra Sracek  Roger Thunvik  Jochen Bundschuh  Maria Eugenia García 《Environmental Earth Sciences》2012,66(3):793-807

Water management in semiarid and arid catchments such as the Poopó Lake Basin requires improved understanding of the complex behavior of the various contaminants, which affect the drinking water quality and considered as crucial for sustainable development of the region. Mechanisms of arsenic (As) release in the surface and groundwater were studied. Hydrochemical data for surface water (4 samples) and groundwater (28 samples) were collected in a small watershed in the Poopó catchment at the highland of the Bolivian Andes (Altiplano). All of them show high electrical conductivity values and moderately oxidizing conditions. The surface water contains high concentration of sulfate and the trace elements As, Zn and Pb in the zone affected by acid mine drainage. There is a large variability of the concentration of As and of the trace elements in the groundwater in the five different regions within the Poopó catchment. The metal concentrations sensitive to changes of redox state and results of speciation modeling suggest that As (V) is a predominant aqueous species, which conforms to the prevailing oxidizing conditions in the shallow groundwater environment. Two generalized trends for As distribution were identified in groundwater: (a) high concentrations are found in the arid zone (100–250 μg/L) in the southern (region III) and in the northwestern (region V) regions, and (b) low concentrations (<50 μg/L) are found in the remaining part of the basin (region I, II and IV). However, the spatial distribution within these regions needs to be investigated further. A conclusion from the present study is that there are multiple sources of As as well as other trace elements (such as Cd, Mn and Zn) in the Poopó Lake Basin. Among the sources and the processes which led to the mobility of As and other trace metals in the region are: (a) weathering of sulfide minerals, (b) oxidation of pyrite and/or arsenopyrite in mineralized areas and (c) desorption from hydrous ferric oxide (HFO) surfaces. In non-mining areas, volcanic ash is suggested to be a significant source of As.  相似文献   

Automatic Representation of Geographical Data from a Semantic Point of View through a New Ontology and Classification Techniques     

Rainer Larin Fonseca  Eduardo Garea Llano 《Transactions in GIS》2011,15(1):61-85

Providing Geographical Information Systems with mechanisms for processing geo‐data based on their semantics may help to solve problems like heterogeneity. This is because GIS could process geo‐data focusing on their meaning and not on their syntax and/or structure. An important aspect for achieving these objectives is the establishment of an automatic means of correspondence between geo‐data and their conceptualization in Higher Levels Ontologies (HLO). In this article, a new type of Ontology is proposed (Data‐Representation Ontology (DRO)). This Ontology describes the semantic embedded in geo‐data, which cannot be represented in current types of Ontologies. Across this Ontology, heterogeneous geographical data can be integrated in the semantic space contributing positively to the development of solutions for the problems of interoperability between heterogeneous systems. Likewise, we propose a new method for the automatic generation of the DRO and its interrelationships with HLO, based on pattern classification techniques. The experiments show that once the DRO is generated, the classifier can classify all data correctly. Thus, these data are semantically enriched. Moreover, this article shows how the topological relationships can enrich the semantics in the generated Ontology and increase the effectiveness of spatial analysis.  相似文献   

Reconstruction of annual winter rainfall since A.D.1579 in central-eastern Spain based on calcite laminated sediment from Lake La Cruz     

Lidia Romero-Viana  Ramon Julià  Martin Schimmel  Antonio Camacho  Eduardo Vicente  M. Rosa Miracle 《Climatic change》2011,107(3-4):343-361

We present the first winter (December to March) rainfall reconstruction based in a novel proxy, the thickness of annual calcite laminations preserved in Lake La Cruz (central–eastern Spain). A previous calibration analysis between laminae thickness and the instrumental data series (1950 to present) indicated a highly significant correlation with winter rainfall. Therefore this study attempts the winter rainfall reconstruction since the onset of laminations (1579 a.d.) by means of the calibration function previously developed. The verification analysis between inferred annual values and earlier instrumental data (1859–1949) confirms the suitability of this novel proxy and the reliability of the series reconstructed. The reconstructed series show the fluctuating character of winter rainfall in the western Mediterranean area; interdecadal dry periods alternated with wetter periods following, in a board sense, the pattern recorded by documentary sources in other regions of the Iberian Peninsula. At present times regional winter rainfall anomalies are highly correlated with the phase of the North Atlantic Oscillation (NAO). However the time series analysis showed the dominance of nonstationary components at high frequencies of the climate signal over the last four centuries suggesting that the connection between winter rainfall and the NAO has not been stable over time and also other modes of variability, not only NAO, may have conditioned winter rainfall variability.  相似文献   

The phase diagram of Na carbonate, an alkaline component of the growth medium of ultradeep diamonds     

N. A. Solopova  Yu. A. Litvin  A. V. Spivak  N. A. Dubrovinskaia  L. S. Dubrovinsky  V. S. Urusov 《Doklady Earth Sciences》2013,453(1):1106-1109

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Effect of the addition of granitic powder to an acidic soil from Galicia (NW Spain) in comparison with lime   总被引：1，自引：1，他引：0  

Benita?Silva  Remigio?ParadeloEmail author  Nuria?Vázquez  Eduardo?García-Rodeja  María?Teresa?Barral 《Environmental Earth Sciences》2013,69(2):429-441

The impact of diffuse pollution, agricultural land use and climate change on the long-term response of subsurface–surface water quality is not well understood, but is a prerequisite for evaluation of water management options. The goal of this study is to model geochemical evolution of water chemistry from the infiltration through soil into the unsaturated zone, transport through bedrocks and granular aquifers to a river in order to identify zones of steep concentration gradients and high dynamics under transient flow conditions. A numerical model was constructed comprising a 2-D 1,500 m × 150 m vertical cross-section of typical sedimentary rock formations, a glacio-fluvial quaternary gravel aquifer in the valley and soil layers. The model coupled saturated/un-saturated flow and reactive transport under steady state and transient conditions. Geochemical interactions, include intra-aqueous kinetic reactions of oxygen with dissolved organic matter, as well as kinetics of carbonate dissolution/precipitation. This model section was chosen to provide insight in to the principal processes and time scales affecting water chemistry along different flow paths. The numerical simulator MIN3P was used, a finite volume program for variably saturated subsurface flow and multi-component reactive transport. The results show that subsurface water residence times range from approximately 2 to 2,000 years. Different zones are to be expected with respect to the development of mineral equilibria; namely, purely atmospherically influenced, as well as open and closed system carbonate dissolution. Short-term responses to daily averaged changes in precipitation, however, are only visible to some extent in the shallower and near-river parts of flow system and solute loads. This can most likely be explained by directional changes in flow paths, indicating that equilibrium geochemical condition predominate at the hillslope scale, i.e. water quality depends on transport pathways rather than on kinetic effects. The extent of reducing conditions is controlled by the presence of organic-rich layers (i.e. peat deposits), the dissolution kinetics of aquifer organic matter and the subsequent mixing with oxygenated water by hydrodynamic dispersion.  相似文献   

Organochlorine compounds in sharks from the Brazilian coast     

Claudio Eduardo de Azevedo e Silva  Adriana de Cássia Lima Dias  José Lailson-Brito  Jean Remy Daveé Guimarães 《Marine pollution bulletin》2009,58(2):294-298

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Macroinvertebrate patterns along environmental gradients and hydrological connectivity within a regulated river-floodplain     

Belinda Gallardo  Mercedes García  Álvaro Cabezas  Eduardo González  María González  Cecilia Ciancarelli  Francisco A. Comín 《Aquatic Sciences - Research Across Boundaries》2008,70(3):248-258

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A non-parametric automatic blending methodology to estimate rainfall fields from rain gauge and radar data   总被引：1，自引：0，他引：1  

Carlos A. Velasco-Forero  Daniel Sempere-Torres  Eduardo F. Cassiraga  J. Jaime Gómez-Hernández 《Advances in water resources》2009

Quantitative estimation of rainfall fields has been a crucial objective from early studies of the hydrological applications of weather radar. Previous studies have suggested that flow estimations are improved when radar and rain gauge data are combined to estimate input rainfall fields. This paper reports new research carried out in this field. Classical approaches for the selection and fitting of a theoretical correlogram (or semivariogram) model (needed to apply geostatistical estimators) are avoided in this study. Instead, a non-parametric technique based on FFT is used to obtain two-dimensional positive-definite correlograms directly from radar observations, dealing with both the natural anisotropy and the temporal variation of the spatial structure of the rainfall in the estimated fields. Because these correlation maps can be automatically obtained at each time step of a given rainfall event, this technique might easily be used in operational (real-time) applications. This paper describes the development of the non-parametric estimator exploiting the advantages of FFT for the automatic computation of correlograms and provides examples of its application on a case study using six rainfall events. This methodology is applied to three different alternatives to incorporate the radar information (as a secondary variable), and a comparison of performances is provided. In particular, their ability to reproduce in estimated rainfall fields (i) the rain gauge observations (in a cross-validation analysis) and (ii) the spatial patterns of radar fields are analyzed. Results seem to indicate that the methodology of kriging with external drift [KED], in combination with the technique of automatically computing 2-D spatial correlograms, provides merged rainfall fields with good agreement with rain gauges and with the most accurate approach to the spatial tendencies observed in the radar rainfall fields, when compared with other alternatives analyzed.  相似文献   

The local environment of H ii galaxies     

Eduardo Telles  Steve Maddox 《Monthly notices of the Royal Astronomical Society》2000,311(2):307-312

We have carried out an investigation of the environments of low redshift H  ii galaxies by cross-correlating their positions on the sky with those of faint field galaxies in the Automatic Plate Measuring Machine (APM) catalogues. We address the question of whether violent star formation in H  ii galaxies is induced by low-mass companions by statistically estimating the mean space density of galaxies around them. We argue that even if low-mass companions were mainly intergalactic H  i clouds, their optical counterparts should be detectable at faint limits of the APM scans.
A significantly positive signal is detected for the H  ii galaxy–APM galaxy angular cross-correlation function, but the amplitude is poorly determined. The projected cross-correlation function has a higher signal-to-noise ratio, and suggests that the amplitude is slightly lower than for normal field galaxies. This implies that these bursting dwarf galaxies inhabit slightly lower density environments than those of normal field galaxies, consistent with other studies of emission-line galaxies. This suggests that in these dwarf starburst galaxies, star formation is not always triggered by tidal interactions, and a significant fraction must have a different origin.  相似文献   

Area usage estimation and spatiotemporal variability in distribution patterns of southern right whales,Eubalaena australis,of southern Brazil          下载免费PDF全文

Eduardo Pires Renault‐Braga  Karina Rejane Groch  Paulo A. de Carvalho Flores  Eduardo R. Secchi  Luciano Dalla‐Rosa 《Marine Ecology》2018,39(3)

Southern right whales—Eubalaena australis (Desmoulins, 1822)—migrate seasonally from high‐latitude feeding grounds to coastal breeding and calving grounds at lower latitudes such as the southern coast of Brazil. Understanding how these whales are distributed along the coast is important for monitoring their postwhaling recovery and defining management strategies. In this study, we applied Kernel density estimators to aerial survey data to determine main occurrence and concentration areas of right whales in southern Brazil and investigate inter‐ and intra‐annual distribution patterns between 2003 and 2012. Our results show considerable variation in area usage within and among years, and changes in the general distribution pattern of right whales in the last years of the study. Intra‐annually, higher concentration area tended to expand from July to September and decrease in November. Some areas stood out as high‐density areas for right whales: Ribanceira/Ibiraquera, Itapirubá Sul/Sol, and from Arroio to Gaivota. Some evidences also suggest preferential areas for mother–calf pairs. The higher concentration area of right whales in southern Brazil was estimated at 52,541 km² and the occurrence area was 682.69 km², which is the whole study area. As right whale distribution in the region is likely expanding due to this population's current recovery, our study provides essential information for management plan of the Right Whale Environmental Protection Area.  相似文献