Diisopropanolamine Biodegradation Potential at Sour Gas Plants   总被引：1，自引：0，他引：1  

Lisa M. Gieg  E. Anne Greene  Debora L. Coy  Phillip M. Fedorak 《Ground Water Monitoring & Remediation》1998,18(3):158-173

The potential for aerobic and anaerobic biodegradation of a sour gas treatment chemical, diisopropanolamine (DIPA), was studied using contaminated aquifer materials from three sour gas treatment sites in western Canada. DIPA was found to be readily consumed under aerobic conditions at 8°C and 28°C in shake flask cultures incubated with aquifer material from each of the sites, and this removal was characterized by first-order kinetics. In addition, DIPA biodegradation was found to occur under nitrate-, Min(IV)., and Fe(III)-reducing conditions at 28°C, and in some cases at 8°C, in laboratory microcosms, DIPA loss corresponded to consumption of nitrate, and production of Mn(II) and Fe(II) in viable microcosms compared to corresponding sterile controls. A threshold DIPA concentration near 40 mg/L was observed in the anaerobic microcosms. This report provides the first evidence that DIPA is biodegraded under anaerobic conditions, and our data suggest that biodegradation may contribute to DIPA attenuation under aerobic and anaerobic conditions in aquifers contaminated with this sour gas treatment chemical.  相似文献   

Spatial and temporal study of nitrate concentration in groundwater by means of coregionalization   总被引：1，自引：0，他引：1  

V. D'Agostino  E. A. Greene  G. Passarella  M. Vurro 《Environmental Geology》1998,36(3-4):285-295

 Spatial and temporal behavior of hydrochemical parameters in groundwater can be studied using tools provided by geostatistics. The cross-variogram can be used to measure the spatial increments between observations at two given times as a function of distance (spatial structure). Taking into account the existence of such a spatial structure, two different data sets (sampled at two different times), representing concentrations of the same hydrochemical parameter, can be analyzed by cokriging in order to reduce the uncertainty of the estimation. In particular, if one of the two data sets is a subset of the other (that is, an undersampled set), cokriging allows us to study the spatial distribution of the hydrochemical parameter at that time, while also considering the statistical characteristics of the full data set established at a different time. This paper presents an application of cokriging by using temporal subsets to study the spatial distribution of nitrate concentration in the aquifer of the Lucca Plain, central Italy. Three data sets of nitrate concentration in groundwater were collected during three different periods in 1991. The first set was from 47 wells, but the second and the third are undersampled and represent 28 and 27 wells, respectively. Comparing the result of cokriging with ordinary kriging showed an improvement of the uncertainty in terms of reducing the estimation variance. The application of cokriging to the undersampled data sets reduced the uncertainty in estimating nitrate concentration and at the same time decreased the cost of the field sampling and laboratory analysis. Received: 23 July 1997 · Accepted: 31 March 1998  相似文献   

Narrow-band spectrophotometry of Ariel,Umbriel, Titania,Oberon, and Triton     

Paul E. Johnson  Thomas F. Greene  Richard W. Shorthill 《Icarus》1978,36(1):75-81

The spectral reflectances of Ariel, Umbriel, Titania, Oberon, and Triton were measured in 28 bandpasses between λ326 and λ976 nm on the night of 28/29 June 1974. These observations were made with the 200-in. Hale telescope and multichannel spectrometer. Bandpasses of 8 nm from λ326 to λ566 nm and 16 nm from λ592 to λ976 nm were employed. The spectral reflectances of Ariel, Oberon, and Titania increase from λ342 to λ534 nm and are relatively flat from λ550 to λ976 nm. Umbriel's reflectance decreases monotonically with increasing wavelength through the entire range of measured wavelengths. Triton is found to have a constant spectral reflectance.  相似文献   

The significance of deep-water cryptic bioturbation in slope-channel massive sand deposits of the lower Rio Dell Formation,Eel River basin,California     

Todd J. Greene  Murray K. Gingras  Gregory S. Gordon  Daniel R. McKeel 《Marine and Petroleum Geology》2012,29(1):152-174

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Paleoclimate histories improve access and sustainability in index insurance programs     

Andrew R. Bell  Daniel E. Osgood  Benjamin I. Cook  Kevin J. Anchukaitis  Geoffrey R. McCarney  Arthur M. Greene  Brendan M. Buckley  Edward R. Cook 《Global Environmental Change》2013,23(4):774-781

Proxy-based climate reconstructions can extend instrumental records by hundreds of years, providing a wealth of climate information at high temporal resolution. To date, however, their usefulness for informing climate risk and variability in policy and social applications has been understudied. Here, we apply tree-ring based reconstructions of drought for the last 700 years in a climate index insurance framework to show that additional information from long climate reconstructions significantly improves our understanding of the underlying climate distributions and variability. We further show that this added information can be used to better characterize risk to insurance providers, in many cases providing meaningful reductions in long-term contract costs to farmers in stand-alone policies. The impact of uncertainty on insurance premiums can also be reduced when insurers diversify portfolios, and the availability of long-term climate information from tree rings across a broad geographic range provides an opportunity to characterize spatial correlation in climate risk across geographic regions. Our results are robust to the range of climate variability experienced over the last 400 years and in model simulations of the twenty-first century, even within the context of changing baselines due to low frequency variability and secular climate trends. These results demonstrate the utility of longer-term climate histories in index insurance applications. Furthermore, they make the case from a climate-variability perspective for the continued importance of such approaches to improving the instrumental climate record, even into a non-stationary climate future.  相似文献   

Pressure solution - The importance of the electrochemical surface potentials     

Kai Kristiansen  George W. Greene  Jacob N. Israelachvili 《Geochimica et cosmochimica acta》2011,75(22):6882-6892

“Pressure solution”, frequently found in clay-rich sandstone, is characterized by enhanced quartz dissolution at inter-grain contacts. The origin of pressure solution and many other related dissolution processes remains elusive. Using an Electrochemical Surface Forces Apparatus we visualized and measured the dissolution of silica glass surfaces close to an electrode surface. The dissolution rates correlate quantitatively with the electrode potential via the Butler-Volmer equation for corrosion. Our experimental results demonstrate that at low temperature, apparent pressure solution and many other mineral dissolution phenomena can be driven by electrochemical processes rather than a pressure-driven process. This finding highlights the role of electrochemical surface potentials in dissolution phenomena at dissimilar material interfaces, and provides new perspectives on pressure solution in particular and a new theoretical basis for predictive control of dissolution phenomena in general.  相似文献   

An evaluation of the progress in reducing heat-related human mortality in major U.S. cities     

Laurence S. Kalkstein  Scott Greene  David M. Mills  Jason Samenow 《Natural Hazards》2011,56(1):113-129

This study estimates the excess mortality attributable to excessive heat events (EHEs) for forty major U.S. cities during 1975–1995 and 1975–2004. We calculate these results using the spatial synoptic classification method to identify EHE days. Step-wise regressions are then used to estimate the location-specific mortality algorithms that can account for the impact of the EHEs’ duration, severity, and timing. Our excess mortality results are expressed both as lives lost and associated mortality rates (excess deaths per 100,000 residents) using 2000 Census population estimates. Our results generally show a reduction in EHE-attributable mortality rates since 1996. Adjusting our results to account for changes in the average number of EHE days per year in each period does not affect this general conclusion. However, this adjustment has a considerable impact on a measure of the cities’ relative performance in terms of reducing this EHE-attributable excess mortality. Our results indicate there is promise for further reductions in EHE-attributable mortality from the approximately 1300 excess deaths per summer we identify using data from the 1975–2004 period. However, the magnitude of this result highlights the significant health burden of EHEs relative to other extreme weather events in the United States and suggests it is worthy of additional attention. Our results also raise important questions with respect to evaluating the performance of EHE notification and response programs and how EHE-attributable mortality should be estimated for future scenarios, notably for climate change projections.  相似文献   

A SYNOPTIC CLIMATOLOGICAL ANALYSIS OF SUMMERTIME PRECIPITATION INTENSITY IN THE EASTERN UNITED STATES     

Scott J. Greene 《自然地理学》2013,34(5):401-418

The spatial patterns of precipitation frequency and intensity over the eastern United States for summer from 1961 to 1990 are analyzed using a recently developed continental-scale air mass-based synoptic classification. This procedure, the spatial synoptic classification (SSC), is based on “seed” day identification of synoptic events and discriminant analysis to group together days that are within the same air-mass type. Results show differences in the types of precipitation associated with different air masses. Two air masses in particular-Moist Tropical and Moist Temperate-appear to be highly correlated with a majority of the precipitation, particularly in the southeast. The synoptic characteristics, daily intensity of rainfall, and radiosonde soundings during prevalence of these two air masses suggest that convective rainfall is common during Moist Tropical, and stratiform-type rainfall occurs during Moist Temperate. A simple stratification scheme based upon a synoptic-based air-mass delineation may be useful for studies that need to divide days into stratiform or convective regimes.  相似文献   

The XMM–Newton view of AGN with intermediate-mass black holes     

G. Miniutti  G. Ponti  J. E. Greene  L. C. Ho  A. C. Fabian  K. Iwasawa 《Monthly notices of the Royal Astronomical Society》2009,394(1):443-453

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Estimated changes in wind speed and wind power density over the western High Plains, 1971–2000     

J. Scott Greene  Matthew Chatelain  Mark Morrissey  Steve Stadler 《Theoretical and Applied Climatology》2012,109(3-4):507-518

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