浓硫酸钠水溶液中的离子对          下载免费PDF全文

刘元会  房春晖 《盐湖研究》2005,13(4):42-46

不同浓度的Na2SO4水溶液的拉曼光谱显示了SO42-的四个拉曼活性带:980 cm-1处的SO42-的对称伸缩振动模式v1带,1 106 cm-1处的反对称伸缩振动模式v3带,448 cm-1处的变形振动模式v2带和617 cm-1处的变形振动模式v4带。482 cm-1处的肩膀峰是由于NaSO4-离子对的形成对448 cm-1的v2带的影响而形成的SO42-的一个新的振动峰。浓Na2SO4水溶液中,水共享离子对[Na+.H2O.SO42-]-是主要的离子对物种。随着Na2SO4水溶液浓度的增加,Na+和SO42-的相互作用增强,NaSO4-离子对所占的摩尔分数增加。  相似文献   

Ionospheric effects in uncalibrated phase delay estimation and ambiguity-fixed PPP based on raw observable model   总被引：7，自引：5，他引：2  

Shengfeng Gu  Chuang Shi  Yidong Lou  Jingnan Liu 《Journal of Geodesy》2015,89(5):447-457

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Microseismicity Induced by Fault Activation During the Fracture Process of a Crown Pillar     

Penghai Zhang  Tianhong Yang  Qinglei Yu  Tao Xu  Wancheng Zhu  Honglei Liu  Jingren Zhou  Yongchuan Zhao 《Rock Mechanics and Rock Engineering》2015,48(4):1673-1682

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Using raw regional climate model outputs for quantifying climate change impacts on hydrology          下载免费PDF全文

Jie Chen  François P. Brissette  Pan Liu  Jun Xia 《水文研究》2017,31(24):4398-4413

General circulation model outputs are rarely used directly for quantifying climate change impacts on hydrology, due to their coarse resolution and inherent bias. Bias correction methods are usually applied to correct the statistical deviations of climate model outputs from the observed data. However, the use of bias correction methods for impact studies is often disputable, due to the lack of physical basis and the bias nonstationarity of climate model outputs. With the improvement in model resolution and reliability, it is now possible to investigate the direct use of regional climate model (RCM) outputs for impact studies. This study proposes an approach to use RCM simulations directly for quantifying the hydrological impacts of climate change over North America. With this method, a hydrological model (HSAMI) is specifically calibrated using the RCM simulations at the recent past period. The change in hydrological regimes for a future period (2041–2065) over the reference (1971–1995), simulated using bias‐corrected and nonbias‐corrected simulations, is compared using mean flow, spring high flow, and summer–autumn low flow as indicators. Three RCMs driven by three different general circulation models are used to investigate the uncertainty of hydrological simulations associated with the choice of a bias‐corrected or nonbias‐corrected RCM simulation. The results indicate that the uncertainty envelope is generally watershed and indicator dependent. It is difficult to draw a firm conclusion about whether one method is better than the other. In other words, the bias correction method could bring further uncertainty to future hydrological simulations, in addition to uncertainty related to the choice of a bias correction method. This implies that the nonbias‐corrected results should be provided to end users along with the bias‐corrected ones, along with a detailed explanation of the bias correction procedure. This information would be especially helpful to assist end users in making the most informed decisions.  相似文献   

Soil property variation mapping through data mining of soil category maps          下载免费PDF全文

Fei Du  A‐Xing Zhu  Lawrence Band  Jing Liu 《水文研究》2015,29(11):2491-2503

Spatial information on soil properties is an important input to hydrological models. In current hydrological modelling practices, soil property information is often derived from soil category maps by the linking method in which a representative soil property value is linked to each soil polygon. Limited by the area‐class nature of soil category maps, the derived soil property variation is discontinuous and less detailed than high resolution digital terrain or remote sensing data. This research proposed dmSoil, a data‐mining‐based approach to derive continuous and spatially detailed soil property information from soil category maps. First, the soil–environment relationships are extracted through data mining of a soil map. The similarity of the soil at each location to different soil types in the soil map is then estimated using the mined relationships. Prediction of soil property values at each location is made by combining the similarities of the soil at that location to different soil types and the representative soil property values of these soil types. The new approach was applied in the Raffelson Watershed and Pleasant Valley in the Driftless Area of Wisconsin, United States to map soil A horizon texture (in both areas) and depth to soil C horizon (in Pleasant Valley). The property maps from the dmSoil approach capture the spatial gradation and details of soil properties better than those from the linking method. The new approach also shows consistent accuracy improvement at validation points. In addition to the improved performances, the inputs for the dmSoil approach are easy to prepare, and the approach itself is simple to deploy. It provides an effective way to derive better soil property information from soil category maps for hydrological modelling. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Evaluation of Reinforcement and Analysis of Stability of a High-Arch Dam Based on Geomechanical Model Testing     

L. Zhang  Y. R. Liu  Q. Yang 《Rock Mechanics and Rock Engineering》2015,48(2):803-818

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Full and ideal mixing behavior between Zr–Wd (K2ZrSi3O9) and Ti–Wd (K2TiSi3O9): evidences from mineral chemistry,X-ray diffraction pattern and Raman spectrum     

Linlin Chang  Xi Liu  Chunming Wu  Xiaoyang Liu  Guowu Li 《Physics and Chemistry of Minerals》2015,42(3):223-234

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Analysis of Main Controlling Factors of Overburden Failure in Coal Mining Under Thick Coal Seam Geological Conditions     

Pang  Lifu  Liu  Weitao  Qin  Yueyun 《Geotechnical and Geological Engineering》2021,39(2):883-896

According to the theory of elastic mechanics half plane, the mechanical model of roof overburden failure is established. Based on the numerical simulation software FLAC^3D, the failure process of roof overburden in 1308 working face is numerically simulated according to the orthogonal experimental design scheme. Matrix analysis and variance analysis are used to analyze and calculate the simulation results to determine the sensitivity of the main control factors to the failure height of overlying rock of mining roof. The results show that: (1) with the increase of mining depth and the advancing distance of working face, the subsidence of roof overburden increases. (2) The order of influence of main controlling factors on roof overburden failure height is: mining depth > working face length > internal friction angle > mining thickness > coal seam dip angle > cohesion > tensile strength. (3) Variance analysis showed that the mining depth height was significant, the working face length and internal friction angle were significant, and the significance of working face length was slightly greater than that of internal friction angle, and other factors were not significant.

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Enhanced fault detection and exclusion based on Kalman filter with colored measurement noise and application to RTK     

Gao  Yuting  Gao  Yang  Liu  Baoyu  Jiang  Yang 《GPS Solutions》2021,25(3):1-15

GPS Solutions - The tropospheric delay is an important error source in the Global Positioning System (GPS) positioning and navigation applications. Although most of the tropospheric delays can be...  相似文献   

Quantifying the impact of landscape changes on hydrological variables in the alpine and cold region using hydrological model and remote sensing data     

Zizhen Jin  Qiudong Zhao  Xiang Qin  Jingtian Zhang  Hui Zhang  Jia Qin  Yu Qin  Hongyuan Li  Jizu Chen  Yushuo Liu  Yanzhao Li  Lihui Wang 《水文研究》2021,35(10):e14392

Quantifying the impact of landscape on hydrological variables is essential for the sustainable development of water resources. Understanding how landscape changes influence hydrological variables will greatly enhance the understanding of hydrological processes. Important vegetation parameters are considered in this study by using remote sensing data and VIC-CAS model to analyse the impact of landscape changes on hydrology in upper reaches of the Shule River Basin (URSLB). The results show there are differences in the runoff generation of landscape both in space and time. With increasing altitude, the runoff yields increased, with approximately 79.9% of the total runoff generated in the high mountains (4200–5900 m), and mainly consumed in the mid-low mountain region. Glacier landscape produced the largest runoff yields (24.9% of the total runoff), followed by low-coverage grassland (LG; 22.5%), alpine cold desert (AL; 19.6%), mid-coverage grassland (MG; 15.6%), bare land (12.5%), high-coverage grassland (HG; 4.5%) and shrubbery (0.4%). The relative capacity of runoff generation by landscapes, from high to low, was the glaciers, AL, LG, HG, MG, shrubbery and bare land. Furthermore, changes in landscapes cause hydrological variables changes, including evapotranspiration, runoff and baseflow. The study revealed that HG, MG, and bare land have a positive impact on evapotranspiration and a negative impact on runoff and baseflow, whereas AL and LG have a positive impact on runoff and baseflow and a negative impact on evapotranspiration. In contrast, glaciers have a positive impact on runoff. After the simulation in four vegetation scenarios, we concluded that the runoff regulation ability of grassland is greater than that of bare land. The grassland landscape is essential since it reduced the flood peak and conserved the soil and water.  相似文献