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21.
Brent L. Lewis Pamela D. Holt Steven W. Taylor Steven W. Wilhelm Charles G. Trick Alison Butler George W. Luther III 《Marine Chemistry》1995,50(1-4)
Thermodynamic stability constants have been estimated for the complexation of iron(III) with catecholate-type siderophores isolated from the marine bacterium Alteromonas luteoviolacea and from the marine cyanobacterium Synechococcus sp. PCC 7002. Stability constants were determined utilizing the “chelate scale” of Taylor et al. (1994). The scale is based upon a linear relationship between the reduction potentials and the pH-independent thermodynamic stability constants for known iron(III) complexes. Log K values for the alterobactin B ferric iron complex are 43.6 ± 1.5 at pH 8.2 and 37.6 ± 1.2 at pH 6, consistent with a shift from bis-catecholate to monosalicylate/monocatecholate iron coordination with decreasing pH. Synechococcus isolates PCC 7002 Nos. 1 and 3 formed iron(III) complexes with stability constants of approximately 38.1 ± 1.2 and 42.3 ± 1.5, respectively. The binding strengths of the iron(III) complexes examined in this study are quite high, suggesting that catecholate siderophores may play a role in the solubilization and biological uptake of iron in the marine environment. 相似文献
22.
C. Graham 《Coastal Engineering》1982,6(4)
This study sets out to define the basic forms in which wind speed and wave height persistence statistics may be defined for offshore engineering applications, and describes the development of a mathematical persistence model.The model incorporates some of the principles laid down by other workers, but it is fundamentally based on a new concept for parameterising persistence statistics, linking wind speed and sea state percentage probability of exceedance with the persistence average duration.North Sea measured wind and wave data have been used to calibrate and test the model. During the course of these test runs it proved necessary to fine tune the basic Weibull equation of the model, but following these adjustments the model runs were found to correlate well with the measured data.It is concluded that the model may be used to predict wind speed and wave height persistence statistics with acceptable accuracy for preliminary stage oil industry planning purposes and that the calibrated model has particular application for those areas where little measured data are currently available. 相似文献
23.
ABSTRACT Understanding temporal patterns in restored environments is important for identifying potential barriers to recovery and improved management of degraded habitats. In this paper, we use temporal beta diversity analyses to compare invertebrate community recovery trajectories in three restored agricultural stream sites under different integrated catchment plans, a native forest reference site, and two unmodified pasture control stream sites over 24 years. The restored sites diverged from their initial community composition over time and became more similar to the reference site community, which was relatively stable over time. Variation partitioning showed that prior to restoration beta diversity was primarily associated with environmental and spatial drivers, whereas post-restoration beta diversity was more influenced by temporal and environmental drivers, including changes in substrate size, fine sediments, water clarity, and nutrients, as well as temperature and flow regime. Species’ contributions to beta diversity varied between sites and years, with sensitive EPT taxa contributing more in reference and control sites. However, contributions of some EPT species, particularly mayflies, increased in restored sites post-ICM. In summary, after nearly two decades of ICM, restored stream sites show recovery towards reference conditions, yet differences persist, indicating that rehabilitation may take longer, depending on the restoration goals. 相似文献
24.
25.
An elongated sea bed depression (pit), 80 by 125 m and 10 m deep located on the Grand Banks of Newfoundland was identified on high resolution surficial geophysical survey lines and investigated using a manned submersible. The pit occurs at the termination of a long (greater than 3 km) iceberg scour, 1.5 m deep, and 80 m wide in 91 m of water. It is similar to other depressions in the region that indent the sea bed up to seven times deeper than the surrounding deepest iceberg furrows. The pit is interpreted to be the sea bed response to impact and loading by a rolling and grounding iceberg. The iceberg scour and pit appear to be of recent origin. 相似文献
26.
Graham P. Wilson Angela L. Lamb Melanie J. Leng Silvia Gonzalez David Huddart 《Estuarine, Coastal and Shelf Science》2005,64(4):685-698
Microfossil analysis (e.g. diatoms, foraminifera and pollen) represents the cornerstone of Holocene relative sea-level (RSL) reconstruction because their distribution in the contemporary inter-tidal zone is principally controlled by ground elevation within the tidal frame. A combination of poor microfossil preservation and a limited range in the sediment record may severely restrict the accuracy of resulting RSL reconstructions. Organic δ13C and C/N analysis of inter-tidal sediments have shown some potential as coastal palaeoenvironmental proxies. Here we assess their viability for reconstructing RSL change by examining patterns of organic δ13C and C/N values in a modern estuarine environment. δ13C and C/N analysis of bulk organic inter-tidal sediments and vegetation, as well as suspended and bedload organic sediments of the Mersey Estuary, U.K., demonstrate that the two main sources of organic carbon to surface saltmarsh sediments (terrestrial vegetation and tidal-derived particulate organic matter) have distinctive δ13C and C/N signatures. The resulting relationship between ground elevation within the tidal frame and surface sediment δ13C and C/N is unaffected by decompositional changes. The potential of this technique for RSL reconstruction is demonstrated by the analysis of part of an early Holocene sediment core from the Mersey Estuary. Organic δ13C and C/N analysis is less time consuming than microfossil analysis and is likely to provide continuous records of RSL change. 相似文献
27.
Rates for nitrification, phytoplankton uptake of ammonium, and regeneration of ammonium were measured in the Delaware River as functions of irradiance and nutrient concentrations, using 15N labeling methods. Phytoplankton uptake increased and nitrification rates declined with increased light intensity. The irradiance level required for maximum uptake by phytoplankton was similar to that for maximal inhibition of nitrification (about 300μEm−2 s−1). Daily, water-column averaged rates, calculated by integration of the observed rate-intensity relationships, indicate that light plays a key role in regulating the balance between oxidation of NH4+ by bacteria and assimilation by phytoplankton in the Delaware. The results show that uptake of ammonium by phytoplankton in the dark may exceed uptake in the light in optically thick systems. 相似文献
28.
G. H. Sutton F. K. Duennebier B. Iwatake J. D. Tuthill B. T. R. Lewis J. Ewing 《Marine Geophysical Researches》1981,5(1):3-34
The purpose of the experiment was to determine the effects of coupling and bottom currents on ocean bottom seismometers. Twelve operational OBSs, three specially designed three-component systems, and a hydrophone were compared with each other. Unlike seismometers placed on hard rock at land stations, ocean bottom seismometers can be affected by soft sediments (which act as lossy mechanical springs) and by buoyancy. Coupling through soft sediments can modify the response to ground motion much as a low pass filter does, and high buoyancy tends to counteract this effect. These effects are observed in the Lopez data, which consist of signals from mechanical transient tests, cap shots, airgun pulses, and general background noise. The modification of response is pronounced for some instruments and barely noticeable in others. Instruments that stand high in the water relative to their base width tend to be susceptible to rocking motion that shows up as a mechanical cross coupling between horizontal and vertical motion. Correlation of Lopez results with coupling theory suggests that it is possible to design ocean bottom seismometers that will couple well to any sediment. Current levels at the Lopez site (<5 cm s-1) were too small to produce noticeable effect on any of the instruments; however, the same design criteria that will minimize coupling problems will also lessen problems caused by ocean currents.Hawaii Institute of Geophysics Contribution No. 1171. 相似文献
29.
The sea as a source of atmospheric phosphorus 总被引:1,自引:0,他引:1
The geochemical fractionation of phosphorus on the drop produced by bubbles bursting in seawater has been studied using a field sampling system called the Bubble Interfacial Microlayer Sampler (BIMS). The droplets from bursting bubbles were collected on filter samples in Narragansett Bay, Rhode Island during the summer of 1975. Phosphorus was found to be fractionated by the bubble-bursting process. The enrichment factor ranged from 4 to 170. Enrichment was found to increase with decreasing phosphorus concentration at 20 cm depth while it decreases with increasing wind velocity. Enrichment was independent of bubbling depth. Together these facts suggest that the sea-surface microlayer is the source of the phosphorus on the ejected drops. Organic phosphorus on the filter samples was found to be enriched relative to surface-water phosphorus by factors of 100–200, while reactive phosphorus was enriched by factors of only 6–8. This suggests that surface-active organic phosphorus compounds are the source phosphorus in the microlayer.The organic phosphorus content of samples of atmospheric particulates collected over the phosphate-rich upwelling waters near the Peru coast was found to correlate significantly with sea-salt sodium. Enrichments calculated using the average phosphorus concentration of the surface water in this area agree well with the results of the BIMS study. Thus it appears that phosphorus fractionation does occur in nature and may be important in supplying this nutrient to some coastal regions of the world. 相似文献
30.
Craig W. Morgan Graham M. Kent Gordon G. Seitz Michaela Novak 《Hydrogeology Journal》2008,16(5):981-994
A hydrogeologic model that has been used by many researchers and consultants to describe an area of South Lake Tahoe, California,
USA impacted by MTBE contamination describes a relatively homogeneous unconfined aquifer comprised of poorly sorted glacial
outwash deposits, within which water-supply wells are able to exert significant alteration in natural groundwater flow. A
re-examination of the area’s hydrogeology is presented, which supports a layered heterogeneous aquifer system constructed
of alternating fine and coarser-grained glacio-lacustrine depositional units. This re-evaluation was accomplished through
a review of lithologic logs across an area of approximately 1 km2, combined with observations of significant hydraulic head differences and knowledge of the depositional environments controlled
by Pleistocene Lake Tahoe high stands. Many of the fine-grained units observed at depths from 6 to 15 m, although relatively
thin, are generally continuous and serve as significant barriers to groundwater flow. The vertical migration of contamination
across these fine-grained units to deeper groundwaters was facilitated by cross-screened monitoring wells installed as part
of site investigation activities. This conclusion highlights the importance of geologic characterization and proper monitoring
well construction at contaminated site investigations.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.
相似文献
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.
Michaela NovakEmail: |