Ab initio calculated electron densities for tetrahedral sheet [H2Si2O5]∞ in phyllosilicates     

Ľ. Benco  Ľ. Smrčok 《Physics and Chemistry of Minerals》1994,21(6):401-406

Periodic ab initio Hartree-Fock LCAO calculations have been carried out on the two dimensional sheet of SiO₄ tetrahedra, representing one of the basic constituting units of layer silicates, using Huzinaga's DZP basis sets. The influence of the basis set on the chemical bonding picture is characterized by Mulliken atomic charges and by electron density maps. Silicon atomic charges +1.6 ¦e¦ are more realistic than those +2.4 ¦e¦ reported for smaller basis sets. The silicon d orbital population is found to be 0.6 in close agreement with molecular data. Electron density maps indicate the absence of charge density in the center of the ditrigonal cavity. The charge buildup of nonbonding basal oxygen orbitals is directed mainly downwards perpendicular to the sheet plane.  相似文献   

Geomagnetic activity as a possible cause of changes in the middle atmosphere and troposphere; observations made in Prague in the years 1932–1987     

Josef Bochníček  Josef Pýcha 《Studia Geophysica et Geodaetica》1994,38(1):103-107

Summary A possible relation between the 10-day, 1-month, and 2-month geomagnetic as well as solar activity, characterized by Kp and Wolf's number R, and temperatures measured at the Prague-Klementinum meteorological station in January–February of the years 1932–1987 was sought. It was found that:1) Kp correlates with the temperature in Prague better than Wolf's number R.2) If the QBO phase is taken into account, the correlations improve.3) Even if the correlations improves with increasing length of the subintervals into which the individual winter periods (January-February) were derived, their statistical significance declines.  相似文献   

Dust particle and solar radiation     

J. Klačka  J. Kaufmannová 《Earth, Moon, and Planets》1993,61(1):63-65

Influence of the solar radiation (electromagnetic and corpuscular - solar wind) on the motion of the interplanetary dust particle is investigated. The ratio time of inspiralling toward the Sun: time of inspiralling neglecting the change of mass of the particle is presented as a function of initial eccentricities.  相似文献   

Genetic and chemical relationships between berthierine,chlorite and cordierite in nodules associated to granitic pegmatites of Sierra Albarrana (Iberian Massif,Spain)     

María del Mar Abad-Ortega  Fernando Mieto 《Contributions to Mineralogy and Petrology》1995,120(3-4):327-336

Chlorite and berthierine occur through alteration of cordierite within enclaves of metamorphic rocks transformed by the Sierra Albarrana pegmatites. The coexistence of both phyllosilicates allows us to study their stability relationships and to compare their chemical compositions. Samples showing incipient replacement of cordierite by small cryptocrystalline aggregates can be identified by X-ray diffraction (XRD) as berthierine with small quantities of chlorite. Electron Microprobe (EMP) analyses give mixed compositions of berthierine and cordierite. Samples with extensive replacement of cordierite by aggregates show similar characteristics to those with incipient replacement, but some small crystals are present. The last type of sample shows complete replacement of cordierite by crystals showing optical properties of chlorite and EMPA compositions coherent with chlorite or berthierine. Their XRD pattern corresponds to chlorite and their high resolution transmission electron microscopy (HRTEM) images only show perfect sequences of 14 Å lattice fringes. The cryptocrystalline aggregates of the samples with incipient and extensive replacement present coexistent areas of 14 Å and 7 Å lattice fringes that are intergrown at different levels: (1) large areas (> 1 m) of 7 Å layers; (2) packets of 7 Å layers between 14 Å layer areas, with visible 7 Å to 14 Å lateral changes; (3) random mixed-layers 7 Å/14 Å. Chlorite is the final stable product of alteration of cordierite, with berthierine as an intermediate metastable phase. Energy dispersive X-ray spectrometry microanalyses of 14 Å, 7 Å and (14+7) Å areas show lack of systematic differences in chemical compositions between both phyllosilicates which may be considered as true polymorphs.  相似文献   

Problems connected with the tangential metric coefficient in the Schwarzschild metric: A possible solution     

Pavel Voráček 《Astrophysics and Space Science》1982,81(1-2):85-94

Four situations are shown where the Schwarzschild metric cannot be used or is subject to unsurmountable problems. The first is the question of a metric useful for PPN-formalism checking different gravitational theories. The second problem occurs in connection with Mach's principle, when the flatness of the spacetime inside a massive hollow sphere is a generally accepted solution. The metrical discontinuity on the same spherical shell is a third problem. The fourth one is the anisotropy of the mass-energy of a test particle in the gravitational field. Three principles for solution are proposed:

1. The space is not dilated, but rather contracted, in the gravitational field; then the measurement-rods are shorter and measured distances have greater magnitudes.
2. The potential energy is to be related to a potential level where a stationary observer is placed and the general relativistic potential must be used.
3. A new metric must be introduced which is distinct from the Schwarzschild metric, so that the space in the gravitational field is warped isotropically.

Then the problems stated are shown to be easily solvable.  相似文献   

TheoreticalPKIKP magnitude determination     

J. Janský  M. Kvasnička 《Studia Geophysica et Geodaetica》1992,36(1):20-25

Summary The estimation of the theoretical magnitude for deep foci based on the vertica component of medium-period PKIKP waves, Earth model PREM and source spectra is presented. The given graphs are valid for period T ranging from 1·6 s to 10 s, source depth of 25 km to 600 km and distance range of 16 500 km to 19 800 km. A simplified method of representing calibration curves is used.  相似文献   

Investigation of the instability of graveyard orbits due to the earth's gravitational perturbations     

Jan Kostelecký  Jaroslav Klokočník 《Studia Geophysica et Geodaetica》1992,36(4):297-301

Summary The Banach theorem is applied to the Lagrange planetary equation for the semimajor axis of a geostationary satellite orbit to estimate the stability of near-geostationary satellite orbits. To achieve a graveyard (disposal) orbit, which will not interfere (=cross) the initial geostationary orbit, the geostationary semi-major axis a_g have to be increased at least by 50 km. Numerical results for a variety of graveyard orbits show that the increase of a_g by about 100 km will yield sufficiently stable orbits (accounting for the Earth's gravitational perturbations only) during the next 150 years.Dedicated to the 75th Birthday of Professor Academician Tibor Kolbenheyer  相似文献   

A combined study of macroseismic data and focal mechanisms applied to the West-Bohemian earthquake,Czechoslovakia     

J. Zahradník  M. Antonini  G. Grünthal  J. Janský  D. Procházková  E. Schmedes  A. Špičak  J. Zedník 《Pure and Applied Geophysics》1990,133(1):53-71

The main shock of the West-Bohemian earthquake swarm, Czechoslovakia, (magnitudem=4.5, depthh=10 km) exhibits an irregular areal distribution of macroseismic intensities 6° to 7° MSK-64. Four lobes of the 6° isoseismal are found and the maximum observed intensity is located at a distance of 8 km from the instrumentally determined epicentre. This distribution can be explained by the energy flux of the directS wave generated by a circular source, the hypocentral location and focal mechanism of which are taken from independent instrumental studies. The theoretical intensity, which is assumed to be logarithmically proportional to the integrated squared ground-motion velocity (i.e.,I=const+log v ² (t)dt), fits the observed intensity with an overall root-mean-square error less than 0.5°. It is important that the present intensity data can also be equally well explained by the isotropic source. The fit was attained by means of a horizontally layered model though large fault zones and an extended sedimentary basin suggest a significant lateral heterogeneity of the epicentral region. The results encourage a broader application of the simple modelling technique used.  相似文献   

Semi-analytical solutions of a contaminant transport equation with nonlinear sorption in 1D     

Peter Frolkovič  Jozef Kačur 《Computational Geosciences》2006,10(3):279-290

A new method to determine semi-analytical solutions of one-dimensional contaminant transport problem with nonlinear sorption is described. This method is based on operator splitting approach where the convective transport is solved exactly and the diffusive transport by finite volume method. The exact solutions for all sorption isotherms of Freundlich and Langmuir type are presented for the case of piecewise constant initial profile and zero diffusion. Very precise numerical results for transport with small diffusion can be obtained even for larger time steps (e.g., when the Courant-Friedrichs-Lewy (CFL) condition failed).  相似文献   

Guest Editors’ Foreword     

Miran Veselič  Heinz Hoetzl  Božidar Biondič  Jože Pezdič 《Environmental Geology》2006,49(6):795-795

  相似文献