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81.
Seismic reflection methods are being developed at the University of Manitoba to aid in determining fine crustal structure in the Precambrian of Manitoba and northwestern Ontario. Present-day environmental concern as well as mineshaft conditions necessitate the detonation of several smaller charges repeated, say, I times and followed by ‘vertical’ stacking. To obtain the familiar √I improvement in signal-to-noise (S:N) amplitude ratio applying the straight-sum (SS) method, one assumes, among other things, that both S:N ratio and signal variance are the same on all traces. Dropping these assumptions, as we must for our data, it becomes necessary to apply weighting coefficients to optimize the S:N ratio of the stacked trace. We still assume the signal shapes to be the same for repeated shots, so for the jth trace on the record of the ith shot we model the time series as: tij=ai (sj+nij); where ai is a scaling factor. The proper weights wi are then shown to be proportional to σsi2ni where σ2 is variance, or to γi/ai where γi is S:N power ratio. Applying the weighted-stack (WS) method gives S:N amplitude ratios which are, on average, 55% of the optimal ratios expected from WS theory compared with only 24% for the SS method. The 45% shortfall in WS performance is ascribed mainly to trace-alignment (or time-delay) errors. Varying noise levels on individual traces, slight dissimilarity of signal shape, and correlated noise may also contribute to a lesser extent (in decreasing order of significance). This WS method appears to strike a good practical balance between S:N improvement and processing efficiency.  相似文献   
82.
The MD dyke swarm is composed of four generations of large basictholeiite dykes which cut the entire Archaean craton of southernWest Greenland. The four successive generations (MD1, MD2, MD3a,MD3b) are characterized by their orientation and cross-cuttingrelationships and by their mineralogy, texture and progressivelyevolved tholeiitic chemistry. Rare-earth element (REE) abundancessuggest that the dykes may have a fairly complex petrogeneticevolution. The suite varies from early (MD1) heteradcumulatenorites to ophitic and sub-ophitic gabbroic and doleritic rocks(MD2 and MD3) and the youngest generation (MD3b) comprises plagioclase-phyricdolerites. The pyroxene chemistry parallels the geochemical evolution ofthe dykes showing an overall Fe-enrichment trend. However, theclinopyroxenes are enigmatic in that, although they occur predominantlyas part of medium and coarse-grained holocrystalline textures,they are chemically highly variable and calcium-poor, many plottingin the metastable field in the system MgSiO3 (En)-CaSiO3 (Wo)-FeSiO3(Fs). Many individual grains are extremely complex and may beregularly or irregularly zoned. Along with more typical pyroxene forms, the MD1 dykes containpyroxene dendrites poikilitically enclosed by plagioclase. Thedendrites vary compositionally from hypersthene bases to branchesof pigeonite and subcalcic augite and terminate in augite branchtips. The MD2 and MD3a dyke pyroxenes are the most complex.The majority of them are sub-ophitic grains, many with successivezones of orthopyroxene, pigeonite, subcalcic augite, augiteand ferroaugite. However, Ca-enrichment or Ca-depletion, Fe-enrichmentor Fe-depletion and apparently opposing zoning trends can occurin neighbouring grains. Even small interstitial pyroxenes showa very wide range of compositions. Morphologically unusual andcomplex clinopyroxene ‘cylinders’ occur in someof the MD3a dykes. They are chemically relatively uniform andare normal tholeiitic augites. The MD3b rocks have small concentricallyzoned sub-ophitic pyroxenes which show Ca-enrichment with arelatively constant Fs component (29 to 39 mol. per cent). Themost extremely zoned grains have hypersthene cores with successivecoronas of pigeonite and subcalcic augite and have margins ofaugite or ferroaugite. The present ‘coexistence’of such compositionally widely variable pyroxenes and the extremeand often irregular nature of their chemical zoning make thedetermination of true original coexisting pyroxene phases andthe use of a two pyroxene geothermometer very difficult andof limited significance. The presence of a wide variety of pyroxenes of apparently bothstable and metastable compositions in these holocrystallinedykes suggests that these rocks have undergone a complex andrather unusual cooling history. The principal genetic factorswhich could have influenced their crystallization are (1) supercooling,(2) the evolution of discrete interstitial liquid cells, (3)augite-pigeonite peritectic reactions and (4) plagioclase growthand delay of pyroxene nucleation during supercooling of liquidto below the basalt liquidus.  相似文献   
83.
Kinetics and Mechanism of Pyrite Exsolution from Pyrrhotite   总被引:4,自引:0,他引:4  
Pyrite exsolution from pyrrhotite at 325 °C occurs by heterogeneousnucleation of pyrite and subsequent growth by volume diffusionof iron away from the nuclei. Sulfur atoms are required to moveonly short distances and although their diffusivity is muchlower than iron, their movement is not the rate determiningfactor. The exsolution rate is primarily dependent on the nucleationrate, which increases with the degree of supersaturation. Inaddition, the impurities in National Bureau of Standards 55diron or 500 ppm of As, Sb, or Bi retard the exsolution rateby two or more orders of magnitude at 325 °C. This reductionis primarily the result of a lower nucleation rate and is believedto be due to a decreased vacancy mobility caused by a high bindingenergy of vacancies with the slow diffusing impurities. Thusthe strain associated with the nucleation cannot be as easilyrelieved. The impurities may also reduce the growth rate bycausing a decrease in mobility of the pyrite interface. The most important general aspect of this study is the effectof a few hundred parts per million of an impurity on the exsolutionrate of this reaction. This suggests that the rate of othermineral reactions may also be dependent on impurities; however,the importance of this factor in any particular mineral reactionrequires experimental verification.  相似文献   
84.
The analysis of nitrate in seawater and hypersaline waters should take account of a significant “salt effect”. Procedures developed for fresh water and marine waters must be applied cautiously to highly saline waters. The most widely used standard method for the determination of nitrate-nitrogen (NO3-N) in fresh and marine waters involves the quantitative reduction of nitrate by the Cd column technique followed by colorimetric procedures. In our study, three approaches to estimate NO3-N in highly saline waters were examined. The first involved dilution. This approach overcame the salt effect but dilution limited the detection of low concentrations of nitrate in highly saline waters. The second involved the use of standard nitrate solutions in saline water. This method is not recommended because of nitrate impurities in AR grade salts. The third- and preferred approach-involved the use of standard additions. “Spikes” of a known volume of NO3-N standard solution were added to natural saline waters. Nitrate values estimated by the stadard addition method were used to calculate an equation for salt error correction at different salinities applicable to waters with the same relative ionic composition as seawater. This could then be used to correct nitrate determinations in highly saline waters where standards made in distilled water were used for calibration. Many previously published data for NO3-N in saline water used methods of analysis which do not take account of salt error and are therefore probably in error.  相似文献   
85.
86.
We examined stable carbon and nitrogen isotopic signatures of 17 fish and 16 invertebrate taxa common to the Newfoundland and Labrador (NL) continental shelf food web. Particular sampling emphasis was placed on Atlantic cod (Gadus morhua) and related prey species (e.g. shrimp, Pandalus borealis, and capelin, Mallotus villosus). We found highly significant (p < 0.0001) differences between near-shore (bays) and offshore (shelf edge) δ15N signatures for cod, ‘other fish’ (pooled) and invertebrates (pooled). In contrast, there were only minor differences in δ13C signatures of ‘other fish’ (p < 0.05) and no difference for cod and invertebrates among the two habitats. We sampled at two times of the year (January and June) and found no systematic effect of season on both δ13C and δ15N in cod, ‘other fish’ and invertebrates. We calculated isotopic fractionation factors for cod from the entire shelf (mixed diet) and for cod with diets composed mainly of capelin or shrimp. These values ranged between 2.2‰ and 3.9‰ for δ15N and −0.4‰ and 0.8‰ for δ13C and, for δ15N, may reflect diet-related differences in bioenergetic status. We discuss potential mechanisms for near-shore versus offshore enrichment of δ15N signatures, and demonstrate the implications of this spatial variation on δ15N-derived trophic position estimates.  相似文献   
87.
88.
Sediment transport and the potential for erosion or deposition have been investigated on the Palos Verdes (PV) and San Pedro shelves in southern California to help assess the fate of an effluent-affected deposit contaminated with DDT and PCBs. Bottom boundary layer measurements at two 60-m sites in spring 2004 were used to set model parameters and evaluate a one-dimensional (vertical) model of local, steady-state resuspension, and suspended-sediment transport. The model demonstrated skill (Brier scores up to 0.75) reproducing the magnitudes of bottom shear stress, current speeds, and suspended-sediment concentrations measured during an April transport event, but the model tended to underpredict observed rotation in the bottom-boundary layer, possibly because the model did not account for the effects of temperature–salinity stratification. The model was run with wave input estimated from a nearby buoy and current input from four to six years of measurements at thirteen sites on the 35- and 65-m isobaths on the PV and San Pedro shelves. Sediment characteristics and erodibility were based on gentle wet-sieve analysis and erosion-chamber measurements. Modeled flow and sediment transport were mostly alongshelf toward the northwest on the PV shelf with a significant offshore component. The 95th percentile of bottom shear stresses ranged from 0.09 to 0.16 Pa at the 65-m sites, and the lowest values were in the middle of the PV shelf, near the Whites Point sewage outfalls where the effluent-affected layer is thickest. Long-term mean transport rates varied from 0.9 to 4.8 metric tons m−1 yr−1 along the 65-m isobaths on the PV shelf, and were much higher at the 35-m sites. Gradients in modeled alongshore transport rates suggest that, in the absence of a supply of sediment from the outfalls or PV coast, erosion at rates of ∼0.2 mm yr−1 might occur in the region southeast of the outfalls. These rates are small compared to some estimates of background natural sedimentation rates (∼5 mm yr−1), but do not preclude higher localized rates near abrupt transitions in sediment characteristics. However, low particle settling velocities and strong currents result in transport length-scales that are long relative to the narrow width of the PV shelf, which combined with the significant offshore component in transport, means that transport of resuspended sediment towards deep water is as likely as transport along the axis of the effluent-affected deposit.  相似文献   
89.
A series of experiments on sandstone and dolerite was undertaken in an attempt to better understand the wetting and drying weathering process. As rock samples are frequently subjected to wet–dry cycles within the simulation of other weathering mechanisms (e.g. freeze–thaw), three common methods of moisture application were used and the influences of these evaluated. It was found that the method of moisture application could affect the nature of the weathering products resulting from wetting and drying. It was also observed that there were changes in the internal properties of the rock (e.g. porosity/microporosity) and that these could influence the synergistic operation of other weathering processes. Although not all of the observations could be explained, it is apparent that wetting and drying has both a direct and an indirect effect on the weathering of rock that has not been taken into account in simulations. Greater cognizance needs to be given to the role of this process both in the field and in laboratory simulations.  相似文献   
90.
The region studied includes the Laurentian Great Lakes and a diversity of smaller glacial lakes, streams and wetlands south of permanent permafrost and towards the southern extent of Wisconsin glaciation. We emphasize lakes and quantitative implications. The region is warmer and wetter than it has been over most of the last 12000 years. Since 1911 observed air temperatures have increased by about 0·11°C per decade in spring and 0·06°C in winter; annual precipitation has increased by about 2·1% per decade. Ice thaw phenologies since the 1850s indicate a late winter warming of about 2·5°C. In future scenarios for a doubled CO2 climate, air temperature increases in summer and winter and precipitation decreases (summer) in western Ontario but increases (winter) in western Ontario, northern Minnesota, Wisconsin and Michigan. Such changes in climate have altered and would further alter hydrological and other physical features of lakes. Warmer climates, i.e. 2 × CO2 climates, would lower net basin water supplies, stream flows and water levels owing to increased evaporation in excess of precipitation. Water levels have been responsive to drought and future scenarios for the Great Lakes simulate levels 0·2 to 2·5 m lower. Human adaptation to such changes is expensive. Warmer climates would decrease the spatial extent of ice cover on the Great Lakes; small lakes, especially to the south, would no longer freeze over every year. Temperature simulations for stratified lakes are 1–7°C warmer for surface waters, and 6°C cooler to 8°C warmer for deep waters. Thermocline depth would change (4 m shallower to 3·5 m deeper) with warmer climates alone; deepening owing to increases in light penetration would occur with reduced input of dissolved organic carbon (DOC) from dryer catchments. Dissolved oxygen would decrease below the thermocline. These physical changes would in turn affect the phytoplankton, zooplankton, benthos and fishes. Annual phytoplankton production may increase but many complex reactions of the phytoplankton community to altered temperatures, thermocline depths, light penetrations and nutrient inputs would be expected. Zooplankton biomass would increase, but, again, many complex interactions are expected. Generally, the thermal habitat for warm-, cool- and even cold-water fishes would increase in size in deep stratified lakes, but would decrease in shallow unstratified lakes and in streams. Less dissolved oxygen below the thermocline of lakes would further degrade stratified lakes for cold water fishes. Growth and production would increase for fishes that are now in thermal environments cooler than their optimum but decrease for those that are at or above their optimum, provided they cannot move to a deeper or headwater thermal refuge. The zoogeographical boundary for fish species could move north by 500–600 km; invasions of warmer water fishes and extirpations of colder water fishes should increase. Aquatic ecosystems across the region do not necessarily exhibit coherent responses to climate changes and variability, even if they are in close proximity. Lakes, wetlands and streams respond differently, as do lakes of different depth or productivity. Differences in hydrology and the position in the hydrological flow system, in terrestrial vegetation and land use, in base climates and in the aquatic biota can all cause different responses. Climate change effects interact strongly with effects of other human-caused stresses such as eutrophication, acid precipitation, toxic chemicals and the spread of exotic organisms. Aquatic ecological systems in the region are sensitive to climate change and variation. Assessments of these potential effects are in an early stage and contain many uncertainties in the models and properties of aquatic ecological systems and of the climate system. © 1997 John Wiley & Sons, Ltd.  相似文献   
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