Influence of physiology and climate on δD of leaf wax n-alkanes from C₃ and C₄ grasses     

Francesca A. Smith  Katherine H. Freeman 《Geochimica et cosmochimica acta》2006,70(5):1172-1187

We measured hydrogen isotope compositions (δD) of high-molecular-weight n-alkanes (C₂₇-C₃₃) from grasses grown in greenhouses and collected from the US Great Plains. In both cases, n-alkanes from C₄ grasses are enriched in D by more than 20‰ relative to those from C₃ grasses. The apparent enrichment factor (ε_C29-GW) between C₂₉n-alkane and greenhouse water is −165 ± 12‰ for C₃ grasses and −140 ± 15‰ for C₄ grasses. For samples from the Great Plains, δD values of C₂₉n-alkanes range from −280 to −136‰, with values for C₄ grasses ca. 21‰ more positive than those for C₃ grasses from the same site. Differences in C₃ and C₄ grass n-alkane δD values are consistent with the shorter interveinal distance in C₄ grass leaves, and greater back-diffusion of enriched water from stomata to veins, than in C₃ grass leaves. Great Plains’ grass n-alkane isotopic ratios largely reflect precipitation δD values. However, the offset or apparent fractionation between n-alkanes and precipitation is not uniform and varies with annual precipitation and relative humidity, suggesting climatic controls on lipid δD values. The dryer sites exhibit smaller absolute apparent fractionation indicative of D-enrichment of source waters through transpiration and/or soil evaporation. To explore the relationship between climate and n-alkane δD values, we develop three models. (1) The ‘direct analog’ model estimates δD_C29 values simply by applying the apparent enrichment factors, ε_C29-GW, observed in greenhouse grasses to precipitation δD values from the Great Plains. (2) The ‘leaf-water’ model uses a Craig-Gordon model to estimate transpirational D-enrichment for both greenhouse and field sites. The transpiration-corrected enrichment factors between C₂₉ and bulk leaf-water, ε_C29-GW, calculated from the greenhouse samples (−181‰ for C₃ and −157‰ for C₄) are applied to estimate δD_C29 values relative to modeled bulk leaf-water δD values. (3) The ‘soil- and leaf-water’ model estimates the combined effects of soil evaporation, modeled by analogy with a flow-through lake, and transpiration on δD_C29 values. Predictions improve with the addition of the explicit consideration of transpiration and soil evaporation, indicating that they are both important processes in determining plant lipid δD values. D-enrichment caused by these evaporative processes is controlled by relative humidity, suggesting that important climatic information is recorded in leaf wax n-alkane δD values. Calibration studies such as this one provide a baseline for future studies of plant-water-deuterium systematics and form the foundation for interpretation of plant wax hydrogen isotope ratios as a paleo-aridity proxy.  相似文献   

Shear wave splitting changes associated with the 2001 volcanic eruption on Mt Etna     

Francesca Bianco  Luciano Scarf&#;  Edoardo Del Pezzo  Domenico Patanè 《Geophysical Journal International》2006,167(2):959-967

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Particulate air pollution from wildfires in the Western US under climate change     

Jia Coco Liu  Loretta J. Mickley  Melissa P. Sulprizio  Francesca Dominici  Xu Yue  Keita Ebisu  Georgiana Brooke Anderson  Rafi F. A. Khan  Mercedes A. Bravo  Michelle L. Bell 《Climatic change》2016,135(3-4):655-668

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Hierarchical simulation of aquifer heterogeneity: implications of different simulation settings on solute-transport modeling     

Alessandro Comunian  Leonardo De Micheli  Claudio Lazzati  Fabrizio Felletti  Francesca Giacobbo  Mauro Giudici  Riccardo Bersezio 《Hydrogeology Journal》2016,24(2):319-334

The fine-scale heterogeneity of porous media affects the large-scale transport of solutes and contaminants in groundwater and it can be reproduced by means of several geostatistical simulation tools. However, including the available geological information in these tools is often cumbersome. A hierarchical simulation procedure based on a binary tree is proposed and tested on two real-world blocks of alluvial sediments, of a few cubic meters volume, that represent small-scale aquifer analogs. The procedure is implemented using the sequential indicator simulation, but it is so general that it can be adapted to various geostatistical simulation tools, improving their capability to incorporate geological information, i.e., the sedimentological and architectural characterization of heterogeneity. When compared with a standard sequential indicator approach on bi-dimensional simulations, in terms of proportions and connectivity indicators, the proposed procedure yields reliable results, closer to the reference observations. Different ensembles of three-dimensional simulations based on different hierarchical sequences are used to perform numerical experiments of conservative solute transport and to obtain ensembles of equivalent pore velocity and dispersion coefficient at the scale length of the blocks (meter). Their statistics are used to estimate the impact of the variability of the transport properties of the simulated blocks on contaminant transport modeled on bigger domains (hectometer). This is investigated with a one-dimensional transport modeling based on the Kolmogorov-Dmitriev theory of branching stochastic processes. Applying the proposed approach with diverse binary trees and different simulation settings provides a great flexibility, which is revealed by the differences in the breakthrough curves.  相似文献   

Reply to Comment on “Impact of groundwater withdrawals on the interaction of multi-layered aquifers in the Viterbo geothermal area (central Italy)”: report published in Hydrogeology Journal (2013) 21:1339–1353, by Antonella Baiocchi,Francesca Lotti and Vincenzo Piscopo     

Baiocchi  Antonella  Lotti  Francesca  Piscopo  Vincenzo 《Hydrogeology Journal》2016,24(2):541-545

Hydrogeology Journal -  相似文献   

DNA and fluorescein tracer tests to study the recharge,groundwater flowpath and hydraulic contact of aquifers in the Umbria-Marche limestone ridge (central Apennines,Italy)     

Lucia Aquilanti  Francesca Clementi  Torquato Nanni  Stefano Palpacelli  Alberto Tazioli  Paola Maria Vivalda 《Environmental Earth Sciences》2016,75(7):626

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Implementing landslide path dependency in landslide susceptibility modelling     

Jalal Samia  Arnaud Temme  Arnold K. Bregt  Jakob Wallinga  John Stuiver  Fausto Guzzetti  Francesca Ardizzone  Mauro Rossi 《Landslides》2018,15(11):2129-2144

Landslide susceptibility modelling—a crucial step towards the assessment of landslide hazard and risk—has hitherto not included the local, transient effects of previous landslides on susceptibility. In this contribution, we implement such transient effects, which we term “landslide path dependency”, for the first time. Two landslide path dependency variables are used to characterise transient effects: a variable reflecting how likely it is that an earlier landslide will have a follow-up landslide and a variable reflecting the decay of transient effects over time. These two landslide path dependency variables are considered in addition to a large set of conditioning attributes conventionally used in landslide susceptibility. Three logistic regression models were trained and tested fitted to landslide occurrence data from a multi-temporal landslide inventory: (1) a model with only conventional variables, (2) a model with conventional plus landslide path dependency variables, and (3) a model with only landslide path dependency variables. We compare the model performances, differences in the number, coefficient and significance of the selected variables, and the differences in the resulting susceptibility maps. Although the landslide path dependency variables are highly significant and have impacts on the importance of other variables, the performance of the models and the susceptibility maps do not substantially differ between conventional and conventional plus path dependent models. The path dependent landslide susceptibility model, with only two explanatory variables, has lower model performance, and differently patterned susceptibility map than the two other models. A simple landslide susceptibility model using only DEM-derived variables and landslide path dependency variables performs better than the path dependent landslide susceptibility model, and almost as well as the model with conventional plus landslide path dependency variables—while avoiding the need for hard-to-measure variables such as land use or lithology. Although the predictive power of landslide path dependency variables is lower than those of the most important conventional variables, our findings provide a clear incentive to further explore landslide path dependency effects and their potential role in landslide susceptibility modelling.  相似文献   

Chronology of the Mediterranean sea-level highstand during the Last Interglacial: a critical review of the U/Th-dated deposits     

Francesca Pasquetti  Monica Bini  Biagio Giaccio  Andrea Ratti  Matteo Vacchi  Giovanni Zanchetta 《第四纪科学杂志》2021,36(7):1174-1189

Relative sea-level (RSL) evolution during Marine Isotopic Stage (MIS) 5 in the Mediterranean basin is still not fully understood despite a plethora of morphological, stratigraphic and geochronological studies carried out on highstand deposits of this area. In this review we assembled a database of 323 U/Th-dated samples (e.g. corals, molluscs, speleothems) which were used to chronologically constrain RSL evolution within MIS 5. The application of strict geochemical criteria to the U/Th samples indicates that only ~33% of data available for the Mediterranean Sea can be considered ‘reliable’. Most of these data (~65%) refer to the MIS 5e highstand, while only ~17% could be related to the MIS 5a. No attribution to MIS 5c can be unequivocally supported. Nevertheless, the resulting framework does not allow us to define a satisfactory RSL trend during the MIS 5e highstand and subsequent MIS 5 substages. Overall, the proposed selection of reliable/unreliable data would be useful for detecting areas where MIS 5 substage attributions are not supported by confident U/Th chronological data and thus the related reconstructions need to be revised. In this regard, the resulting framework calls for a reappraisal and re-examination of the Mediterranean records with advanced geochronological methodologies.  相似文献   

Evaluating soil erosion by water in a small alpine catchment in Northern Italy: comparison of empirical models     

Berteni  Francesca  Barontini  Stefano  Grossi  Giovanna 《中国地球化学学报》2021,40(4):507-524

Acta Geochimica - To quantify water erosion rates and annual soil loss in mountainous areas, two different empirical models were used to estimate the effects of soil erosion in a small mountain...  相似文献   

Seismic image quality beneath strongly scattering structures and implications for lower crustal imaging: numerical simulations     

Francesca Martini  Christopher J. Bean  Sean Dolan  David Marsan† 《Geophysical Journal International》2001,145(2):423-435

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