Intermittent generation of mafic enclaves in the 1991–1995 dacite of Unzen Volcano recorded in mineral chemistry     

Hiroaki?SatoEmail author  Francois?Holtz  Roman?E.?Botcharnikov  Setsuya?Nakada 《Contributions to Mineralogy and Petrology》2017,172(4):22

Mafic enclaves in the 1991–1995 dacite of Unzen volcano show chemical and textural variability, such as bulk SiO₂ contents ranging from 52 to 62 wt% and fine- to coarse-grained microlite textures. In this paper, we investigated the mineral chemistry of plagioclase and hornblende microlites and distinguished three enclave types. Type-I mafic enclaves contain high-Mg plagioclase and low-Cl hornblende as microlites, whereas type-III enclaves include low-Mg plagioclase and high-Cl hornblende. Type-II enclaves have an intermediate mineral chemistry. Type-I mafic enclaves tend to show a finer-grained matrix, have slightly higher bulk rock SiO₂ contents (56–60 wt%) when compared with the type-III mafic enclaves (SiO₂?=?53–59 wt%), but the overall bulk enclave compositions are within the trend of the basalt–dacite eruptive products of Quaternary monogenetic volcanoes around Unzen volcano. The origin of the variation of mineral chemistry in mafic enclaves is interpreted to reflect different degree of diffusion-controlled re-equilibration of minerals in a low-temperature mushy dacitic magma reservoir. Mafic enclaves with a long residence time in the dacitic magma reservoir, whose constituent minerals were annealed at low-temperature to be in equililbrium with the rhyolitic melt, represent type-III enclaves. In contrast, type-I mafic enclaves result from recent mafic injections with a mineral assemblage that still retains the high-temperature mineral chemistry. Taking temperature, Ca/(Ca?+?Na) ratio of plagioclase, and water activity of the hydrous Unzen magma into account, the Mg contents of plagioclase indicate that plagioclase microlites in type-III enclaves initially crystallized at high temperature and were subsequently re-equilibrated at low-temperature conditions. Compositional profiles of Mg in plagioclase suggest that older mafic enclaves (Type-III) had a residence time of ~100 years at 800 °C in a stagnant magma reservoir before their incorporation into the mixed dacite of the 1991–1995 Unzen eruption. Presence of different types of mafic enclaves suggests that the 1991–1995 dacite of Unzen volcano tapped mushy magma reservoir intermittently replenished by high-temperature mafic magmas.  相似文献   

Numerical simulation of the 30–45 ka debris avalanche flow of Montagne Pelée volcano,Martinique: from volcano flank collapse to submarine emplacement     

Brunet  Morgane  Moretti  Laurent  Le Friant  Anne  Mangeney  Anne  Fernández Nieto  Enrique Domingo  Bouchut  Francois 《Natural Hazards》2017,85(2):1189-1208

Natural Hazards - In November 2015, China government announced that the national carbon emissions trading market is expected to start in 2017. Carbon emission trading system is a raising concern...  相似文献   

Twentieth century precipitation trends in the upper Mzingwane sub-catchment of the northern Limpopo basin,Zimbabwe     

Maviza  Auther  Grab  Stefan  Engelbrecht  Francois 《Theoretical and Applied Climatology》2022,149(1-2):309-325

Theoretical and Applied Climatology - This study evaluates precipitation trends in the upper Mzingwane sub-catchment (UMS) of Zimbabwe using ten World Meteorological Organization (WMO)’s...  相似文献   

Geological time formalization: an improved formal model for describing time successions and their correlation   总被引：1，自引：1，他引：0  

Michel Perrin  Laura S. Mastella  Olivier Morel  Alexandre Lorenzatti 《Earth Science Informatics》2011,4(2):81-96

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The effect of titanium and phosphorus on ferric/ferrous ratio in silicate melts: an experimental study     

Alexander Borisov  Harald Behrens  Francois Holtz 《Contributions to Mineralogy and Petrology》2013,166(6):1577-1591

The effect of TiO₂ and P₂O₅ on the ferric/ferrous ratio in silicate melts was investigated in model silicate melts at air conditions in the temperature range 1,400–1,550 °C at 1-atm total pressure. The base composition of the anorthite–diopside eutectic composition was modified with 10 wt % Fe₂O₃ and variable amounts of TiO₂ (up to 30 wt %) or P₂O₅ (up to 20 wt %). Some compositions also contained higher SiO₂ concentrations to compare the role of SiO₂, TiO₂, and P₂O₅ on the Fe³⁺/Fe²⁺ ratio. The ferric/ferrous ratio in experimental glasses was analyzed using a wet chemical technique with colorimetric detection of ferrous iron. It is shown that at constant temperature, an increase in SiO₂, TiO₂, and P₂O₅ content results in a decrease in the ferric/ferrous ratio. The effects of TiO₂ and SiO₂ on the Fe³⁺/Fe²⁺ ratio was found to be almost identical. In contrast, adding P₂O₅ was found to decrease ferric/ferrous ratio much more effectively than adding silica. The results were compared with the predictions from the published empirical equations forecasting Fe³⁺/Fe²⁺ ratio. It was demonstrated that the effects of TiO₂ are minor but that the effects of P₂O₅ should be included in models to better describe ferric/ferrous ratio in phosphorus-bearing silicate melts. Based on our observations, the determination of the prevailing fO₂ in magmas from the Fe³⁺/Fe²⁺ ratio in natural glasses using empirical equations published so far is discussed critically.  相似文献   

A Compilation of Silicon,Rare Earth Element and Twenty‐One other Trace Element Concentrations in the Natural River Water Reference Material SLRS‐5 (NRC‐CNRC)     

Delphine Yeghicheyan  Cécile Bossy  Martine Bouhnik Le Coz  Chantal Douchet  Guy Granier  Alexie Heimburger  Francois Lacan  Aurélie Lanzanova  Tristan C. C. Rousseau  Jean‐Luc Seidel  Mickaël Tharaud  Frédéric Candaudap  Jérôme Chmeleff  Christophe Cloquet  Sophie Delpoux  Marie Labatut  Rémi Losno  Catherine Pradoux  Yann Sivry  Jeroen E. Sonke 《Geostandards and Geoanalytical Research》2013,37(4):449-467

The natural river water certified reference material SLRS‐5 (NRC‐CNRC) was routinely analysed in this study for major and trace elements by ten French laboratories. Most of the measurements were made using ICP‐MS. Because no certified values are assigned by NRC‐CNRC for silicon and 35 trace element concentrations (rare earth elements, Ag, B, Bi, Cs, Ga, Ge, Li, Nb, P, Rb, Rh, Re, S, Sc, Sn, Th, Ti, Tl, W, Y and Zr), or for isotopic ratios, we provide a compilation of the concentrations and related uncertainties obtained by the participating laboratories. Strontium isotopic ratios are also given.  相似文献   

Preserving the Ocean Circulation: Implications for Climate Policy   总被引：3，自引：2，他引：1  

Klaus Keller  Kelvin Tan  François M. M. Morel  David F. Bradford 《Climatic change》2000,47(1-2):17-43

Climate modelers have recognized the possibility of abrupt climate changes caused by a reorganization of the North Atlantic's current pattern (technically known as a thermohaline circulation collapse). This circulation system now warms north-western Europe and transports carbon dioxide to the deep oceans. The posited collapse of this system could produce severe cooling in northwestern Europe, even when general global warming is in progress. In this paper we use a simple integrated assessment model to investigate the optimal policy response to this risk. Adding the constraint of avoiding a thermohaline circulation collapse would significantly reduce the allowable greenhouse gas emissions in the long run along an optimal path. Our analysis implies that relatively small damages associated with a collapse (less than 1% of gross world product) would justify a considerable reduction of future carbon dioxide emissions.  相似文献   

Adaptation of the vertical resolution in the mixed layer for HYCOM   总被引：1，自引：0，他引：1  

Ccile Renaudie  Rmy Baraille  Yves Morel  Gwenaëlle Hello  Herv Giordani 《Ocean Modelling》2009,30(2-3):178-189

This paper focuses on the dynamics of the mixed layer. When the mixed layer depth increases, the vertical discretisation eventually becomes too sparse at the bottom of this layer to accurately resolve its evolution and strong numerical errors can appear. This is linked to the fact that the vertical resolution is concentrated in the upper part of the ocean and does not adapt to the deepening of the mixed layer.Knowing that the HYbrid Coordinate Ocean Model (HYCOM) is able to modify the distribution of the vertical levels, we suggest in this paper a method to adapt the resolution to the mixed layer extension. This method is tested in 1-D configurations for two academic atmospheric forcing conditions (strong convection and wind-mixing) and a realistic forcing extending over one year, with seasonal restratification following strong winter convection. The new method improves the results in all cases, and in particular when the mixed layer reaches deep layers.  相似文献   

Ekman drift and vortical structures     

Yves Morel  Leif N. Thomas   《Ocean Modelling》2009,27(3-4):185-197

In this article, the authors study the influence of a constant wind on the displacement of a vortex. The well known Ekman current develops in the surface layer and is responsible for a transport perpendicular to the wind: the Ekman drift.An additional process is, however, evidenced, whose importance is as strong as the Ekman drift. There indeed exists a curl of the wind-driven acceleration along isopycnic surfaces when they are spatially variable (they enter and leave the depth where the wind stress acts), which generates potential vorticity anomalies. This diabatic effect is shown to generate potential vorticity anomalies which acts on the propagation of vortical waves and non linear vortices.It is shown that this effect drastically reduces the effect of the Ekman drift for linear waves and surface intensified vortices, while extending its effect to subsurface vortices. It also generates along wind propagation, whose sign depends on the vortex characteristics.  相似文献   

The Ultimate CCD for Laser Guide Star Wavefront Sensing on Extremely Large Telescopes     

James W. Beletic  Sean Adkins  Barry Burke  Robert Reich  Bernie Kosicki  Vyshnavi Suntharalingham  Charlie Bleau  Ray DuVarney  Richard Stover  Jerry Nelson  Francois Rigaut 《Experimental Astronomy》2005,19(1-3):103-109

All of the extremely large telescopes (ELTs) will utilize sodium laser guide star (LGS) adaptive optics (AO) systems. Most of these telescopes plan to use the Shack-Hartmann approach for wavefront sensing. In these AO systems, the laser spots in subapertures at the edge of the pupil will suffer from spot elongation due to the 10 km extent of the sodium layer and the large separation from the projection laser. This spot elongation will severely degrade the performance of standard geometry wavefront sensing systems. In this paper, we present a CCD with custom pixel morphology that aligns the pixels of each subaperture with the radial extension of the LGS spot. This CCD design will give better performance than a standard geometry CCDs for continuous wave lasers. In addition, this CCD design is optimal for a pulsed sodium laser. The pixel geometry enables each subaperture to follow a laser pulse traversing the sodium layer, providing optimal sampling of a limited number of detected photons. In addition to novel pixel layout, this CCD will also incorporate experimental JFET sense amplifiers and use CMOS design approaches to simplify the routing of biases, clocks and video output. This CCD will attain photon-noise limited performance at high frame rates, and is being incorporated in the plans for the Thirty Meter Telescope (TMT).  相似文献