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21.
The major element composition of plagioclase, pyroxene, olivine,and magnetite, and whole-rock 87Sr/86Sr data are presented forthe uppermost 2·1 km of the layered mafic rocks (upperMain Zone and Upper Zone) at Bierkraal in the western BushveldComplex. Initial 87Sr/86Sr ratios are near-constant (0·7073± 0·0001) for 24 samples and imply crystallizationfrom a homogeneous magma sheet without major magma rechargeor assimilation. The 2125 m thick section investigated in drillcore comprises 26 magnetitite and six nelsonite (magnetite–ilmenite–apatite)layers and changes up-section from gabbronorite (An72 plagioclase;Mg# 74 clinopyroxene) to magnetite–ilmenite–apatite–fayaliteferrodiorite (An43; Mg# 5 clinopyroxene; Fo1 olivine). The overallfractionation trend is, however, interrupted by reversals characterizedby higher An% of plagioclase, higher Mg# of pyroxene and olivine,and higher V2O5 of magnetite. In the upper half of the successionthere is also the intermittent presence of cumulus olivine andapatite. These reversals in normal fractionation trends definethe bases of at least nine major cycles. We have calculateda plausible composition for the magma from which this entiresuccession formed. Forward fractional crystallization modelingof this composition predicts an initial increase in total iron,near-constant SiO2 and an increasing density of the residualmagma before magnetite crystallizes. After magnetite beginsto crystallize the residual magma shows a near-constant totaliron, an increase in SiO2 and decrease in density. We explainthe observed cyclicity by bottom crystallization. Initiallymagma stratification developed during crystallization of thebasal gabbronorites. Once magnetite began to crystallize, periodicdensity inversion led to mixing with the overlying magma layer,producing mineralogical breaks between fractionation cycles.The magnetitite and nelsonite layers mainly occur within fractionationcycles, not at their bases. In at least two cases, crystallizationof thick magnetitite layers may have lowered the density ofthe basal layer of melt dramatically, and triggered the proposeddensity inversion, resulting in close, but not perfect, coincidenceof mineralogical breaks and packages of magnetitite layers. KEY WORDS: layered intrusion; mineral chemistry; isotopes; magma; convection; differentiation  相似文献   
22.
Stochastic Structural Modeling   总被引:3,自引:0,他引:3  
A consistent stochastic model for faults and horizons is described. The faults are represented as a parametric invertible deformation operator. The faults may truncate each other. The horizons are modeled as correlated Gaussian fields and are represented in a grid. Petrophysical variables may be modeled in a reservoir before faulting in order to describe the juxtaposition effect of the faulting. It is possible to condition the realization on petrophysics, horizons, and fault plane observations in wells in addition to seismic data. The transmissibility in the fault plane may also be included in the model. Four different methods to integrate the fault and horizon models in a common model is described. The method is illustrated on an example from a real petroleum field with 18 interpreted faults that are handled stochastically.  相似文献   
23.
Climate Dangers and Atoll Countries   总被引:2,自引:1,他引:2  
Climate change-induced sea-level rise, sea-surface warming, and increased frequency and intensity of extreme weather events puts the long-term ability of humans to inhabit atolls at risk. We argue that this risk constitutes a dangerous level of climatic change to atoll countries by potentially undermining their national sovereignty. We outline the novel challenges this presents to both climate change research and policy. For research, the challenge is to identify the critical thresholds of change beyond which atoll social-ecological systems may collapse. We explain how thresholds may be behaviorally driven as well as ecologically driven through the role of expectations in resource management. The challenge for the international policy process, centred on the UN Framework Convention on Climate Change (UNFCCC), is to recognize the particular vulnerability of atoll countries by operationalising international norms of justice, sovereignty, and human and national security in the regime.  相似文献   
24.
25.
Fluid flow in fractured rock is an increasingly central issue in recovering water and hydrocarbon supplies and geothermal energy, in predicting flow of pollutants underground, in engineering structures, and in understanding large-scale crustal behaviour. Conventional wisdom assumes that fluids prefer to flow along fractures oriented parallel or nearly parallel to modern-day maximum horizontal compressive stress, or SHmax. The reasoning is that these fractures have the lowest normal stresses across them and therefore provide the least resistance to flow. For example, this view governs how geophysicists design and interpret seismic experiments to probe fracture fluid pathways in the deep subsurface. Contrary to these widely held views, here we use core, stress measurement, and fluid flow data to show that SHmax does not necessarily coincide with the direction of open natural fractures in the subsurface (>3 km depth). Consequently, in situ stress direction cannot be considered to predict or control the direction of maximum permeability in rock. Where effective stress is compressive and fractures are expected to be closed, chemical alteration dictates location of open conduits, either preserving or destroying fracture flow pathways no matter their orientation.  相似文献   
26.
This paper reviews key characteristics of kimberlites on the Ekati property, NWT, Canada. To date 150 kimberlites have been discovered on the property, five of which are mined for diamonds. The kimberlites intrude Archean basement of the central Slave craton. Numerous Proterozoic diabase dykes intrude the area. The Precambrian rocks are overlain by Quaternary glacial sediments. No Phanerozoic rocks are present. However, mudstone xenoliths and disaggregated sediment within the kimberlites indicate that late-Cretaceous and Tertiary cover (likely <200 m) was present at the time of emplacement. The Ekati kimberlites range in age from 45 to 75 Ma. They are mostly small pipe-like bodies (surface area mostly <3 ha but up to 20 ha) that typically extend to projected depths of 400–600 m below current surface. Pipe morphologies are strongly controlled by joints and faults. The kimberlites consist primarily of variably bedded volcaniclastic kimberlite (VK). This is dominated by juvenile constituents (olivine and lesser kimberlitic ash) and variable amounts of exotic sediment (primarily mud), with minor amounts of xenolithic wall-rock material (generally <5%). Kimberlite types include: mud-rich resedimented VK (mRVK); olivine-rich VK (oVK); sedimentary kimberlite; primary VK (PVK); tuffisitic kimberlite (TK) and magmatic kimberlite (MK). The presence and arrangement of these rock types varies widely. The majority of bodies are dominated by oVK and mRVK, but PVK is prominent in the lower portions of certain kimberlites. TK is rare. MK occurs primarily as precursor dykes but, in a few cases, forms pipe-filling intrusions. The internal geology of the kimberlites ranges from simple single-phase pipes (RVK or MK), to complex bodies with multiple, distinct units of VK. The latter include pipes infilled with steep, irregular VK blocks/wedges and at least one case in which the pipe is occupied by well-defined sub-horizontal VK phases, including a unique, 100-m-thick graded sequence. The whole-rock compositions of VK samples suggest significant loss of kimberlitic fines during eruption followed by variable dilution by surface sediment and concurrent incorporation of kimberlitic ash. Diamond distribution within the kimberlites reflects the amount and nature of mantle material sampled by individual kimberlite phases, but is modified considerably by eruption and depositional processes. The characteristics of the Ekati kimberlites are consistent with a two-stage emplacement process: (1) explosive eruption/s causing vent clearing followed by formation of a significant tephra rim/cone of highly fragmented, olivine-enriched juvenile material with varying amounts of kimberlitic ash and surface sediments (predominantly mud); and (2) infilling of the vent by direct deposition from the eruption column and/or resedimentation of crater rim materials. The presence of less fragmented, juvenile-rich PVK in the lower portions of certain pipes and the intrusion of large volumes of MK to shallow levels in some bodies suggest emplacement of relatively volatile-depleted, less explosive kimberlite in the later stages of pipe formation and/or filling. Explosive devolatilisation of CO2-rich kimberlite magma is interpreted to have been the dominant eruption mechanism, but phreatomagmatism is thought to have played a role and, in certain cases, may have been dominant.  相似文献   
27.
New Rb–Sr age determinations using macrocrystal phlogopite are presented for 27 kimberlites from the Ekati property of the Lac de Gras region, Slave Province, Canada. These new data show that kimberlite magmatism at Ekati ranges in age from at least Late Paleocene (61 Ma) to Middle Eocene time (45 Ma). Older, perovskite-bearing kimberlites from Ekati extend this age range to Late Cretaceous time (74 Ma). Within this age range, emplacement episodes at 48, 51–53, 55–56 and 59–61 Ma can be recognized. Middle Eocene kimberlite magmatism of the previously dated Mark kimberlite (47.5 Ma) is shown to include four other pipes from the east-central Ekati property. A single kimberlite (Aaron) may be younger than the 47.5 Ma Mark kimberlite. The economically important Panda kimberlite is precisely dated in this study to be 53.3±0.6 Ma using the phlogopite isochron method, and up to six additional kimberlites from the central Ekati property have Early Eocene ages indistinguishable from that of Panda, including the Koala and Koala North occurrences. Late Paleocene 55–56 Ma kimberlite magmatism, represented by the Diavik kimberlite pipes adjacent to the southeastern Ekati property, is shown to extend onto the southeastern Ekati property and includes three, and possibly four, kimberlites. A precise eight-point phlogopite isochron for the Cobra South kimberlite yields an emplacement age of 59.7±0.4 Ma; eight other kimberlites from across the Ekati property have similar Late Paleocene Rb–Sr model ages. The addition of 27 new emplacement ages for kimberlites from the Ekati property confirms that kimberlite magmatism from the central Slave Province is geologically young, despite ages ranging back to Cambrian time from elsewhere in the Slave Province. With the available geochronologic database, Lac de Gras kimberlites with the highest diamond potential are currently restricted to the 51–53 and 55–56 Ma periods of kimberlite magmatism.  相似文献   
28.
This article provides an analysis of a wetland site in southern Illinois from presettlement to the present. The study area is part of the Cache River‐Cypress Creek Wetland, which has international importance, as recognized by the Ramsar Convention on Wetlands. Land‐cover data for 1807, 1938, and 1993 were created and analyzed with a geographic information system (GIS). Land‐use change by topographic setting (uplands, transitional, and bottomlands) and soil productivity was quantified and studied. Interviews with local experts informed this analysis. Results illustrate the complexity of environmental change and its driving forces. First, notable forest and swamp acreage was converted to cropland between 1807 and 1938 and, to a lesser degree, from 1938 to 1993. Second, there were land‐use variations by topographic region. Between 1807 and 1938, the largest transformation occurred in the uplands, with substantial acreage converted from forest to cropland. Between 1938 and 1993, however, agriculture decreased in the upland areas as hilly areas reverted to forest cover. At the same time, agriculture expanded in the bottomlands as this land was drained for farming. Third, there are interesting patterns within these categories of land‐use change, as soil productivity is an indicator of what lands were taken out of cropland and converted back to grassland and forest.  相似文献   
29.
The articles that comprise this critical review serve to draw attention to research papers published in specific fields of interest during 2003, provide critical comment on the relevance and importance of individual publications in these fields, and offer an overview of the comparative importance of advances in particular areas. In this way, these articles aim to assist experts in the field by keeping them informed of relevant recent publications, as well as providing an important resource for students or early career researchers who are embarking on studies in an area new to them. This year, five papers provide summaries of developments in bulk sample determinations employing (1) ICP-AES and ICP-MS (trace elements), (2) XRF and atomic absorption spectrometry and INAA, (3) isotope ratio measurements (TIMS, MC-ICP-MS, ICP-MS, ToF), as well as in situ measurements conducted using (4) secondary ion mass spectrometry and (5) laser ablation ICP-MS (trace element and isotope ratio determinations).  相似文献   
30.
Soil freeze–thaw events have important implications for water resources, flood risk, land productivity, and climate change. A property of these phenomena is the relationship between unfrozen water content and sub-freezing temperature, known as the soil freezing characteristic curve (SFC). It is documented that this relationship exhibits hysteretic behaviour when frozen soil thaws, leading to the definition of the soil thawing characteristic curve (STC). Although explanations have been given for SFC/STC hysteresis, the effect that ‘scale’ – particularly ‘measurement scale’ – may have on these curves has received little attention. The most commonly used measurement scale metric is the ‘support’, which is the spatial (or temporal) unit within which the measured variable is integrated or soil volume sampled. We show (a) measurement support can influence the range and shape of the SFC and (b) hysteresis can be attributed, in part, to the support and location of the measurements comprising the SFC/STC. We simulated lab measured temperature, volumetric water content (VWC), and permittivity from soil samples undergoing freeze–thaw transitions using Hydrus-1D and a modified Dobson permittivity model. To assess the effect of measurement support and location on SFC/STC, we masked the simulated temperature and VWC/permittivity extent to match the instrument's support and location. By creating a detailed simulation of the intra- and inter-support variability associated with the penetration of a freezing front, we demonstrate how measurement support and location can influence the temperature range over which water freezing events are captured. We show it is possible to simulate hysteresis in homogenous media with purely geometric considerations, suggesting that SFC/STC hysteresis may be more of an apparent phenomenon than mechanistically real. Lastly, we develop an understanding of how the location and support of soil temperature and VWC/permittivity measurements influence the temperature range over which water freezing events are captured.  相似文献   
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