Immunotoxicity of the xenoestrogen 4-nonylphenol to the cockle Cerastoderma glaucum     

Valerio Matozzo  Giulio Rova  Francesco Ricciardi  Maria Gabriella Marin 《Marine pollution bulletin》2008,57(6-12):453

The in vivo effects of 4-nonylphenol (NP) on functional responses of haemocytes from the cockle Cerastoderma glaucum were investigated after 7 days exposure to sublethal NP concentrations (0, 0+acetone, 0.0125, 0.025, 0.05 and 0.1 mg/l NP). Haemocytes from both controls and exposed cockles were collected, and the effects of NP on total haemocyte count (THC) and volume of circulating cells, intracellular superoxide anion () levels, acid phosphatase and lysozyme-like activities in both haemocyte lysate (HL) and cell-free haemolymph (CFH) were evaluated. Exposure of cockles to 0.1 mg/l NP significantly increased THC (p < 0.05) with respect to controls. Analysis of haemocyte size frequency distribution showed that the haemocyte fraction of about 7–8 μm in diameter and 250 femtolitres in volume increased markedly in cockles exposed to the highest NP concentration tested. Apoptosis resulting in cell volume reduction in NP-exposed animals cannot be excluded. No statistically significant variation in intracellular levels was observed. Conversely, significant increases (p < 0.05) in acid phosphatase activity were observed in CFH from 0.05 and 0.1 mg/l NP-exposed animals; no significant differences in enzyme activity were recorded in HL. Lysozyme-like activity also increased significantly in CFH from cockles exposed to 0.05 mg/l NP (p < 0.05) and 0.1 mg/l NP (p < 0.001). Instead, lysozyme-like activity decreased significantly (p < 0.05) in the HL of animals exposed to 0.05 mg/l NP. Our results suggest that NP induces variations in the functional responses of haemocytes of C. glaucum, mainly by reducing cell membrane stability and promoting cell degranulation.  相似文献   

A numerical study on seismic damage of masonry fortresses     

Giulio Castori  Marco Corradi  Alessandro De Maria  Romina Sisti  Antonio Borri 《Bulletin of Earthquake Engineering》2018,16(10):4561-4580

Studies oriented to restoration and conservation of historical monumental buildings have recourse to structural analysis as a way to investigate the genuine structural features of the construction, to better understand its present condition and actual causes of existing damage, to estimate its safety conditions and to determine necessary remedial measures. Based on this background, this paper discusses on the seismic vulnerability of masonry fortresses by means of an analysis methodology based on three different analytical procedures, according to an increased knowledge of the structure. As a relevant case study the Albornoz fortress, a 14th stone masonry construction located in central Italy, was selected. Initially, the strategy proposed to perform this task was aimed at testing and developing an expeditious and non-destructive procedure to evaluate both the seismic vulnerability and the main mechanical properties of the different masonry typologies. The macroscale structural behavior of the fortress was then evaluated through a nonlinear static analysis (pushover) and a more simple approach based on the kinematic theorems of the limit analysis. From this point of view, by comparing the capacity of the construction to withstand lateral loads with the expected demands resulting from seismic actions, these methods provided a highly effective means of verifying the safety of the masonry structure and its vulnerability to extensive damage and collapse.  相似文献   

Updating knowledge on growth,population dynamics,and ecology of the blue and red shrimp,Aristeus antennatus (Risso, 1816), on the basis of the study of its instars     

Lidia Orsi Relini  Alessandro Mannini  Giulio Relini 《Marine Ecology》2013,34(1):90-102

Both national (GRUND) and international (MEDITS) trawl surveys carried out in the Italian seas since 1994 have produced consistent and rather homogeneous samples of red shrimps (per season, gear, and methods to ascertain abundance). Study and discussion of data regarding Aristeus antennatus (Risso, 1816) from Ligurian fishing grounds during the REDs project (FISH/2004/03‐32) made it possible to verify how key instars of the life of the female shrimp can be recognized from length frequency distributions derived from trawl surveys, allowing the age distributions to be split up. The segment of life that can be studied spans ages 1 and 10 and includes 20 instars, but larger sizes have been found which may extend the life span another 3 years. After age 5, only one growth instar per year occurs. Based on our study of the instars, we developed a size/age key for A. antennatus and used it to derive a von Bertalanffy growth function, total mortality rates and exploitation rates. Our results are related to basic biological and ecological characteristics of this species. Large individuals (females ≥50 mm CL at age 5 onward) present in a considerable percentage in the Ligurian Sea, are very important because (i) their fecundity is very high and therefore greatly influences the reproductive potential and (ii) they represent commercially the most valuable part of the catch. In addition, substantial relationships between the life history of A. antennatus and local oceanographic processes exist because the long life span of the species enlarges the area to which eggs and larvae are transported in surface currents, as well as the active return movements in deep waters where adult life mainly takes place. In the study area, the Northern Current provides the possibility of great horizontal displacement of A. antennatus eggs, larvae and early juveniles and, in general, attention to surface circulation may help to identify affinities in distant Mediterranean populations. This study presents A. antennatus in terms of a resource on the move at a Western Mediterranean scale.  相似文献   

Settling and compaction of olivine in basaltic magmas: an experimental study on the time scales of cumulate formation     

Max W. Schmidt  Melanie Forien  Giulio Solferino  Nickolai Bagdassarov 《Contributions to Mineralogy and Petrology》2012,164(6):959-976

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Geothermal mineralized scales in the pipe system of the geothermal Piancastagnaio power plant (Mt. Amiata geothermal area): a key to understand the stibnite,cinnabarite and gold mineralization of Tuscany (central Italy)     

Giulio Morteani  Giovanni Ruggieri  Peter Möller  Christine Preinfalk 《Mineralium Deposita》2011,46(2):197-210

The CO₂-rich geothermal fluids produced in the Piancastagnaio geothermal field (Mt. Amiata geothermal area, Southern Tuscany, Italy) show temperatures up to 360°C and pressures of about 200 bar at depths of around 3,500 m (Giolito, Ph.D. thesis, Università degli Studi di Firenze, Italy, pp 1–147, 2005). CaCO₃- and/or SiO₂-dominated scales are deposited in the pipes leading to the pressure and atmospheric separators of the geothermal wells. High content of metastibnite and/or stibnite in both calcite and silica scales and Sb contents of up to 50 mg/L in the fluids indicate their mineralising potential. The red or black colours of the scales depend on the predominance of red metastibnite or black stibnite, respectively. In our condensation experiments, as well as during deposition of the scales, metastibnite is the first Sb₂S₃ mineral to form. In a second stage, metastibnite is transformed to stibnite. During depressurization the Hg content of geothermal fluids partitions preferentially into the gas phase, whereas Sb and As remain in the liquid phase. This separation explains the often observed areal separation of Hg and Sb mineralization. The multistage deposition of Sb in the mining district of Tuscany is due to a periodic restoration of the permeability of the ore-bearing faults by microseismic events and subsequent host rock brecciation. The still ongoing microseismic events are induced by the accumulation of high-pressure CO₂-rich fluids along faults followed by mechanical failure of the faults.  相似文献   

Seismic characterization and monitoring of Fucino Basin (Central Italy)   总被引：1，自引：1，他引：0  

F. Cara  G. Di Giulio  G. P. Cavinato  D. Famiani  G. Milana 《Bulletin of Earthquake Engineering》2011,9(6):1961-1985

The Fucino basin (Central Italy) is one of the largest intramountain alluvial plain in the Apennines range. It has a tectonic origin related to the presence of important systems of faults located in its northern and eastern edges. Some of these faults are still active and capable of generating strong seismic events. Site effects related to the soft soils filling the basin can be very important. In this paper we show the preliminary results of a seismic network installed in the Fucino area in order to collect information about site amplification effects and geometry of the basin. We analyze ambient seismic vibrations and recordings of about 150 local earthquakes mainly related to the seismic sequence of the April 6th 2009 Mw 6.3 L’Aquila event. Moreover the strongest events of L’Aquila sequence were analyzed at the three permanent strong-motion stations operating in the area. Using standard spectral techniques we investigate the variation of resonance frequencies within the basin. The ground motion recorded in the Fucino plain is mainly characterized by strong energy at low-frequencies (f < 1 Hz) affecting both horizontal and vertical components. This is particularly evident for stations deployed in correspondence of very thick deposits of sedimentary filling, where a significant increase of ground-motion amplitude and duration is likely caused by locally generated surface waves. The amplification at low-frequencies (<1 Hz) on the horizontal components can reach up a factor of 10 in comparison to nearby stiff sites. However, we found evidences of seismic amplification phenomena also for stiff sites surrounding the basin, including stations of the Italian strong motion network. The independent geological information and the shallow shear-velocity profiles available for the basin can be combined with resonance frequencies for deriving representative geological sections to be used as base for future numerical 2D–3D modeling of the basin.  相似文献   

40Ar/39Ar laser probe dating of the Central European tektite‐producing impact event     

Marinella A. LAURENZI  Giulio BIGAZZI  Maria Laura BALESTRIERI  Vladimìr BOU&#x;KA 《Meteoritics & planetary science》2003,38(6):887-893

Abstract— A new ⁴⁰Ar/³⁹Ar data set is presented for tektites from the Central European strewn field (moldavites). This is the only strewn field that is entirely situated in a continental environment and still characterized by scattered ages (14–15.3 Myr). The main objectives of the study were to define more precisely the moldavite formation age and provide a good calibration for a glass standard proposed for fission‐track dating. The laser total fusion ages obtained on chips from 7 individual specimens from the Southern Bohemian and Moravian subfields are restricted to a narrow interval of time, with an average of 14.34 ± 0.08 Myr relative to the 27.95 ± 0.09 Myr of the Fish Canyon Tuff biotite. This result gives a more precise age not only for the tektite field but also for its producing impact. If the genetic link between the moldavites and the Nördlinger Ries impact crater is maintained, then this new age has to be considered a reliable estimate for the Ries crater also. This new value places the formation of Central European tektites within the Lower Serravallian period in the latest geologic timescales. Evidence of their impact products, such as glass spherules or shocked minerals, can, therefore, be sought in sedimentary marine formations in a more precisely defined age interval.  相似文献   

Neogene exhumation of the Marrakech High Atlas (Morocco) recorded by apatite fission-track analysis     

Maria Laura Balestrieri  Giovanna Moratti  Giulio Bigazzi  Ahmed Algouti 《地学学报》2009,21(2):75-82

Apatite fission-track (AFT) data have been obtained along a traverse across the Marrakech High Atlas to constrain its tectono-thermal evolution. AFT ages vary between 212 ± 15 Ma and 20 ± 4 Ma. An Early Miocene AFT age accompanied by long mean track length from the central part of the chain has been interpreted as the timing of the main inversion of this region with the creation of relief because of the shortening induced by the interplay between the African and Eurasian plates. Thermal modelling of samples collected south of the South Atlas Fault Zone indicates a Middle-Late Miocene or even later cooling that has been attributed to the component of the uplift of the chain related to the thermal anomaly present beneath the Atlas Mountains.  相似文献   

K‐Ar illite age constraints on the Proterozoic formation and reactivation history of a brittle fault in Fennoscandia     

Giulio Viola  Horst Zwingmann  Jussi Mattila  Asko Käpyaho 《地学学报》2013,25(3):236-244

K‐Ar ages of authigenic illite from two drill‐core gouge samples of a fault in the Palaeoproterozoic basement of Finland record two distinct faulting events. The older sample yields apparent ages from 1240 ± 26 to 1006 ± 21 Ma for four grain size fractions between 6 and <0.1 μm. The second sample is structurally younger and yields statistically distinct ages ranging from 978 ± 20 to 886 ± 18 Ma. We interpret the ages of the <0.1 m fractions, which are the youngest, as representing the actual time of faulting. XRD analysis and age modelling exclude significant age contamination of the finest dated fractions with inherited host rock components. These results provide therefore an example of meaningful isotopic dating of illite‐type clay material formed during Precambrian faulting, demonstrate and constrain fault reactivation and give evidence for brittle Sveconorwegian Mesoproterozoic shortening and Neoproterozoic extension in Fennoscandia.  相似文献   

Ab-initio structure, energy and stable Fe isotope equilibrium fractionation of some geochemically relevant H-O-Fe complexes     

Giulio Ottonello 《Geochimica et cosmochimica acta》2009,73(21):6447-6654

The hexa-aqua complexes [Fe(H₂O)_6−m−n(OH)_n]⁽²⁻ⁿ⁾⁺n = 0 → 3, m = 0 → 6 − n; [Fe(H₂O)_6−m−n(OH)_n]⁽³⁻ⁿ⁾⁺n = 0 → 4, m = 0 → 6 − n were investigated by ab-initio methods with the aim of determining their ground-state geometries, total energies and vibrational properties by treating their inner solvation shell as part of their gaseous precursor¹ (or “hybrid approach”). After a gas-phase energy optimization within the Density Functional Theory (DFT), the molecules were surrounded by a dielectric representing the Reaction Field through an implicit Polarized Continuum Model (PCM). The exploration of several structural ligand arrangements allowed us to quantify the relative stabilities of the various ionic species and the role of the various forms of energy (solute-solvent electronic interaction, cavitation, dispersion, repulsion, liberation free energy) that contribute to stabilize the aqueous complexes. A comparison with experimental thermochemistries showed that ab-initio gas-phase + solvation energies are quite consistent with experimental evidence and allow the depiction of the most stable form in solution and the eventual configurational disorder of water/hydroxyl species around central cations. A vibrational analysis performed on the ⁵⁴Fe, ⁵⁶Fe, ⁵⁷Fe and ⁵⁸Fe isotopomers indicated important separative effects systematically affected by the extent of deprotonation. The role of the system’s redox state (fO₂) and acidity (pH) on the isotopic imprinting of the aqueous species in solution was investigated by coupling the separative effects with speciation calculations. The observed systematics provided a tool of general utility in the interpretation of the iron isotopic signature of natural waters. Applications to the interpretation of isotopic fractionation in solution dictated by redox equilibria and to the significance of the Fe-isotopic imprinting of Banded Iron Formations are given.  相似文献