High-pressure stability relations in cobalt and nickel silicates have been studied over the pressure range 130–330 kbar employing a double-staged split-sphere-type high-pressure apparatus.γ-Co2SiO4 and γ-Ni2SiO4 decompose directly into their constituent oxide mixtures (rocksalt plus stishovite) 175 kbar and 280 kbar, respectively. The result that γ-Ni2SiO4 has a wider stability field in pressure than γ-Co2SiO4, is consistent with simple crystal-field theory.The experimental precision is high enough to show that the decomposition boundary of γ-Co2SiO4 has a positive slope (dP/dT > 0) and a preliminary determination of the boundary curve is P(kbar) = 0.065 T (°C) + 110.No positive evidence for the existence of high-pressure forms of CoSiO3 and NiSiO3 has been obtained in these quenching experiments, and they finally decompose into constituent oxide mixtures as in the cases of orthosilicates. 相似文献
Magnesium orthosilicate with spinel structure (γ-Mg2SiO4) was synthesized at about 250 kbar and 1000°C. Unit cell dimension was established to be 8.076 ± 0.001Å. X-ray powder diffraction pattern revealed a significant difference between γ-Mg2SiO4 and other γ-M2SiO4 spinels (M = Fe, Co, and Ni) in the intensities of (111) and (331) reflections, both of which are virtually absent in the Mg2SiO4 spinel. This feature could be thoroughly understood by the calculation of the intensities for several silicate spinels. 相似文献
Abstract. Bottom-simulating reflectors suggestive of the presence of methane hydrates are widely distributed below the ocean floor around Japan. In late 1999, drilling of the MITI Nankai Trough wells was conducted to explore this potential methane hydrate resource and a Tertiary conventional structure. The wells are located in the Northwest Pacific Ocean off Central Japan at a water depth of 945 m. A total of six wells were drilled, including the main well, two pilot wells, and three post survey wells at intervals of 10–100 m. All wells except the first confirmed the occurrence of hydrates based on logging-while-drilling, wire-line logging and/or coring using a pressure and temperature coring system in addition to conventional methods. Based on the various well profiles, four methane hydrate-bearing sand-rich intervals in turbidite fan deposits were recognized. Methane hydrates fill the pore spaces in these deposits, reaching saturation of up to 80 % in some layers. The methane hydrate-bearing turbiditic sand layers are less than 1 m thick, with a total thickness of 12–14 m. The bottom depth of high hydrate concentration correlates well with the depth of the bottom-simulating reflector. Based on these exploration results, the Japanese government inaugurated a 16-year methane hydrate exploitation program in 2001. 相似文献
To investigate the characteristics of ablation at Koryto Glacier, a mountain glacier under maritime climate in Kamchatka Peninsula, Russia, we made field observations from August to early September 2000. At a site near the equilibrium line, the 31‐day average net radiation, sensible heat flux, and latent heat flux were 43, 59 and 31 W?2, respectively. We developed a new distributed ablation model, which only needs measurements of air temperature and global radiation at one site. Hourly ablation rates at this site obtained by the energy balance method are related to measured air temperature and global radiation by linear multiple regression. A different set of multiple regression coefficients is fitted for snow and ice surfaces. Better estimates of ablation rate can be obtained by this approach than by other temperature index models. These equations are then applied to each grid cell of a digital elevation model to estimate spatially distributed hourly melt. Air temperature is extrapolated using a constant temperature lapse rate and global radiation is distributed considering topographic effects. The model enables us to calculate the hourly spatial distribution of ablation rates within the glacier area and could well provide a realistic simulation of ablation over the whole glacier. 相似文献
Due to a continual rainfall, a flowslide occurred in Yamashina area, Kanazawa City, Japan on November 8, 2002 in the Tertiary
mudstone area. The sliding mass was fully fluidized during the motion and moved downward the slope for a long distance. On
December 31, 2003, slope failure was triggered by intensive rainfall and snowmelt water at the same site again, and resulted
in the second occurrence of flowslide. The total displacement of the slope was recorded with an extensometer. Through field
investigation, the difference of the sliding mechanism between the two flowslides was examined. 相似文献
Data recorded by a seismic network deployed the day after the 2004 Mid Niigata Prefecture Earthquake (M6.8) in central Japan are used to determine the major source faults responsible for the mainshock and major aftershocks. Using this high-resolution seismic data, three major source faults are identified: two parallel faults dipping steeply to the west located 5 km apart, and the other dipping eastward and oriented perpendicular to the west-dipping faults. The analysis also reveals that the lateral variation in seismic velocity observed at the surface extends to a depth of 15 km, encompassing the source area of the mainshock. This strong heterogeneity of the crust, related to the complex geological and tectonic evolution of the area, is considered to be responsible for the prominent aftershock activity following the 2004 Niigata event. 相似文献
We determined the partition coefficients of 19 elements between metallic liquid and silicate liquid at 20 GPa and 2500°C, and between metallic liquid and silicate perovskite at 27 GPa and 2200°C. Remarkable differences were observed in the partitioning behaviors of Si, P, W, Re, and Pb among the silicate liquid, perovskite, and magnesiowüstite coexisting with metallic liquid, reflecting incompatibility of the elements in the silicate or oxide phase. We could not observe any significant difference in the partitioning behaviors of V, Cr, Mn, Co, Ni, and Cu among the phases coexisting with metallic liquid.
Comparison of the present partitioning data with those obtained previously at lower pressure and temperature suggests that the exchange partition coefficients, Kmet/sil, of Co, Ni, Mo, and W decrease, whereas those of V, Cr, and Mn increase and tend to approach unity with increasing pressure and temperature. We also made preliminary experiments to clarify the effect of sulfur on the partitioning behaviors. Sulfur lowers the exchange partition coefficients, Kmet/sil, of Mo and W between metallic liquid and silicate liquid significantly at 20 GPa and 2300°C.
The mantle abundances of Co, Ni, Cu, Mo, and W calculated for the metal-silicate equilibrium model are lower than those of the real mantle, whereas P, K, and Mn are overabundant in the calculated mantle. The discrepancies in the abundances of Co and Ni could be explained by the chemical equilibrium at higher pressure and temperature. Large discrepancies in Mo and W between the calculated and real mantles could be accounted for by the effect of sulfur combined with the effects of pressure and temperature on the chemical equilibrium. The mantle abundances of P, K, and Cu could be accounted for by volatile loss in the nebula, perhaps before accretion of the Earth, combined with the chemical equilibrium at higher pressure and temperature. Thus the observed mantle abundances of P, K, Co, Ni, Cu, Mo, and W may be consistent with a model of sulfur-bearing metal-silicate equilibrium in lower-mantle conditions. 相似文献