Esterification of vertebrate-like steroids in the eastern oyster (Crassostrea virginica)     

Gemma Janer  Sonia Mesia-Vela  Margy L. Wintermyer  Keith R. Cooper  Fred C. Kauffman  Cinta Porte 《Marine environmental research》2004,58(2-5):481

The esterification of two model vertebrate steroid hormones – estradiol (E2) and dehidroepiandrosterone (DHEA) – was studied in the oyster Crassostrea virginica. The activity of acyl-CoA:steroid acyltransferase was characterized in microsomal fractions isolated from oyster digestive glands. The apparent K_m and V_max values changed with the fatty acid acyl-CoA used (C20:4, C18:2, C18:1, C16:1, C18:0 or C16:0), and were in the range of 9–17 μM, and 35–74 pmol/min/mg protein for E2, and in the range of 45–120 μM, and 30–182 pmol/min/mg protein for DHEA. Kinetic parameters were also assessed in gonadal tissue. The enzyme saturated at similar concentrations, although conjugation rates were lower than in digestive gland. Preliminary data shows that tributyltin (TBT) in the low μM range (1–50) strongly inhibits E2 and DHEA esterification, the esterification of E2 being more sensitive to inhibition than that of DHEA. Overall, results indicate that apolar conjugation occurs in oysters, in both digestive gland and gonads, at a very similar rate to mammals, suggesting that this is a well conserved conjugation pathway during evolution. Esterification, together with other mechanisms, can modulate endogenous steroid levels in C. virginica, and might be a target for endocrine disrupters, such as TBT.  相似文献   

Acoustic evidences of gas in the continental slope sediments of the Gulf of Cadiz (E Atlantic)   总被引：1，自引：1，他引：1  

D. Casas  G. Ercilla  J. Baraza 《Geo-Marine Letters》2003,23(3-4):300-310

Detailed reviews of high-resolution acoustic studies in the continental slope of the Gulf of Cadiz has revealed the following gas-related features: acoustic turbidity and blanking, bright spots, ancient and modern pockmarks, high-amplitude diffractions, acoustic plumes and turbidity in the water column, and BSRs. The origin of the gas is believed to be biogenic and thermogenic. The BSR-like acoustic anomalies occur intermittently in some areas of the upper slope and tend to occur in the volcanoes/diapirs. The pressure–temperature conditions deduced for the location of those acoustic anomalies do not correspond to the conditions of stability of gas hydrates. It is suggested that these volcanoes/diapirs intrusions may locally induce anomalously higher pore pressure conditions on the immediately surrounding sediments, affecting the stability field of the gas hydrates.  相似文献   

A Textural Record of Solidification and Cooling in the Skaergaard Intrusion, East Greenland   总被引：2，自引：0，他引：2  

Holness  Marian B.; Tegner  Christian; Nielsen  Troels F. D.; Stripp  Gemma; Morse  Stearns A. 《Journal of Petrology》2007,48(12):2359-2377

The clinopyroxene–plagioclase–plagioclase dihedralangle, _cpp, in gabbroic cumulates records the time-integratedthermal history in the sub-solidus and provides a measure oftextural maturity. Variations in _cpp through the Layered Seriesof the Skaergaard intrusion, East Greenland, demonstrate thatthe onset of crystallization of clinopyroxene (within LZa),Fe–Ti oxides (at the base of LZc) and apatite (at thebase of UZb) as liquidus phases in the bulk magma is recordedby a stepwise increase in textural maturity, related to an increasein the contribution of latent heat to the total heat loss tothe surroundings and a reduction in the specific cooling rateat the crystallization front of the intrusion. The onset ofboth liquidus Fe–Ti oxide and apatite crystallizationis marked by a transient increase in textural maturity, probablylinked to overstepping before nucleation. Textural maturationat pyroxene–plagioclase–plagioclase triple junctionseffectively ceases in the uppermost parts of the Layered Seriesas a result of the entire pluton cooling below the closure temperaturefor dihedral angle change, which is 1075°C. Solidificationof the Layered Series of the Skaergaard intrusion occurred viathe upwards propagation of a mush zone only a few metres thick. KEY WORDS: magma; partial melting; asthenosphere; olivine; mantle  相似文献   

On board short-time high temperature heat treatment of ballast water: a field trial under operational conditions   总被引：2，自引：1，他引：1  

Quilez-Badia G  McCollin T  Josefsen KD  Vourdachas A  Gill ME  Mesbahi E  Frid CL 《Marine pollution bulletin》2008,56(1):127-135

A ballast water short-time high temperature heat treatment technique was applied on board a car-carrier during a voyage from Egypt to Belgium. Ballast water from three tanks was subjected for a few seconds to temperatures ranging from 55 degrees C to 80 degrees C. The water was heated using the vessel's heat exchanger steam and a second heat exchanger was used to pre-heat and cool down the water. The treatment was effective at causing mortality of bacteria, phytoplankton and zooplankton. The International Maritime Organization (IMO) standard was not agreed before this study was carried out, but comparing our results gives a broad indication that the IMO standard would have been met in some of the tests for the zooplankton, in all the tests for the phytoplankton; and probably on most occasions for the bacteria. Passing the water through the pump increased the kill rate but increasing the temperature above 55 degrees C did not improve the heat treatment's efficacy.  相似文献   

Sedimentary processes in the Selvage sediment-wave field, NE Atlantic: new insights into the formation of sediment waves by turbidity currents   总被引：5，自引：0，他引：5  

Russell B. Wynn  Philip P. E. Weaver  Gemma Ercilla  Dorrik A. V. Stow  & Douglas G. Masson 《Sedimentology》2000,47(6):1181-1197

An integrated geophysical and sedimentological investigation of the Selvage sediment-wave field has revealed that the sediment waves are formed beneath unconfined turbidity currents. The sediment waves occur on the lower continental rise and display wavelengths of up to 1 km and wave heights of up to 6 m. Wave sediments consist of interbedded turbidites and pelagic/hemipelagic marls and oozes. Nannofossil-based dating of the sediments indicates a bulk sedimentation rate of 2·4 cm 1000 years^–1, and the waves are migrating upslope at a rate of 0·28 m 1000 years^–1. Sediment provenance studies reveal that the turbidity currents maintaining the waves are largely sourced from volcanic islands to the south. Investigation of existing models for sediment-wave formation leads to the conclusion that the Selvage sediment waves form as giant antidunes. Simple numerical modelling reveals that turbidity currents crossing the wave field have internal Froude numbers of 0·5–1·9, which is very close to the antidune existence limits. Depositional flow velocities range from <6 to 125 cm^–1. There is a rapid increase in wavelength and flow thickness in the upper 10 km of the wave field, which is unexpected, as the slope angle remains relatively constant. This anomaly is possibly linked to a topographic obstacle just upslope of the sediment waves. Flows passing over the obstacle may undergo a hydraulic jump at its boundary, leading to an increase in flow thickness. In the lower 15 km of the wave field, flow thickness decreases downslope by 60%, which is comparable with results obtained for other unconfined turbidity currents undergoing flow expansion.  相似文献   

The impact of ditch blocking on the hydrological functioning of blanket peatlands   总被引：1，自引：0，他引：1       下载免费PDF全文

Joseph Holden  Sophie M. Green  Andy J. Baird  Richard P. Grayson  Gemma P. Dooling  Pippa J. Chapman  Christopher D. Evans  Mike Peacock  Graeme Swindles 《水文研究》2017,31(3):525-539

Ditch blocking in blanket peatlands is common as part of peatland restoration. The effects of ditch blocking on flow regimes and nearby water tables were examined in a field trial. After an initial 6‐month monitoring period, eight ditches had peat dams installed 10 m apart along their entire length (dammed), four of these ditches were also partially infilled through bank reprofiling (reprofiled). Four ditches were left open with no dams or reprofiling (open). These 12 ditches and the surrounding peat were monitored for 4 more years. An initial five‐fold reduction in discharge occurred in the dammed and the reprofiled ditches with the displaced water being diverted to overland flow and pathways away from the ditches. However, there was a gradual change over time in ditch flow regime in subsequent years, with the overall volume of water leaving the dammed and the reprofiled ditches increasing per unit of rainfall to around twice that which occurred in the first year after blocking. Hence, monitoring for greater than one year is important for understanding hydrological impacts of peatland restoration. Overland flow and flow in the upper ~4 cm of peat was common and occurred in the inter‐ditch areas for over half of the time after ditch blocking. There was strong evidence that topographic boundaries of small ditch catchments, despite being defined using a high‐resolution Light Detection And Ranging‐based terrain model, were not always equivalent to actual catchment areas. Hence, caution is needed when upscaling area‐based fluxes, such as aquatic carbon fluxes, from smaller scale studies including those using ditches and small streams. The effect of ditch blocking on local water tables was spatially highly variable but small overall (time‐weighted mean effect <2 cm). Practitioners seeking to raise water tables through peatland restoration should first be informed either by prior measurement of water tables or by spatial modelling to show whether the peatland already has shallow water tables or whether there are locations that could potentially undergo large water‐table recoveries.  相似文献   

A Least-Cost Approach to Personal Exposure Reduction     

Gemma Davies  Duncan Whyatt 《Transactions in GIS》2009,13(2):229-246

Concerns over the potential negative health effects from exposure to air pollution have led to interest in assessing personal exposure and finding ways to reduce it. As journey-time exposure accounts for a disproportionately high amount of an individual's total exposure, this article assesses the potential to apply least-cost techniques within a GIS in order to identify paths of lower journey-time exposure. The methodology adopted uses pollution surfaces for PM₁₀ and CO generated by the dispersion model ADMS, with an analysis mask derived from OS MasterMap to create a least-cost surface. Actual routes taken by a cohort of 11–13 year old children on their journeys to school are used to compare observed journey time exposure with the exposure along alternative routes generated using the least-cost path function. While the least-cost approach proved to be successful in defining low exposure routes the ability to scale up this approach is constrained by the amount of editing required to successfully create an analysis mask from OS MasterMap data. Such alternative routes have the potential to assist in promoting safer environmental choices, however, their likelihood of adoption is dependant on a number of social and environmental influences which affect an individual's route choice.  相似文献   

Water‐level dynamics in natural and artificial pools in blanket peatlands          下载免费PDF全文

Joseph Holden  Catherine S. Moody  T. Edward Turner  Rebecca McKenzie  Andy J. Baird  Mike F. Billett  Pippa J. Chapman  Kerry J. Dinsmore  Richard P. Grayson  Roxane Andersen  Clare Gee  Gemma Dooling 《水文研究》2018,32(4):550-561

Perennial pools are common natural features of peatlands, and their hydrological functioning and turnover may be important for carbon fluxes, aquatic ecology, and downstream water quality. Peatland restoration methods such as ditch blocking result in many new pools. However, little is known about the hydrological function of either pool type. We monitored six natural and six artificial pools on a Scottish blanket peatland. Pool water levels were more variable in all seasons in artificial pools having greater water level increases and faster recession responses to storms than natural pools. Pools overflowed by a median of 9 and 54 times pool volume per year for natural and artificial pools, respectively, but this varied widely because some large pools had small upslope catchments and vice versa. Mean peat water‐table depths were similar between natural and artificial pool sites but much more variable over time at the artificial pool site, possibly due to a lower bulk specific yield across this site. Pool levels and pool‐level fluctuations were not the same as those of local water tables in the adjacent peat. Pool‐level time series were much smoother, with more damped rainfall or recession responses than those for peat water tables. There were strong hydraulic gradients between the peat and pools, with absolute water tables often being 20–30 cm higher or lower than water levels in pools only 1–4 m away. However, as peat hydraulic conductivity was very low (median of 1.5 × 10^?5 and 1.4 × 10^?6 cm s^?1 at 30 and 50 cm depths at the natural pool site), there was little deep subsurface flow interaction. We conclude that (a) for peat restoration projects, a larger total pool surface area is likely to result in smaller flood peaks downstream, at least during summer months, because peatland bulk specific yield will be greater; and (b) surface and near‐surface connectivity during storm events and topographic context, rather than pool size alone, must be taken into account in future peatland pool and stream chemistry studies.  相似文献   

The Baraza Slide: model and dynamics     

D. Casas  G. Ercilla  M. Yenes  F. Estrada  B. Alonso  M. Garc??a  L. Somoza 《Marine Geophysical Researches》2011,32(1-2):245-256

The Baraza Slide is located in the northwestern Alboran Sea, western Mediterranean region, between 590 and 830?m water depth, and its morphology, seismic facies and sedimentary structure are analyzed based on multibeam bathymetry and very high to medium resolution single-channel seismic records. During the Pleistocene and Late Quaternary this landslide has undergone repeated slope failures characterized by a succession of two main types of mass movement, the first of the mass-flow type and the second of the slide type. This study also reveals that the western sector of this landslide could still be active. The relatively high slope gradients, a sedimentary column characterized by the presence of under consolidated layers and earthquake shaking related to tectonic activity on the margin are the factors governing the genesis and post-mobility behavior of the Baraza mass movement. The recognition and analysis of these factors suggest that the Baraza Slide should be considered as a geo-hazard in the tectonically active Alboran Sea.  相似文献   

KARSYS hydrogeological 3D modeling of alpine karst aquifers developed in geologically complex areas: Picos de Europa National Park (Spain)     

Daniel Ballesteros  Arnauld Malard  Pierre-Yves Jeannin  Montserrat Jiménez-Sánchez  Joaquín García-Sansegundo  Mónica Meléndez-Asensio  Gemma Sendra 《Environmental Earth Sciences》2015,74(12):7699-7714

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