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31.
Nitrate reductase activity and the concentrations of selenite and selenate were monitored for six months at the mouth of Chesapeake Bay (USA). A positive correlation was found between nitrate reductase activity and the concentration of selenite, suggesting that selenite may be formed in coastal waters and nitrate reductase may be involved in the process.  相似文献   
32.
Thermodynamic stability constants have been estimated for the complexation of iron(III) with catecholate-type siderophores isolated from the marine bacterium Alteromonas luteoviolacea and from the marine cyanobacterium Synechococcus sp. PCC 7002. Stability constants were determined utilizing the “chelate scale” of Taylor et al. (1994). The scale is based upon a linear relationship between the reduction potentials and the pH-independent thermodynamic stability constants for known iron(III) complexes. Log K values for the alterobactin B ferric iron complex are 43.6 ± 1.5 at pH 8.2 and 37.6 ± 1.2 at pH 6, consistent with a shift from bis-catecholate to monosalicylate/monocatecholate iron coordination with decreasing pH. Synechococcus isolates PCC 7002 Nos. 1 and 3 formed iron(III) complexes with stability constants of approximately 38.1 ± 1.2 and 42.3 ± 1.5, respectively. The binding strengths of the iron(III) complexes examined in this study are quite high, suggesting that catecholate siderophores may play a role in the solubilization and biological uptake of iron in the marine environment.  相似文献   
33.
The build-up of pore-water pressure by waves can lead to sediment liquefaction and subsequent transport by traction currents. This process was investigated by measuring pore-water pressures both in a field experiment and laboratory wave tank tests. Liquefaction was observed in the wave tank tests. The results suggest that sand is less susceptible than silts to wave-induced liquefaction because of the tendency to partially dissipate pore-water pressures. However, previous studies have determined that pore-water pressures must approach liquefaction before current velocities necessary to initiate transport are reduced. Once liquefaction has occurred more sediment can be transported.  相似文献   
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Storms and shoreline retreat in the southern Gulf of St. Lawrence   总被引:1,自引:0,他引:1  
Storms play a major role in shoreline recession on transgressive coasts. In the southern Gulf of St. Lawrence (GSL), southeastern Canada, long-term relative sea-level rise off the North Shore of Prince Edward Island has averaged 0.3 m/century over the past 6000 years (>0.2 m/century over 2000 years). This has driven long-term coastal retreat at mean rates >0.5 m/a but the variance and details of coastal profile response remain poorly understood. Despite extensive sandy shores, sediment supply is limited and sand is transferred landward into multidecadal to century-scale storage in coastal dunes, barrier washover deposits, and flood-tidal delta sinks. Charlottetown tide-gauge records show mean relative sea-level rise of 3.2 mm/a (0.32 m/century) since 1911. A further rise of 0.7±0.4 m is projected over the next 100 years. When differenced from tidal predictions, the water-level data provide a 90-year record of storm-surge occurrence. Combined with wind, wave hindcast, and sea-ice data, this provides a catalogue of potentially significant coastal storms. We also document coastal impacts from three recent storms of great severity in January and October 2000 and November 2001. Digital photogrammetry (1935–1990) and shore-zone surveys (1989–2001) show large spatial and temporal variance in coastal recession rates, weakly correlated with the storm record, in part because of wave suppression or coastal protection by sea ice. Large storms cause rapid erosion from which recovery depends in part on local sand supply, but barrier volume may be conserved by washover deposition. Barrier shores with dunes show high longshore and interdecadal variance, with extensive multidecadal healing of former inlet and overwash gaps. This reflects recovery from an episode of widespread overwash prior to 1935, possibly initiated by intense storms or groups of storms in the latter half of the 19th century. With evidence from the storms of 2000–2001, this points to the importance of storm clustering on scales of weeks to years in determining erosion vulnerability, as well as the need for a long-term, large-scale perspective in assessing coastal stability. The expected acceleration in relative sea-level rise, together with projections of increasing storm intensity and greatly diminished winter ice cover in the southern GSL, implies a significant increase in coastal erosion hazards in future.  相似文献   
37.
Early life stages of Spisula solidissima (1-, 4-, 8- and 12-h post-fertilization) were exposed to various concentrations of silver in solution (0, 4, 8, 24, 44, 124 and 278 μg liter?1) for 1 h. An additional group of 1-h post-fertilized eggs was treated with 0, 4, 11 and 24 μg liter?1 silver continuously for 48h. Results indicate that younger embryos are more susceptible to Ag. Exposure of one-hour-old embryos to silver for only 1 h gives results similar to a continuous 48-h exposure to the same concentration of Ag. The calculated EC50 for 48-h continuously exposed embryos was similar to the EC50 for 1-h post-fertilized embryos that were exposed to silver for only 1 h.  相似文献   
38.
Th sorption and export models in the water column: A review   总被引:2,自引:3,他引:2  
Over the past few decades, the radioisotope pair of 238U / 234Th has been widely and increasingly used to describe particle dynamics and particle export fluxes in a variety of aquatic systems. The present paper is one of five review articles dedicated to 234Th. It is focused on the models associated with 234Th whereas the companion papers (same issue) are focused on present and future methodologies and techniques (Rutgers van der Loeff et al.), C / 234Th ratios (Buesseler et al.), 234Th speciation (Santschi et al.) and present and future applications of 234Th [Waples, J.T., Benitez-Nelson, C.R., Savoye, N., Rutgers van der Loeff, M., Baskaran, M., Gustafsson, Ö., this issue. An Introduction to the application and future use of 234Th in aquatic systems. Marine Chemistry, FATE special issue]. In this paper, we review current 234Th scavenging models and discuss the relative importance of the non-steady state and physical terms associated with the most commonly used model to estimate 234Th flux. Based on this discussion we recommend that for future work the use of models should be accompanied by a discussion of the effect that model and data uncertainty have on the model results. We also suggest that future field work incorporate repeat occupations of sample sites on time scales of 1–4 weeks in order to evaluate steady state versus non-steady state estimates of 234Th export, especially during high flux events (> ca. 800 dpm m− 2 d− 1). Finally, knowledge of the physical oceanography of the study area is essential, particularly in ocean margins and in areas of established upwelling (e.g., Equatorial Pacific). These suggestions will greatly enhance the application of 234Th as a tracer of particle dynamics and flux in more complicated regimes.  相似文献   
39.
A unique whale call with 50–52 Hz emphasis from a single source has been tracked over 12 years in the central and eastern North Pacific. These calls, referred to as 52-Hz calls, were monitored and analyzed from acoustic data recorded by hydrophones of the US Navy Sound Surveillance System (SOSUS) and other arrays. The calls were noticed first in 1989, and have been detected and tracked since 1992. No other calls with similar characteristics have been identified in the acoustic data from any hydrophone system in the North Pacific basin. Only one series of these 52-Hz calls has been recorded at a time, with no call overlap, suggesting that a single whale produced the calls. The calls were recorded from August to February with most in December and January. The species producing these calls is unknown. The tracks of the 52-Hz whale were different each year, and varied in length from 708 to 11,062 km with travel speeds ranging from 0.7 to 3.8 km/h. Tracks included (A) meandering over short ranges, (B) predominantly west-to-east movement, and (C) mostly north-to-south travel. These tracks consistently appeared to be unrelated to the presence or movement of other whale species (blue, fin and humpback) monitored year-round with the same hydrophones.  相似文献   
40.
A series of transient tests were conducted to determine the seafloor coupling characteristics of a new ocean-bottom seismometer (OBS) developed for the United States Office of Naval Research (ONR). The OBS comprises a large recording package and a separate sensor package that is deployed from the recording package. In addition to the coupling characteristics of both the sensor and the recording packages, the seismic energy radiated from the main recording package as a result of motion of the recording package was measured. The observed vertical coupling resonances of both the recording package and the sensor package are in good agreement with those predicted by a simple model of soil-structure interaction. The most important result of this study is that significant energy is radiated from the recording package in response to horizontal motions of the recording package. When the sensor package is 1 m from the recording package, the amplitude of the recorded signal is similar to that recorded in the recording package. In the field, this effect will result in distortion of seismic signals and increased background noise recorded by the sensor package if the recording package is disturbed by seafloor currents or biological activity. The amplitude of this signal attenuates by approximately a factor of two as sensor/recorder separation is increased from 1 to 6 m, suggesting that an improved response can be achieved by increasing the separation between the recording package and the sensors. This effect is much less severe for vertical disturbances of the recording package.  相似文献   
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