Calcite Dissolution Kinetics     

Rolf?S.?ArvidsonEmail author  Cornelius?Fischer  Andreas?Luttge 《Aquatic Geochemistry》2015,21(5):415-422

We compare the canonical treatment of calcite’s dissolution rate from the literature in a closed system, particle batch reactor, with the alternative approach suggested by Truesdale (Aquat Geochem, 2015). We show that the decay of rate over time can be understood in terms of the evolution and distribution of reactive sites on the surface of these particles. We also emphasize that interpretation of observed rates must not exclude the fundamental role of crystal defects, whose importance is already implicitly reflected in the common form of rate laws in geochemistry. The empirical behavior of overall rate in closed systems, such as those described by Truesdale, may thus reflect relationships between defect centers and the generation of steps over the calcite surface (previously documented for silicates), such that below a critical free energy limit, there is insufficient driving force to open hollow cores and thus a loss of reaction mechanism. Dissolution in this very-near-equilibrium regime will be dependent on the distribution of extant steps and the energetics of new kink site nucleation. However, these sensitivities are complicated in the case of particle systems by grain boundaries, edges, corners, and other terminations. Such discontinuities constitute a defect class whose overall kinetic importance will be strongly tied to particle diameter and which can act independently of the internal strain field imposed by screw and edge dislocations.  相似文献   

Highly gravity-driven flow of a NAPL in water-saturated porous media using the discontinuous Galerkin finite-element method with a generalised Godunov scheme     

Lauriane Schneider  Raphaël di Chiara Roupert  Gerhard Schäfer  Philippe Helluy 《Computational Geosciences》2015,19(4):855-876

  相似文献   

Winter-to-spring temperature dynamics in Turkey derived from tree rings since AD 1125   总被引：2，自引：1，他引：1  

Ingo Heinrich  Ramzi Touchan  Isabel Dorado Liñán  Heinz Vos  Gerhard Helle 《Climate Dynamics》2013,41(7-8):1685-1701

In the eastern Mediterranean in general and in Turkey in particular, temperature reconstructions based on tree rings have not been achieved so far. Furthermore, centennial-long chronologies of stable isotopes are generally also missing. Recent studies have identified the tree species Juniperus excelsa as one of the most promising tree species in Turkey for developing long climate sensitive stable carbon isotope chronologies because this species is long-living and thus has the ability to capture low-frequency climate signals. We were able to develop a statistically robust, precisely dated and annually resolved chronology back to AD 1125. We proved that variability of δ¹³C in tree rings of J. excelsa is mainly dependent on winter-to-spring temperatures (January–May). Low-frequency trends, which were associated with the medieval warm period and the little ice age, were identified in the winter-to-spring temperature reconstruction, however, the twentieth century warming trend found elsewhere could not be identified in our proxy record, nor was it found in the corresponding meteorological data used for our study. Comparisons with other northern-hemispherical proxy data showed that similar low-frequency signals are present until the beginning of the twentieth century when the other proxies derived from further north indicate a significant warming while the winter-to-spring temperature proxy from SW-Turkey does not. Correlation analyses including our temperature reconstruction and seven well-known climate indices suggest that various atmospheric oscillation patterns are capable of influencing the temperature variations in SW-Turkey.  相似文献   

An ESA NEOCC Effort to Eliminate High Palermo Scale Virtual Impactors     

Marco Micheli  Detlef Koschny  Gerhard Drolshagen  Olivier Hainaut  Fabrizio Bernardi 《Earth, Moon, and Planets》2014,113(1-4):1-13

In this work we summarize the initial results of a targeted effort of the ESA NEO Coordination Centre to obtain additional observational data in order to eliminate or reduce the impact probability estimate of a subset of the known near-Earth objects representing the highest fraction of the total known impact risk, as measured by the Palermo Scale.  相似文献   

Views and news     

L. C. Gerhard 《Environmental Geology》1995,26(2):136-137

  相似文献   

Solar irradiance below 120 nm and its variations     

Gerhard Schmidtke 《Solar physics》1981,74(1):251-263

The solar irradiance below 120 nm was first predicted by astronomers. Since its accurate measurement required the solution of a variety of technological problems, little is known about the variability before 1972, though for more than two decades data have been collected. Therefore, on a quantitative basis only a very rough picture can be given for the solar cycle 19. Also, not enough data with sufficient absolute accuracy are available to describe the solar EUV flux variations of the solar cycle 20, especially during the period of solar maximum. However, due to technological improvements of space and laboratory instrumentations, an almost complete set of data has been obtained from 1972 to date. These observations exhibit strong differences of the flux variations from solar cycle 20 to 21. - For the theoretical and for semi-empirical treatments of many aeronomic processes controlled by the solar EUV radiation, its adequate representation e.g. as indices is required. The problems involved and possible solutions are discussed. Results from some relevant aeronomically oriented computations based on variable solar EUV fluxes are presented.Proceedings of the 14th ESLAB Symposium on Physics of Solar Variations, 16–19 September 1980, Scheveningen, The Netherlands.  相似文献   

Theoretical density distribution of plasma streaming around a cylinder     

R. Grabowski  T. Fischer 《Planetary and Space Science》1975,23(2):287-304

The distribution of plasma density around a metallic cylinder in a collisionfree plasma is determined by the system of Vlassov equations and the Poisson equation. The plasma may have a streaming velocity perpendicular to the cylinder axis producing a wake behind the cylinder. In the region outside a thin double layer at the cylinder surface the problem allows some simplification. Then numerical solutions become possible-even if the streaming velocity is low. Some numerical solutions are presented. A magnetic field produces an asymmetric shape of the wake, if the gyration radius of the ion becomes comparable to the cylinder radius.  相似文献   

The ‘land-locked’ viewpoint     

Gerhard Hafner 《Marine Policy》1981,5(3):281-282

While the Draft Convention still leaves the land-locked states with very considerable disadvantages, it can be said to represent a success for such states in so far as the notion of land-locked states forms a definite part of the proposed law of the sea and therefore provided them with the power to influence further developments.  相似文献   

Is there a black hole among the black-hole candidates?     

Wolfgang Kundt  Daniel Fischer 《Journal of Astrophysics and Astronomy》1989,10(1):119-138

None of the tentative black-hole identifications has remained without serious difficulties. As a class, the black-hole candidates differ in no obvious property from neutron-star binaries other than in their estimated high mass. We favour an interpretation of the black-hole candidates as binary neutron stars surrounded by a more or less massive accretion disc  相似文献   

Topography and minimization of the standard deviation in one-dimensional magnetotelluric modelling     

Gaston Fischer  B. V. Le  Quang 《Geophysical Journal International》1981,67(2):279-292

  相似文献