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21.
Analyses have been made of many groundwater samples, some of which were collected from the vicinity of uranium deposits and others from unmineralized areas, for dissolved uranium and for the four naturally occurring isotopes of radium: 226Ra (238U decay series,
y), 228Ra and 224Ra (232Th decay series,
y and 3.8 d) and 223Ra (235U decay series,
d). The radium isotopes 226Ra, 224Ra and 223Ra, are measured by alpha-spectrometry after extraction from a water sample soon after collection and 228Ra at a later time by determining the amount of ingrown 212Po. 相似文献
22.
Charles S. Hopkinson Anne E. Giblin Jane Tucker Robert H. Garritt 《Estuaries and Coasts》1999,22(4):863-881
Benthic metabolism and nutrient exchange across the sediment-water interface were examined over an annual cycle at four sites along a freshwater to marine transect in the Parker River-Plum Island Sound estuary in northeastern Massachusetts, U.S. Sediment organic carbon content was highest at the freshwater site (10.3%) and decreased along the salinity gradient to 0.2% in the sandy sediments at the marine end of the estuary. C:N ratios were highest in the mid estuary (23:1) and lowest near the sea (11:1). Chlorophyll a in the surface sediments was high along the entire length of the estuary (39–57 mg chlorophyll a m−2) but especially so in the sandy marine sediments (172 mg chlorophyll a m−2). Chlorophyll a to phaeophytin ratios suggested most chlorophyll is detrital, except at the sandy marine site. Porewater sulfide values varied seasonally and between sites, reflecting both changes in sulfate availability as overlying water salinity changed and sediment metabolism. Patterns of sediment redox potential followed those of sulfide. Porewater profiles of inorganic N and P reflected strong seasonal patterns in remineralization, accumulation, and release. Highest porewater NH4 + values were found in upper and mid estuarine sediments, occasionally exceeding 1 mM N. Porewater nitrate was frequently absent, except in the sandy marine sediments where concentrations of 8 μM were often observed. Annual average respiration was lowest at the marine site (13 mmol O2 m−2 d−1 and 21 mmol TCO2 m−2 d−1) and highest in the mid estuary (130 mmol O2 m−2 d−1 and 170 mmol TCO2 m−2 d−1) where clam densities were also high. N2O and CH4 fluxes were low at all stations throughout the year: Over the course, of a year, sediments varied from being sources to sinks of dissolved organic C and N, with the overall spatial pattern related closely to sediment organic content. There was little correlation between PO4 3− flux and metabolism, which we attribute to geochemical processes. At the two sites having the lowest salinities, PO4 3− flux was directed into the sediments. On average, between 22% and 32% of total system metabolism was attributable to the benthos. The mid estuary site was an exception, as benthic metabolism accounted for 95% of the total, which is attributable to high densities of filter-feeding clams. Benthic remineralization supplied from less than 1% to over 190% of the N requirements and 0% to 21% of the P requirements of primary producers in this system. Estimates of denitrification calculated from stoichiometry of C and N fluxes ranged from 0% for the upper and mid estuary site to 35% for the freshwater site to 100% of sediment organic N remineralization at the marine site. We hypothesize that low values in the upper and mid estuary are attributable to enhanced NH4 + fluxes during summer due to desorption of exchangeable ammonium from rising porewater salinity. NH4 + desorption during summer may be a mechanism that maintains high rates of pelagic primary production at a time of low inorganic N inputs from the watershed. 相似文献
23.
Carbon Cycling and the Coupling Between Proton and Electron Transfer Reactions in Aquatic Sediments in Lake Champlain 总被引:1,自引:0,他引:1
Wei-Jun Cai George W. LutherIII Jeffrey C. Cornwell Anne E. Giblin 《Aquatic Geochemistry》2010,16(3):421-446
We used fine-scale porewater profiles and rate measurements together with a multiple component transport–reaction model to
investigate carbon degradation pathways and the coupling between electron and proton transfer reactions in Lake Champlain
sediments. We measured porewater profiles of O2, Mn2+, Fe2+, HS−, pH and pCO2 at mm resolution by microelectrodes, and profiles of NO3
−, SO4
2−, NH4
+, total inorganic carbon (DIC) and total alkalinity (TA) at cm resolution using standard wet chemical techniques. In addition,
sediment–water fluxes of oxygen, DIC, nitrate, ammonium and N2 were measured. Rates of gross and net sulfate reduction were also measured in the sediments. It is shown that organic matter
(OM) decomposes via six pathways: oxic respiration (35.2%), denitrification (10.4%), MnO2 reduction (3.6%), FeOOH reduction (9.6%), sulfate reduction (14.9%), and methanogenesis (26.4%). In the lake sediments, about
half of the benthic O2 flux is used for aerobic respiration, and the rest is used for the regeneration of other electron acceptors produced during
the above diagenetic reactions. There is a strong coupling between O2 usage and Mn2+ oxidation. MnO2 is also an important player in Fe and S cycles and in pH and TA balance. Although nitrate concentrations in the overlying
water were low, denitrification becomes a quantitatively important pathway for OM decomposition due to the oxidation of NH4
+ to NO3
−. Finally, despite its low concentration in freshwater, sulfate is an important electron acceptor due to its high efficiency
of internal cycling. This paper also discusses quantitatively the relationship between redox reactions and the porewater pH
values. It is demonstrated here that pH and pCO2 are sensitive variables that reflect various oxidation and precipitation reactions in porewater, while DIC and TA profiles
provide effective constraints on the rates of various diagenetic reactions. 相似文献
24.
Joanna K. York Gabrielle Tomasky Ivan Valiela Anne E. Giblin 《Estuaries and Coasts》2010,33(5):1069-1079
We measured fluxes of NH4+ and NO3− and δ15N of NH4+, sediment, and porewater NH4+ from incubated sediment cores along a nitrate gradient and in different seasons from Childs River, MA. NH4+ flux was low at the downstream site with the lowest concentration of organic matter (high salinity) but otherwise did not
differ along the estuary. The δ15N of regenerated NH4+ ranged from +6.1‰ to +15.3‰ but did not vary significantly with season or salinity; the mean for the entire estuary was +10.4 ± 0.5‰.
Based on differences between the δ15N of regenerated NH4+ and sediment, and expected isotopic fractionation due to remineralization, we concluded that nitrification occurred after
remineralization of NH4+. Differences between the δ15N of regenerated NH4+ and the δ15N of porewater NH4+ provided further evidence of nitrification. We estimated that 11% to 48% of remineralized NH4+ underwent coupled nitrification–denitrification before release into the water column. In spite of losses to denitrification,
NH4+ flux released 1.4 mol N m−2 year−1 to the water column and could provide 42% of phytoplankton nitrogen requirements. 相似文献
25.
Peter A. Siver Richard Ricard Richard Goodwin Anne E. Giblin 《Journal of Paleolimnology》2003,29(2):179-197
Sediment cores were used to estimate in-lake alkalinity generation resulting from sulfate reduction relative to inferred changes in lakewater pH and trophic status over the last century in three Connecticut lakes. Despite being situated in geological settings with crystalline bedrock and thin, poorly buffered soils, and being impacted with high rates of acidic precipitation, none of the study lakes have declined in inferred pH based on scaled chrysophyte and diatom remains. In fact, the pH of one of the lakes, Coventry Lake, has significantly increased over the last century. Over the last 44 to 69 years the amount of sulfur stored in the sediments from each lake increased from ~two to three times resulting in mean rates of alkalinity generation ranging from 78 to 145 meq m–2 yr–1, significantly higher than the 45 to 48 meq m–2 yr–1 of hydrogen ions falling directly on the lake surfaces. In-lake alkalinity generation resulting from sulfate reduction has been sufficient to neutralize all of the acid falling directly onto the lake surfaces, as well as between 9% and 25% of the acid deposited onto the surrounding watersheds. Despite the increased importance of in-lake alkalinity generation, our findings support the hypothesis that significant amounts of alkalinity are also being generated in the catchments of the study lakes. The bulk of the increases in stored sulfur in all three lakes were as Fe sulfides and not in the form of organic sulfur, suggesting that the increases were the result of dissimilatory bacterial reduction of sulfate. As a result of the large increases in storage of Fe sulfides the ratio of total iron to chromium reducible sulfur (Fe:CRS) has declined in all cores over time. Despite the overall decline in Fe:CRS in recent sediments, values are still largely above 3 in more recent sediments of two of the lakes. However, values of Fe:CRS have dropped below 1 in surface sediments of Uncas Lake, suggesting that in-lake loading of phosphorus may be responsible for a recent shift in the algal flora towards a slightly more eutrophic condition. 相似文献
26.
Woods PM Kouveliotou C van Paradijs J Briggs MS Hurley K Göğüş E Preece RD Giblin TW Thompson C Duncan RC 《The Astrophysical journal》1999,527(1):L47-L50
We present evidence for burst emission from SGR 1900+14 with a power-law high-energy spectrum extending beyond 500 keV. Unlike previous detections of high-energy photons during bursts from soft gamma repeaters (SGRs), these emissions are not associated with extraordinarily bright flares. Not only is the emission hard, but the spectra are better fitted by D. Band's gamma-ray burst (GRB) function rather than by the traditional optically thin thermal bremsstrahlung model. We find that the spectral evolution within these hard events obeys a hardness/intensity anticorrelation. Temporally, these events are distinct from typical SGR burst emissions in that they are longer ( approximately 1 s) and have relatively smooth profiles. Despite a difference in peak luminosity of greater, similar1011 between these bursts from SGR 1900+14 and cosmological GRBs, there are striking temporal and spectral similarities between the two kinds of bursts, aside from spectral evolution. We outline an interpretation of these events in the context of the magnetar model. 相似文献
27.
We present results from 27 impact experiments using porous (porosity ranging from 0.39 to 0.54) ice targets and solid ice projectiles at impact speeds ranging from 90 to 155 m/s. These targets were designed to simulate Kuiper Belt Objects (KBOs) in structure. We measured a specific energy for shattering, , of 2.1×105 erg/g for those snowball targets hit by intact ice projectiles; this is of the same order as that measured for solid ice targets. The fragment mass distribution follows a power law, although the exponent is not simply related to the largest fragment size as assumed by fragmentation models. We provide the first measurement of the three-dimensional mass-velocity distribution for disrupted ice targets and find that fragment speeds range from ∼2 to ∼20 m/s. The fraction of collisional kinetic energy that is partitioned into ejecta speeds is between 1 and 15% (although it should be noted that the lower limit is more reliable than the upper). 相似文献
28.
Melanie Hayn Robert Howarth Roxanne Marino Neil Ganju Peter Berg Kenneth H. Foreman Anne E. Giblin Karen McGlathery 《Estuaries and Coasts》2014,37(1):63-73
West Falmouth Harbor, a shallow lagoon on Cape Cod, has experienced a threefold increase in nitrogen load since the mid- to late 1990s due to input from a groundwater plume contaminated by a municipal wastewater treatment plant. We measured the exchange of nitrogen and phosphorus between the harbor and the coastal waters of Buzzards Bay over several years when the harbor was experiencing this elevated nitrogen load. During summer months, the harbor not only retained the entire watershed nitrogen load but also had a net import of nitrogen from Buzzards Bay. During the spring and fall, the harbor had a net export of nitrogen to Buzzards Bay. We did not measure the export in winter, but assuming the winter net export was less than 112 % of the load, the harbor exported less than half of the watershed nitrogen load on an annual basis. For phosphorus, the harbor had a net import from coastal waters in the spring and summer months and a net export in the fall. Despite the large increase in nitrogen load to the harbor, the summertime import of phosphorus from Buzzards Bay was sufficient to maintain nitrogen limitation of primary productivity during the summer. Our findings illustrate that shallow systems dominated by benthic producers have the potential to retain large terrestrial nitrogen loads when there is sufficient supply of phosphorus from exchange with coastal waters. 相似文献