Copper sulphide formation chemistry at low temperatures   总被引：1，自引：0，他引：1  

Dr. D. T. Rickard 《Mineralogy and Petrology》1973,19(1):60-76

Summary Covellite, blaubleibender covellite, djurleite and chalcocite have been synthesized by the reaction between Cu₂O with aqueous Na₂S solutions at low temperatures. Digenite was produced by heating the dried products of the aqueous experimentation at 105°C for 50 days, but not directly from aqueous solution. Anilite was formed through air oxidation of chalcocite at room temperature. The pH and Eh conditions of formation of these phases have been studied and it has been shown that the synthetic results broadly reflect the theoretical stability fields for these compounds, inasmuch as more reduced copper sulphides are formed under higher pH and lower Eh conditions. Studies of the changes in these parameters during the course of the experiments have been used to outline the mechanisms involved in the reactions. It has been demonstrated that the form of the copper sulphide produced around neutral pH values is almost independent of the oxidation state of the copper reactant, but highly sensitive to the presence and concentration of elemental sulphur. A detailed discussion of the formation chemistry of copper sulphides in low temperature aqueous solutions is presented.

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Chemie der Kupfersulfidbildung bei niedrigen Temperaturen

Zusammenfassung Covellin, blaubleibender Covellin, Djurleit und Chalkosin wurden durch Reaktion zwischen Cu₂O und wäßrigen Na₂S-Lösungen bei niedrigen Temperaturen synthetisiert. Digenit entstand, wenn die getrockneten Produkte aus wäßrigen Lösungen 50 Tage bei 105°C getempert wurden, aber nicht direkt aus wäßriger Lösung. Anilit bildete sich aus Chalkosin bei Zimmertemperatur durch Oxidation an der Luft. Die pH- und Eh-Bedingungen für die Bildung dieser Phasen wurden untersucht und es wurde gezeigt, daß die Syntheseergebnisse im wesentlichen den theoretischen Stabilitätsfeldern dieser Verbindungen entsprechen, indem sich die stärker reduzierten Kupfersulfide unter höherem pH und kleinerem Eh bilden. Untersuchungen über die Änderung dieser Parameter im Verlauf der Experimente wurden zur Umreißung der Reaktionsmechanismen benützt. Es wurde gezeigt, daß die Art des Kupfersulfides, welches sich um neutrale pH-Werte bildet, fast nicht vom Oxidationszustand des reagierenden Kupfers, aber stark von der Anwesenheit und der Konzentration von elementarem Schwefel abhängt. Die Chemie der Bildung von Kupfersulfiden in wäßrigen Lösungen niedriger Temperatur wird ausführlich diskutiert.

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With 2 Figures  相似文献   

Glaciotectonic structures and their relation to topography at Dinas Dinlle,Arvon, northwest Wales     

Charles Harris  Peter J. Brabham  Graham D. Williams 《第四纪科学杂志》1995,10(4):397-397

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THE METEORITICAL SOCIETY     

A.L. Graham 《Meteoritics & planetary science》1980,15(1):93-103

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Cryostorage of hepatic microsomes from two marine mammal species: effects on cytochrome P450-monooxygenase activities and content     

Tilley RE  Kemp GD  Hall AJ 《Marine pollution bulletin》2003,46(5):654-658

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Impacts of the Jessica oil spill: an introduction     

Edgar GJ  Snell HL  Lougheed LW 《Marine pollution bulletin》2003,47(7-8):273-275

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Seismic Hazard and Risk Assessment for Tulbagh,South Africa: Part I – Assessment of Seismic Hazard     

Kijko  A.  Retief  S. J. P.  Graham  G. 《Natural Hazards》2002,26(2):175-201

In this part of our study the probabilistic seismic hazard analysis (PSHA) for Tulbagh was performed. The applied procedure is parametric and consists essentially of two steps. The first step is applicable to the area in the vicinity of Tulbagh and requires an estimation of the area-specific parameters, which, in this case, is the mean seismic activity rate, , the Gutenberg-Richter parameter, b, and the maximum regional magnitude, m_max. The second step is applicable to the Tulbagh site, and consists of parameters of distribution of amplitude of the selected ground motion parameter. The current application of the procedure provides an assessment of the PSHA in terms of peak ground acceleration (PGA) and spectral acceleration (SA). The procedure permits the combination of both historical and instrumental data. The historical part of the catalogue only contains the strongest events, whereas the complete part can be divided into several subcatalogues, each assumed complete above a specified threshold of magnitude. In the analysis, the uncertainty in the determination of the earthquake was taken into account by incorporation of the concept of `apparent magnitude'. The PSHA technique has been developed specifically for the estimation of seismic hazard at individual sites without the subjective judgement involved in the definition of seismic source zones, when the specific active faults have not been mapped or identified, and where the causes of seismicity are not well understood. The results of the hazard assessment are expressed as probabilities that specified values of PGA will be exceeded during the chosen time intervals, and similarly for the spectral accelerations. A worst case scenario sketches the possibility of a maximum PGA of 0.30g. The results of the hazard assessment can be used as input to a seismic risk assessment.  相似文献   

The influence of diet on comparative trace metal cadmium,copper and zinc accumulation in Thais clavigera (Gastropoda: Muricidae) preying on intertidal barnacles or mussels     

Blackmore G  Morton B 《Marine pollution bulletin》2002,44(9):870-876

The influence of diet on comparative metal accumulation was investigated using a predatory muricid gastropod Thais clavigera. Individuals were fed for up to 56 days on either barnacles, i.e., Tetraclita squamosa, or mussels, i.e., Perna viridis, collected from metal-contaminated and clean sites. Barnacles and mussels have contrasting metal handling strategies and, therefore, different body concentrations, intracellular distributions and detoxification systems. Field collection of prey items that accumulated body metal concentrations over a lifetime of exposure allowed bioavailability to the predator, T. clavigera, to be assessed naturally, which may not be the case for prey exposed to metals for a short time in the laboratory. T. clavigera that was fed cadmium- and copper-contaminated barnacles or mussels ingested significantly greater amounts compared to those fed conspecifics collected from clean locations. T. clavigera body cadmium and copper concentrations were not, however, significantly different between individuals fed either contaminated or clean prey. Amount of zinc ingested was similar in mussels collected from clean and contaminated environments but much less when compared to the barnacle prey. The body concentrations of zinc in T. clavigera fed mussels collected from both sites fell. In contrast, the amount of zinc ingested from barnacle prey was significantly greater from those collected from the metal-contaminated site as compared to the clean one. This was reflected as significantly greater body zinc concentrations in T. clavigera fed contaminated barnacles compared to those fed clean individuals. Copper and zinc accumulation from prey was, therefore, complex. It varied between metal and between prey type, but appeared to be related to the amount ingested and the metal handling strategy of the prey.  相似文献   

Assessing climate change impacts on hydrology from an ensemble of regional climate models,model scales and linking methods – a case study on the Lule River basin     

L. Phil Graham  Johan Andréasson  Bengt Carlsson 《Climatic change》2007,81(1):293-307

This paper investigates how using different regional climate model (RCM) simulations affects climate change impacts on hydrology in northern Europe using an offline hydrological model. Climate change scenarios from an ensemble of seven RCMs, two global climate models (GCMs), two global emissions scenarios and two RCMs of varying resolution were used. A total of 15 climate change simulations were included in studies on the Lule River basin in Northern Sweden. Two different approaches to transfer climate change from the RCMs to hydrological models were tested. A rudimentary estimate of change in hydropower potential on the Lule River due to climate change was also made. The results indicate an overall increase in river flow, earlier spring peak flows and an increase in hydropower potential. The two approaches for transferring the signal of climate change to the hydrological impacts model gave similar mean results, but considerably different seasonal dynamics, a result that is highly relevant for other types of climate change impacts studies.  相似文献   

Platinum-group elements (Ir,Pd, Pt and Rh) in road-deposited sediments in two urban watersheds,Hawaii     

Ross A. Sutherland  D. Graham Pearson  Chris J. Ottley 《Applied Geochemistry》2007

This study represents the first detailed investigation of platinum-group elements (PGEs) in road-deposited sediment (RDS) in Hawaii, USA. Thirty-three sample locations, in two urban watersheds in Honolulu, Oahu, Hawaii were sampled. The <63 μm fraction of RDS was digested with aqua regia, followed by matrix separation with Dowex AG50-X8 cation exchange resin. PGEs were analyzed with inductively coupled plasma-mass spectrometry (ICP-MS) equipped with a desolvating nebulizer. Concentrations of Rh, Pd and Pt in residential streets reached 64, 105 and 506 ng/g, respectively. Maximum enrichment ratios, computed as RDS concentrations relative to baseline values, exceeded 400, indicating a significant anthropogenic signal with the sequence Rh > Pt > Pd. Iridium concentrations were uniformly low <1 ng/g, and enrichment ratios support a geogenic source. Significant interelement PGE correlations (Pd–Pt–Rh), combined with the magnitude of PGE pair-wise ratios (Pt/Pd, Pt/Rh and Pd/Rh), and relative percentages comparable to European RDS and roadside soil in Indiana, USA all suggest an automobile source. Attrition of PGE-loaded automobile catalytic converters and subsequent loss to the environment by exhaust emissions explains the significant environmental signal of PGEs in road environments of Hawaii. Further PGE work is required to quantify urban transport paths as PGEs are known to bioaccumulate, cause cellular damage and may have detrimental human health effects.  相似文献   

The creative reconstruction of the Internet: Google and the privatization of cyberspace and DigiPlace   总被引：2，自引：0，他引：2  

Matthew A. Zook  Mark Graham   《Geoforum》2007,38(6):1322-1343

The Internet has often been portrayed as the ultimate leveler of information where existing hierarchies of power and privilege are undermined by meritocracy. Some websites and functions are, however, more equal than others. In particular, search engines such as Google have been a key means to construct meaning out of disorder. This ordering (or enclosing of the Internet commons), however, comes at a cost as a location within the top 10 Google search results, marks the boundary (albeit a fluid one) between the core and the periphery of the Internet. The recent incorporation of spatial elements into the Google indexing raises fresh and geographically relevant concerns. This article focuses on the construction, access and use of Google derived rankings to deploy geo-referenced information in the physical environment and the way this melding of code and place affects how people interact with place. Using the theoretical concept of DigiPlace this article analyzes how Google Maps and Google Earth are structured and shape what appears (and what does not) in cyberspace and DigiPlace. Of particular concern are the implications of a private corporation controlling this new space.  相似文献