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21.
Detrital zircon (DZ) U‐Pb laser ablation‐inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS) has revolutionised the way geologists approach many Earth science questions. Although recent research has focused on rapid sample throughput, acquisition rates are limited to 100–300 analyses h?1. We present a method to acquire zircon U‐Pb dates at rates of 120, 300, 600 and 1200 analyses h?1 (30, 12, 6 and 3 s per analysis) by multi‐collector LA‐ICP‐MS. We demonstrate the efficacy of this method by analysing twelve zircon reference materials with dates from ~ 3465 to ~ 28 Ma. Mean offset from high‐precision dates increases with faster rates from 0.9% to 1.1%; mean random 1s uncertainty increases from 0.6% to 1.3%. We tested this new method on a sandstone sample previously characterised by large‐n DZ geochronology. Quantitative comparison shows increased correspondence among age distributions comprising > 300 dates. This new method holds promise for DZ geochronology because (a) it requires no major changes to hardware, but rather modifications to software; (b) it yields robust age distributions well‐suited for quantitative analysis and maximum depositional age calculations; (c) there is only a minor sacrifice of accuracy and measurement uncertainty; and (d) there is less burden to researchers in terms of time investment and analytical cost.  相似文献   
22.
The Arctic is more vulnerable to climate change than are mid latitudes. Therefore, palaeolimnological studies from the High Arctic are important in providing insights into the dynamics of the climate system. Here we present a multi‐proxy study from one of the world's northernmost lakes: Bliss Lake, Peary Land, Greenland. The early Holocene (10 850–10 480 cal. a BP) is characterized by increased erosion and gradually more marine conditions. Full marine conditions developed from 10 480 cal. a BP until the lake was isolated at 7220 cal. a BP. From its marine isolation at 7220 cal. a BP Bliss Lake becomes a lacustrine environment. Evidence from geochemical proxies (δ13C and total organic carbon) suggests that warmer conditions prevailed between 7220 and 6500 cal. a BP, corresponding to the Holocene thermal maximum, and from 3300 until 910 cal. a BP. From 850 to 500 cal. a BP colder climate conditions persisted. The transition from warmer to colder climate conditions taking place around 850 cal. a BP may be associated with the transition from the Medieval Warm Period to the Little Ice Age. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
23.
The enthalpies of transition at T= 298 K between zinc metasilicate assemblages, measured by molten oxide solution calorimetry, are:
  相似文献   
24.
According to the present state of science and technology, the ultimate disposal of critical substances such as chemotoxic wastes, metal slurries, radioactive substances, etc., as well as houshold waste, necessitates enclosure within a multi-barrier system. The geology of the disposal site plays an important role. The site itself defines the geological barrier which has to fulfill at least two requirements: namely low permeability and retention, respectively retardation qualities. These can be achieved to a certain degree either by clay minerals, zeolites or an artificial product such as active coal. In order to increase the imperviousness and retardation potentials of e.g. clayey geological barriers, technical barriers have to be added. One of them and the most important is the mineralogic barrier. It consists of clay dominated layers and according to the multimineral barrier concept the different layers have to meet different functions.  相似文献   
25.
The equilibrium diffusion technique has become a valuable tool for ecological and biogeochemical studies in aquatic environments. In sediment ecosystems, changes in concentration of microbial metabolites with increasing depth can be determined dependably and reproducibly with this technique. Since the permeation characteristics of the membranes employed are crucial, selecting the proper membrane requires knowledge about its behavior under conditions which prevail in the natural environment. Thirteen polymer sheets were evaluated comparing permeation terms for biogeochemically relevant solutes, biodegradability, and mechanical strength. Cellulose-based dialysis membranes are most satisfactory when employed in low temperature anoxic environments. For this membrane, correction terms were calculated to account for diffusion losses during retrieval and sampling. Optimal incubation times can now be predicted from experimentally determined permeation coefficients for several porewater solutes. Dialysis porewater samplers (DPS) have been successfully applied during more than 100 independent experiments for the collection of interstitial water from surface sediments. DPS were used for water depths as deep as 290 meters.  相似文献   
26.
Mantle fragments of ultramafic composition are widespread in the Scandinavian Caledonides (SC). Lenses and boudins of Alpine-type peridotites in the Scandinavian Caledonides represent parts of dismembered ophiolite sequences and fragments of sub-continental upper mantle. Metaperidotites of nappes in internal positions are generally isofacial with the metamorphic envelope, usually Caledonian metasediments but in places also Precambrian metagranitoids forming the basement cores of the nappes. Caledonian metamorphism strongly modified the texture and mineralogy of the peridotites and resulted in a systematic metamorphic pattern which is consistent with the pattern observed in the envelope.

Metaperidotites of the external massifs display at least a two-stage metamorphic history: an early Caledonian high-pressure high-temperature phase related to early crustal stacking and a late Caledonian regional metamorphic overprint which produced a regular Barrovian-type metamorphic pattern of in-situ metamorphism.

Metaperidotites from nappes in intermediate positions (Iapetus Ocean ophiolites and ultramafic rocks from island arc environments) show strongly diverging histories. Metaperidotites from internal ophiolites (oceanic ophiolites, Köli) lack any evidence of subduction metamorphism, are serpentinized to various degrees, show abundant primary mantle relic mineralogies and the Caledonian metamorphic overprint is low. Metaperidotites from external (island arc) ophiolites and other associations (Seve) often show relic high-pressure metamorphism related to the Finnmarkian phase of the Caledonian orogeny. The Seve metaperidotites are occasionally associated with eclogites and show a weak overprint of late Caledonian regional metamorphism. Alpine-type peridotites are absent in the foreland of the Baltic Shield and in the innermost nappes (Lofoten).

The metamorphic characteristics and evolution recorded by the metaperidotites in the Scandinavian Caledonides allow a general reconstruction of the dynamics of collision belt formation.  相似文献   

27.
Zusammenfassung Die vorquartäre Geschichte des Molassebeckens nördlich der Alpen läßt sich in 3 Großabschnitte unterteilen, in deren Ablauf sich umrißhaft die jeweils zugehörigen Entwicklungsstadien des aufsteigenden Gebirges widerspiegeln, die bisweilen umgekehrt auch von Ereignissen im Vorland beeinflußt werden. Der 1. Abschnitt (Obereozän bis Aquitan/ Ober-Eger) ist von der in den Westalpen beginnenden Hebung sowie von Bewegungen der savischen Dislokationsphase geprägt, in besonderem Maße ferner an der Rupel/ChattGrenze von der größten Meeresspiegelsenkung seit dem Kambrium. Im 2. Abschnitt (Burdigal/Eggenburg bis Unterpannon) verlagert sich die Hebungsaktivität zu den Ostalpen, womit im Vorland die große, E-W gerichtete Flußschüttung der Oberen Süßwassermolasse ausgelöst wird. In ihr verursacht die gewaltige Erderschütterung des Riesmeteoriten-Einschlags im höheren Baden vermutlich die Flußverlegung der Enns, eines ihrer beiden Hauptzubringer, zum Grazer Becken und damit eine sich u. a. im Schwermineralbestand (als A-Grenze) abzeichnende Änderung der Materialzufuhr aus dem Gebirge. Im 3. Abschnitt (Unterpannon bis Pliozän) geht infolge weiteren Aufsteigens der Alpen samt Vorland bei gleichzeitiger Verlagerung des Hebungszentrums wieder zur Westschweiz die bisherige Akkumulation in Denudation über, die von dem sich nun von Niederösterreich aus ins Molassebecken hineinfressenden Donausystem besorgt wird.Die während des 2. Großabschnitts von der Auflast der vorrückenden kalkalpinen Dekken aus ihrem Ablagerungsraum herausgequetschte ältere Molasse ist zu den alpenparallelen Mulden des gefalteten Bereichs zusammengeschoben, mit einer wohl erst im 3. Abschnitt entstandenen Achsendepression zwischen Iller und Mangfall. In diesen Zeitraum vor allem fällt auch die Verformung der jüngeren ungefalteten Molasse zu einer alpenparallelen Großmulde, deren Achse nach SW und E aushebt.
The pre-Quaternary history of the Molasse basin north of the Alps can be subdivided into three major phases, in the course of which the respective associated evolutional stages of the rising mountains are reflected in outline. On the other hand, these stages are occasionally also influenced by events in the foreland. The first phase (Upper Eocene to Aquitanian/Upper Egerian) ist characterized by the uplifting beginning in the Western Alps and movements of the Savic dislocation phase, and in particular also at the Rupelian/Chattian boundary by the greatest eustatic lowering of the sea level since the Cambrian period. During the second phase (Burdigalian/Eggenburgian to Lower Pannonian) the uplifting shifts to the Eastern Alps, bringing about in the foreland the large E-W directed fluvial accretion of the Upper Fresh-water-Molasse. During its progress the enormous earth-tremor of the Ries meteoric impact in the upper Badenian presumably leads to the diversion of the Enns river, being one of the two main tributaries, to the Graz basin, resulting in a change in the material supply from the mountains, which is reflected in the heavy mineral content (designated as A-boundary). In the third phase (Lower Pannonian to Pliocene) the previous accumulation, as a result of the continuing uplifting of the Alps and the foreland with simultaneous shifting of the uplift centre back to Western Switzerland, turns to denudation which is effected by the Danube system extending from Lower Austria into the Molasse basin.The older Molasse squeezed out of its deposition area by the overburden of the advancing Austroalpine nappes has been compressed to the throughs of the folded zone along the Alps, with an axis depression between the rivers Iller and Mangfall, which has presumably not developed until the third phase. Above all, during this period the deformation of the younger unfolded Molasse to a large trough paralleling the Alps also took place; its axis rises to the SW and E.

Résumé L'histoire préquaternaire du bassin molassique au nord des Alpes peut se diviser en trois périodes principales dont le déroulement reflète à grands traits les phases de développement corrélatives de la chaîne en voie de soulèvement. D'autre part, ces phases de développement sont de temps en temps influencées par des événements intervenus dans le bassin. La première période (Eocène supérieur à Aquitanien/Egerien supérieur) est marquée par le soulèvement commençant dans les Alpes occidentales, ainsi que par des mouvements de la phase de dislocation savique et, en particulier à la limite du Rupélien/Chattien, par le plus grand abaissement eustatique du niveau de la mer depuis le Cambrien. Pendant la seconde période (Burdigalien/Eggenburgien à Pannonien inférieur) l'activité de soulèvement se déplace vers les Alpes orientales, provoquant dans le bassin préalpin la grande accrétion fluviale de la Süßwassermolasse (Molasse d'eau douce) supérieure dirigée de l'est vers l'ouest. Le violent ébranlement terrestre produit dans celle-ci par l'impact de la météorite dans le Ries pendant le Badénien supérieur mène probablement le détournement de l'Enns, l'un des deux fleuves tributaires principaux, vers le bassin de Graz, donnant lieu à un changement dans le transport de matériaux venant des montagnes, ce qui se reflète dans la teneur en minerais lourds (dénommé « limite A »). Pendant la troisième période (Pannonien inférieur à Pliocène), l'accumulation antérieure, par suite du soulèvement continu des Alpes et du bassin préalpin, accompagné de la retraite du centre du soulèvement vers la Suisse occidentale, tourne à la dénudation qui est effectuée par le système danubien s'étendant dès lors de la Basse-Autriche au bassin molassique.La Molasse plus ancienne expulsée pendant la seconde période principale de son milieu de sedimentation par la pression des nappes austroalpines susjacentes en progression a été comprimée en auges de la zone pliée le long des Alpes, avec un abaissement axial entre l'Iller et le Mangfall, qui ne s'est probablement formé que dans la troisième période. Dans cette période surtout intervient la déformation de la Molasse plus récente non plissée qui prend la forme d'une grande auge parallèle aux Alpes, dont l'axe s'élève vers le sud-ouest et l'est.

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Herrn Dr. Dr. h. c. Artur Roll (Tübingen) gewidmet

Nach einem Vortrag auf der 73. Jahrestagung der Geologischen Vereinigung in Berchtesgaden am 25. Februar 1983.  相似文献   
28.
29.
Results of a numerical method for the simulation of nonlinear flow in coastal seas are presented. The method is based on a neutral semi-implicit scheme which is modified into a stability-enhancing two-step algorithm. By means of this method the simulation of highly nonlinear flow patterns is possible in a stable and economic way. Three examples of models of different North Sea coastal regions are discussed under certain aspects to demonstrate the reliability of the method.  相似文献   
30.
Hydraulic properties of the crystalline basement   总被引:1,自引:1,他引:1  
Hydraulic tests in boreholes, up to 4.5 km deep, drilled into continental crystalline basement revealed hydraulic conductivity (K) values that range over nine log-units from 10−13−10−4 m s−1. However, K values for fractured basement to about 1 km depth are typically restricted to the range from 10−8 to 10−6 m s−1. New data from an extended injection test at the KTB research site (part of the Continental Deep Drilling Program in Germany) at 4 km depth provide K=5 10−8 m s−1. The summarized K-data show a very strong dependence on lithology and on the local deformation history of a particular area. In highly fractured regions, granite tends to be more pervious than gneiss. The fracture porosity is generally saturated with Na–Cl or Ca–Na–Cl type waters with salinities ranging from <1 to >100 g L−1. The basement permeability is well within the conditions for advective fluid and heat transport. Consequently, fluid pressure is hydrostatic and a Darcy flow mechanism is possible to a great depth. Topography-related hydraulic gradients in moderately conductive basement may result in characteristic advective flow rates of up to 100 L a−1 m−2 and lead to significant advective heat and solute transfer in the upper brittle crust. An erratum to this article can be found at  相似文献   
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