Sorption and desorption processes are an important part of biological and geochemical metallic isotope cycles. Here, we address the dynamic aspects of metallic isotopic fractionation in a theoretical and experimental study of Fe sorption and desorption during the transport of aqueous Fe(III) through a quartz-sand matrix. Transport equations describing the behavior of sorbing isotopic species in a water saturated homogeneous porous medium are presented; isotopic fractionation of the system (Δsorbedmetal-soln) being defined in terms of two parameters: (i) an equilibrium fractionation factor, αe; and (ii) a kinetic sorption factor, α1. These equations are applied in a numerical model that simulates the sorption-desorption of Fe isotopes during injection of a Fe(III) solution pulse into a quartz matrix at pH 0-2 and explores the effects of the kinetic and equilibrium parameters on the Fe-isotope evolution of porewater. The kinetic transport theory is applied to a series of experiments in which pulses of Na and Fe(III) chloride solutions were injected into a porous sand grain column. Fractionation factors of αe = 1.0003 ± 0.0001 and α1 = 0.9997 ± 0.0004 yielded the best fit between the transport model and the Fe concentration and δ56Fe data. The equilibrium fractionation (Δ56FesorbedFe-soln) of 0.3‰ is comparable with values deduced for adsorption of metallic cations on iron and manganese oxide surfaces and suggests that sandstone aquifers will fractionate metallic isotopes during sorption-desorption reactions. The ability of the equilibrium fractionation factor to describe a natural system, however, depends on the proximity to equilibrium, which is determined by the relative time scales of mass transfer and chemical reaction; low fluid transport rates should produce a system that is less dependent on kinetic effects. The results of this study are applicable to Fe-isotope fractionation in clastic sediments formed in highly acidic conditions; such conditions may have existed on Mars where acidic oxidizing ground and surface waters may have been responsible for clastic sedimentation and metallic element transport. 相似文献
This classification of gem corundum (ruby and sapphire) deposits takes into consideration petrographic data, and the mode of genesis of the deposits. It is aimed at being practical and useful in the field, particularly for prospecting purposes.Deposits are classified into primary and secondary deposits. Primary deposits include igneous and metamorphic deposits. Igneous gem corundum deposits are rare and include sapphire-bearing syenites from Kenya. Emphasis is put on metamorphic deposits, that are subdivided into metamorphic s.s., metasomatic, and anatectic deposits. Many gem corundum deposits result from metasomatic processes. Small-scale metasomatism mostly involves desilication reactions between silico-aluminous rocks (pegmatites, gneisses, etc) and silica-poor rocks (ultramafites, meta-carbonates), and leads to the formation of limited-size deposits. Large-scale (diffuse) metasomatism is usually more difficult to characterize, and therefore is not separated from isochemical metamorphism in this classification. In metamorphic deposits, gem corundum results from transformation of an Al-rich and/or Si-poor protolith. Such deposits include ruby-bearing mafic granulites, ruby-bearing meta-limestones, and ruby/sapphire-bearing gneisses and granulites. An intermediate category includes anatectic deposits. Secondary deposits encompass sedimentary and volcanic (xenoclastic) occurrences. In sedimentary deposits, gem corundum occurs as clasts originating from other lithologies. In volcanic deposits, gem corundums are xenocrysts that have a range of origins.The proposed classification outlines geological environments favorable to the crystallization and distribution of gem corundum, thus facilitating prospecting and mining of this gemstone. 相似文献
In the Alps, interglacial and interstadial deposits are rarely preserved due to the intense erosive effect of glaciers in the valleys. Fortunately, some outcrops and cored sequences located in the field area ranging from Lyon to Evian provided sedimentary profiles datable by palynostratigraphy in a highly documented geomorphological context. An overview of several palynological sequences studied in this large area is proposed, and their position in a general chronostratigraphical pattern is discussed. Particular attention is paid to palynostratigraphical evidence whose relevance is tested with systematic comparisons with long reference European pollen sequences spanning several glacial cycles. Minimum ages are suggested for non-glacial episodes corresponding to the deposits studied. 相似文献
The Journal of Natural Resources Research (NRR) has, since its foundation in 1992, published and continues to publish peer-reviewed articles that make significant impact on resourcing future generations. This is in keeping with its aims and scope of publishing articles on quantitative analyses of natural (mainly but not limited to mineral) resources with regard to exploration, evaluation and exploitation, as well as environmental and risk-related aspects. However, the new papers introduced in this special issue of NRR are mostly qualitative studies with implications for policy decision-making relevant to the issue of resourcing future generations. These new papers and the recent inclusion of NRR for coverage in the Science Citation Index Expanded? (or SciSearch®) and Journal Citation Reports® (JCR) Science Edition will make NRR more attractive to researchers in the fields that are relevant to the issue of resourcing future generations, both as a source of knowledge as well as a medium for publication of research results. 相似文献
GIS software applications and other mapping tools enable users to correlate data from multiple layers and gain insight from the resulting visualizations. However, most of these applications only feature basic, monolithic layer compositing techniques. These techniques do not always support users effectively in their tasks, as we observed during interviews with GIS experts. We introduce MapMosaic, a novel approach based on dynamic visual compositing that enables users to interactively create and manipulate local composites of multiple vector and raster map layers, taking into account the semantics and attribute values of objects and fields in the compositing process. We evaluate MapMosaic ’s interaction model against that of QGIS (a widely used desktop GIS) and MAPublisher (a professional cartography tool) using the ‘Cognitive Dimensions’ framework and through an analytical comparison, showing that MapMosaic ’s model is more flexible and can support users more effectively in their tasks. We also report on feedback obtained from experts, which further confirms the potential of this highly dynamic approach to map layer compositing. 相似文献
The implementation of neoliberal economic reforms with its resultant effects on rural agricultural economies has facilitated the migration of young girls from northern to southern Ghana to seek for alternative livelihoods in the urban informal economy as head porters (Kayayei). Using semi-structured questionnaires and interviews with 45 Kayayei in Makola and Agbogbloshie Markets, Accra, this study examines how migration as a livelihood strategy contributes to an improvement in the living conditions of young girls and their families. The paper also looks more closely into the pathways through which the livelihoods of these young female migrants may contribute to local economic development. The study highlights that Kayayei contribute to local economic development through market exchange and revenue generation, also there is significant perceived positive impact of head portering on standard of living of these young girls through improved access to income, health care and asset accumulation while their families benefit from remittances. The study concludes by advocating for the need to provide access to credit and skills training in enhancing the livelihood of Kayayei. 相似文献
We present a software package for combining three monochromatic images of an astronomical object into a trichromatic color image. We first discuss the meaning of true colors in astronomical images. We then describe the different steps of our method, choosing the relevant dynamic intensity range in each filter, inventorying the different colors, optimizing the color map, modifying the balance of colors, and enhancing contrasts at low intensity levels. While the first steps are automatic, the last two are interactive. 相似文献
Dissolution of carbonates in acidic fluids, which has attracted much research attention in recent years, is of great significance for the formation of high-quality reservoirs. The dissolution stage under low temperature and low pressure in shallow burial is one of the most important processes of reservoir dissolution and transformation. However, the dissolution dynamics of carbonate rocks in shallow burial and their formation have been controversial for a long time, and there are still disputes in the dissolution processes about how associated minerals and accessory minerals (e.g., pyrite) in carbonate reservoirs influence the formation of secondary pores. Additional metal ions in acidic fluids can change fluid properties and dissolution processes, and consequently affect reservoir quality. However, there are few laboratory studies done on the effect of associated minerals on the dissolution dynamics of carbonates. To clarify the specific impact of Fe-bearing associated minerals and Fe3+ on the dissolution of carbonates in shallow burial reservoirs, six samples of typical carbonate rocks in the Zigui area of Hubei Province, China were studied. The dissolution kinetics of carbonates in dilute hydrochloric acid and sulfuric acid solutions containing metal ions (Fe3+/Ca2+/Mn2+) at ambient temperature and pressure (T?=?25 °C, P?=?1 atm) were studied, by laboratory dissolution experiments combined with numerical simulations using PHREEQC. The results show that the Fe3+ is of great significance on the dissolution of carbonate rocks, while the influences of Ca2+ and Mn2+ are relatively weak. The dissolutions degrees of micritic limestone (ZG-L25), dolomitic limestone (ZG-L7) and dolomite (ZG-D9) were better than the other carbonates under the influence of metal ions (Fe3+/Ca2+/Mn2+) in acid solutions. Therefore, the dolomite reservoir of the Cambrian Qinjiamiao Formation, the dolomitic limestone reservoir of the Tianheban Formation and the limestone reservoir of the Triassic Daye Formation in the Zigui area are potential high-quality reservoirs. The carbonate reservoirs associated with Fe-bearing minerals were easier to dissolve and formed secondary pores under shallow burial. This process is beneficial to the formation of high-quality reservoirs. Moreover, the addition of Fe3+ into hydrochloric acid solution may be conducive to improving the reservoirs acidizing effect. Furthermore, the results gave innovative results from multiple perspectives of geo-material science and computational geosciences, which may provide new avenues for in-depth study of carbonate dissolution in shallow burial based on water–rock reaction, chemical dissolution, computational simulation, and geological background.
