9000 years of changes in peat organic matter composition in Store Mosse (Sweden) traced using FTIR-ATR     

Antonio Martínez Cortizas  Jenny K. Sjöström  Eleonor E. Ryberg  Malin E. Kylander  Joeri Kaal  Olalla López-Costas  Noemi Álvarez Fernández  Richard Bindler 《Boreas: An International Journal of Quaternary Research》2021,50(4):1161-1178

Store Mosse (the ‘Great Bog’ in Swedish) is one of the most extensive bog complexes in southern Sweden (~77 km²), where pioneering palaeoenvironmental research has been carried out since the early 20th century. This includes, for example, vegetation changes, carbon and nitrogen dynamics, peat decomposition, atmospheric metal pollution, mineral dust deposition, dendrochronology, and tephrochronology. Even though organic matter (OM) represents the bulk of the peat mass and its compositional change has the potential to provide crucial ecological information on bog responses to environmental factors, peat OM molecular composition has not been addressed in detail. Here, a 568-cm-deep peat sequence was studied at high resolution, by attenuated reflectance Fourier-transform infrared spectroscopy (FTIR-ATR) in the mid-infrared region (4000–400 cm^–1). Principal components analysis was performed on selected absorbances and change-point modelling was applied to the records to determine the timing of changes. Four components accounted for peat composition: (i) depletion/accumulation of labile (i.e. carbohydrates) and recalcitrant (i.e. lignin and other aromatics, aliphatics, organic acids and some N compounds) compounds, due to peat decomposition; (ii) variations in N compounds and carbohydrates; (iii) residual variation of lignin and organic acids; and (iv) residual variation of aliphatic structures. Peat decomposition showed two main patterns: a long-term trend highly correlated to peat age (r = 0.87), and a short-term trend, which showed five main phases of increased decomposition (at ~8.4–8.1, ~7.0–5.6, ~3.5–3.1, ~2.7–2.1 and ~1.6–1.3 ka) – mostly corresponding to drier climate and its effect on bog hydrology. The high peat accumulation event (~5.6–3.9 ka), described in earlier studies, is characterized by the lowest degree of peat decomposition of the whole record. Given that FTIR-ATR is a quick, non-destructive, cost-effective technique, our results indicate that it can be applied in a systematic way (including multicore studies) to peat research and provide relevant information on the evolution of peatlands.  相似文献   

Resource Model Updating For Compositional Geometallurgical Variables     

Prior  Ángel  Tolosana-Delgado  Raimon  van den Boogaart  K. Gerald  Benndorf  Jörg 《Mathematical Geosciences》2021,53(5):945-968

In the field of mineral resources extraction, one main challenge is to meet production targets in terms of geometallurgical properties. These properties influence the processing of the ore and are often represented in resource modeling by coregionalized variables with a complex relationship between them. Valuable data are available about geometalurgical properties and their interaction with the beneficiation process given sensor technologies during production monitoring. The aim of this research is to update resource models as new observations become available. A popular method for updating is the ensemble Kalman filter. This method relies on Gaussian assumptions and uses a set of realizations of the simulated models to derive sample covariances that can propagate the uncertainty between real observations and simulated ones. Hence, the relationship among variables has a compositional nature, such that updating these models while keeping the compositional constraints is a practical requirement in order to improve the accuracy of the updated models. This paper presents an updating framework for compositional data based on ensemble Kalman filter which allows us to work with compositions that are transformed into a multivariate Gaussian space by log-ratio transformation and flow anamorphosis. This flow anamorphosis, transforms the distribution of the variables to joint normality while reasonably keeping the dependencies between components. Furthermore, the positiveness of those variables, after updating the simulated models, is satisfied. The method is implemented in a bauxite deposit, demonstrating the performance of the proposed approach.

  相似文献   

Uncoupled transport of chlorofluorocarbons and anthropogenic carbon in the subpolar North Atlantic     

Marta Álvarez  Claire Gourcuff 《Deep Sea Research Part I: Oceanographic Research Papers》2010,57(7):860-868

Chlorofluorocarbon (CFC) 11 and 12 transports across the transoceanic World Ocean Circulation Experiment (WOCE) A25 section in the subpolar North Atlantic are derived from an inverse model using hydrographic and ADCP data (Lherminier et al., 2007). CFC and anthropogenic carbon (C_ANT) advective transports contrary to expected are uncoupled: C_ANT is transported northeastwards (82±39 kmol s^?1) mainly within the overturning circulation, while CFC-11 and CFC-12 are transported southwestwards (?24±4 and ?11±2 mol s^?1, respectively) as part of the large-scale horizontal circulation. The main reason for this uncoupled behaviour is the complex CFC vs. C_ANT relation in the ocean, which stems from the contrasting temperature relation for both tracers: more C_ANT dissolves in warmer waters with a low Revelle factor, while CFC’s solubility is higher in cold waters. These results point to C_ANT and CFC having different routes of uptake, accumulation and transport within the ocean, and hence: C_ANT transport would be more sensitive to changes in the overturning circulation strength, while CFC to changes in the East Greenland Current and Labrador Sea Water formation in the Irminger Sea. Additionally, C_ANT and CFCs would have different sensitivities to circulation and climate changes derived from global warming as the slowdown of the overturning circulation, increase stratification due to warming and changes in wind stress.  相似文献   

Middle Pleistocene large‐mammal faunas from North Iberia: palaeobiogeographical and palaeoecological implications          下载免费PDF全文

Diego J. Álvarez‐Lao 《Boreas: An International Journal of Quaternary Research》2016,45(2):191-206

The rich Quaternary fossil record from the Cantabrian region (NW Iberia) is virtually restricted to the Late Pleistocene, with Middle Pleistocene findings very rare. This work presents the study of two Middle Pleistocene palaeontological sites in the Cantabrian region: Llantrales quarry and Mestas de Con mine, both discovered and first described in the 1950s but never studied in detail thereafter. The material was here re‐analysed and re‐evaluated. Taxonomic attributions have been changed in most cases and, consequently, chronological assignments of the fossils have also been changed. This first detailed study of the assemblage from Llantrales quarry revealed the occurrence of the large‐sized deer Praemegaceros solilhacus, which has never been reported previously in North Iberia. Cervus cf. elaphus and Stephanorhinus cf. hundsheimensis were also identified. The age of these fossils was originally regarded as Pontian (late Miocene), but new palaeontological results indicate a much younger age, most likely from around 0.8 to 0.5 Ma. A taxonomic re‐evaluation of the fossils from Mestas de Con provided different results with respect to the 1950s works. The faunal association is composed of a large‐sized deer (probably corresponding to Praemegaceros), Cervus elaphus, Capreolus cf. capreolus, Bison sp. (small sized), Equus sp. (large sized), Stephanorhinus hemitoechus, Ursus sp. and Homotherim latidens. This faunal association was evaluated within a western European context and proves to be highly analogous to other contemporary assemblages there. The chronology was initially regarded as late Villafranchian (in a broader sense). New results, documenting the co‐occurrence of Stephanorhinus hemitoechus and Homotherium latidens, indicate a more precise and younger age, most likely between 0.6 and 0.4 Ma. These two fossil assemblages provide new and relevant information on the Middle Pleistocene faunas from a geographical region where this information, compared with other western European areas, is rare and poorly known.  相似文献   

Biogeography of the deep-sea galatheid squat lobsters of the Pacific Ocean     

Enrique Macpherson  Bertrand Richer de Forges  Kareen Schnabel  Sarah Samadi  Marie-Catherine Boisselier  Antoni Garcia-Rubies 《Deep Sea Research Part I: Oceanographic Research Papers》2010,57(2):228-238

We analyzed the distribution patterns of the galatheid squat lobsters (Crustacea, Decapoda, Galatheidae) of the Pacific Ocean. We used the presence/absence data of 402 species along the continental slope and continental rise (200–2000 m) obtained from 54 cruises carried out in areas around the Philippines, Indonesia, Solomon, Vanuatu, New Caledonia, Fiji, Tonga, Wallis and Futuna and French Polynesia. The total number of stations was ca. 3200. We also used published data from other expeditions carried out in the Pacific waters, and from an exhaustive search of ca. 600 papers on the taxonomy and biogeography of Pacific species. We studied the existence of biogeographic provinces using multivariate analyses, and present data on latitudinal and longitudinal patterns of species richness, rate of endemism and the relationship between body sizes with the size of the geographic ranges. Latitudinal species richness along the Western and Eastern Pacific exhibited an increase from higher latitudes towards the Equator. Longitudinal species richness decreased considerably from the Western to the Central Pacific. Size frequency distribution for body size was strongly shifted toward small sizes and endemic species were significantly smaller than non-endemics. This study concludes that a clear separation exists between the moderately poor galatheid fauna of the Eastern Pacific and the rich Western and Central Pacific faunas. Our results also show that the highest numbers of squat lobsters are found in the Coral Sea (Solomon-Vanuatu-New Caledonia islands) and Indo-Malay-Philippines archipelago (IMPA). The distribution of endemism along the Pacific Ocean indicates that there are several major centres of diversity, e.g. Coral Sea, IMPA, New Zealand and French Polynesia. The high proportion of endemism in these areas suggests that they have evolved independently.  相似文献   

Energy balance and evaporation loss of an agricultural reservoir in a semi‐arid climate (south‐eastern Spain)     

B. Gallego‐Elvira  A. Baille  B. Martín‐Górriz  V. Martínez‐Álvarez 《水文研究》2010,24(6):758-766

A typical agricultural water reservoir (AWR) of 2400 m² area and 5 m depth, located in a semi‐arid area (southern Spain), was surveyed on a daily basis for 1 year. The annual evaporation flux was 102·7 W m^?2, equivalent to an evaporated water depth of 1310 mm year^?1. The heat storage rate G exhibited a clear annual cycle with a peak gain in April (G ～ 45 W m^?2) and a peak loss in November (G ～ 40 W m^?2), leading to a marked annual hysteretic trend when evaporation (λE) was related to net radiation (R_n). λE was strongly correlated with the available energy A, representing 91% of the annual AWR energy loss. The sensible heat flux H accounted for the remaining 9%, leading to an annual Bowen ratio in the order of 0·10. The equilibrium and advective evaporation terms of the Penman formula represented 76 and 24%, respectively, of the total evaporation, corresponding to a annual value of the Priestley–Taylor (P–T) coefficient (α) of 1·32. The P–T coefficient presented a clear seasonal pattern, with a minimum of 1·23 (July) and a maximum of 1·65 (December), indicating that, during periods of limited available energy, AWR evaporation increased above the potential evaporation as a result of the advection process. Overall, the results stressed that accurate prediction of monthly evaporation by means of the P–T formula requires accounting for both the annual cycle of storage and the advective component. Some alternative approaches to estimating R_n, G and α are proposed and discussed. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

Distribution of benthic flora in the lower course of the Valdivia River,Chile     

Carlos Ramírez  Heriberto Figueroa  Enrique Hauenstein  Domingo Contreras 《Estuaries and Coasts》1989,12(2):111-118

The Valdivia River (Lake Region, Chile) originates in Riñihue Lake and flows into the sea at Corral Bay (39°52′S latitude), changing names several times along its course. The aquatic benthic flora (algae and aquatic plants) of the Valdivia River was characterized, based on 22 sites sampled and 124 plant species collected. Four benthic vegetation zones were established using presence-absence data: a freshwater zone and a marine zone were found at the extremes of the transect; an estuarine zone and a discontinuity zone were detected in the middle of this transect. The freshwater zone was characterized by a relatively diverse assemblage of vascular plants, the marine zone was dominated by algae and was rich in species. By contrast the estuarine zone was inhabited by only a few species but in great abundance, while the discontinuity zone was poor, in species and low in cover vegetation.  相似文献   

Application of the telluric and magnetotelluric methods in selection of sites for nuclear plants     

A. Ádám  J. Verö 《Journal of Earth System Science》1990,99(4):657-667

The paper deals with the application of the telluric method and of magnetotelluric soundings including experimental and model data on the localization of tectonic disturbances in connection with the selection of appropriate sites for nuclear plants.  相似文献   

Discrete models for vertical vibrations of surface and embedded foundations     

Francisco C. P. De Barros  J. Enrique Luco 《地震工程与结构动力学》1990,19(2):289-303

A five-parameter discrete model that approximates the dynamic force4isplacement relationship for rigid foundations undergoing vertical vibrations on a uniform elastic half-space is presented. The model involves a combination of two springs, two viscous dampers and a mass. Values of the parameters for circular, square and rectangular foundations placed on the surface or embedded in an elastic half-space are listed. The parameters are obtained by minimizing the discrepancy between the force4isplacement relation for the model and that obtained by solution of the mixed boundary-value problem of the rigid foundation on an elastic half-space. The definition of an appropriate input motion to represent wave excitation is also discussed. The input motion to the discrete model differs from the input motion that should be used in a continuum model.  相似文献   

Volcanic hazards in the surroundings of Pico de Orizaba,eastern Mexico     

Ármann Höskuldsson  Jean Marie Cantagrel 《Natural Hazards》1994,10(3):197-219

Volcanic hazards from Pico de Orizaba volcano are presented here tor the first time. Some 1.3 million people live within the hazard zone, which in the most severe case would encompass the Mexican Gulf coast, east of the volcano. Three major cities located in the eastern part of the hazard zone account for 800 000 of this population and about 200 000 people live within a 20 km radius of the volcano. Probability calculations are presented as an attempt to quantify the hazards in the surroundings of the volcano. Such quantification can be of use in planning for future land use within the hazard zones.A zone of about 10 km radius centred on the top crater is a high hazard zone for gravity-driven flows and fallout ejecta. For large volume eruptions, the radius could be extended to 120 km to the east and 60 km to the west. The asymmetrical distribution is related to the topography of the volcano. Hazards from Pyroclastic-fall deposits are principally to the west of the volcano, since easterly winds are dominant in the area lava-flow hazards are greatest within a 10 km radius from the summit crater. Pyroclastic flow hazards are high up to 20 km from the volcano summit.In the case of reactivation of the volcano, melting of a glacier covering the summit of Pico de Orizaba having a volume equivalent to some 45 × 10⁹ litres of water, would produce lahars which would descend the flanks of the volcano.  相似文献