Petrology and CHIME geochronology of Pan-African high K and Sr/Y granitoids in the Nkambe area, Cameroon   总被引：1，自引：1，他引：0  

Samuel Tetsopgang  Kazuhiro Suzuki  Emmanuel Njonfang 《Gondwana Research》2008,14(4):686

The Central African Belt in the Nkambe area, northwestern Cameroon represents a collisional zone between the Saharan metacraton and the Congo craton during the Pan-African orogeny, and exposes a variety of granitoids including foliated and massive biotite monzogranites in syn- and post-kinematic settings. Foliated and massive biotite monzogranites have almost identical high-K calc-alkaline compositions, with 73–67 wt.% SiO₂, 17–13 wt.% Al₂O₃, 2.1–0.9 wt.% CaO, 4.4–2.7 wt.% Na₂O and 6.3–4.4 wt.% K₂O. High concentrations of Rb (264–96 ppm), Sr (976–117 ppm), Ba (3680–490 ppm) and Zr (494–99 ppm), with low concentrations of Y (mostly< 20 ppm with a range 54–6) and Nb (up to 24 ppm) suggest that the monzogranites intruded in collisional and post-collisional settings. The Sr/Y ratio ranges from 25 to 89. K, Rb and Ba resided in a single major phase such as K-feldspar in the source. Garnet was present in the source and remained as restite at the site of magma generation. This high K₂O and Sr/Y granitic magma was generated by partial melting of a granitic protolith under high-pressure and H₂O undersaturated conditions where garnet coexists with K-feldspar, albitic plagioclase. CHIME (chemical Th–U-total Pb isochron method) dating of zircon yields ages of 569 ± 12–558 ± 24 Ma for the foliated biotite monzogranite and 533 ± 12–524 ± 28 Ma for the massive biotite monzogranite indicating that the collision forming the Central African Belt continued in to Ediacaran (ca 560 Ma).  相似文献   

IAG/AIG Newsletter No. 29 (3/2013)          下载免费PDF全文

Emmanuel Reynard  Sunil Kumar De 《地球表面变化过程与地形》2014,39(3):419-425

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A trigger-tube tracer dilution technique for determining Darcy and apparent velocities of groundwater in dug wells: A case study on phreatic aquiferous formation in Bamenda-Cameroon     

Akoanung Ayaba ABENDONG  ENDENE Emmanuel  Enoh Jeanot FONGOH  AKOACHERE Richard Ayuk II  NJENG Napoleon Ngenge 《地下水科学与工程》2019,7(2):182-194

The need to understand flow within aquiferous formations for a complete evaluation of groundwater resource and quality control prompts the determination of groundwater velocities through well dilution technique. Well dilution techniques utilize tracer solutions after establishing an initial homogenous condition to monitor the flow rate of ambient groundwater into the wells. Application of dilution techniques in wells makes it feasible to determine the velocities of groundwater in the aquiferous formation surrounding the well. In this study, a simple trigger-tube tracer dilution technique was employed to determine the Darcy and apparent velocities of groundwater in the phreatic aquiferous formation in Bamenda, Cameroon. Eighteen(18) hand dug-wells at different locations within Bamenda were sampled by utilizing sodium chloride(NaCl) as the conservative tracer. Field estimates of groundwater flow velocities in the phreatic aquiferous formation in Bamenda reveal Darcy's groundwater velocity in the range of 0.39 m/d at Nacho to 130.64 m/d at Foncha Street and apparent velocity in the range of 0.78 m/d at Nacho to 277.86 m/d at Foncha Street. The immense variations in the velocities of groundwater indicate that the groundwater flows at different rates and directions within the aquiferous formation in Bamenda, possibly due to variations in their hydraulic conductivities. Moreover, the spatial variations in the formation types, facies changes, thickness, and layering of the aquiferous formation also contribute to the variation of velocities. Areas with low groundwater velocities are associated with a lower contaminant transport rate when compared to areas with high groundwater velocities. The findings of this study are important for assessing the rates of pollutant movement in the subsurface, as well as the effectiveness and efficacy of the trigger-tube technique in evaluating the hydraulic properties of aquiferous formations.  相似文献   

Modeling vertical stratification of CO₂ injected into a deep layered aquifer     

Mohamed Hayek  Emmanuel MoucheClaude Mügler 《Advances in water resources》2009

The vertical stratification of carbon dioxide (CO₂) injected into a deep layered aquifer made up of high-permeability and low-permeability layers, such as Utsira aquifer at Sleipner site in Norway, is investigated with a Buckley–Leverett equation including gravity effects. In a first step, we study both by theory and simulation the application of this equation to the vertical migration of a light phase (CO₂), in a denser phase (water), in 1D vertical columns filled with different types of porous media: homogeneous, piecewise homogeneous, layered periodic and finally heterogeneous. For each case, we solve the associated Riemann problems and propose semi-analytical solutions describing the spatial and temporal evolution of the light phase saturation. These solutions agree well with simulation results. We show that the flux continuity condition at interfaces between high-permeability and low-permeability layers leads to CO₂ saturation discontinuities at these interfaces and, in particular, to a saturation increase beneath low-permeability layers. In a second step, we analyze the vertical migration of a CO₂ plume injected into a 2D layered aquifer. We show that the CO₂ vertical stratification under each low-permeability layer is induced, as in 1D columns, by the flux continuity condition at interfaces. As the injection takes place at the bottom of the aquifer the velocity and the flux function decrease with elevation and this phenomenon is proposed to explain the stratification under each mudstone layer as observed at Sleipner site.  相似文献   

Migration and internal architecture of marine dunes in the eastern English Channel over 14 and 56 year intervals: the influence of tides and decennial storms     

Y. Ferret  S. Le Bot  B. Tessier  T. Garlan  R. Lafite 《地球表面变化过程与地形》2010,35(12):1480-1493

Submarine dune dynamics are controlled by tidal currents and wind forces. According to the relative influence of these forces and the nature of dune sediment, different bedform behaviors can be observed. The footprint of the different hydrodynamic agents is recorded into the internal architecture of dunes. This paper is concerned with bedforms that compose the thick sediment wedge located in the eastern English Channel, off the Bay of Somme. This sedimentary archive constitutes an interesting feature to achieve a better understanding of seabed sediment dynamics and its timeline building stages. The dynamics of large submarine dunes, which are organized in fields, are studied thanks to bathymetric and seismic data over the periods 1937–1993 and 1993–2007. Dune morphology presents low lee and stoss side slopes (on average 8° and 3°, respectively) and dune migration rate is not very high. Dune movements are in the direction of residual tidal currents, i.e. toward the east, with mean migration rates around 0·8 to 5 ± 0·25 m yr^?1 and up to 6·6 ± 0·7 m yr^?1, respectively, at multi‐decennial and decennial time scales. The dune internal architecture is complex with superimposed eastward prograding units, displaying locally opposite progradation. Second‐order discontinuities (dip of 0·5°–4° perpendicular to dune crests) constitute dune master bedding. By counting the number of second‐order reflectors between 1937–1993 and 1993–2007, the formation periodicity of these bounding surfaces is estimated to range from 4 to 18 years. These time intervals coincide with the long‐term tidal cyclicities and also with the inter‐annual to decennial variability of storm activity in northern Europe. Two theories were made to interpret the dune internal structures: the second‐order surfaces are interpreted either as the depositional surfaces corresponding to the marks of weak energy periods (weak tidal and storm action), or as erosive surfaces due to an opposite direction of dune migration provoked temporarily by exceptional storms from the northeast. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Long-term monitoring of a large deep-seated landslide (La Clapiere,South-East French Alps): initial study   总被引：1，自引：1，他引：0  

Edouard Palis  Thomas Lebourg  Emmanuel Tric  Jean-Philippe Malet  Maurin Vidal 《Landslides》2017,14(1):155-170

The large-scale deformation of high mountain slopes finds its origin in many phenomena (inherent parameters, external stresses) with very different time constants (instantaneous to geological scale). Gravitational effect, tectonic forces and water infiltration are generally the principal causes of slope instability. However, it can be very difficult to distinguish which cause is dominant and which are their respective effects. To gain a better understanding of the complex processes taking place during the evolution of an unstable slope and separate the causes responsible of the landslide dynamic, an observational study based on geodetic, meteorological, seismological and electrical data has been performed on the La Clapière rockslide (Southern French Alps). This deep-seated landslide (DSL) is known for many years as one of the largest and fastest rock slide in Europe (60 million m³ of highly weathered metamorphic material, moving at 1 to 3 m year^?1). The set-up of the “Observatoire Multidisciplinaire des Instabilités de Versants” (OMIV, http://omiv.osug.fr) in 2011 has allowed the production and availability of an important and original data set over several years of accurate monitoring. Thus, for the first time, the long-term study of geodetic data permitted us to highlight acceleration phases in the general movement of the landslide that affect its dynamic. These modifications are associated with variations of the velocity by a factor 3 to 6. The characterization of the origin of these variations was possible due to the comparison with meteorological, electrical and seismological data. Based on these various signals, we were able to establish correlations and contributions of meteorological water infiltration in the dynamic evolution of the La Clapière slope. We determine several response times to the meteorological stress for seismic endogenous events (mainly rockfalls), the resistivity of the ground (quasi-instantaneous) and the kinematics of the slope (from 2 weeks to 2.5 months). Moreover, our results strongly suggest the existence of rainfall threshold of 3.5?±?1 mm day^?1 from which the number of seismic endogenous events is highly increased.  相似文献   

Hydrochemical characteristics of groundwater and surface water for domestic and irrigation purposes in Vea catchment,Northern Ghana     

Kouakou Valentin Koffi  Emmanuel Obuobie  Andre Banning  Stefan Wohnlich 《Environmental Earth Sciences》2017,76(4):185

The Vea catchment, mainly underlain by crystalline basement rocks, is located in Northern Ghana. Hydrogeochemical studies were carried out in this area with the objective of identifying the geochemical processes influencing water quality and suitability of surface and groundwater for agricultural and domestic uses. Sixty-one groundwater and four surface water samples were collected from boreholes, dams and rivers and analysed for Ca²⁺, Mg²⁺, Na⁺, K⁺, HCO₃ ^?, Cl^?, and SO₄ ^2?, Fe_tot, PO₄ ^3?, Mn_tot, NH₄ ⁺, NO₃ ^?, NO₂ ^?. In addition, pH, total dissolved solids, electrical conductivity, total hardness, turbidity, colour, salinity and dissolved oxygen were analysed. Chloro-alkaline indices 1 and 2, and characterization of weathering processes suggest that the chemistry of groundwater is dominated by the interaction between water and rocks. Cation exchange and silicate weathering are the dominant processes controlling the chemical composition of the groundwater in the area studied. Mineral saturation indices indicate the presence of at least three groups of groundwater in the Vea catchment with respect to residence time. The meteoric genesis index suggests that 86% of the water samples belong to the shallow meteoric water percolation type. The findings further suggest that the groundwater and surface water in the basin studied are mainly Ca–Mg–HCO₃ water type, regardless of the geology. Compared to the water quality guidelines of WHO, the study results on sodium absorption ratio, sodium percentage, magnesium hazard, permeability index and residual sodium carbonate indicate that groundwater and surface water in the Vea catchment are generally suitable for drinking and irrigation purposes.  相似文献   

Carbon Monoxide on Jupiter: Evidence for Both Internal and External Sources     

Bruno Bézard  Emmanuel LellouchDarrell Strobel  Jean-Pierre Maillard  Pierre Drossart 《Icarus》2002,159(1):95-111

Thirteen lines of the CO band near 4.7 μm have been observed on a jovian hot spot at a resolution of 0.045 cm⁻¹. The measured line profiles indicate that the CO mole fraction is 1.0±0.2 ppb around the 6-bar level and is larger in the upper troposphere and/or stratosphere. An external source of CO providing an abundance of 4⁺³₋₂×10¹⁶ molecules cm⁻² is implied by the observations in addition to the amount deposited at high altitude by the Shoemaker-Levy 9 collision. From a simple diffusion model, we estimate that the CO production rate is (1.5-10)×10⁶ molecules cm⁻² s⁻¹ assuming an eddy diffusion coefficient around the tropopause between 300 and 1500 cm² s⁻¹. Precipitation of oxygen atoms from the jovian magnetosphere or photochemistry of water vapor from meteoroidal material can only provide a negligible contribution to this amount. A significant fraction of the CO in Jupiter's upper atmosphere may be formed by shock chemistry due to the infall of kilometer- to subkilometer-size Jupiter family comets. Using the impact rate from Levison et al. (2000, Icarus143, 415-420) rescaled by Bottke et al. (2002, Icarus156, 399-433), this source can provide the observed stratospheric CO only if the eddy diffusion coefficient around the tropopause is 100-300 cm² s⁻¹. Higher values, ∼700 cm² s⁻¹, would require an impact rate larger by a factor of 5-10, which cannot be excluded considering uncertainties in the distribution of Jupiter family comets. Such a large rate is indeed consistent with the observed cratering record of the Galilean satellites (Zahnle et al. 1998, Icarus136, 202-222). On the other hand, the ∼1 ppb concentration in the lower troposphere requires an internal source. Revisiting the disequilibrium chemistry of CO in Jupiter, we conclude that rapid vertical mixing can provide the required amount of CO at ∼6 bar for a global oxygen abundance of 0.2-9 times the solar value considering the uncertainties in the convective mixing rate and in the chemical constants.  相似文献   

Periodic orbits in a dynamical system with three degrees of freedom     

Emmanuel Davoust 《Celestial Mechanics and Dynamical Astronomy》1983,31(3):293-301

We use the analytical method of Lindstedt to make an inventory of the regular families of periodic orbits and to obtain approximate analytical solutions in a three-dimensional harmonic oscillator with perturbing cubic terms. We compare these solutions to the results of numerical computations at a specific orbital resonance.  相似文献   

Boron isotopic fractionation related to boron sorption on humic acid and the structure of surface complexes formed     

Emmanuel Lemarchand  Jérôme Gaillardet 《Geochimica et cosmochimica acta》2005,69(14):3519-3533

Boron isotopic fractionation during adsorption onto Ca-flocculated Aldrich humic acid (HA) has been investigated experimentally as a function of solution pH at 25°C and I = 0.15 M. Boron aqueous concentration and isotopic composition were determined by Cs₂BO₂⁺ Positive Thermal Ionization Mass Spectrometry analysis, while the structure of B surface complexes on HA was characterized using ¹¹B Magic Angle Spinning Nuclear Magnetic Resonance (MAS NMR). Significant B sorption on HA was observed at 6 < pH < 12 with a maximum value of Kd, the partition coefficient between adsorbed and aqueous boron, equal to 40 at pH = 9.5-10. Combined ¹¹B MAS NMR analysis and FITEQL modeling of B sorption on HA showed that this element forms tetrahedrally coordinated five- or six-membered ring chelates, most likely 1,2-diol and 1,3-diol complexes at alkaline pH (8 < pH < 11) and dicarboxylic complexes at near neutral conditions (6 < pH < 9). Results of this study demonstrate for the first time that boron sorption on HA induces a strong pH-dependent isotope fractionation—with ¹¹B depleted at the surface of HA—that reaches a maximum at 5 < pH < 9 (α = 0.975, Δ = −25‰) and decreases sharply at pH >9. The measured isotope fractionation cannot be modeled assuming that the isotopic composition of the sorbed borate species is identical to that of B(OH)₄^- species in the parent solution. It is shown that the extent of isotopic fractionation depends not only on B aqueous speciation but also on the distribution and structure of the borate surface complexes formed. In agreement with energetic constrains, calculation of the isotope fractionation factors between aqueous boric acid and boron surface complexes suggests that the formation of the strained six-membered ring 1,3-diol complex yields a much higher fractionation (α_BLP1−III = 0.954-0.960, Δ = −41/-47‰) than that of the very stable five-membered ring 1,2-diol (α_BLP2−III = 0.983, Δ = −18‰). The results of this study open new perspectives to understand and model boron biogeochemical cycle. It is predicted that boron sorption onto organic matter can have important consequences for the boron isotopic composition of surface water reservoirs (seawater, groundwater, soil waters) in which either abundant organic surfaces or significant boron concentrations are available. In addition, the large isotope fractionation between aqueous boric acid and surface boron-organic complexes found in the present work makes boron a promising tracer of biologic activity.  相似文献