Estimating Aquifer Sensitivity to Nitrate Contamination Using Geochemical Information     

Michael D. Trojan  Moira E. Campion  Jennifers Maloney  James M. Stockinger  Erin P. Eid 《Ground Water Monitoring & Remediation》2002,22(4):100-108

Methods for predicting aquifer sensitivity to contamination typically ignore geochemical factors that affect the occurrence of contaminants such as nitrate. Use of geochemical information offers a simple and accurate method for estimating aquifer sensitivity to nitrate contamination. We developed a classification method in which nitrate-sensitive aquifers have dissolved oxygen concentrations > 1.0 mg/L, Eh values >250 mV, and either reduced iron concentrations < 0.1 mg/L or total iron concentrations < 0.7 mg/L. We tested the method in four Minnesota aquifer systems having different geochemical and hydrologic conditions. A surficial sand aquifer in central Minnesota exhibited geochemical zonation, with a rapid shift from aerobic to anaerobic conditions 5 m below the water table. A fractured bedrock aquifer in east-central Minnesota remained aerobic to depths of 50 m, except in areas where anaerobic ground water discharged upward from an underlying aquifer. A bedrock aquifer in southeast Minnesota exhibited aerobic conditions when overlain by surficial deposits lacking shale, whereas anaerobic conditions occurred under deposits that contained shale. Surficial sand aquifers in northwest Minnesota contained high concentrations of sulfate and were anaerobic throughout their extent. Nitrate-nitrogen was detected at concentrations exceeding 1 mg/L in 135 of 149 samples classified as sensitive. Nitrate was not detected in any of the 109 samples classified as not sensitive. We observed differences between our estimates of sensitivity and existing sensitivity maps, which are based on methods that do not consider aquifer geochemistry. Because dissolved oxygen, reduced iron, and Eh are readily measured in the field, use of geochemistry provides a quick and accurate way of assessing aquifer sensitivity to nitrate contamination.  相似文献   

Chlorinated and brominated organic contaminants and metabolites in the plasma and diet of a captive killer whale (Orcinus orca)     

Erin R. Bennett  David Huff  Robert J. Letcher 《Marine pollution bulletin》2009,58(7):1078-89

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Relationships between phytoplankton standing crop and physical, chemical, and biological gradients in the Suwannee River and plume region, U.S.A.     

Erin L. Bledsoe  Edward J. Phlips 《Estuaries and Coasts》2000,23(4):458-473

The Suwannee River (USA) is an amber stained, nutrient rich, blackwater river which flows into relatively clear oceanic waters resulting in the formation of a coastal region with unique physical, chemical, and biological gradients. The intent of this study was to describe the spatial and temporal variability of phytoplankton as it relates to these gradients. Ten stations along a transect ranging from 5 km up river to 31 km offshore, were sampled during four different flow regimes. All four sampling periods included in our study of the Suwannee River and plume region exhibited a similar pattern of phytoplankton abundance; low phytoplankton biomass in the Suwannee River and offshore stations with an area of elevated biomass seaward of the Suwannee River outflow. The results of our analysis of light and nutrient limitation in the region support the hypothesis that this spatial pattern of phytoplankton abundance is strongly influenced by color dependent light limitation in the river and outflow area, combined with nutrient limitation offshore. Our results suggest that both light and nutrient availability control abundance and composition of phyto plankton in this coastal area.  相似文献   

Rapid movement of wastewater from on-site disposal systems into surface waters in the Lower Florida Keys     

John H. Paul  Molly R. McLaughlin  Dale W. Griffin  Erin K. Lipp  Rodger Stokes  Joan B. Rose 《Estuaries and Coasts》2000,23(5):662-668

Viral tracer studies have been used previously to study the potential for wastewater contamination of surface marine waters in the Upper and Middle Florida Keys. Two bacteriophages, the marine bacteriophage ϕHSIC and theSalmonella phage PRD1, were used as tracers in injection well and septic tank studies in Saddlebunch Keys of the Lower Florida Keys and in septic tank studies in Boot Key Harbor, Marathon, of the Middle Keys. In Boot Key Harbor, both phages were detected in a canal adjacent to the seeded septic tank within 3 h 15 min of the end of the seed period. The tracer was then detected at all sampling sites in Boot Key Harbor, including one on the opposite side of U.S. Highway 1 in Florida Bay, and at an Atlantic Ocean beach outside Boot Key Harbor. Rates of migration based on first appearance of the phage ranged from 1.7 to 57.5 m h⁻¹. In Saddlebunch Keys, ϕHSIC and PRD1 were used to seed a residential septic tank and a commercial injection well. The septic tank tracer was not found in any surface water samples. The injection well tracer was first detected at a site most distant from the seed site, a channel that connected Sugarloaf Sound with the Atlantic Ocean. The, rate of tracer migration from the injection well to this channel ranged from 66.8 to 141 m h⁻¹. Both tracer studies showed a rapid movement of wastewater from on-site sewage treatment and disposal systems in a southeasterly direction toward the reef tract and Atlantic Ocean, with preferential movement through tidal channels. These studies indicate that wastewater disposal systems currently in widespread use in the Florida Keys can rapidly contaminate the marine environment.  相似文献   

Catalogue of large alluvial fans in martian impact craters     

Erin R. Kraal  Erik Asphaug  Alan Howard 《Icarus》2008,194(1):101-110

We conducted a systematic, global survey using Thermal Emission Imaging System Infrared (THEMIS IR) coverage (∼100 m/pixel) to search for large alluvial fans in impact craters on Mars. Our survey has focused on large fans (apron areas greater than ∼40 km², usually located in craters greater than 20 km in diameter) due to the resolution of the THEMIS images and Mars Orbiter Laser Altimeter (MOLA) coverage. We find that the host craters are found to have a distinctive diameter range from 30-150 km. The fans generally cluster in three geographic areas—southern Margaritifer Terra, southwestern Terra Sabaea, and southwestern Tyrrhena Terra, however several outliers do exist. The alluvial fans do not form in a particular orientation along the crater rim nor are they associated with the location of current high rim topography. Fan area magnitude and variability increase with crater diameter while fan concavity magnitude and variability increase with decreasing crater diameter. Smaller fan aprons in general have higher, more variable concavity. The source of the water forming these fans is uncertain given the challenges of accommodating the global distribution pattern and formation patterns within the craters.  相似文献   

Effects of land use on ground water quality in the Anoka Sand Plain Aquifer of Minnesota   总被引：6，自引：0，他引：6  

Trojan MD  Maloney JS  Stockinger JM  Eid EP  Lahtinen MJ 《Ground water》2003,41(4):482-492

We began a study, in 1996, to compare ground water quality under irrigated and nonirrigated agriculture, sewered and nonsewered residential developments, industrial, and nondeveloped land uses. Twenty-three monitoring wells were completed in the upper meter of an unconfined sand aquifer. Between 1997 and 2000, sampling occurred quarterly for major ions, trace inorganic chemicals, volatile organic compounds (VOCs), herbicides, and herbicide degradates. On single occasions, we collected samples for polynuclear aromatic hydrocarbons (PAHs), perchlorate, and coliform bacteria. We observed significant differences in water chemistry beneath different land uses. Concentrations of several trace inorganic chemicals were greatest under sewered urban areas. VOC detection frequencies were 100% in commercial areas, 52% in sewered residential areas, and <10% for other land uses. Median nitrate concentrations were greatest under irrigated agriculture (15,350 microg/L) and nonsewered residential areas (6080 microg/L). Herbicides and degradates of acetanilide and triazine herbicides were detected in 86% of samples from irrigated agricultural areas, 68% of samples from nonirrigated areas, and <10% of samples from other land uses. Degradates accounted for 96% of the reported herbicide mass. We did not observe seasonal differences in water chemistry, but observed trends in water chemistry when land use changes occurred. Our results show land use is the dominant factor affecting shallow ground water quality. Trend monitoring programs should focus on areas where land use is changing, while resource managers and planners must consider potential impacts of land use changes on ground water quality.  相似文献   

Groundwater development in Lemoa, Guatemala     

Erin Lepper  Andrew Curtis Elmore 《Environmental Geology》2005,48(1):49-56

In the rural Guatemalan Central Highlands, drinking water wells are a rare commodity due to lack of data regarding depth and sustainability of groundwater. At a study well in Lemoa, aquifer sustainability and other characteristics were estimated using hydrograph data and Theiss recovery method for pumping tests. These tests showed that while specific capacity remained fairly constant, transmissivity increased, indicating development of the well subsequent to installation of the study well. The time domain electromagnetic (TDEM) method was evaluated at the site as a prospective groundwater prospecting technique. Characterization of subsurface conditions using TDEM is feasible with local subsurface data for correlation; however, it is limited to delineating low electrical resistive zones without geologic data for correlation. Data showed that groundwater produced from volcanic alluvium at approximately 79 m in depth is sustainable at the study area at current use rates.  相似文献   

Secondary mineral formation associated with respiration of nontronite,NAu-1 by iron reducing bacteria     

S?Erin?O'Reilly  Janet?Watkins  Yoko?FurukawaEmail author 《Geochemical transactions》2005,6(4):67

Experimental batch and miscible-flow cultures were studied in order to determine the mechanistic pathways of microbial Fe(III) respiration in ferruginous smectite clay, NAu-1. The primary purpose was to resolve if alteration of smectite and release of Fe precedes microbial respiration. Alteration of NAu-1, represented by the morphological and mineralogical changes, occurred regardless of the extent of microbial Fe(III) reduction in all of our experimental systems, including those that contained heat-killed bacteria and those in which O₂, rather than Fe(III), was the primary terminal electron acceptor. The solid alteration products observed under transmission electron microscopy included poorly crystalline smectite with diffuse electron diffraction signals, discrete grains of Fe-free amorphous aluminosilicate with increased Al/Si ratio, Fe-rich grains, and amorphous Si globules in the immediate vicinity of bacterial cells and extracellular polymeric substances. In reducing systems, Fe was also found as siderite. The small amount of Fe partitioned to the aqueous phase was primarily in the form of dissolved Fe(III) species even in the systems in which Fe(III) was the primary terminal electron acceptor for microbial respiration. From these observations, we conclude that microbial respiration of Fe(III) in our laboratory systems proceeded through the following: (1) alteration of NAu-1 and concurrent release of Fe(III) from the octahedral sheets of NAu-1; and (2) subsequent microbial respiration of Fe(III).  相似文献   

P-T evolution of metasediments from the Eclogite Zone, south-central Tauern Window, Austria   总被引：2，自引：0，他引：2  

F.S. Spear  G. Franz 《Lithos》1986,19(3-4):219-234

Petrologic data on the paragenesis of (I) kyanite-zoisite marbles and (II) garnet-chloritoid quartz-mica schists are presented with the goal of providing constraints on the pressure-temperature evolution of the Eclogite Zone, Tauern Window, Austria. The peak metamorphic assemblages in the two rock types are: (I) kyanite + zoisite + dolomite + quartz; zoisite + muscovite + dolomite + calcite + quartz; and (II) garnet + chloritoid + kyanite + muscovite + quartz + epidote ± dolomite ± Zn-staurolite. The estimated peak metamorphic conditions are 19 ± 2 kbar, 590 ± 20°C.

Secondary alteration of the kyanite-zoisite marbles was accomplished in two stages. The early stage resulted in the production of margarite, paragonite, secondary muscovite and chlorite and the later stage resulted in the formation of sudoite (a di/trioctahedral Mg---Al layer silicate) and kaolinite. The early alteration is bracketed at conditions between 3 and 10 kbar, 450–550°C and the later alteration between 200 and 350°C, P 3 kbar.

The P-T path is characterized by maximum burial to approximately 19 kbar (60–70 km) (at≈590°C), followed by nearly isothermal decompression to approximately 10 kbar (30 km), and then more gradual decompression with cooling to approximately 3 kbar (10 km). Alteration was apparently accomplished by the influx of H₂O-rich fluids, with the composition of the fluid locally buffered by the mineral assemblage.  相似文献   

Amphibole-plagioclase equilibria: An empirical model for the relation albite+tremolite=edenite+4 quartz   总被引：2，自引：0，他引：2  

Frank S. Spear 《Contributions to Mineralogy and Petrology》1981,77(4):355-364

Equilibria between plagioclase, calcic amphibole and quartz can be described, in part, by the relation among mineral components: NaAlSi₃O₈+Ca₂Mg₅Si₈O₂₂(OH)₂ = NaCa₂Mg₅AlSi₇O₂₂(OH)₂+4SiO₂; this relation governs the partitioning of Na between plagioclase and the A-site of coexisting amphibole. Data from natural amphibolites reveal that this partitioning is systematic and sensitive to metamorphic grade. The ideal portion of the equilibrium constant (K _id = X _{Na, A}/X_{, A} · X _Ab) derived from natural samples is sensitive to bulk composition, inasmuch as both plagioclase and amphibole are highly non-ideal. Samples from a single outcrop have values ranging from 0.5 (X _Ab=0.74) to 4.1 (X _Ab=0.10). The continuous reaction, NaAlSi₃O₈+Ca₂Mg₅Si₈O₂₂(OH)₂ = NaCa₂Mg₅AlSi₇O₂₂(OH)₂+4SiO₂, proceeds to the right with increasing grade of metamorphism and for a given bulk composition, K _id increases with increasing temperature. Two related discontinuous reactions, actinolite+albite=hornblende+oligoclase+quartz and actinolite+oligoclase=hornblende+anorthite+quartz, also proceed to the right with increasing metamorphic grade and result in changes in the topology of a phase diagram that describes the partitioning of Na between plagioclase and amphibole A-site. A Schreinemakers' net is presented that is consistent with natural occurrences. The results of this study should aid in the delineation of metamorphic facies within amphibolites.  相似文献