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61.
Lithium abundances and isotope compositions are presented for a suite of sediments from the surroundings of the Ries Impact structure, paralleled by new Li data for central European tektites (moldavites) from several substrewn fields (South Bohemia, Moravia, Cheb Basin, Lusatia), including a specimen from the newly discovered substrewn field in Poland. The data set was supplemented by three clay fractions isolated from sedimentary samples. Moldavites measured in this study show a very narrow range in δ7Li values (?0.6 to 0.3‰ relative to L‐SVEC) and Li contents (23.9–48.1 ppm). This contrasts with sediments from the Ries area which show remarkable range in Li isotope compositions (from ?6.9 to 13.4‰) and Li contents (0.6–256 ppm). The OSM sediments which, based on chemical similarity, formed the major part of moldavites, show a range in δ7Li values from ?2.0 to 7.9‰ and Li contents from 5.8 to 78.9 ppm. Therefore, the formation of moldavites was apparently accompanied by large‐scale mixing, paralleled by chemical and isotope homogenization of their parent matter. The proposed Li mixing model indicates that sands, clayey sediments, and low volumes of carbonates are the major components for tektite formation whereas residual paleokarst sediments could have been a minor but important component for a subset of moldavites. Striking homogenization of Li in tektites, combined with limited Li loss during impacts, may suggest that moderately volatile elements are not scavenged and isotopically fractionated during large‐scale collisions, which is consistent with recent models. In general, whether homogenization of bodies with distinct Li isotope systematics takes place, or collision of bodies with similar Li systematics operates cannot be resolved at present stage but Li isotope homogeneity of solar system planets and asteroidal bodies tentatively implies the latter.  相似文献   
62.
ABSTRACT

Flow–duration curves (FDCs) are essential to support decisions on water resources management, and their regionalization is fundamental for the assessment of ungauged basins. In comparison with calibrated rainfall–runoff models, statistical methods provide data-driven estimates representing a useful benchmark. The objective of this work is the interpolation of FDCs from ~500 discharge gauging stations in the Danube. To this aim we use total negative deviation top-kriging (TNDTK), as multi-regression models are shown to be unsuitable for representing FDCs across all durations and sites. TNDTK shows a high accuracy for the entire Danube region, with overall Nash-Sutcliffe efficiency values computed in a leave-p-out cross-validation scheme (p equal to one site, one-third and half of the sites), all above 0.88. A reliability measure based on kriging variance is attached to each interpolated FDC at ~4000 prediction nodes. The GIS layer of regionalized FDCs is made available for broader use in the region.  相似文献   
63.
ABSTRACT

The abstract classification system Nature in Norway (NiN) has detailed ecological definitions of a high number of ecosystem units, but its applicability in practical vegetation mapping is unknown because it was not designed with a specific mapping method in mind. To investigate this further, two methods for mapping – 3D aerial photographic interpretation of colour infrared photos and field survey – were used to map comparable neighbouring sites of 1 km2 in Hvaler Municipality, south-eastern Norway. The classification accuracy of each method was evaluated using a consensus classification of 160 randomly distributed plots within the study sites. The results showed an overall classification accuracy of 62.5% for 3D aerial photographic interpretation and 82.5% for field survey. However, the accuracy varied for the ecosystem units mapped. The classification accuracy of ecosystem units in acidic, dry and open terrain was similar for both methods, whereas classification accuracy of calcareous units was highest using field survey. The mapping progress using 3D aerial photographic interpretation was more than two times faster than that of field survey. Based on the results, the authors recommend a method combining 3D aerial photographic interpretation and field survey to achieve effectively accurate mapping in practical applications of the NiN system.  相似文献   
64.
65.
Top‐kriging is a method for estimating stream flow‐related variables on a river network. Top‐kriging treats these variables as emerging from a two‐dimensional spatially continuous process in the landscape. The top‐kriging weights are estimated by regularising the point variogram over the catchment area (kriging support), which accounts for the nested nature of the catchments. We test the top‐kriging method for a comprehensive Austrian data set of low stream flows. We compare it with the regional regression approach where linear regression models between low stream flow and catchment characteristics are fitted independently for sub‐regions of the study area that are deemed to be homogeneous in terms of flow processes. Leave‐one‐out cross‐validation results indicate that top‐kriging outperforms the regional regression on average over the entire study domain. The coefficients of determination (cross‐validation) of specific low stream flows are 0.75 and 0.68 for the top‐kriging and regional regression methods, respectively. For locations without upstream data points, the performances of the two methods are similar. For locations with upstream data points, top‐kriging performs much better than regional regression as it exploits the low flow information of the neighbouring locations. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
66.
The Diffuse Galactic Syncrotron Emission (DGSE) is the most important diffuse foreground component for future cosmological 21-cm observations. The DGSE is also an important probe of the cosmic ray electron and magnetic field distributions in the turbulent interstellar medium (ISM) of our galaxy. In this paper we briefly review the Tapered Gridded Estimator (TGE) which can be used to quantify the angular power spectrum C ? of the sky signal directly from the visibilities measured in radio-interferometric observations. The salient features of the TGE are: (1) it deals with the gridded data which makes it computationally very fast, (2) it avoids a positive noise bias which normally arises from the system noise inherent to the visibility data, and (3) it allows us to taper the sky response and thereby suppresses the contribution from unsubtracted point sources in the outer parts and the side lobes of the antenna beam pattern. We also summarize earlier work where the TGE was used to measure the C ? of the DGSE using 150 MHz GMRT data. Earlier measurements of C ? are restricted to \(\ell \le \ell _{\max } \sim 10^{3}\) for the DGSE, the signal at the larger ? values is dominated by the residual point sources after source subtraction. The higher sensitivity of the upcoming SKA1 Low will allow the point sources to be subtracted to a fainter level than possible with existing telescopes. We predict that it will be possible to measure the C ? of the DGSE to larger values of \(\ell _{\max }\) with SKA1 Low. Our results show that it should be possible to achieve \(\ell _{\max }\sim 10^{4}\) and ~105 with 2 minutes and 10 hours of observations respectively.  相似文献   
67.
68.
Crushed rock from two caprock samples, a carbonate-rich shale and a clay-rich shale, were reacted with a mixture of brine and supercritical CO2 (CO2–brine) in a laboratory batch reactor, at different temperature and pressure conditions. The samples were cored from a proposed underground CO2 storage site near the town of Longyearbyen in Svalbard. The reacting fluid was a mixture of 1 M NaCl solution and CO2 (110 bar) and the water/rock ratio was 20:1. Carbon dioxide was injected into the reactors after the solution had been bubbled with N2, in order to mimic O2-depleted natural storage conditions. A control reaction was also run on the clay-rich shale sample, where the crushed rock was reacted with brine (CO2-free brine) at the same experimental conditions. A total of 8 batch reaction experiments were run at temperatures ranging from 80 to 250 °C and total pressures of 110 bar (∼40 bar for the control experiment). The experiments lasted 1–5 weeks.Fluid analysis showed that the aqueous concentration of major elements (i.e. Ca, Mg, Fe, K, Al) and SiO2 increased in all experiments. Release rates of Fe and SiO2 were more pronounced in solutions reacted with CO2–brine as compared to those reacted with CO2-free brine. For samples reacted with the CO2–brine, lower temperature reactions (80 °C) released much more Fe and SiO2 than higher temperature reactions (150–250 °C). Analysis by SEM and XRD of reacted solids also revealed changes in mineralogical compositions. The carbonate-rich shale was more reactive at 250 °C, as revealed by the dissolution of plagioclase and clay minerals (illite and chlorite), dissolution and re-precipitation of carbonates, and the formation of smectite. Carbon dioxide was also permanently sequestered as calcite in the same sample. The clay-rich shale reacted with CO2–brine did not show major mineralogical alteration. However, a significant amount of analcime was formed in the clay-rich shale reacted with CO2-free brine; while no trace of analcime was observed in either of the samples reacted with CO2–brine.  相似文献   
69.
River sediment produced through weathering is one of the principal landscape modification processes on earth.Rivers are an integral part of the hydrologic cycle and are the major geologic agents that erode the continents and transport water and sediments to the oceans.Estimation of suspended sediment yield is always a key parameter for planning and management of any river system.It is always challenging to model sediment yield using traditional mathematical models because they are incapable of handling the complex non-linearity and non-stationarity.The suspended sediment modeling of the river depends on the number of factors such as rock type,relief,rainfall,temperature,water discharge and catchment area.In this study,we proposed a hybrid genetic algorithm-based multi-objective optimization with artificial neural network(GA-MOO-ANN)with automated parameter tuning model using these factors to estimate the suspended sediment yield in the entire Mahanadi River basin.The model was validated by comparing statistically with other models,and it appeared that the GA-MOO-ANN model has the lowest root mean squared error(0.009)and highest coefficient of correlation(0.885)values among all comparative models(traditional neural network,multiple linear regression,and sediment rating curve)for all stations.It was also observed that the proposed model is the least biased(0.001)model.Thus,the proposed GA-MOOANN is the most capable model,compared to other studied models,for estimating the suspended sediment yield in the entire Mahanadi river basin,India.The results also suggested that the proposed GA-MOO-ANN model is unable to estimate suspended sediment yield satisfactorily at gauge stations having very small catchment areas whereas performing satisfactorily on locations having moderate to the large catchment area.The models provide the best result at Tikarapara,the gauge station location in the extreme downstream,having the largest catchment area.  相似文献   
70.
Redshifted 21-cm radiation originating from the cosmological distribution of neutral hydrogen (H  i ) appears as background radiation in low-frequency radio observations. The angular and frequency domain fluctuations in this radiation carry information concerning cosmological structure formation. We propose that correlations between visibilities measured at different baselines and frequencies in radio-interferometric observations be used to quantify the statistical properties of these fluctuations. This has an inherent advantage over other statistical estimators in that it deals directly with the visibilities which are the primary quantities measured in radio-interferometric observations. Also, the visibility correlation has a very simple relation with the power spectrum. We present estimates of the expected signal for nearly the entire post-recombination era, from the dark ages to the present epoch. The epoch of reionization, where H  i has a patchy distribution, has a distinct signature where the signal is determined by the size of the discrete ionized regions. The signal at other epochs, where H  i follows the dark matter, is determined largely by the power spectrum of dark matter fluctuations. The signal is strongest for baselines where the antenna separations are within a few hundred times the wavelength of observation, and an optimal strategy would preferentially sample these baselines. In the frequency domain, for most baselines the visibilities at two different frequencies are uncorrelated beyond  Δν∼ 1 MHz  , a signature which, in principle, would allow the H  i signal to be easily distinguished from the continuum sources of contamination.  相似文献   
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