Leaching mechanisms of oxyanionic metalloid and metal species in alkaline solid wastes: A review     

Geert Cornelis  C. Anette Johnson  Tom Van Gerven  Carlo Vandecasteele 《Applied Geochemistry》2008

An overview is presented on possible mechanisms that control the leaching behaviour of the oxyanion forming elements As, Cr, Mo, Sb, Se, V and W in cementituous systems and alkaline solid wastes, such as municipal solid waste incinerator bottom ash, fly ash and air pollution control residues, coal fly ash and metallurgical slags. Although the leachability of these elements generally depends on their redox state, speciation measurements are not common. Therefore, experimental observations available in the literature are combined with a summary of the thermal behaviour of these elements to assess possible redox states in freshly produced alkaline wastes, given their origin at high temperature. Possible redox reactions occurring at room temperature, on the other hand, are reviewed because these may alter the initial redox state in alkaline wastes and their leachates. In many cases, precipitation of oxyanions as a pure metalate cannot provide a satisfactory explanation for their leaching behaviour. It is therefore highly likely that adsorption and solid solution formation with common minerals in alkaline waste and cement reduce the leachate concentration of oxyanions below pure-phase solubility.  相似文献   

Contribution of the SISCam Web-based GIS to the seismotectonic study of Campania (Southern Apennines): an example of application to the Sannio-area     

Rosa Nappi  Giuliana Alessio  Giovanni Bronzino  Carlo Terranova  Giuseppe Vilardo 《Natural Hazards》2008,45(1):73-85

In this article the implementation and potential of the Seismotectonic Information System of the Campania Region (SISCam) are described, in particular an application of this Web-based GIS system to the seismotectonic analysis of the Sannio area (Southern Apennines) is performed. WEB-GIS technologies greatly contribute to both the environmental monitoring and the disaster management of areas affected by high natural risks. Specifically the SISCam system has been developed with the aim of providing easy access and fast diffusion, through Internet technology, of the most significant geological, geophysical, and territorial data relative to the Campania Region. The Sannio area has been selected as our application example because it is among the most active seismic regions in Italy. This portion of the Southern Apennines which was hit by the June 5, 1688 strong earthquake (M _W = 6.7, CPTI 1999) and by some low- and moderate-energy seismic sequences (1990–1992, 1997), is characterized by a complex inherited tectonic setting and low-tectonic deformation rates that hide the seismogenic sources position. Since this case study turned out to be complicated, the use of the SIScam WEB-GIS has become indispensable because it allowed us to visualize, integrate and analyze all the data available, in order to obtain an accurate and direct picture of the seismotectonic setting of the area. Moreover, a different approach of data analysis was necessary, due to the lack of up-to-date neotectonic and structural data; therefore, the operation of this GIS system enabled us to process and generate some original informative layers, through image analysis, such as new structural lineaments represented on a map of the potential active faults of the area, which has been the final result of our application, as a contribution to new knowledge about the local seismic risk parameters.  相似文献   

Editorial     

Z. Švestka  C. De Jager 《Solar physics》1969,8(1):3-4

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Total content and chemical speciation of arsenic in the polychaete Sabella spallanzanii     

Fattorini D  Bocchetti R  Bompadre S  Regoli F 《Marine environmental research》2004,58(2-5):839-843

An unusual feature has been observed in polychaetes regarding their capacity to accumulate high levels of relatively toxic forms of arsenic in specific tissues. Basal levels of arsenic and distribution of its compounds were investigated in tissues of the Mediterranean polychaete Sabella spallanzanii. Particularly high concentrations were measured in the branchial crown (1036+/-136 microg/g d.w.) and chemical speciation revealed that the predominant form was the relatively toxic dimethylarsinate (DMA). These data suggest a potential role of As as anti-predatory strategy in polychaetes.  相似文献   

Steady-state analysis of undersea cables     

A. P. K. De Zoysa 《Ocean Engineering》1978,5(3):209-223

A numerical solution and computer program developed to analyse undersea flexible cable problems is presented. The cable is subject to hydrodynamic loads from a surrounding fluid medium. The object is to determine the cable profile and tensile forces developed. The cable equations and boundary conditions result in a classical two-point boundary value problem. An iteration ‘shooting method’ is used for solution. The program has been written to analyse a class of towing and anchoring problems. However the analysis is general and applicable to most steady-state cable problems.  相似文献   

南海尖峰海山多金属结壳地球化学   总被引：4，自引：5，他引：4  

梁宏锋  姚德  刘新波  梁德华 《海洋地质与第四纪地质》1991,(4)

南海尖峰海山多金属结壳富含30多种元素,其锰铁矿物主要由钡镁锰矿,δ-MnO_2和FeOOH·xH_2O组成。与其它海区的结壳相比,尖峰海山结壳富含Cu、Ni、Ba、Zn、Pb等元素,而Co、Ti、稀土元素(REE)、Sr等元素相对较贫。研究表明,HREE亏损,具明显的Ce正异常,较明显的Tb正异常和Yb负异常。这是氧化弱碱性海洋环境所致。结壳是水成作用的产物,它的形成受南海独特的古海洋环境所控制,海底火山热液作用,可能也是影响因素之一。  相似文献   

Sensitivity to stress of the estuarine bivalve Macoma balthica from areas between the Netherlands and its southern limits (Gironde)     

H. Hummel  C. Amiard-Triquet  G. Bachelet  M. Desprez  J. Marchand  B. Sylvand  J.C. Amiard  H. Rybarczyk  R.H. Bogaards  J. Sinke  Y. De Wit  L. De Wolf 《Journal of Sea Research》1996,35(4):315-321

Variation in the sensitivity to stress of Macoma balthica was measured in several French and Dutch estuaries. For adult and juvenile Macoma balthica exposed to copper under conditions of starvation, differences in mortality rate, condition, glycogen, burrowing rate and copper content were assessed. No significant differences were observed between adults and juveniles; the influence of treatment and origin was always evident. Animals from the most southern estuaries, Loire and Gironde, near to the species's southern limit of distribution, showed, in the field, the strongest deviations for the ecophysiological traits measured, and were in the experiments the most sensitive to stress.  相似文献   

Investigating the use of proxies for fecundity to improve management advice for western horse mackerel Trachurus trachurus     

De Oliveira  J.A.A.; Roel  B.A.; Dickey-Collas  M. 《ICES Journal of Marine Science》2006,63(1):25-35

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Factors involved in growth plasticity of cockles Cerastoderma edule (L.), identified by field survey and transplant experiments     

Xavier De Montaudouin 《Journal of Sea Research》1996,36(3-4)

In Arcachon Bay, a macrotidal coastal lagoon in southwest France, growth rates of cockles Cerastoderma edule (L.) differ greatly between locations. Sampling of populations at different tidal levels showed that the mean shell length was significantly and positively correlated with immersion time, whereas no correlation was found with population density and microphytobenthos biomass. Transplants of cockles between two intertidal sites were used to examine the relative importance of habitat and site of origin for growth rate and condition index. Artifacts due to manipulation were assessed, i.e. the impact of enclosures on growth, conditon index and mortality. During a 5-mo reciprocal transplant experiment, growth rates of the transplanted cockles and the cockles already present were similar, whereas the sites of origin did not affect growth rate. Condition index, however, displayed significant differences in relation to both transplant and origin sites. During a further 6-mo experiment in which cockles were transplanted from one site to four new sites, growth was mainly influenced by tidal level. These results indicate that net growth started when cockles were immersed 30% of the time. It is concluded that, on the scale of Arcachon Bay (156 km²), differences in growth and condition between cockle populations are largely phenotypic. Tidal level (i.e. food supply and emersion stress) accounts for most of these differences, but the existence of genetically or physiologically different populations cannot be excluded.  相似文献   

Seabed Morphology and Pollution Along the Bagnoli Coast (Naples, Italy): a Hypothesis for Environmental Restoration     

Tommaso De  Pippo  Carlo Donadio  Micla Pennetta  Francesco Terlizzi  Carlo Vecchione  Margherita Vegliante 《Marine Ecology》2002,23(S1):154-168

Abstract. The interaction of coastal and submarine morphology with the hydrodynamic regimes exerts a control on coastal dynamic processes, conditioning the dispersion of sediments and potential pollutants existing in the area. Thus, the study of such parameters is useful in order to define environmental threats. Within the submerged sector of the Bagnoli coast and particularly in the southern part of the investigated area, there are sediment groups composed of very fine sands located in low-energy zones due to wave refraction and diffraction; they can also be found on the sea bottom and on the man-made structures typical of this zone. These areas show high pollutant levels of N, P, Cu, Fe, Mn, Ni, Pb, Zn, Cd, polyaromatic hydrocarbons (PAHs) and polychlorinated bi-phenyls (PCBs). The northern area, a place of high-energy hydrodynamic processes, also shows high concentration levels of pollutants due to the presence of secondary cell circulation.
Morphological research and analysis of textural characteristics of bottom sediments along the Bagnoli coast allowed the actual processes and their evolution in space and time to be defined. It has also been possible to correlate such processes to the seabed morphology system, the wave formations which affect the coast, the complex system of sediment transport, as well as to the man-made interventions in the area. The results of recent chemical analyses of beach sediments and bottom sediments off the Bagnoli coast were also incorporated. They prove the presence of heavy metals, PAHs and PCBs in high and sometimes very high concentrations. Finally, based on the results of research and analyses, a hypothesis for an intervention for environmental restoration has been formulated in order to renaturalise the coast through dredging and treatment of the sand, both on the seabed and on the emerged beach.  相似文献