Isotopic evidence on the diagenetic evolution of coastal sabkha reservoirs from the Solimões Basin, northern Brazil     

Andreia Dias Elias  Luiz Fernando De Ros  Ana Maria Mizusaki  Koji Kawashita 《Gondwana Research》2007,11(4):553-567

The isotopic composition of diagenetic carbonates, sulfates, illites and associated diagenetic constituents of the Carboniferous Juruá sandstones, Solimões Basin, largest hydrocarbon reservoirs of northern Brazil, was analyzed in conjunction with petrographic characterization and chemical composition. Eolian Juruá sandstones, deposited in a coastal sabkha of a wide cratonic sag, are the best reservoirs, but diagenetic processes introduced strong and complex heterogeneities, which affect hydrocarbon production. Dolomite and anhydrite cementation, together with compaction, exerts the main control on the quality of the reservoirs. Early dolomite cements precipitated under strong evaporation, while late dolomites are related to thermal decarboxylation. Late anhydrite cements are related to the interbedded evaporites and possibly to the oxidation of dissolved sulfide. Authigenic illite K–Ar ages are related to the voluminous Triassic basic magmatism (around 200 Ma), and to the Jurassic–Cretaceous tectonism (around 150 Ma), which may have also affected the late anhydrite and dolomite–ankerite cementation. This isotopic study revealed the major conditions of the diagenetic processes that strongly affected the Juruá reservoirs, which are essential for the development of models that will optimize the production, as well as decrease the risks in the exploration for new Juruá reservoirs.  相似文献   

Projection of future climate change conditions using IPCC simulations, neural networks and Bayesian statistics. Part 1: Temperature mean state and seasonal cycle in South America     

Jean-Philippe Boulanger  Fernando Martinez  Enrique C. Segura 《Climate Dynamics》2006,27(2-3):233-259

Projections for South America of future climate change conditions in mean state and seasonal cycle for temperature during the twenty-first century are discussed. Our analysis includes one simulation of seven Atmospheric-Ocean Global Circulation Models, which participated in the Intergovernmental Panel on Climate Change Project and provided at least one simulation for the twentieth century (20c3m) and one simulation for each of three Special Report on Emissions Scenarios (SRES) A2, A1B, and B1. We developed a statistical method based on neural networks and Bayesian statistics to evaluate the models’ skills in simulating late twentieth century temperature over continental areas. Some criteria [model weight indices (MWIs)] are computed allowing comparing over such large regions how each model captures the temperature large scale structures and contributes to the multi-model combination. As the study demonstrates, the use of neural networks, optimized by Bayesian statistics, leads to two major results. First, the MWIs can be interpreted as optimal weights for a linear combination of the climate models. Second, the comparison between the neural network projection of twenty-first century conditions and a linear combination of such conditions allows the identification of the regions, which will most probably change, according to model biases and model ensemble variance. Model simulations in the southern tip of South America and along the Chilean and Peruvian coasts or in the northern coasts of South America (Venezuela, Guiana) are particularly poor. Overall, our results present an upper bound of potential temperature warming for each scenario. Spatially, in SRES A2, our major findings are that Tropical South America could warm up by about 4°C, while southern South America (SSA) would also undergo a near 2–3°C average warming. Interestingly, this annual mean temperature trend is modulated by the seasonal cycle in a contrasted way according to the regions. In SSA, the amplitude of the seasonal cycle tends to increase, while in northern South America, the amplitude of the seasonal cycle would be reduced leading to much milder winters. We show that all the scenarios have similar patterns and only differ in amplitude. SRES A1B differ from SRES A2 mainly for the late twenty-first century, reaching more or less an 80–90% amplitude compared to SRES A2. SRES B1, however, diverges from the other scenarios as soon as 2025. For the late twenty-first century, SRES B1 displays amplitudes, which are about half those of SRES A2.  相似文献   

Back-arc basin basalt systematics   总被引：7，自引：0，他引：7  

Brian Taylor  Fernando Martinez 《Earth and Planetary Science Letters》2003,210(3-4):481-497

The Mariana, east Scotia, Lau, and Manus back-arc basins (BABs) have spreading rates that vary from slow (<50 mm/yr) to fast (>100 mm/yr) and extension axes located from 10 to 400 km behind their island arcs. Axial lava compositions from these BABs indicate melting of mid-ocean ridge basalt (MORB)-like sources in proportion to the amount added of previously depleted, water-rich, arc-like components. The arc-like end-members are characterized by low Na, Ti and Fe, and by high H₂O and Ba/La; the MORB-like end-members have the opposite traits. Comparisons between basins show that the least hydrous compositions follow global MORB systematics and an inverse correlation between Na8 and Fe8. This is interpreted as a positive correlation between the average degree and pressure of mantle melting that reflects regional variations in mantle potential temperatures (Lau/Manus hotter than Mariana/Scotia). This interpretation accords with numerical model predictions that faster subduction-induced advection will maintain a hotter mantle wedge. The primary compositional trends within each BAB (a positive correlation between Fe8, Na8 and Ti8, and their inverse correlation with H₂O(8) and Ba/La) are controlled by variations in water content, melt extraction, and enrichments imposed by slab and mantle wedge processes. Systematic axial depth (as a proxy for crustal production) variations with distance from the island arc indicate that compositional controls on melting dominate over spreading rate. Hydrous fluxing enhances decompression melting, allowing depleted mantle sources just behind the island arc to melt extensively, producing shallow spreading axes. Flow of enriched mantle components around the ends of slabs may augment this process in transform-bounded back-arcs such as the east Scotia Basin. The re-circulation (by mantle wedge corner flow) to the spreading axes of mantle previously depleted by both arc and spreading melt extraction can explain the greater depths and thinner crust of the East Lau Spreading Center, Manus Southern Rifts, and Mariana Trough and the very depleted lavas of east Scotia segments E8/E9. The crust becomes mid-ocean ridge (MOR)-like where the spreading axes, further away from the island arc and subducted slab, entrain dominantly fertile mantle.  相似文献   

DEVELOPMENT OF A LOW-COST MOBILE MAPPING SYSTEM: A SOUTH AMERICAN EXPERIENCE   总被引：2，自引：0，他引：2  

João Fernando C. da Silva  Paulo de Oliveira Camargo  Rodrigo B. A. Gallis 《The Photogrammetric Record》2003,18(101):5-26

This paper presents the prototype of a low-cost terrestrial mobile mapping system (MMS) composed of a van, two digital video cameras, two GPS receivers, a notebook computer, and a sound frame synchronisation system. The imaging sensors are mounted as a stereo video camera on top of the vehicle together with the GPS antennae. The GPS receivers and the notebook computer are configured to record data referred to the vehicle position at a planned time interval. This position is subsequently transferred to the road images. This set of equipment and methods provide the opportunity to merge distinct techniques to make topographic maps and also to build georeferenced road image databases. Both vector maps and raster image databases, when integrated appropriately, can give spatial researchers and engineers a new technique whose application may realise better planning and analysis related to the road environment. The experimental results proved that the MMS developed at the São Paulo State University is an effective approach to inspecting road pavements, to map road marks and traffic signs, electric power poles, telephone booths, drain pipes, and many other applications important to people's safety and welfare. A small number of road images have already been captured by the prototype as a consequence of its application in distinct projects. An efficient organisation of those images and the prompt access to them justify the need for building a georeferenced image database. By expanding it, both at the hardware and software levels, it is possible for engineers to analyse the entire road environment on their office computers.  相似文献   

Comparative geochemistry of cadmium, rhenium, uranium, and molybdenum in continental margin sediments     

BjØrn Sundby  Philippe Martinez  Charles Gobeil 《Geochimica et cosmochimica acta》2004,68(11):2485-2493

The concentrations of authigenic phases of Cd, Re, U, and Mo increase with depth in four 45-cm-long sediment box cores collected along the axis of the Laurentian Trough, Gulf of St. Lawrence. Average authigenic accumulation rates, estimated from element inventories, are similar to rates in other continental margin environments. Strong regional variations in sediment accumulation rate and sulfide concentration have little influence on the accumulation rates of Cd and Re. This suggests that slow precipitation kinetics controls the accumulation of Cd and Re in these sediments. The accumulation rate of authigenic U is more variable; it may be tied to the kinetics of microbially mediated U reduction and be controlled by the availability of reactive organic matter. Authigenic Mo is distinguished by a sharp subsurface concentration minimum, above which Mo cycles with manganese. Mo released to pore water upon reduction of Mn oxides diffuses downward and enriches the subsurface sediment. Mo accumulates most rapidly in the sediment with the highest sulfide content. Slow conversion of molybdate to thiomolybdate may explain the much slower Mo accumulation rate in the less sulfidic sediments. A component of authigenic Mo accumulates with pyrite in an approximately constant Mo:Fe ratio. The accumulation rate of pyrite and associated Mo is insensitive to AVS abundance. Pyrite formation may be limited by the reactivity of iron oxide minerals.  相似文献   

Controls on the geometry of tails around rigid circular inclusions: insights from analogue modelling in simple shear     

Santanu Bose  Fernando O. Marques   《Journal of Structural Geology》2004,26(12):2145-2156

We used analogue modelling to investigate the factors controlling tail geometry in porphyroclast systems. Results show that: (1) σ inclusions can develop in both slipping and non-slipping modes, but δ-inclusions only form in the latter. (2) σ inclusions develop when the mantle production rate is constant and the mantle is transected by the separatrix. δ inclusions form when the mantle is initially outside the separatrix and later comes inside this line. (3) In the slipping mode, the wedge-shaped tail of σ-inclusions always has a straight external surface parallel to the shear plane, whereas in the non-slipping mode the external surface is curved inwards (external embayments). (4) Together with earlier theoretical results, σ- and δ inclusions always show stair-stepping of tails when embedded in a viscous matrix under homogeneous simple shear deformation. (5) Maximum stair-stepping occurs in the slipping mode and is at least equal to the inclusion diameter. If our models bear significant similarity to nature, then (i) the straight or curved character of σ-inclusions could mean that they had, respectively, a slipping or non-slipping interface with the surrounding recrystallized matrix, and (ii) δ-inclusions may result from shear deformation under retrogressive metamorphic conditions in thrust systems.  相似文献   

The structure and the phyllosilicates (chemistry, crystallinity and texture) of Talas Ala-Tau (Tien Shan, Kyrgyz Republic): comparison with more recent subduction complexes     

Isabel Abad  Gabriel Gutirrez-Alonso  Fernando Nieto  Igor Gertner  Alex Becker  Ana Cabero 《Tectonophysics》2003,365(1-4):103

Geological mapping and structural analysis of the Talas Ala Tau (Tien Shan, Kyrgyz Republic) have revealed a complex structure composed of folds with axial-plane cleavage and thrust faults verging towards the NE. The main structures of the range correspond to minor Tertiary and Carboniferous–Permian deformation superimposed on the main deformation event that took place during the Baikalian orogeny. The pervasive axial-plane cleavage diminishes in penetrativity from the hinterland to the foreland in both the Uzunakhmat and Karagoin sheets. The main thrusts developed phyllonitic shear-related rocks on the hangingwall immediately above the thrust planes. A crystal-chemical study of the phyllosilicates growth during the Baikalian deformation event along a cross-section revealed changes in the crystallinity, composition and lattice parameters of them. The phyllosilicates present in the Talas Ala Tau rocks were crystallized in very low-grade metamorphic conditions, that is below 300 °C, as indicated by their Kübler Index (KI), which decreases from SW towards the NE. Detailed TEM study of the phyllosilicates reveals a clear textural difference at the lattice level between samples with higher or lower KI parameters. There is also a clear difference in crystal-chemical parameters (KI and b) and composition between the phyllosilicates growth in relation to the axial-plane cleavage and the ones belonging to the thrust-related phyllonites. The first ones are more affected by the ferrimuscovitic vector than the phyllosilicates of phyllonites, closer to the theoretical phengitic component. Huge ranges of values of phengitic content of micas at sample level are interpreted as the result of a decompression path from at least 8 kbar. We propose a subduction geodynamic environment for the regional deformation and the origin of the phyllosilicates, as they are similar to those obtained in more recent accretionary complexes.  相似文献   

The pulsating λ Bootis star HD 105759     

Peter Martinez    C. Koen    G. Handler  & E. Paunzen 《Monthly notices of the Royal Astronomical Society》1998,301(4):1099-1103

We present spectroscopic and multisite time series photometric observations of the star HD 105759 which confirm that this is a new pulsating λ Bootis star. Our spectroscopy indicates an overall metallicity of [Z] = log Z − log Z_⊙ = −1 and that T _eff = 8000 ± 300 K and log  g  = 4.0 ± 0.2. The photometric data reveal that this star pulsates with at least five frequencies: 8.62, 12.69, 20.15, 21.27 and 23.66 d⁻¹. These frequencies do not all match those found in an earlier single-site study, indicating that the pulsation spectrum changes with time.  相似文献   

Non‐linear analysis of a collapsed reinforced concrete chimney     

Wei Huang  Phillip L. Gould  Raul Martinez  Gayle S. Johnson 《地震工程与结构动力学》2004,33(4):485-498

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Free Radicals and Fast Photochemistry during BERLIOZ   总被引：4，自引：0，他引：4  

U. Platt  B. Alicke  R. Dubois  A. Geyer  A. Hofzumahaus  F. Holland  M. Martinez  D. Mihelcic  T. Klüpfel  B. Lohrmann  W. Pätz  D. Perner  F. Rohrer  J. Schäfer  J. Stutz 《Journal of Atmospheric Chemistry》2002,42(1):359-394

The free radicals OH, HO₂, RO₂, and NO₃ are known to be the driving force for most chemical processes in the atmosphere. Since the low concentration of the above radicals makes measurements particularly difficult, only relatively few direct measurements of free radical concentrations have been reported to date.We present a comprehensive set of simultaneous radical measurements performed by Laser Induced Fluorescence (LIF), Matrix Isolation –Electron spin Resonance (MI-ESR), Peroxy Radical Chemical Amplification (PERCA), and Differential Optical Absorption Spectroscopy (DOAS) during the BERLIner OZonexperiment (BERLIOZ) during July and August of 1998 near Berlin, Germany. Most of the above radical species were measured by more than one technique and an intercomparison gave good agreement. This data set offered the possibility to study and quantify the role of each radical at a rural, semi-polluted site in the continental boundary layer and to investigate interconnections and dependencies among these free radicals.In general (box) modelled diurnal profiles of the different radicals reproduced the measurements quite well, however measured absolute levels are frequently lower than model predictions. These discrepancies point to disturbing deficiencies in our understanding of the chemical system in urban air masses.In addition considerable night-time peroxy radical production related to VOC reactions with NO₃ and O₃ could be quantified.  相似文献