A new approach to interpreting Rock-Eval S₂ and TOC data for kerogen quality assessment     

Birger Dahl  Jrgen Bojesen-Koefoed  Anders Holm  Holger Justwan  Egil Rasmussen  Erik Thomsen 《Organic Geochemistry》2004,35(11-12):1461

A simple method for application in source potential mapping is used to assess the original oil and gas potentials in source rock horizons based upon Rock-Eval potential (S₂) and total organic carbon (TOC) values. The method assumes that kerogens consist of mixtures of end-members with assigned hydrogen index values. Based on suggested algorithms, the average amounts of oil-prone, gas-prone and inert organic material over source rock intervals are determined in TOC units. The method uses regression lines from plots of remaining hydrocarbon potentials (S₂) versus total organic carbon (TOC), and “quick-look” transparent overlays are used to read the appropriate kerogen mixture.Mineral matrix effects during pyrolysis, when strong, can cause erroneous results. This effect which occurs for oil-prone kerogens and adsorptive minerals can cause problems particularly for lean samples (S₂ = 0–3 mg HC/g rock) whilst the errors for richer samples are less.The method is applied on three sections of Upper Jurassic organic-rich rocks from the Danish North Sea sector, which are at different maturity stages. One of these sections is dominated by gas-prone material, one is dominated by oil-prone material and the third section contains a mixture of oil- and gas-prone material.The method has been compared with other methods that split kerogens in oil and gas generating potential and has given reasonable results.Experience using the method and a presented example suggest that sedimentological, system tract information may be derived from S₂ to TOC cross-plots. A constructed modelling example suggests that the end-member concept used in this approach may be used in forward type source rock prediction models when combined with sedimentological models. The resulting S₂–TOC plots can be used in order to check the forward modelling results against observed values.  相似文献   

Laser microprobe sulphur isotope analysis of arsenopyrite: experimental calibration and application to the Boliden Au–Cu–As massive sulphide deposit     

Thomas Wagner  Adrian J. Boyce  Erik Jonsson  Anthony E. Fallick 《Ore Geology Reviews》2004,25(3-4):311-325

Metamorphic remobilization of arsenopyrite-rich ores is a globally important process which can lead to significant concentrations of gold. In order to understand this and related processes, relations of sulphur isotopes can give a number of important clues. To resolve such relations in detail, we have successfully calibrated and applied a laser combustion system for in situ analysis of sulphur isotopic compositions of arsenopyrite. Experimental calibration of the laser fractionation factor (+0.4‰) was obtained by using compositionally and isotopically homogeneous natural samples from ore deposits at Boliden (Sweden) and Freiberg (Germany); subsequent to detailed microscopic study, the S isotope ratios of these samples were measured by conventional and laser combustion techniques.The present application to different types of arsenopyrite in the Palaeoproterozoic metamorphosed VHMS ores of the Boliden Au–Cu–As deposit, Skellefte district, northern Sweden, shows that the sulphur isotope composition of arsenopyrite is essentially unmodified during medium-grade metamorphic recrystallization and remobilization. Here, massive arsenopyrite ore is crosscut by later veins that carry a complex quartz–sulphosalt–sulphide assemblage. The latter ore type is markedly Au-rich compared to the host ore, and thus of significant economic interest. We find that both ore types exhibit very similar sulphur isotope compositions, ca. +2‰ to +3‰ (V-CDT), which is similar to most massive sulphide deposits in the Skellefte district. Thus, the crosscutting Au-rich vein ore has inherited the sulphur isotope composition from sulphur liberated by metamorphic reactions affecting the massive ore, and most likely also inherited the Au through this mechanism. The latter finding clearly has important implications both for the general discussion on, and the prospecting for, similar high-grade Au ores in this world-class mining region.  相似文献   

The First Upper Triassic Vertebrate Locality in Antarctica     

W.R. Hammer  J.W. Collinson  R.A. Askin  W.J. Hickerson 《Gondwana Research》2004,7(1):199-204

In December 1999 we collected bones of two small reptiles from Upper Triassic mudstone on Mount Dearborn in southern Victoria Land, Antarctica. One specimen includes indeterminate limb fragments of a small reptile and the other is a tusk of a small dicynodont. We found both specimens in loose clasts on a slope of fine-grained strata above the second major channel-form sandstone above the base of member C in the Lashly Formation. The fossils occur in medium gray mudstone of the same lithology as the surrounding bedrock. Lashly member C at Mount Dearborn and in southern Victoria Land is composed of fining-upward cycles. At Mount Dearborn the cycles begin with channel-form, medium- to fine-grained sandstone. Quartz pebbles and cobbles occur at the base and in lenses with mudstone clasts. Lenses of coal occur along bedding planes and scours. The cycles fine upward gradually from sandstone to siltstone and carbonaceous mudstone with coal at the top. The Dicroidium flora is better preserved in the upper part of the cycles. A palynomorph assemblage from one of the bone-bearing samples suggests a Late Triassic (Carnian) age for the locality.This is the first report of Upper Triassic vertebrates in Antarctica and also of terrestrial vertebrates in Victoria Land. All previous vertebrate localities have been in non-carbonaceous beds in the central Transantarctic Mountains. The discovery expands the sequence of tetrapod occurrences in Lower, Middle and Upper Triassic and Lower Jurassic rocks in the Transantarctic Mountains. It appears that reptilian faunas managed to inhabit high latitudes (>60°), at least intermittently, for a period of 50 million years, suggesting a relatively warm climate for parts of Antarctica during those times.  相似文献   

The influence of foliation on the fragility of granitic rocks, image analysis and quantitative microscopy   总被引：6，自引：0，他引：6  

Urban   kesson  Jimmy Stigh  Jan Erik Lindqvist  Mattias G  ransson 《Engineering Geology》2003,68(3-4):275-288

Fabric-dependent anisotropy is important in understanding the mechanical behaviour of foliated rocks because the foliation creates mechanically weak discontinuities. Using optical microscopy, a foliation index (FIX) was calculated for a group of granitic rocks in southern Sweden that displays a range of textures from foliated to nonfoliated. Image analysis from scanning electron microscope with backscattered detector (SEM/BSE) images was used in order to measure the rock texture of these samples. The analyses were compared with the Los Angeles (LA) test, which measures resistance of rock aggregate to fragmentation. The results demonstrate that the measured grain size, shape and spatial arrangement are important parameters controlling the fragility of the rock. Both the texture and foliation must be taken into account to obtain a significant relationship with the mechanical analyses. We suggest that this alternative method could be a helpful tool for predicting a rock's suitability as an aggregate as it gives a better understanding of the material properties compared to mechanical testing.  相似文献   

Aspects of the structural evolution of the Lusitanian Basin in Portugal and the shelf and slope area offshore Portugal     

Erik S. Rasmussen  Steen Lomholt  Claus Andersen  Ole V. Vejbk 《Tectonophysics》1998,300(1-4):199-225

The study provides a regional seismic interpretation and mapping of the Mesozoic and Cenozoic succession of the Lusitanian Basin and the shelf and slope area off Portugal. The seismic study is compared with previous studies of the Lusitanian Basin. From the Late Triassic to the Cretaceous the study area experienced four rift phases and intermittent periods of tectonic quiescence. The Triassic rifting was concentrated in the central part of the Lusitanian Basin and in the southernmost part of the study area, both as symmetrical grabens and half-grabens. The evolution of half-grabens was particularly prominent in the south. The Triassic fault-controlled subsidence ceased during the latest Late Triassic and was succeeded by regional subsidence during the early Early Jurassic (Hettangian) when deposition of evaporites took place. A second rift phase was initiated in the Early Jurassic, most likely during the Sinemurian–Pliensbachian. This resulted in minor salt movements along the most prominent faults. The second phase was concentrated to the area south of the Nazare Fault Zone and resulted here in the accumulation of a thick Sinemurian–Callovian succession. Following a major hiatus, probably as a result of the opening of the Central Atlantic, resumed deposition occurred during the Late Jurassic. Evidence for Late Jurassic fault-controlled subsidence is widespread over the whole basin. The pattern of Late Jurassic subsidence appears to change across the Nazare Fault Zone. North of the Nazare Fault, fault-controlled subsidence occurred mainly along NNW–SSE-trending faults and to the south of this fault zone a NNE–SSW fault pattern seems to dominate. The Oxfordian rift phase is testified in onlapping of the Oxfordian succession on salt pillows which formed in association with fault activity. The fourth and final rift phase was in the latest Late Jurassic or earliest Early Cretaceous. The Jurassic extensional tectonism resulted in triggering of salt movement and the development of salt structures along fault zones. However, only salt pillow development can be demonstrated. The extensional tectonics ceased during the Early Cretaceous. During most of the Cretaceous, regional subsidence occurred, resulting in the deposition of a uniform Lower and Upper Cretaceous succession. Marked inversion of former normal faults, particularly along NE–SW-trending faults, and development of salt diapirs occurred during the Middle Miocene, probably followed by tectonic pulses during the Late Miocene to present. The inversion was most prominent in the central and southern parts of the study area. In between these two areas affected by structural inversion, fault-controlled subsidence resulted in the formation of the Cenozoic Lower Tagus Basin. Northwest of the Nazare Fault Zone the effect of the compressional tectonic regime quickly dies out and extensional tectonic environment seems to have prevailed. The Miocene compressional stress was mainly oriented NW–SE shifting to more N–S in the southern part.  相似文献   

Finite Prandtl number 2-D convection at high Rayleigh numbers     

Catherine A. Hier Majumder  David A. Yuen  Erik O. Sevre  John M. Boggs  Stephen Y. Bergeron 《Visual Geosciences》2002,7(1):1-53

Finite Prandtl number thermal convection is important to the dynamics of planetary bodies in the solar system. For example, the complex geology on the surface of the Jovian moon Europa is caused by a convecting, brine-rich global ocean that deforms the overlying icy “lithosphere”. We have conducted a systematic study on the variations of the convection style, as Prandtl numbers are varied from 7 to 100 at Rayleigh numbers 106 and 108. Numerical simulations show that changes in the Prandtl number could exert significant effects on the shear flow, the number of convection cells, the degree of layering in the convection, and the number and size of the plumes in the convecting fluid. We found that for a given Rayleigh number, the convection style can change from single cell to layered convection, for increasing Prandtl number from 7 to 100. These results are important for determining the surface deformation on the Jovian moon Europa. They also have important implications for surface heat flow on Europa, and for the interior heat transfer of the early Earth during its magma ocean phase. Electronic Supplementary Material is available if you access this article at . On that page (frame on the left side), a link takes you directly to the supplementary material. Electronic Supplementary Material is available if you access this article at . On that page (frame on the left side), a link takes you directly to the supplementary material.  相似文献   

Algebraic Solution of GPS Pseudo-Ranging Equations     

Joseph L. Awange  Erik W. Grafarend 《GPS Solutions》2002,5(4):20-32

Several procedures for solving, in a closed form the GPS pseudo-ranging four-point problem P4P in matrix form already exist. We present here alternative algebraic procedures using Multipolynomial resultant and Groebner basis to solve the same problem. The advantage is that these algebraic algorithms have already been implemented in algebraic software such as “Mathematica” and “Maple”. The procedures are straightforward and simple to apply. We illustrate here how the algebraic techniques of Multipolynomial resultant and Groebner basis explicitly solve the nonlinear GPS pseudo-ranging four-point equations once they have been converted into algebraic (polynomial) form and reduced to linear equations. In particular, the algebraic tools of Multipolynomial resultant and Groebner basis provide symbolic solutions to the GPS four-point pseudo-ranging problem. The various forward and backward substitution steps inherent in the clasical closed form solutions of the problem are avoided. Similar to the Gauss elimination techniques in linear systems of equations, the Multipolynomial resultant and Groebner basis approaches eliminate several variables in a multivariate system of nonlinear equations in such a manner that the end product normally consists of univariate polynomial equations (in this case quadratic equations for the range bias expressed algebraically using the given quantities) whose roots can be determined by existing programs (e. g., the roots command in MATLAB). © 2002 Wiley Periodicals, Inc.  相似文献   

GPS Solutions: Closed Forms, Critical and Special Configurations of P4P   总被引：1，自引：0，他引：1  

Erik W. Grafarend  Jeffrey Shan 《GPS Solutions》2002,5(3):29-41

P4P is the pseudo-ranging 4-point problem as it appears as the basic configuration of satellite positioning with pseudo-ranges as observables. In order to determine the ground receiver/satellite receiver (LEO networks) position from four positions of satellite transmitters given, a system of four nonlinear (algebraic) equations has to be solved. The solution point is the intersection of four spherical cones if the ground receiver/satellite receiver clock bias is implemented as an unknown. Here we determine the critical configuration manifold (Determinantal Loci, Inverse Function Theorem, Jacobi map) where no solution of P4P exists. Four examples demonstrate the critical linear manifold. The algorithm GS solves in a closed form P4P in a manner similar to Groebner bases: The algebraic nonlinear observational equations are reduced in the forward step to one quadratic equation in the clock bias unknown. In the backward step two solutions of the position unknowns are generated in closed form. Prior information in P4P has to be implemented in order to decide which solution is acceptable. Finally, the main target of our contribution is formulated: Can we identify a special configuration of satellite transmitters and ground receiver/satellite receiver where the two solutions are reduced to one. A special geometric analysis of the discriminant solves this problem. ? 2002 Wiley Periodicals, Inc.  相似文献   

Functional assessment of a reference wetland set as a tool for science, management and restoration   总被引：1，自引：0，他引：1  

Stuart E. G. Findlay  Erik Kiviat  W. Charles Nieder  Elizabeth A. Blair 《Aquatic Sciences - Research Across Boundaries》2002,64(2):107-117

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Elektronenmikroskopische Untersuchungen an mikritischen Kalken     

Prof. Dr. Erik Flügel 《International Journal of Earth Sciences》1967,56(1):341-358

Zusammenfassung Es werden die Entstehungsmöglichkeiten von mikritischen Kalken diskutiert und an Hand von elektronenmikroskopischen Aufnahmen Hinweise auf genetische Interpretationen vorgeführt.

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The origin of micritic limestones is discussed and genetic interpretation of micrites from different environments, studied by electron microscope, is given.

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Résumé L'origine des calcaires micritic est discutée et une interprétation génétique des micrites de milieux différents est donnée à l'aide de la microscopie électronique.

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Vorgetragen auf der 56. Jahresversammlung der Geologischen Vereinigung in Wien im Februar 1966.  相似文献