Geochemistry and geochronology of meta-igneous rocks from the Tokat Massif, north-central Turkey: implications for Tethyan reconstructions     

Elizabeth J. Catlos  Kathryn Huber  Timothy A. Shin 《International Journal of Earth Sciences》2013,102(8):2175-2198

Located in the eastern Pontides of the Sakarya Zone in north-central Turkey, the Tokat Massif records the closure of both the Paleo-Tethyan (Karakaya Complex) and Neo-Tethyan ocean basins. Meta-igneous samples collected from the region were studied to determine their sources and ages. We find significant geochemical differences between metagabbros of the Karakaya and Neo-Tethyan units in terms of their trace elements: Neo-Tethyan rocks are consistent with generation in an island arc setting, whereas Karakaya assemblages were likely generated in an oceanic spreading-center environment. Karakaya metagabbros also contain glaucophane, consistent with subduction subsequent to formation. Small (2–50 μm) zircon and baddeleyite grains from four Karakaya metagabbros were dated in thin section using an ion microprobe. The results demonstrate the reliability of the method to directly constrain the tectonomagmatic history of these types of assemblages. The rocks yield Late Permian/Early Triassic ²³⁸U/²⁰⁶Pb crystallization ages of 258 ± 14 Ma (±1σ, zircon) and 254 ± 8 Ma (±1σ, baddeleyite) and an Early Cretaceous minimum metamorphic age of 137 ± 8 Ma (±1σ, zircon). Some zircon grains and baddeleyite grains with zircon overgrowths yield Early to Middle Jurassic ages. Here we present a model in which metamorphism and deformation in this region occurred during northward subduction and closure of a Paleo-Tethyan ocean basin and accretion of the Karakaya units to the Laurasian continental margin. This was followed by the onset of closure of the Neo-Tethys during the Campanian-Paleocene and accretion of island arc units to the Tokat region.  相似文献   

Photochemical and Microbial Transformations of Dissolved Organic Matter in Temperate Streams Associated with Land Use: Molecular Characterization Using Fourier Transform Ion Cyclotron Resonance Mass Spectrometry     

LI Xiaping  LU Yuehan  Rajaa MESFIOUI  James E. BAUER  Elizabeth A. CANUEL  R. M. CHAMBERS  Patrick G. HATCHER 《《地质学报》英文版》2013,87(Z1):640-640

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Measurement of soluble reactive phosphorus concentration profiles and fluxes in river-bed sediments using DET gel probes   总被引：3，自引：0，他引：3  

Helen P. Jarvie  Robert J.G. Mortimer  Elizabeth J. Palmer-Felgate  Katherine St. Quinton  Sarah A. Harman  Patricia Carbo 《Journal of Hydrology》2008,350(3-4):261-273

DET (diffusive equilibrium in thin films) gel probes were used for sampling river-bed sediment porewaters, to characterise in situ soluble reactive phosphorus (SRP) concentration profiles and fluxes. DET probes were deployed in three contrasting rural streams: (1) a headwater ‘pristine’ stream, with minimal P inputs from low intensity grassland and no point sources, (2) an intensively cultivated arable catchment, and (3) a stream subject to high P loadings from sewage effluent and intensive arable farming. The DET results showed highly enriched porewater SRP concentrations of between ca. 400 and 5000 μg-P l⁻¹ in the sewage-impacted stream. In contrast, the arable and pristine streams had porewater SRP concentrations <70 μg-P l⁻¹ and <20 μg-P l⁻¹, respectively. Porewater SRP concentration profiles in both the sewage-impacted and arable-impacted streams showed well-defined vertical structure, indicating internal sources and sinks of SRP within the sediment. However, there was little variability in porewater SRP concentrations in the pristine stream. The DET porewater profiles indicated net diffusion of SRP (a) from the overlying river water into the surface sediment and (b) from subsurface sediment upwards towards the sediment–water interface. A mass balance for the sewage-impacted site showed that the influx of SRP into the surface sediments from the overlying river water was small (ca. 1% of the daily river SRP load). The DET results indicated that, in the arable and sewage-impacted streams, the surface ‘cap’ of fine sediment may play an important role in inhibiting upward movement of SRP from subsurface porewaters into the overlying river water, under steady-state, low-flow conditions.  相似文献   

Blood metal levels and metal-influenced immune functions of harbour seals in captivity   总被引：2，自引：0，他引：2  

Kakuschke A  Valentine-Thon E  Griesel S  Rosenberger T  Mundry R  Siebert U  Prange A 《Marine pollution bulletin》2008,56(4):764-769

Immunological blood parameters and the effects of environmental pollutants on the immune system are important to assess the health status of seals. Animals living permanently in seal centres are useful for development and validation of diagnostic tools for free-ranging animals. In this study, parameters of cellular immunity as well as metal concentrations in blood and metal influence on cell proliferation of seven seals from a seal centre were investigated repeatedly using multi-element analysis and a lymphocyte proliferation assay. The metal concentrations, except for tin and chromium, were in general comparable to those of free-ranging animals of the North Sea. The unstimulated and mitogen-stimulated lymphocyte proliferation showed strong intra- and inter-individual variability, which reflected variability in activation of the immune status. Furthermore, both immunosuppressive and stimulative influences of metals on lymphocytes were found. Summarising, the methods used in this investigation provided useful information on these animals, and their application to free-ranging animals can be recommended.  相似文献   

A local model for analysis of pump and treat systems with vertical barrier walls     

Elizabeth Mesa  Erik I. Anderson 《Advances in water resources》2008

We present a mathematical model of local, steady groundwater flow near a vertical barrier wall. Flow features represented in the model include an impermeable arc-shaped barrier wall and multiple wells; distant boundary conditions are not included explicitly, but their effects on the local flow field are modelled by specifying a uniform flow at infinity and a constant areal recharge within a local domain. We develop an explicit closed-form solution to the boundary-value problem using the analytic element method. The solution is an extension of a harmonic solution presented by Anderson and Mesa [Anderson EI, Mesa E. The effects of vertical barrier walls on the hydraulic control of contaminated groundwater. Adv Water Resourc 2006;29(1):89–98] which does not include the effects of recharge. We demonstrate that the general solution with recharge consists of the harmonic solution superposed on a special case of the harmonic solution along with two elementary one-dimensional flow solutions. The results are used to investigate the effects of areal recharge on the capture zone envelopes of the pumping wells and on the reduction in discharge that can be achieved by including a barrier wall in a pump and treat design. We find that the benefits of including an open barrier wall in a design, measured as a reduction in the pumping rate required to contain a plume, increase for higher recharge rates. Dimensionless plots of capture zone envelopes are presented for a practical well and barrier wall configuration.  相似文献   

Holocene Foraminifera as Indicators of Relative Estuarine–Lagoonal and Oceanic Influences in Estuarine Sediments of the River Murray, South Australia: Volume 53, Number 3 (2000), pages 378–391     

John H. Cann  Robert P. Bourman  Elizabeth J. Barnett 《Quaternary Research》2000,54(3):378

In southeastern South Australia, the River Murray debouches through a coastal barrier separating euryhaline estuarine-lagoonal waters from the Southern Ocean. Depending upon the relative freshwater outflow of the river and ingress of the ocean, water salinity varies greatly within the lower estuary. Ammonia beccarii and Elphidium articulatum are euryhaline species of foraminifera that characterize the estuary and back-barrier Coorong Lagoon. The inner-shelf marine environment hosts an assemblage in which Discorbis dimidiatus, E. crispum, E. macelliforme, and various cibicidid species predominate. In cored sediments recovered from the shallow lower estuary, the relative abundance of A. beccarii + E. articulatum was compared with that of D. dimidiatus + E. crispum + E. macelliforme + other species. These data, and AMS radiocarbon ages determined for foraminifera and ostracods, provide evidence of a change from maximum oceanic influence (5255 ± 60 yr B.P.) to maximum estuarine influence (3605 ± 70 yr B.P.). Over this same time interval, sea level fell relatively by about 2 m. However, the event was also contemporaneous with falling water levels in several Victorian lakes, and it is thus attributed to onset of climatic aridity. Reduced precipitation in the River Murray catchment and reduced freshwater outflow enhanced development of the flood-tide delta and constriction of the mouth.  相似文献   

The Geographer and the Fengshui Practitioner: So close and yet so far apart?     

Elizabeth Kenworthy Teather  Chun Shing Chow 《The Australian geographer》2000,31(3):309-332

Fengshui deserves serious scrutiny from geographers. Fengshui has been a highly significant influence on the shaping of human environments in the Chinese cultural sphere for at least 4000 years. Efforts to eliminate it in the twentieth century, by Chinese governments intent on modernisation, have failed. Advice on fengshui is still eagerly sought today by families and businesses in Chinese communities, whether on the mainland, offshore or overseas. The first part of this paper briefly introduces fengshui . The second part applies Lefebvre's three modalities of space to the time-space manipulations and outcomes of the operation of fengshui . The third part explores what fengshui offers a postmodern world, concentrating on (a) the nature of the 'harmony' it seeks to establish between people and nature; (b) the nature of fengshui 's time-universe; and (c) the extent to which fengshui 's goals of time-space harmony offer a framework for approaching sustainable development.  相似文献   

The reliability of emplacement temperature estimates using palaeomagnetic methods: a case study from Santorini, Greece   总被引：1，自引：0，他引：1  

Leon Bardot  Elizabeth McClelland 《Geophysical Journal International》2000,143(1):39-51

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Seasonal mixing from intermittent flow drives concentration-discharge behaviour in a stream affected by coal mine drainage     

Meaghan Shaw  Lindsey Yazbek  David Singer  Elizabeth Herndon 《水文研究》2020,34(17):3669-3682

Abandoned mining operations continue to severely degrade many ecosystems worldwide by releasing acidic water and/or heavy metals into surface and groundwater. Contaminant concentrations in affected streams vary with discharge in patterns that reflect both geochemical reactions and variable mixing of contaminated and non-contaminated waters. However, controls on concentration-discharge (C-Q) patterns remain unclear, particularly for constituents that experience changing solubility across redox and pH gradients. Understanding the C-Q behaviour of contaminants aids in predicting both downstream transport and effects on aquatic life under variable flow. Here, we examined the C-Q behaviours of non-reactive (Na, K, Ca, Mg, Cl⁻) and reactive (Fe, Mn, Al, H⁺, SO₄²⁻) solutes in a stream contaminated with acid mine drainage in northeastern Ohio, USA. Concentration-discharge patterns at the watershed outlet primarily reflected mixing of contaminated baseflow with intermittent inputs of high pH water draining from a passive limestone treatment system into the stream. The treatment system acted as an ephemeral tributary that mitigated contamination in the stream by diluting solutes, raising pH, and driving metal precipitation, but only when flow was present during wet seasons. Consequently, AMD-derived reactive solutes (H⁺, Fe, Mn, Al) decreased with increasing stream discharge while relatively conservative solutes (e.g., Ca, Mg, K, Na) decreased only slightly or were chemostatic. This study highlights both the unique C-Q patterns of reactive solutes when compared to those of non-reactive solutes and the potential for intermittent streams to control C-Q behaviour in headwater catchments.  相似文献   

Very Small Array observations of the Sunyaev–Zel'dovich effect in nearby galaxy clusters     

Katy Lancaster †  Ricardo Genova-Santos  Nelson Falcòn  Keith Grainge  Carlos Gutièrrez  Rüdiger Kneissl  Phil Marshall  Guy Pooley  Rafael Rebolo  Jose-Alberto Rubiño-Martin  Richard D. E. Saunders  Elizabeth Waldram  Robert A. Watson 《Monthly notices of the Royal Astronomical Society》2005,359(1):16-30

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