Plastic deformation of wadsleyite: II. High-pressure deformation in shear     

E. Thurel  P. Cordier  D. Frost  S.-I. Karato 《Physics and Chemistry of Minerals》2003,30(5):267-270

 We have studied the dislocation microstructures that develop in (Mg_0.9Fe_0.1)₂SiO₄ wadsleyite deformed by simple shear at high pressure. The experiments were performed in a multianvil apparatus with the shear assembly designed by Karato and Rubie (1997). The samples were synthesized in a separate experiment from high-purity oxides. The deformation experiments were carried out at 14 GPa and 1300 °C with time durations ranging from 1 to 8 h leading to plastic shear strains of 60 and 73%, respectively. The microstructures investigated by transmission electron microscopy (TEM) show that dislocation glide is activated under these conditions over the whole experimental time. The easy slip systems at 1300 °C involve 1/2<111> dislocations gliding in {101} as well as [100] dislocations gliding in (010) and {011}. Received: 15 July 2002 / Accepted: 14 February 2003 Acknowledgements High-pressure experiments were performed at the Bayerisches Geoinstitut under the EU IHP — Access to Research Infrastructures Programme (Contract no. HPRI-1999-CT-00004 to D.C. Rubie). The quality of the preparation of the TEM specimens by H. Schultze is greatly appreciated.  相似文献   

Employment and worktravel in a selection of English inner cities     

Martin Frost  Nigel Spence 《Geoforum》1981,12(2):107-160

The inner parts of many of the western world's metropolitan areas are currently suffering such drastic decline that many governments are attempting to rejuvenate their economic fortunes This is the context in which the present study is set, focusing attention on five major English cities — London, Manchester, Birmingham, Nottingham and Leicester — and using census employment and worktravel data for small areas. The study first reports on the relationships between the skills offered by residents, both male and female, and those demanded by employers in inner city areas. In addition to the consideration of the detailed variety of manufacturing and servicing activities taking place, an examination of the office and non-office components of both is undertaken. The second main aspect of the study considers the patterns of worktravel movement linking the places of residence and workplaces so described. The research concludes with a view on the policy implications of the results in the light of the overall context of the rejuvenation of inner city areas.  相似文献   

Analysis of atmospheric flow over a surface protrusion using the turbulence kinetic energy equation     

Walter Frost  W. L. Harper  G. H. Fichtl 《Boundary-Layer Meteorology》1975,8(3-4):401-417

Flow over surface obstructions can produce significantly large wind shears such that adverse flying conditions can occur for aeronautical systems (helicopters, STOL vehicles, etc.) Atmospheric flow fields resulting from a semi-elliptical surface obstruction in an otherwise horizontally homogeneous statistically stationary flow are modelled with the boundary-layer / Boussinesq-approximation of the governing equation of fluid mechanics. The turbulence kinetic energy equation is used to determine the dissipative effects of turbulent shear on the mean flow. Mean-flow results are compared with those given in a previous paper where the same problem was attacked using a Prandtl mixing-length hypothesis. The diffusion and convection of turbulence kinetic energy not accounted for in the Prandtl mixing-length concept cause departures of the mean wind profiles from those previously computed, primarily in the regions of strong pressure gradients. Iso-lines of turbulence kinetic energy and turbulence intensity are plotted in the plane of the flow. They highlight regions of high turbulence intensity in the stagnation zone and sharp gradients in intensity along the transition from adverse to favourable pressure gradient.  相似文献   

Forecasting the spatial extent of the annual flood in the Okavango delta, Botswana   总被引：1，自引：0，他引：1  

T. Gumbricht  P. Wolski  P. Frost  T. S. McCarthy   《Journal of Hydrology》2004,290(3-4):178-191

The pristine Okavango Delta wetland of northern Botswana is potentially under threat due to water abstraction from its tributaries. We have developed a statistical model which makes it possible to predict the extent of wetland loss which will arise from water abstraction. The model also permits prediction of the maximum area of flooding, and its spatial distribution, three months in advance of the flood maximum. The model was calibrated using maximum areas of seasonal inundation extracted from satellite imagery covering the period 1985–2000, which were correlated with rainfall and total flood discharge. A technique was developed to translate the modelled flood area into a flood map. The methodology can predict maximum area of flooding and its distribution with better than 90% accuracy. An important, although relatively minor, source of error in the spatial distribution of the flood arises from a secular change in flood distribution in the distal Delta which has taken place over the last 15 years. Reconstruction of flooding history back to 1934 suggests that the Delta may be subject to a quasi 80 year climatic oscillation. If this oscillation continues, the extent of flooding will increase in the coming decades.  相似文献   

Si in the core? New high-pressure and high-temperature experimental data     

Va?rie Malavergne  Julien Siebert  Fra?ois Guyot  Laurent Gautron  Tahar Hammouda  Dan Frost 《Geochimica et cosmochimica acta》2004,68(20):4201-4211

High-pressure high-temperature experiments have been carried out up to 25 GPa and 2200°C in a multianvil press on assemblages made of silicates and iron-silicon alloys. At 20 GPa, silicon is extracted from the metal phase, forming stishovite reaction rims around metal grains. The silicon content in metal has been measured by analytical electron microscopy and electron microprobe. In contrast with earlier experiments, the present data were obtained by using silicon-rich metal alloys as starting materials instead of studying incorporation of silicon in initially silicon-free metal. As in most of previous studies carried out below 25 GPa, the silicon content in liquid metal increases with increasing pressure and with decreasing oxygen fugacity. The oxygen fugacity in most experiments was calculated by using two independent buffers: iron/?stite (IW) and SiO₂/Si, allowing to link consistently the Fe contents in silicates, the Si contents in metal and the temperatures of the experiments. At oxygen fugacities 4 log units below IW, silicates are in equilibrium with Si-rich metallic alloys (up to 17 wt% of Si in metal at 20 GPa and 2200°C). Extrapolation to 2 log units below IW leads to less than 0.1 wt% Si in the metal phase. Presence of several wt% of silicon in the Earth’s core thus requires highly reduced initial materials that, if equilibrated at conditions relevant to small planets, should already contain significant amount of silicon dissolved in metal.  相似文献   

Strategies for high-temperature oxygen isotope thermometry: a worked example from the Laramie Anorthosite Complex, Wyoming, USA Earth. Planet. Sci. Lett. 117, 407–422, 1993     

James Farquhar  Thomas Chacko  B. Ronald Frost 《Earth and Planetary Science Letters》1995,130(1-4):235

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On Silica Activity and Serpentinization   总被引：10，自引：0，他引：10  

Frost  B. Ronald; Beard  James S. 《Journal of Petrology》2007,48(7):1351-1368

Serpentinites have the lowest silica activity of common crustalrocks. At the serpentinization front, where olivine, serpentine,and brucite are present, silica activities (relative to quartz)are of the order of 10^–2·5 to 10^–5, dependingon the temperature. Here we argue that this low silica activityis the critical property that produces the unusual geochemicalenvironments characteristic of serpentinization. The formationof magnetite is driven by the extraction of silica from theFe₃Si₂O₅(OH)₄ component of serpentine, producing extremely reducingconditions as evinced by the rare iron alloys that partiallyserpentinized peridotites contain. The incongruent dissolutionof diopside to form Ca²⁺, serpentine, and silica becomes increasinglyfavored at lower T, producing the alkalic fluids characteristicof serpentinites. The interaction of these fluids with adjacentrocks produces rodingites, and we argue that desilication isalso part of the rodingite-forming process. The low silica activityalso explains the occurrence of low-silica minerals such ashydrogrossular, andradite, jadeite, diaspore, and corundum inserpentinites or rocks adjacent to serpentinites. The tendencyfor silica activity to decrease with decreasing temperaturemeans that the presence of certain minerals in serpentinitescan be used as indicators of the temperature of serpentinization.These include, with decreasing temperature, diopside, andraditeand diaspore. Because the assemblage serpentine + brucite marksthe lowest silica activity reached in most serpentinites, thepresence and distribution of brucite, which commonly is a crypticphase in serpentinites, is critical to interpreting the processesthat lead to the hydration of any given serpentinite. KEY WORDS: serpentinization; serpentinites; silica activity; oxygen fugacity; rodingites; magnetization of serpentinites  相似文献   

Oil well produced water discharges to the North Sea. Part I: comparison of deployed mussels (Mytilus edulis), semi-permeable membrane devices, and the DREAM model predictions to estimate the dispersion of polycyclic aromatic hydrocarbons     

Durell G  Utvik TR  Johnsen S  Frost T  Neff J 《Marine environmental research》2006,62(3):194-223

The oil companies operating in the Norwegian sector of the North Sea have conducted field studies since the mid-1990s to monitor produced water discharges to the ocean. These studies have been used to refine monitoring methods, and to develop and validate a dispersion and impact assessment model. This paper summarizes monitoring data from surveys conducted in two major oil and gas production areas, and compares the results to concentrations of polycyclic aromatic hydrocarbons (PAH) in surface waters predicted by the dose-related risk and effect assessment model (DREAM). Blue mussels and semi-permeable membrane devices (SPMDs) were deployed in the Ekofisk and Tampen Regions and analyzed for more than 50 PAH. PAH concentrations in ambient seawater were estimated based on the mussels and SPMD concentrations, and compared to model predictions. Surface water total PAH concentrations ranged from 25 to 350 ng/L within 1 km of the platform discharges and reached background levels of 4-8 ng/L within 5-10 km of the discharge; a 100,000-fold dilution of the PAH in the discharge water. The PAH concentrations in surface water, predicted by three methods, compared well for the Ekofisk Region. The model predicted higher concentrations than the field-based methods for parts of the Tampen Region; particularly the most tidally influenced areas. Tidally-mediated fluctuations in PAH concentrations in surface water must be considered because they affect the estimation of PAH concentrations from mussel and SPMD residue data, and the predictions by the DREAM model. Predictions using mussels, SPMDs, and modeling support and complement each other; all are valuable tools for estimating the fate and impact of chemical contaminants in produced water that are discharged to the ocean.  相似文献   

Oil well produced water discharges to the North Sea. Part II: comparison of deployed mussels (Mytilus edulis) and the DREAM model to predict ecological risk     

Neff JM  Johnsen S  Frost TK  Utvik TI  Durell GS 《Marine environmental research》2006,62(3):224-246

Large volumes of water often are produced with oil and gas from offshore platforms. The produced water is separated from the oil and gas and either reinjected into a deep formation or discharged to the ocean. The Norwegian oil and gas industry advocates ecological risk assessment as the basis for managing produced water discharges to the North Sea. In this paper, we compare estimates of ecological risks to water-column communities based on data on hydrocarbon residues in soft tissues of blue mussels deployed for a month near offshore platforms and based on predictions of the Dose related Risk and Effect Assessment Model (DREAM). The study was performed near produced water discharges to the Tampen and Ekofisk Regions of the Norwegian Sector of the North Sea. Because polycyclic aromatic hydrocarbons (PAH) are considered the most important contributors to the ecological hazard posed by produced water discharges, comparisons made here focus on this group of compounds. The mussel approach is based on predicted environmental concentrations (PECs) of individual PAH, estimated from PAH residues in mussels following deployment for a month near several produced water discharges, and predicted no effects concentrations (PNECs) based on a K(ow) regression model. In the DREAM method, PECs for three PAH fractions are estimated in the three-dimensional area around produced water discharge with the DREAM model. PNECs for each fraction are based on the chronic toxicity of a representative PAH from each fraction divided by an assessment factor to account for uncertainty in the chronic value. The mussel method gives much lower estimates of ecological risk than the DREAM method. The differences are caused by the much lower PNECs used in DREAM than derived from the regression model, and by the lower concentrations of aqueous PAH predicted by DREAM than estimated from PAH residues in mussel tissues. However, the two methods rank stations at different distances from produced water discharges in the same order and both identify 2- and 3-ring PAHs as the main contributors to the ecological risk of produced water discharges. Neither method identifies a significant ecological risk of PAH in the upper water column of the oil fields. The DREAM model may produce an overly conservative estimate of ecological risk of produced water discharges to the North Sea.  相似文献   

The wetting ability of Si-bearing liquid Fe-alloys in a solid silicate matrix—percolation during core formation under reducing conditions?     

Ute Mann  Daniel J. Frost  David C. Rubie 《Physics of the Earth and Planetary Interiors》2008,167(1-2):1-7

The wetting characteristics of liquid Fe–Si alloys in a matrix of the respective predominating stable silicate mantle mineral (forsterite or silicate perovskite) at pressures of 2–5 and 25 GPa and temperatures of 1600–2000 °C were studied by determining the liquid metal–solid silicate contact angles. The median angle values from texturally equilibrated samples were found to be independent of pressure, temperature, silicate mineralogy and the Si content in the metal fraction and range between 130° and 140° which is far above the critical wetting boundary of 60°. This shows that within the studied range of conditions dissolved Si does not lower the surface energies between Fe-rich liquids and silicate mantle grains. As a consequence, under reducing conditions the presence of Si in the metal phase of planetary bodies would not have enhanced percolative flow as an effective metal–silicate separation process.  相似文献