Evidence for Strong Copper(I) Complexation by Organic Ligands in Seawater     

M. Fernanda C. Leal  Constant M. G. Van Den Berg 《Aquatic Geochemistry》1998,4(1):49-75

Thiols like glutathione and cysteine form such stable complexes with copper(I) that they preclude the presence of copper(II). Conventionally seawater is titrated with copper(II) whilst monitoring the labile or reactive copper concentration by voltammetry or with other techniques, to determine the concentration of copper(II) binding complexing ligands in seawater. Titrations of seawater to which copper(I) binding ligands have been added reveal that the copper(I) binding ligands are detected when seawater is titrated with copper(II). The copper(II) in seawater is reduced to copper(I) within 2 to 40 minutes depending on the nature of the copper(I) binding ligand. The titrations of seawater with copper(II) thus give a response to the presence of copper(I) binding ligands indiscernible from that for copper(II) binding ligands. The stoichiometry of the detected apparent ligand concentrations for given concentrations of glutathione and cysteine suggest that 2 : 1 (thiol : Cu) complexes are formed. This was confirmed using voltammetry of free glutathione. Values of 21.2 and 22.2 were found for log _CuL for glutathione and cysteine respectively (for the reaction of Cu + 2L CuL₂). The complex stability is similar to that of natural organic species in the oceanic water column. The high stability of the copper(I) complexes was apparent from values of 32.1 and 32.6 for log Cu(I)L2 (for the reaction Cu⁺ + 2L CuL₂) for the copper(I) complexes with glutathione and cysteine in seawater. Glutathione and other thiols are common in the marine system including the water column. It is therefore possible that at least some of the ligands detected in seawater, and previously assumed to be copper(II) binding ligands, are in fact strongly complexed as copper(I). The copper(I) oxidation state may thus be stabilised in seawater.  相似文献   

Bulk transfer velocity to and from natural and artificial surfaces     

Fernanda Trombetti  Marina Caporaloni  Francesco Tampieri 《Boundary-Layer Meteorology》1978,14(4):585-595

A wide set of published mass and heat transfer data is reviewed in terms of the stochastic renewal theory. A simple model is then proposed describing the transfer in terms of the fluid bulk properties. Two expressions are presented and they enable us to evaluate the bulk transfer velocity as a function of the turbulence of the flow for smooth and fully-rough surfaces in large ranges of Schmidt (or Prandtl) and Reynolds numbers. The transfer over transitional surfaces can also be evaluated by using a simple criterion for the choice of the right expression. The proposed relationships agree satisfactorily with data from laboratory and atmospheric measurements, for both solid and liquid surfaces.  相似文献   

Zircon saturation in silicate melts: a new and improved model for aluminous and alkaline melts   总被引：1，自引：0，他引：1  

Fernanda Gervasoni  Stephan Klemme  Eduardo R.V. Rocha-Júnior  Jasper Berndt 《Contributions to Mineralogy and Petrology》2016,171(3):21

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Low-latitude “dusty events” vs. high-latitude “icy Heinrich events”     

Elsa Jullien  Francis Grousset  Bruno Malaiz  Josette Duprat  Maria Fernanda Sanchez-Goni  Frdrique Eynaud  Karine Charlier  Ralph Schneider  Aloys Bory  Viviane Bout  Jose Abel Flores 《Quaternary Research》2007,68(3):379-386

It has been proposed that tropical events could have participated in the triggering of the classic, high-latitude, iceberg-discharge Heinrich events (HE). We explore low-latitude Heinrich events equivalents at high resolution, in a piston core recovered from the tropical north-western African margin. They are characterized by an increase of total dust, lacustrine diatoms and fibrous lacustrine clay minerals. Thus, low-latitude events clearly reflect severe aridity events that occurred over Africa at the Saharan latitudes, probably induced by southward shifts of the Inter Tropical Convergence Zone. At a first approximation, it seems that there is more likely synchronicity between the high-latitude Heinrich Events (HEs) and low-latitude events (LLE), rather than asynchronous behaviours.  相似文献   

Chemical Characterisation of Chromites by XRF Spectrometry     

Maria Fernanda Gazulla  Antonio Barba  María Pilar Gómez  Monica Orduña 《Geostandards and Geoanalytical Research》2006,30(3):237-243

The present study was undertaken to establish and validate a methodology for determining the chemical composition of chromite ores, as no detailed information could be found in the literature. Chromite ores from South Africa, Kazajistan and Mongolia were analysed. X-ray fluorescence (XRF) spectrometry was used for chemical characterisation. Sample preparation in the form of fused beads was optimised in terms of sample:flux ratio, type of flux, type of release agent, fusion temperature and time. Calibration and validation samples were prepared from mixtures of reference materials. The proposed methodology was then used in an interlaboratory test for preparing a new chromite-rich reference material.
L'analyse présentée id a été entreprise afin d'établir et de valider une méthodologie pour déterminer la composition chimique de minerals de chromite, car aucune information détaillée là dessus ne pouvait etre trouvée dans la littérature. Des minerals de chromite d'Afrique du Sud, du Kazakhstan et de Mongolie ont été analysés par spectrométrie de Fluorescence de Rayons X (XRF) afin d'être caractérisés chimiquement. La préparation des échantillons afin d'obtenir des perles fondues a été optimisée en termes du rapport "échantillon/fondant", type de fondant, d'agent mouillant, température et durée de fusion. La calibration et la validation ont été faites à partir de mixtures de matériau de référence. La méthodologie proposée a été ensuite appliquée à un test d'inter-comparaison en vue de préparer un nouveau matériau de référence riche en chromite .  相似文献   

Plastic ingestion by Procellariiformes in Southern Brazil     

Colabuono FI  Barquete V  Domingues BS  Montone RC 《Marine pollution bulletin》2009,58(1):93-96

The Procellariiformes are the birds most affected by plastic pollution. Plastic fragments and pellets were the most frequent items found in the digestive tract of eight species of Procellariiformes incidentally caught by longline fisheries as well as beached birds in Southern Brazil. Plastic objects were found in 62% of the petrels and 12% of the albatrosses. The Great shearwater, Manx shearwater, Cory's shearwater and Antarctic fulmar were found to have greater quantities and frequencies of occurrence of plastic. There was no significant difference in the number of plastics between the birds from longline fisheries and beached birds. No correlation was found between the number of prey and number of plastics in the digestive tract of the birds analyzed, but this does not discard the hypothesis that, in some cases, the presence of plastic in the digestive tract has a negative effect on the feeding efficiency of these birds.  相似文献   

Chlorinated pesticides, polychlorinated biphenyls and polycyclic aromatic hydrocarbons in the fat tissue of seabirds from King George Island, Antarctica     

Satie Taniguchi  Rosalinda C. Montone  Fernanda Imperatrice Colabuono  Jose L. Sericano 《Marine pollution bulletin》2009,58(1):129-133

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The glutathione antioxidant system as a biomarker suite for the assessment of heavy metal exposure and effect in the grey mangrove, Avicennia marina (Forsk.) Vierh   总被引：1，自引：0，他引：1  

Caregnato FF  Koller CE  MacFarlane GR  Moreira JC 《Marine pollution bulletin》2008,56(6):1119-1127

Alterations in the glutathione antioxidant system and lipid peroxidation in Avicennia marina were studied under laboratory and field conditions. The activity of glutathione peroxidase (GPx) was found to respond to Zn exposure, and a significant positive relationship between leaf Zn concentration and GPx activity was observed after 96 h and 8 weeks. Lipid hydroperoxides increased proportionally with increasing leaf Zn concentration after 2 and 8 weeks, while no changes in total glutathione were observed. Induction of GPx at 96 h predicted effects at the individual level at a later time interval (reduced biomass at 8 weeks). Results from the field revealed that increasing leaf metal concentration (Zn, Cu or Pb) produced a proportional increase in GPx activity whereas lipid hydroperoxides and total glutathione were not affected. The utility of GPx as an early warning biomarker is suggested, since GPx activity increases in a dose-dependant fashion in response to accumulated leaf metals, and is predictive of later effects on growth.  相似文献   

Phytoplankton functional groups: Short‐term variation in a tropical tidal‐forced estuarine system     

Helen Michelle de Jesus Affe  Fernanda Reinhardt Piedras  Lucineide Maria Santana  Gleyci Aparecida Oliveira Moser  Maringela Menezes  Jos Marcos de Castro Nunes 《Marine Ecology》2019,40(4)

Functional groups have become an important tool for characterizing communities of marine and estuarine environments. Their use also holds promise for a better understanding of the temporal dynamics of phytoplankton. This study aimed to evaluate the contributions of phytoplankton size fractions and functional groups characterizing short‐term variation throughout tidal cycles and between dry and rainy seasons in a tropical estuarine system. Camamu Bay is an oligotrophic estuarine system that is under strong influence from tropical shelf waters and is characterized by high salinity and low concentrations of dissolved nutrients. Surface‐water samples were collected at nine sampling sites distributed among the three hydrodynamic regions of the bay, and at a mooring, at 3‐hr intervals during tidal cycles (12 hr each) in both the rainy and the dry season. Although the abundances of the phytoplankton fractions (pico‐, nano‐, and micro‐) were higher in the rainy season and during periods of higher tide, they were not significantly higher. The phytoplankton community in the bay comprises three functional groups: GI = “colonial” (i.e., chain‐forming diatoms and filamentous cyanobacteria); GII = “GALD >40” (i.e., pennate and centric diatoms with MDL >40 µm), and GIII = “flagellates” (i.e., species with motility via flagella). Nanoflagellates were the most abundant form in the bay, while chain‐forming diatoms, in particular, contributed to the microphytoplankton fraction during both the rainy and dry seasons. Functional groups, as defined by cluster analysis, reflected ecological strategies compatible with the high hydrodynamics of Camamu Bay, which is characterized by processes of tidal‐forced intense mixing, mainly during periods of spring tides. The phytoplankton of the bay was found to possess a series of attributes (functional traits) that endow them with some resistance to sinking. Functional diversity indexes (FEve, FDiv, and FDis) indicated a stable community without significant short‐term variation due to low variability in the environmental conditions of the system during the study period.  相似文献   

Community structure and functional traits of mollusks associated with coastal reef macroalgae in Northeastern Brazil     

Dbora Ferreira Barbosa  Thelma Lúcia Pereira Dias  Srgio de Faria Lopes  Rafaela Cristina de Souza Duarte  Fernanda Maria Duarte do Amaral 《Marine Ecology》2019,40(5)

This study investigated the community structure and functional traits of the mollusk fauna associated with macroalgae with different thallus morphologies in a reef environment in Northeastern Brazil. A total of 15 individuals of each species of macroalgae adhered to natural substrate and 15 individuals of Padina gymnospora detached from the substrate were collected. The structural complexity of algal habitats was measured and the associated malacofauna screened and identified. All three macroalgae differed significantly in the complexity of their habitat, with Sargassum polyceratium being the most complex. A total of 823 specimens of mollusks belonging to 22 species and 11 families were recorded, of which Columbellidae was the most represented with six species. The functional trait “size” revealed that micromollusks smaller than 10 millimeters were predominant in the community; however, individuals of larger sizes (up to 24.54 millimeters) belonging to young stages of other species were also present. Eight functional trophic groups were identified, of which “carnivorous” stood out with seven species. Six functional groups of microhabitats were identified, with intra‐specific variation in habitats, while habitat expansion was documented for species not yet recorded in association with macroalgae. The structure of the molluskan community differed among the three algae species with the greatest richness, abundance, and diversity of mollusks and functional traits occurring with S. polyceratium. Community structure differed between algae adhered to natural substrate and detached algae, with the latter having lower mollusk richness and diversity, but with greater abundance of some species that remained on algal fronds after release from the reef environment. This study reinforces the importance of algal habitat for marine invertebrate fauna, especially for micromollusks that spend their entire life cycle, or part of it, in association with macroalgae.  相似文献