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21.
This study presents U–Pb ages for zircon, titanite, allanite and epidote, and initial Hf isotopic compositions for zircon of Upper Carboniferous granites, diorites and syenites from the Aar massif, central Alps. The rocks were emplaced during three magmatic pulses after Hercynian collisional tectonics: (A) a shoshonitic-ultrapotassic series at 334±2.5 Ma; (B) scattered diorites and granites at 308–310 Ma; and (C) a high-K cale-alkaline granite batholith at 298±2 Ma. Inheritance of old zircons is negligible among all three groups. The Southern Aar granite, in contrast, is a syn-tectonic, probably ca. 350 Ma old granite that contains large amounts of inherited Precambrian zircons. Alpine metamorphism caused weak lead loss in many analyzed zircon fractions, but left the titanite U–Pb system undisturbed: thorites were almost completely reset by Alpine and recent lead loss. Mineral isochrons defined by titanite, allanite, epidote and apatite yield initial Pb isotopic compositions that are in agreement with the model values of Stacey and Kramers. Initial Hf isotopic compositions range from Hf=–8 to +3.5. The data follow a trend of increasing Hf with decreasing age. The Hf versus element concentration relationships suggest mixing between a mantle and a crustal component. These relationships can be explained in terms of generation of the melts from a subcontinental mantle that had been enriched during subduction events at about 1 Ga and by 300 Ma had developed an isotopic signature distinct from that of MORB-type mantle. Further contamination of the melts occurred during ascent and differentiation in the crust. This late Hercynian magmatism can be related to post-collisional strike-slip tectonics.  相似文献   
22.
Preliminary results on new CCD photometry inV andB bands of approximately 5000 stars in four overlapping fields in the globular cluster M3 are presented. The colour-magnitude diagram shows a very well-defined sequence with a small scatter, going fainter than previously published work on this cluster. The turn-off point found atV=19.1±0.2 mag and (B-V)=0.445±0.01, is slightly redder than those obtained in previous studies.Paper presented at the 11th European Regional Astronomical Meetings of the IAU on New Windows to the Universe, held 3–8 July, 1989, Tenerife, Canary Islands, Spain.  相似文献   
23.
The global behaviour and fine structure of the distribution of sunspot decay rates from activity cycle 13 to 20 are presented. It is shown that the distribution of this parameter is lognormal. Statistically significantly lower values of decay rates are found in cycles 13, 14, and 18 for isolated spots. The complex groups had no appreciable changes.Paper presented at the 11th European Regional Astronomical Meetings of the IAU on New Windows to the Universe, held 3–8 July, 1989, Tenerife, Canary Islands, Spain.  相似文献   
24.
Multi-equilibrium thermobarometry shows that low-grade metapelites (Cubito-Moura schists) from the Ossa–Morena Zone underwent HP–LT metamorphism from 340–370 °C at 1.0–0.9 GPa to 400–450 °C at 0.8–0.7 GPa. These HP–LT equilibriums were reached by parageneses including white K mica, chlorite and chloritoid, which define the earliest schistosity (S1) in these rocks. The main foliation in the schists is a crenulation cleavage (S2), which developed during decompression from 0.8–0.7 to 0.4–0.3 GPa at increasing temperatures from 400–450 °C to 440–465 °C. Fe3+ in chlorite decreased greatly during prograde metamorphism from molar fractions of 0.4 determined in syn-S1 chlorites down to 0.1 in syn-S2 chlorites. These new data add to previous findings of eclogites in the Moura schists indicating that a pile of allochtonous rocks situated next to the Beja-Acebuches oceanic amphibolites underwent HP–LT metamorphism during the Variscan orogeny. To cite this article: G. Booth-Rea et al., C. R. Geoscience 338 (2006).  相似文献   
25.
Crystallization under confinement conditions is a very important process in geochemistry and geophysics. Computer simulations of fluids in nanometer scale pore spaces can provide a unique microscopic insight into the structure, dynamics and forces arising from the crystallization process. We discuss in this paper molecular dynamics computer simulations of crystallization in pores of nanometer dimensions. The crystallization pressure due to the freezing of a model of Argon in a nanopore is computed using molecular dynamics simulations. We also investigate the influence of pore geometry in determining the dynamics of confined fluids, as well as mass separation in binary mixtures. It turns out that the pore geometry reveals itself as an important variable, leading to 1) new mechanisms for fast diffusion in confined spaces, and 2) accumulation of solute in specific regions inside the pore.  相似文献   
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27.
The Dalsfjord Complex is an allochthonous crystalline unit in the hanging wall of a major extensional detachment of the Caledonian orogen on the western coast of Norway. U-Pb geochronology has been carried out to test a previously proposed correlation between this unit and the Jotun Nappe Complex, a member of the Middle Allochthon now occupying a foreland position to the east. A monzonite sample of the Dalsfjord suite yields a zircon age of 1,634Dž Ma, whereas a crosscutting gabbro was formed at 1,464Lj Ma. Both rocks were strongly overprinted during the Sveconorwegian orogeny, especially the monzonite whose zircons U-Pb data were strongly pulled towards a lower intercept age of 882ᆱ Ma, and whose titanite indicates a two-stage growth history at >960 Ma and <920 Ma. These relationships support the correlation of these units with the Jotun Complex, and to some degree also with the Lindås Nappe in the Bergen Arcs.  相似文献   
28.
Rhenium and osmium isotopes in sulfide minerals from the Bagdad porphyry Cu–Mo deposit have been used to determine timing of mineralization and the source of osmium and, by inference, ore metals. Molybdenite, chalcopyrite and pyrite were analyzed mainly from the quartz monzonite and porphyritic quartz monzonite units, which are characterized by moderate to strong potassic alteration (secondary biotite and K-feldspar). Rhenium concentrations in molybdenite are between 330 and 642 ppm. Four Re–Os analyses of two molybdenite samples from the quartz monzonite and porphyritic quartz monzonite yield a weighted average age of 71.8±0.2 Ma (2s). Analyses of a third sample from a molybdenite vein in Precambrian rocks, outside of the main ore zone, yield a weighted average age of 75.9±0.2 Ma (2s), and provide evidence of two separate mineralization episodes. Chalcopyrite samples contain 6 to 12 ppt Os and 1.7 to 4.1 ppb Re; 187Os/ 188Os initial ratios are between 0.1 and 0.8. Pyrite samples have osmium and rhenium concentrations varying in the range 8–17 ppt and 3.9–6.8 ppb, respectively. Analyses from these pyrite samples yield an eight-point isochron with an age of 77±15 Ma (2s) and an initial 187Os/ 188Os ratio of 2.1±0.8 (MSWD=0.90). The results presented here add to the growing body of work indicating that porphyry-type mineralization is produced by long-term, multiple episodes of magmatism and associated mineralization. The data also support the hypothesis that a significant part of the metals and magmas may have a crustal source, as has been suggested for other copper deposits and districts in Arizona.  相似文献   
29.
. A isotope dilution thermal ionisation mass spectrometry U-Pb geochronological study was carried out on the high-pressure and high-temperature units (HP-HT units) overlying the oceanic suture in the Allochthonous Complexes of the NW Iberian Variscan Belt. The rocks investigated are seven granulite- to eclogite-facies paragneisses and one leucosome within mafic high-pressure granulites in the Ordenes and Cabo Ortegal Complexes of NW Spain. U-Pb dating of zircon, monazite, titanite and rutile reveal the presence of a pervasive Early Ordovician metamorphic event at ca. 500-480 Ma and a later Early Devonian event at ca. 400-380 Ma. The U-Pb ages, in conjunction with petrological and structural data, indicate that the high-pressure event recorded by these rocks is Early Ordovician in age. Monazite ages in the paragneisses suggest that peak metamorphic conditions were reached at ca. 500-485 Ma. Subsequently, the rock ensemble underwent exhumation accompanied by partial melting and zircon growth at ca. 485-470 Ma. Melting of mafic granulites was coeval with this latter episode as indicated by zircon crystallisation age in the leucosomes dated at ca. 486 Ma. Based on these data and on the general features of magmatism and metamorphic evolution, it is proposed that this process took place at a convergent plate boundary within a peri-Gondwanan oceanic domain. Monazite, titanite and rutile data in some of the samples studied show evidence of a second metamorphic episode that took place between ca. 400 and 380 Ma (with a peak at ca. 390-385 Ma). This Early Devonian event, at variance with the previous one, was not pervasive, but, rather, was localised in areas of intense Variscan tectonothermal reworking. It is claimed that this later metamorphic event was recorded by the U-Pb system in areas where monazite and titanite growth was enhanced by fluid circulation in highly strained rocks (Variscan shear zones). According to previous structural studies and Ar-Ar dating of fabrics, this Early Devonian episode took place as the HP-HT units were deformed and thrusted upon the ophiolitic units in the early stages of the Variscan collision.  相似文献   
30.
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