Density measurements of liquid Fe–Si alloys at high pressure using the sink–float method     

Ryuji Tateyama  Eiji Ohtani  Hidenori Terasaki  Keisuke Nishida  Yuki Shibazaki  Akio Suzuki  Takumi Kikegawa 《Physics and Chemistry of Minerals》2011,38(10):801-807

The compositional dependence on the density of liquid Fe alloys under high pressure is important for estimating the amount of light elements in the Earth’s outer core. Here, we report on the density of liquid Fe–Si at 4 GPa and 1,923 K measured using the sink–float method and our investigation on the effect of the Si content on the density of the liquid. Our experiments show that the density of liquid Fe–Si decreases from 7.43 to 2.71 g/cm³ non-linearly with increasing Si content (0–100 at%). The molar volume of liquid Fe–Si calculated from the measured density gradually decreases in the compositional range 0–50 at% Si, and increases in the range 50–100 at% Si. It should be noted that the estimated molar volume of the alloys shows a negative volume of mixing between Fe and Si. This behaviour is similar to Fe–S liquid (Nishida et al. in Phys Chem Miner 35:417–423, 2008). However, the excess molar volume of mixing for the liquid Fe–Si is smaller than that of liquid Fe–S. The light element contents in the outer core estimated previously may be an underestimation if we take into account the possible negative value of the excess mixing volume of iron–light element alloys in the outer core.  相似文献   

Systematic study of hydrogen incorporation into Fe-free wadsleyite     

Konstantin D. Litasov  Anton Shatskiy  Eiji Ohtani  Tomoo Katsura 《Physics and Chemistry of Minerals》2011,38(1):75-84

The H₂O content of wadsleyite were measured in a wide pressure (13–20 GPa) and temperature range (1,200–1,900°C) using FTIR method. We confirmed significant decrease of the H₂O content of wadsleyite with increasing temperature and reported first systematic data for temperature interval of 1,400–1,900°C. Wadsleyite contains 0.37–0.55 wt% H₂O at 1,600°C, which may be close to its water storage capacity along average mantle geotherm in the transition zone. Accordingly, water storage capacity of the average mantle in the transition zone may be estimated as 0.2–0.3 wt% H₂O. The H₂O contents of wadsleyite at 1,800–1,900°C are 0.22–0.39 wt%, indicating that it can store significant amount of water even under the hot mantle environments. Temperature dependence of the H₂O content of wadsleyite can be described by exponential equation C_{\textH2 \textO} = 6 3 7.0 7 \texte ^{- 0.00 4 8T} , C_{{{\text{H}}_{2} {\text{O}}}} = 6 3 7.0 7 {\text{e}}^{ - 0.00 4 8T} , where T is in °C. This equation is valid for temperature range 1,200–2,100°C with the coefficient of determination R ² = 0.954. Temperature dependence of H₂O partition coefficient between wadsleyite and forsterite (D _wd/fo) is complex. According to our data apparent D_wd/fo decreases with increasing temperature from D _wd/fo = 4–5 at 1,200°C, reaches a minimum of D _wd/fo = 2.0 at 1,400–1,500°C, and then again increases to D _wd/fo = 4–6 at 1,700–1,900°C.  相似文献   

Compressibility of strontium orthophosphate Sr<Subscript>3</Subscript>(PO<Subscript>4</Subscript>)<Subscript>2</Subscript> at high pressure     

Shuangmeng Zhai  Weihong Xue  Daisuke Yamazaki  Shuangming Shan  Eiji Ito  Naotaka Tomioka  Akira Shimojuku  Ken-ichi Funakoshi 《Physics and Chemistry of Minerals》2011,38(5):357-361

High pressure in situ synchrotron X-ray diffraction experiment of strontium orthophosphate Sr₃(PO₄)₂ has been carried out to 20.0 GPa at room temperature using multianvil apparatus. Fitting a third-order Birch–Murnaghan equation of state to the P–V data yields a volume of V ₀ = 498.0 ± 0.1 Å³, an isothermal bulk modulus of K _T  = 89.5 ± 1.7 GPa, and first pressure derivative of K _T ′ = 6.57 ± 0.34. If K _T ′ is fixed at 4, K _T is obtained as 104.4 ± 1.2 GPa. Analysis of axial compressible modulus shows that the a-axis (K _a  = 79.6 ± 3.2 GPa) is more compressible than the c-axis (K _c  = 116.4 ± 4.3 GPa). Based on the high pressure Raman spectroscopic results, the mode Grüneisen parameters are determined and the average mode Grüneisen parameter of PO₄ vibrations of Sr₃(PO₄)₂ is calculated to be 0.30(2).  相似文献   

Calcium and Magnesium‐bearing Sabugalite from the Tono Uranium Deposit,Central Japan     

Masataka Nakata  Eiji Sasao  Kosei Komuro 《Resource Geology》2013,63(4):404-411

Calcium and magnesium‐bearing sabugalite occurs as aggregations of yellowish platy crystals in veinlets or druses in conglomerate from the oxidized parts of the Tono uranium deposit, Central Japan. X‐ray powder diffractometry of this mineral has reflections consistent with previous powder diffraction data of sabugalite. It is included in the monoclinic system with space group C2/m and calculated cell parameters of a = 19.68Å, b = 9.89Å, c = 9.82Å α = γ = 90°, β‐96.93° and V = 1897.83ų. Chemical analysis yields a formula of (Ca_0.10 Mg_0.09)_Σ0.19Al_0.53(UO₂)_2.04((PO₄)_1.99(AsO₄)_0.01)_Σ2.00·11.22H₂O. EMPA mapping shows that the mineral is compositionally uniform with no micron‐scale layering. Charge of cations including Ca and Mg in the cation‐H₂O layer is 1.98 being identical to that of autunite group minerals. This suggests that the charge balance in the cation‐H₂O layer of the mineral could be made by the alkaline earth or alkaline elements rather than by hydrogen ions.  相似文献   

Relativistic expansion of magnetic loops at the self-similar stage     

Hiroyuki R. Takahashi  Eiji Asano  Ryoji Matsumoto 《Monthly notices of the Royal Astronomical Society》2009,394(1):547-568

We obtained self-similar solutions of relativistically expanding magnetic loops taking into account the azimuthal magnetic fields. We neglect stellar rotation and assume axisymmetry and a purely radial flow. As the magnetic loops expand, the initial dipole magnetic field is stretched into the radial direction. When the expansion speed approaches the light speed, the displacement current reduces the toroidal current and modifies the distribution of the plasma lifted up from the central star. Since these self-similar solutions describe the free expansion of the magnetic loops, i.e.  d v /d t = 0  , the equations of motion are similar to those of the static relativistic magnetohydrodynamics. This allows us to estimate the total energy stored in the magnetic loops by applying the virial theorem. This energy is comparable to that of the giant flares observed in magnetars.  相似文献   

Sources of uncertainty in estimating stream solute export from headwater catchments at three sites          下载免费PDF全文

Ruth D. Yanai  Naoko Tokuchi  John L. Campbell  Mark B. Green  Eiji Matsuzaki  Stephanie N. Laseter  Cindi L. Brown  Amey S. Bailey  Pilar Lyons  Carrie R. Levine  Donald C. Buso  Gene E. Likens  Jennifer D. Knoepp  Keitaro Fukushima 《水文研究》2015,29(7):1793-1805

Uncertainty in the estimation of hydrologic export of solutes has never been fully evaluated at the scale of a small‐watershed ecosystem. We used data from the Gomadansan Experimental Forest, Japan, Hubbard Brook Experimental Forest, USA, and Coweeta Hydrologic Laboratory, USA, to evaluate many sources of uncertainty, including the precision and accuracy of measurements, selection of models, and spatial and temporal variation. Uncertainty in the analysis of stream chemistry samples was generally small but could be large in relative terms for solutes near detection limits, as is common for ammonium and phosphate in forested catchments. Instantaneous flow deviated from the theoretical curve relating height to discharge by up to 10% at Hubbard Brook, but the resulting corrections to the theoretical curve generally amounted to <0.5% of annual flows. Calibrations were limited to low flows; uncertainties at high flows were not evaluated because of the difficulties in performing calibrations during events. However, high flows likely contribute more uncertainty to annual flows because of the greater volume of water that is exported during these events. Uncertainty in catchment area was as much as 5%, based on a comparison of digital elevation maps with ground surveys. Three different interpolation methods are used at the three sites to combine periodic chemistry samples with streamflow to calculate fluxes. The three methods differed by <5% in annual export calculations for calcium, but up to 12% for nitrate exports, when applied to a stream at Hubbard Brook for 1997–2008; nitrate has higher weekly variation at this site. Natural variation was larger than most other sources of uncertainty. Specifically, coefficients of variation across streams or across years, within site, for runoff and weighted annual concentrations of calcium, magnesium, potassium, sodium, sulphate, chloride, and silicate ranged from 5 to 50% and were even higher for nitrate. Uncertainty analysis can be used to guide efforts to improve confidence in estimated stream fluxes and also to optimize design of monitoring programmes. © 2014 The Authors. Hydrological Processes published John Wiley & Sons, Ltd.  相似文献   

Eutectic temperatures and melting relations in the Fe–O–S system at high pressures and temperatures     

Kyusei Tsuno  Eiji Ohtani 《Physics and Chemistry of Minerals》2009,36(1):9-17

We have investigated melting relations in the Fe–O–S ternary system in the pressure range of 15–27 GPa and 1873 K. Subsolidus phase relations are Fe, Fe₃S₂, and FeO up to 17 GPa and Fe, Fe₃S, and FeO above this pressure. The eutectic temperature slightly decreases from ambient pressure to 17 GPa, whereas increases above this pressure. The eutectic temperature in this study is 100 K lower than that in the Fe–S binary system. The oxygen content in the Fe–O–S eutectic liquid drops when the coexisting solid phases changes from FeS to Fe₃S₂. The cotectic lines in the ternary phase diagram lie close to the Fe–FeS binary axis. The isothermal sections indicate that oxygen solubility in the Fe–O–S liquid increases with increasing temperature, and with increasing sulfur content. The solubility of sulfur in the solid Fe has a maximum value at the eutectic temperature, and decreases with increasing temperature. Our results could have important implications for formation and composition of the Martian core.  相似文献   

Deep slab subduction and dehydration and their geodynamic consequences: Evidence from seismology and mineral physics   总被引：14，自引：9，他引：5  

Dapeng Zhao  Eiji Ohtani   《Gondwana Research》2009,16(3-4):401-413

We present new pieces of evidence from seismology and mineral physics for the existence of low-velocity zones in the deep part of the upper mantle wedge and the mantle transition zone that are caused by fluids from the deep subduction and deep dehydration of the Pacific and Philippine Sea slabs under western Pacific and East Asia. The Pacific slab is subducting beneath the Japan Islands and Japan Sea with intermediate-depth and deep earthquakes down to 600 km depth under the East Asia margin, and the slab becomes stagnant in the mantle transition zone under East China. The western edge of the stagnant Pacific slab is roughly coincident with the NE–SW Daxing'Anling-Taihangshan gravity lineament located west of Beijing, approximately 2000 km away from the Japan Trench. The upper mantle above the stagnant slab under East Asia forms a big mantle wedge (BMW). Corner flow in the BMW and deep slab dehydration may have caused asthenospheric upwelling, lithospheric thinning, continental rift systems, and intraplate volcanism in Northeast Asia. The Philippine Sea slab has subducted down to the mantle transition zone depth under Western Japan and Ryukyu back-arc, though the seismicity within the slab occurs only down to 200–300 km depths. Combining with the corner flow in the mantle wedge, deep dehydration of the subducting Pacific slab has affected the morphology of the subducting Philippine Sea slab and its seismicity under Southwest Japan. Slow anomalies are also found in the mantle under the subducting Pacific slab, which may represent small mantle plumes, or hot upwelling associated with the deep slab subduction. Slab dehydration may also take place after a continental plate subducts into the mantle.  相似文献   

Variability of Monsoon Climate in East Asia at the End of the Last Glaciation   总被引：3，自引：0，他引：3  

Zhou Weijian  Douglas J. Donahue  Stephen C. Porter  Timothy A. Jull  Li Xiaoqiang  Minze Stuiver  An Zhisheng  Eiji Matsumoto  Dong Guangrong 《Quaternary Research》1996,46(3):219-229

High-resolution paleomonsoon proxy records from peat and eolian sand–paleosol sequences at the desert–loess transition zone in China denote a rapid oscillation from cold–dry conditions (11,200–10,600¹⁴C yr B.P.) to cool–humid conditions (10,600–10,200¹⁴C yr B.P.), followed by a return to cold–dry climate (10,200–10,000¹⁴C yr B.P.). Variations in precipitation proxies suggest that significant climatic variability occurred in monsoonal eastern Asia during the Younger Dryas interval. Late-glacial climate in the Chinese desert–loess belt that lies downwind from Europe was strongly influenced by cold air from high latitudes and from the North Atlantic via the westerlies. The inferred precipitation variations were likely caused by variations in the strength of the Siberian high, which influenced the pressure gradient between land and ocean and therefore influenced the position of the East Asian monsoon front.  相似文献   

A Study Of The Atmospheric Boundary Layer Using Radon And Air Pollutants As Tracers     

Toshio Kataoka  Eiji Yunoki  Mitsuo Shimizu  Tadashige Mori  Osamu Tsukamoto  Yukitaka Ohashi  Ken Sahashi  Toshihiko Maitani  Koh’ichi Miyashita  Toru Iwata  Yoko Fujikawa  Akira Kudo  Roger H. Shaw 《Boundary-Layer Meteorology》2001,101(2):131-156

Concentrations of radon ²²²Rn andair pollutants, meteorological parametersnear the surface and vertical profiles of meteorological elements were measured atUchio (Okayama City, Okayama Prefecture, Japan) 12 km north from the coast ofthe Inland Sea of Japan. In the nighttime, the ²²²Rn concentration increased in the case of weak winds, but did not increase as much in the case of moderate or strong winds, as had been expected. In the daytime, the ²²²Rn concentrationheld at a slightly higher than average level for the period from sunrise to about 1100 JST. It is considered that this phenomenon is due to a period of morning calm, that is, a transition period from land breeze to sea breeze.NO, which is sensitive to traffic volume,brought information concerning advection.Oxidant concentrations,which reflect the availability of sunlight,acted in the reverse manner to ²²²Rnconcentrations. Thus, a set of ²²²Rn and air pollutants could provide useful information regarding the local conditions of the atmospheric boundary layer.  相似文献