Investigation of Reductive Dechlorination Supported by Natural Organic Carbon   总被引：1，自引：0，他引：1  

Heather V. Rectanus  Mark A. Widdowson  Francis H. Chapelle  Catherine A. Kelly  John T. Novak 《Ground Water Monitoring & Remediation》2007,27(4):53-62

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Naturally Enhanced Ion-Acoustic Spectra And Their Interpretation     

Francis Sedgemore-Schulthess  Jean-Pierre St. Maurice 《Surveys in Geophysics》2001,22(1):55-92

Incoherent scatter radars are designed to detect scatter from thermalfluctuations in the ionosphere. These fluctuations contain, among other things,features associated with ion-acoustic waves driven by random motions within theplasma. The resulting spectra are generally broad and noisy, but neverthelessthe technique can, through a detailed analysis of spectra, be used to measure arange of physical parameters in the Earth's upper atmosphere, and provides apowerful diagnostic in studies of magnetosphere-ionosphere coupling,thermosphere dynamics and the geospace environment in general. In recent yearsthere has been much interest in naturally occurring (as opposed to artificiallystimulated) enhanced ion-acoustic spectra seen in the auroral zone andcusp/cleft region. A study of the plasma instability processes that lead tosuch spectra will help us to better understand auroral particle acceleration,wave-particle and wave-wave interactions in the ionosphere, and theirassociation with magnetospheric processes. There is now a substantial body ofliterature documenting observations of enhanced ion-acoustic spectra, but thereremains controversy over generation mechanisms. We present a review ofliterature documenting observations of naturally enhanced ion-acoustic spectra,observed mainly along the geomagnetic field direction, along with a discussionof the theories put forward to explain such phenomena.  相似文献   

Evaluation of Pb-Pb and U-Pb Laser Ablation ICP-MSZircon Dating using Matrix-Matched Calibration Sampleswith a Frequency Quadrupled (266 nm)Nd-YAG Laser     

Olivier Bruguier  Philippe Télouk  Alain Cocherie  Anne-Marie Fouillac  Francis Albarède 《Geostandards and Geoanalytical Research》2001,25(2-3):361-373

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Moment tensor inversion of some aftershocks of the April 18, 1985 Luquan earthquake of Yunnan Province, China     

Jiangchuan Ni  Yuntai Chen  Ming Wang  Mingxi Wu  Jiayu Zhou  Peide Wang  Francis T. Wu 《地震学报(英文版)》1992,5(3):459-467

Based on the three component accelerograms, recorded at near-field distance by a temporary seismic network consisting of digital cassette tape recording accelerographs, the focal mechanisms of three aftershocks of the April 18, 1985, Luquan, Yunnan Province, China, earthquake ofM _S=6.1, are calculated using seismic moment tensor inversion technique. The phases of direct P, S and converted SP waves in the displacement seismograms, produced by twice integrations of the observed accelerograms, are identified via forward calculation using Green’s functions for homogeneous semi-infinite elastic medium, and used in the inversion. The results of inversion show that a better fit of synthetic to the observed seismograms of direct as well as converted phases can be achieved if appropriate weighting functions are used in solving the over definite linear equations. While these aftershocks are of different magnitudes (M _L=4.8, 3.2 and 3.5, respectively) and hypocentral locations, their focal mechanisms are very similar and consistent with that of the main shock. This feature demonstrates the intrinsic correlation between the occurrence of aftershocks and the seismogenic fault of main shock. Our experimentations show that using the near field accelerogram obtained from the digital seismic network with appropriate azimuthal coverage on the focal sphere, with the aid of even simple medium model, not only the shear dislocation source, but also the isotropic part and CLVD (compensated linear vector dipole) can be retrieved by the technique of moment tensor inversion. The Chinese version of this paper appeared in the Chinese edition ofActa Seismologica Sinica,13, 412–419, 1991. This work is supported by the Chinese Joint Seismological Sciences Foundation and the Western Yunnan Earthquake Prediction Test Site (WYEPTS), State Seismological Bureau.  相似文献   

Competitive Exclusion of Sulfate Reduction by Fe(lll)-Reducing Bacteria: A Mechanism for Producing Discrete Zones of High-Iron Ground Water     

Francis H. Chapelle  Derek R. Lovley 《Ground water》1992,30(1):29-36

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Land degradation impacts on tropical agricultural basins and their management: the Nigerian example     

Francis O. Odemerho   《Geoforum》1992,23(4)

This study uses the fault-tree technique to identify the major effects of land degradation caused by the adoption of a malfunctioning shifting cultivation technology for food production in tropical basins. Through reference to existing empirical research, the sequence of events in the process of degradation of the Nigerian agricultural basins and the adjoining river systems was identified and related to the appropriate causal agent. A complete picture of the cost of land degradation goes beyond the degraded terrain and includes damage in areas where there is an unloading of large quantities of run-off and sediments. The causal pathway showed that existing land degradation management policies have focused on the symptoms rather than on the cause of the degradation process. Through a thorough examination of those malfunctioning components of the traditional farming technology, appropriate management strategies are proferred. An institutional organization for land degradation management in Nigeria which includes the federal, state and local governments is strongly recommended.  相似文献   

The phase velocities of Rayleigh waves and the lateral variation of lithospheric structure in Tibetan Plateau   总被引：1，自引：0，他引：1  

Guo-Ying Chen  Rong-Sheng Zeng  Francis T. Wu  Xiao-Lan Su 《地震学报(英文版)》1993,6(2):289-297

According to a Sino-U. S. joint project, eleven broadband digital PASSCAL seismometers had been deployed inside the Tibetan Plateau, of which 7 stations were on the profile from Lhasa to Golmud and other 4 stations situated at Maxin, Yushu, Xigatze and Linzhi. Dispersions and phase velocities of the Rayleigh surface waves (10s–120s) were obtained on five paths distributed in the different blocks of Tibetan Plateau. Inversions of the S-wave velocity structures in Songpan-Ganzi block, Qiang-Tang block, Lhasa block and the faulted rift zone were obtained from the dispersion data. The results show that significant lateral variation of the S-wave velocity structures among the different blocks exists. The path from Wenquan to Xigatze (abbreviated as Wndo-Xiga) passes through the rift-zone of Yadong-Anduo. The phase velocities of Rayleigh waves from 10s to 100s on this path are significantly higher than that on other paths. The calculated mean crustal velocity on this path is 3.8 km/s, much greater than that on other paths, where mean crustal velocities of 3.4–3.5 km/s are usually observed. Low velocity zones with different thicknesses and velocities are observed in the middle-lower crust for different paths. Songpan-Ganzi block, located in the northern part of Tibetan Plateau is characterized by a thinner crust of 65 km thick and a prominent low velocity zone in the upper mantle. The low velocity zone with a velocity of 4.2 km/s is located at a depth form 115 km to 175 km. While in other blocks, no low velocity zone in the upper mantle is observed. The value of Sn in Songpan-Ganzi is calculated to be 4.5 km/s, while those in Qiang-Tang and Lhasa blocks are about 4.6 km/s. The Chinese version of this paper appeared in the Chinese edition ofActa Seismologica Sinica,14, Supp., 566–573, 1992.  相似文献   

Preliminary study of crust-upper mantle structure of the Tibetan Plateau by using broadband teleseismic body waveforms   总被引：2，自引：0，他引：2  

Lu-Pei Zhu  Rong-Sheng Zeng  Francis T. Wu  Thomas J. Owens  George E. Randall 《地震学报(英文版)》1993,6(2):305-316

As part of a joint Sino-U.S. research project to study the deep structure of the Tibetan Plateau, 11 broadband digital seismic recorders were deployed on the Plateau for one year of passive seismic recording. In this report we use teleseimic P waveforms to study the seismic velocity structure of crust and upper mantle under three stations by receiver function inversion. The receiver function is obtained by first rotating two horizontal components of seismic records into radial and tangential components and then deconvolving the vertical component from them. The receiver function depends only on the structure near the station because the source and path effects have been removed by the deconvolution. To suppress noise, receiver functions calculated from events clustered in a small range of back-azimuths and epicentral distances are stacked. Using a matrix formalism describing the propagation of elastic waves in laterally homogeneous stratified medium, a synthetic receiver function and differential receiver functions for the parameters in each layer can be calculated to establish a linearized inversion for one-dimensional velocity structure. Preliminary results of three stations, Wen-quan, Golmud and Xigatze (Coded as WNDO, TUNL and XIGA), located in central, northern and southern Plateau are given in this paper. The receiver functions of all three stations show clear P-S converted phases. The time delays of these converted phases relative to direct P arrivals are: WNDO 7.9s (for NE direction) and 8.3s (for SE direction), TUNL 8.2s, XIGA 9.0s. Such long time delays indicate the great thickness of crust under the Plateau. The differences between receiver function of these three station shows the tectonic difference between southern and north-central Plateau. The waveforms of the receiver functions for WNDO and TUNL are very simple, while the receiver function of XIGA has an additional midcrustal converted phase. The S wave velocity structures at these three stations are estimated from inversions of the receiver function. The crustal shear wave velocities at WNDO and TUNL are vertically homogeneous, with value between 3.5–3.6 km/s down to Moho. This value in the lower crust is lower than the normal value for the lower crust of continents, which is consistent with the observed strong Sn attenuation in this region. The velocity structure at XIGA shows a velocity discontinuity at depth of 20 km and high velocity value of 4.0 km/s in the midcrust between 20–30 km depth. Similar results are obtained from a DSS profile in southern Tibet. The velocity under XIGA decreases below a depth of 30 km, reaching the lowest value of 3.2 km/s between 50–55 km. depth. This may imply that the Indian crust underthrusts the low part of Tibetan crust in the southern Plateau, forming a “double crust”. The crustal thickness at each of these sites is: WNDO, 68 km; TUNL, 70 km; XI-GA, 80 km. The Chinese version of this paper appeared in the Chinese edition ofActa Seismologica Sinica,14, Supp., 581–592, 1992.  相似文献   

Review of Carboniferous-Permian volcanicity in Scotland     

E. H. Francis 《International Journal of Earth Sciences》1967,57(1):219-246

The main Carboniferous outcrop in Scotland is in the Midland Valley rift, though rocks of that age also occur farther south along the English Border. The cyclic sedimentary sequence comprises up to 3,000 m. of Dinantian (mainly Viséan) and 2,000 m. of Silesian beds which at one locality or another include lavas or tuffs almost at every level. The distribution of these volcanic rocks is known in exceptional detail because of mining and exploratory borings in the Viséan oil shale field and in the various Namurian and Westphalian coalfields.The lavas and tuffs form part of an alkaline (sodic) magma series. Their outpourings were greatest in volume during the Dinantian, with the formation of the extensive lava piles which now form the Clyde Plateau (maximum thickness c. 900 m.) in the west, the Garleton Hills (c. 600 m.) and Burntisland Anticline (c. 400 m.) in the east, and the Kelso Traps of the Tweed Basin (c. 120 m.), the Birrenswark Lavas of Dumfriesshire (c. 90 m.), the Kershopefoot Basalt of Liddesdale (c. 60 m.) and the Glencartholm Volcanic Beds (mostly tuffs) of Eskdale (c. 180 m.) to the south. Most of the lavas are varieties of olivine-basalt, but subordinate trachybasalts, trachytes and rhyolites are included in the upper parts of the Clyde Plateau and Garleton Hills successions. The areas covered by individual lava fields are difficult to assess because they varied from time to time and occasionally overlapped.By the end of the Dinantian this form of activity had ceased everywhere except in West Lothian, where it continued into early Namurian (E₁). Thereafter volcanicity continued periodically from scattered centres and gave rise to relatively short-lived ash-cones. They formed in Ayrshire (E₁ age) but were most abundant in Fife, occurring there almost throughout the Namurian succession. The highly explosive nature of this phase of volcanicity is apparent from the rarity of associated lavas (though minor basaltic intrusions occur in the necks) and from the presence within the surrounding sediments of thin layers of tuff representing fine ash carried for distances of up to 32 km from source. These layers, some of which are kaolinized and are a variety of tonstein, are of local use in correlation.The explosive phase is now known to have continued throughout Westphalian A and possibly into Westphalian B in Fife, but in Ayrshire volcanicity was more intermittent and is represented by two outpourings of basalt lavas, one late Namurian to early Westphalian in age and up to 150 m. thick, the other Stephanian in age and 90 to 237 m. thick. The Stephanian lavas and associated necks in Ayrshire, like some of the necks exposed on the classic Fife coastal section on the Firth of Forth, were until recently believed to be Permian, but there is now no positive evidence of Permian eruption in Scotland.Two groups of intrusions cut the Carboniferous rocks. The most extensive is of alkaline dolerites which are co-magmatic with the basaltic lavas and tuffs, and are of similar geographic distribution. They form sills up to 120 m. thick and are probably of various ages up to Stephanian. It is possible that some of them were high-level reservoirs from which diatremes issued. The other group is of quartz-dolerite or tholeiite which forms a series of east-west dykes and a sill-complex extending over an area of about 1500 km² and having a maximum thickness of 127 m. Their age is late Carboniferous.The distribution of the Carboniferous volcanic rocks is not apparently related to the rift-valley, but is clearly linked in places to the earlier Caledonoid structures which determined the pattern of sedimentation. The lavas and, to a lesser extent, the tuffs, influenced the sedimentary processes by partially enclosing basins, by causing local anomalies in cyclic sequences and by providing sources of atypical sediment.

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Zusammenfassung Im Midland Valley (Schottland) war der permokarbonische Alkali-(Na)-Vulkanismus besonders im Dinantium aktiv, wobei bis 900 m mächtige Laven (Olivinbasalte, untergeordnet Trachytandesite, Trachyte und Rhyolite) gefördert wurden. Gegen Ende des Dinantium hörte diese Art der Aktivität fast ganz auf, dafür setzte eine explosive, periodische Tätigkeit ein, die zu kurzlebigen Aschenkegeln führte. Ein Beweis für das früher angenommene permische Alter dieser Necks läßt sich nicht erbringen.Zwei Gruppen von Intrusiva sind in die karbonischen Sedimente eingedrungen. Die größere der beiden wird durch Alkali-Dolerite (Sills) gebildet, die co-magmatisch zu den Laven und Tuffen sind. Die andere besteht aus Quarz-Doleriten und Tholeyiten (vorwiegend Dykes), die spätkarbonisch bis frühpermischen Alters sind.Die Verbreitung der karbonischen Vulkanite ist nicht an das Midland Valley, sondern an frühere caledonische Strukturen gebunden und für den Sedimentationsprozeß von Bedeutung.

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Résumé Le principal affleurement carbonifère en Ecosse se trouve dans le graben du Midland Valley, quoiqu'on rencontre les roches de cet âge le long de la frontière anglaise. La succession du cycle sédimentaire comprend jusqu'à 3,000 m. de roches de l'âge Dinantien (principalement Viséen) et à 2,000 m. des couches Silésiennes qui dans une localité quelconque comprennent des laves ou des tufs à presque tous les niveaux. La distribution de ces roches volcaniques est bien connu dans tous les détails à cause des mines et des forages.Les laves et les tufs font partie d'une série alkaline (sodique) magma. Leurs éruptions atteignirent leur maximum en volume pendant Ie Dinantien, avec la formation du Plateau de Clyde (épaisseur maximum 900 m. env.) à l'ouest, les Collines de Garleton (600 m. env.) et l'anticlinal de Burntisland (400 m. env.) a l'est, et les Kelso Traps du bassin du Tweed (120 m. env.), les Birrenswark Lavas de Dumfriesshire (90 m. env.), le Kershopefoot Basait de Liddesdale (60 m. env.) et les Glencartholm Volcanic Beds (des tufs pour la plupart) d'Eskdale (180 m. env.) au sud. La plupart des laves sont des variétés de basalte-olivine, mais des quantié peu considérables de trachybasalte, trachytes et rhyolites sont comprises dans les parties supérieures dans les successions du Plateau de Clyde et des Collines de Garleton.A la fin du Dinantien, cette forme d'activité avait cessé partout excepté dans l'Ouest Lothian, où elle continuait jusqu'au commencement du Namurien. Après cela le volcanisme continua périodiquement des centres dispersés, et donna naissance à des cônes de cendre de relativement petite durée. Ceux-ci se formèrent en Ayrshire (age E₁), mais on les trouvait beaucoup plus souvent en Fife, et on les y rencontrait presque pendant toute la succession namurienne. La nature explosive de cette phase de volcanisme est apparente par la rareté des laves et par la présence dans le sédiment qui se trouve dans les couches étroites de tuf, résultat du cendre fin porté jusqu'à 32 km. de sa source. Ces couches-ci dont quelques-unes furent transformées en kaolin, sont une variété de tonstein qui s'emploie beaucoup en corrélation. La distribution des quelques cheminées volcaniques coïncide aux structures nord—est d'un âge précarbonifère.La phase explosive est maintenant connue d'avoir continué à travers toute la Westphalie «Äs» et possiblement d'avoir pénétré dans la Westphalie «B» en Fife, mais en Ayrshire le volcanisme était plus intermittent et est représenté par deux éruptions de lave basaltique, l'une pendant la fin du Namurien jusqu'au début du Westphalien et d'une épaisseur de 150 m., l'autre du Stéphanien et d'une épaisseur de 90 à 237 m. Les laves du Stéphanien et les cheminées associées étaient classées auparavant comme Permien, mais maintenant il n'y a aucune évidence positive d'éruption permianique en Ecosse.Deux groupes d'intrusions scindèrent les roches carbonifères. Le groupe le plus étendu est fait de dolérites alkalines qui sont co-magmatiques avec les laves basaltiques et les tufs, et sont de pareille distribution géographique. Elles forment des silles d'une épaisseur jusqu; à 120 m. et elles sont probablement d'âges variés jusqu'au Stéphanien. Il est possible que quelques-une d'entre elles furent des réservoirs de haut-niveau desquels des diatrèmes sortirent. L'autre groupe est fait de quartz-dolérite ou tholéiite qui forme une série de dikes est—ouest et une sille-complexe couvrant une étendue de 1,500 km² et ayant une épaisseur maximale de 127 km. Leur áge est de la fin du Carbonifère ou du début du Permien.

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Published by permission of the Director, Institute of Geological Sciences.  相似文献   

On the experimental silicification of microorganisms II. On the time of appearance of eukaryotic organisms in the fossil record     

S. Francis  L. Margulis  E.S. Barghoorn 《Precambrian Research》1978,6(1):65-100

On the basis of ultrastructural, biochemical and genetic studies, bacteria and blue green algae (Kingdom Monera, all prokaryotes) differ unambiguously from the eukaryotic organisms (Fungi, plants sensu stricto) and protists or protoctists, (Copeland, 1956). The gap between eukaryotes and prokaryotes is recognized as the most profound evolutionary discontinuity in the living world. This gap is reflected in the fossil record. Fossil remains of Archaean and Proterozoic Aeons primarily consist of prokaryotes and the Phanerozoic is overwhelmingly characterized by fossils of the megascopic eukaryotic groups, both metazoa and metaphyta. Based on the morphological interpretation of microscopic objects structurally preserved in Precambrian cherts, the time of appearance of remains of eukaryotic organisms in the fossil record has been claimed to be as early as 2.7 · 10⁹ years ago, (Ka?mierczak, 1976). Others suggest chronologies varying between 1.7 to 1.3 · 10⁹ (Schopf et al., 1973) or a time approaching 1.3 · 10⁹ years (Cloud, 1974).There is general agreement that many of the Ediacaran faunas, which have been dated at about 680 m.y. are fossils of megascopic soft-bodied invertebrate animals. Since all invertebrates are eukaryotic, the ca. 680 m.y. date for deposition of these animal assemblages may represent the earliest appearance of eukaryotic organisms. But the question remains as to whether there is definitive evidence for eukaryotic cells before this “benchmark” of the late Precambrian.An excellent discussion of this particular problem as especially relating to acritarchs extending from rocks of Upper Riphean through Vendian and into the basal Cambrian is presented in recent studies by Vidal (1974, 1976) in Late Precambrian microfossils from the Visingsö rocks of southern Sweden.Previous work on the laboratory silicification of wood and algal mat communities (Leo and Barghoorn, 1976) suggested that further analysis of “artificial fossils” might be of aid in the interpretation of fossil morphology toward the ultimate solution of this problem. Thus the procedure developed by one of us (ESB) for laboratory wood silicification was adapted to various smaller objects.By successive immersions of wet cellular aggregates, colonies of various organisms and abiotic organic microspheres in tetraethyl orthosilicate, silicified cells and structures are produced which bear an interesting resemblance to ancient chert-embedded microfossils. Our observation of these microorganisms and proteinoid microspheres silicified in the laboratory as well as of degrading microorganisms, both eukaryotic and prokaryotic, have led us to conclude that many, if not all, of the criteria for assessing fossil eukaryotic microorganisms are subject to serious criticism in interpretation. We studied a large variety of prokaryotic algae, some eukaryotic algae, fungi, protozoa, and abiotic organic microspheres stable at essentially neutral pH. In some cases, degradation and/or silicification systematically altered both size and appearances of microorganisms. By the use of monoalgal cultures of blue-green algae, features resembling nuclei, chloroplasts, tetrads, pyrenoids, and large cell size may be simulated. In many cases individual members of these cultures show so much variation that they may be mistaken as belonging to more than one species. The size ranges for silicified prokaryotic and eukaryotic algae overlap. Several prokaryotes routinely yielded spherical or filamentous structures that resembled large cells. Because of genuine large sizes (e.g., Prochloron), shrinkage, systematic alteration or congregation of unicells to form other structures we find sizes to be of very limited use in determining whether an organism of simple morphology was prokaryotic or eukaryotic. Although some “prebiotic proteinoid microspheres” (of Fox and Harada, 1960) are impossible to silicify with our laboratory methods, those stable at neutral pH (Hsu and Fox, 1976) formed spherical objects that morphologically resemble silicified algae or fungal spores. Many had internal structure. We conclude that even careful morphometric studies of fossil microorganisms are subject to many sources of misinterpretation. Even though it is a logical deduction that eukaryotic microorganisms evolved before Ediacaran time there is no compelling evidence for fossil eukaryotes prior to the late Precambrian metazoans.  相似文献