WEATHERING BY WETTING AND DRYING: SOME EXPERIMENTAL RESULTS     

KEVIN HALL  ALIDA HALL 《地球表面变化过程与地形》1996,21(4):365-376

A series of experiments on sandstone and dolerite was undertaken in an attempt to better understand the wetting and drying weathering process. As rock samples are frequently subjected to wet–dry cycles within the simulation of other weathering mechanisms (e.g. freeze–thaw), three common methods of moisture application were used and the influences of these evaluated. It was found that the method of moisture application could affect the nature of the weathering products resulting from wetting and drying. It was also observed that there were changes in the internal properties of the rock (e.g. porosity/microporosity) and that these could influence the synergistic operation of other weathering processes. Although not all of the observations could be explained, it is apparent that wetting and drying has both a direct and an indirect effect on the weathering of rock that has not been taken into account in simulations. Greater cognizance needs to be given to the role of this process both in the field and in laboratory simulations.  相似文献   

The relationship between magnetic field strength and reversal frequency: Preliminary palaeointensity results from the cretaceous quiet zone     

Graham J. Sherwood  John Shaw 《Studia Geophysica et Geodaetica》1991,35(4):325-333

Summary It has been predicted that the geomagnetic field strength will be at its highest during periods of low reversal frequency. Using basaltic lavas from Israel and India, which were erupted during the 35 Ma interval of normal polarity in the mid-Cretaceous (the Cretaceous Quiet Zone), we have obtained palaeointensity estimates. The mean virtual dipole moments from the two areas are about 75% of the present value. This suggests that there is no simple relationship between the time averaged strength of the dipole and the frequency of reversals.  相似文献   

Synthetic fluid inclusions - VI. Quantitative evaluation of the decrepitation behaviour of fluid inclusions in quartz at one atmosphere confining pressure   总被引：1，自引：0，他引：1  

R. J. BODNAR  P. R. BINNS  D. L. HALL 《Journal of Metamorphic Geology》1989,7(2):229-242

ABSTRACT The decrepitation behaviour of fluid inclusions in quartz at one atmosphere confining pressure has been evaluated using pure H₂O synthetic inclusions formed by healing fractures in natural quartz. Three different modes of non-elastic deformation, referred to as stretching, leakage or partial decrepitation, and total decrepitation have been observed. The internal pressure required to initiate non-elastic deformation is inversely related to inclusion size according to the equation: internal pressure (kbar) = 4.26 D^-0.423 where D is the inclusion diameter in microns. Regularly shaped inclusions require a higher internal pressure to initiate non-elastic deformation than do irregularly shaped inclusions of similar size. Heating inclusions through the α/β quartz inversion results in mechanical instability in the quartz crystal and leads to mass decrepitation of inclusions owing to structural mismatches generated by pressure gradients in the quartz around each inclusion. Long-term heating experiments (∼2 years) suggest that the internal pressure required to initiate non-elastic deformation does not decrease significantly with time and indicates that short-lived thermal fluctuations in natural systems should not alter the inclusion density and homogenization temperature. Inclusions that do exhibit decreased density (higher homogenization temperature) are, however, always accompanied by a change in shape from irregular to that of a negative crystal. Observations of this study are consistent with elasticity theory related to fracture generation and propagation around inclusions in minerals. These results indicate that an inclusion will not be influenced by a neighbouring inclusion, or other defect in the host phase, as long as the distance between the two is >2–4 diameters of the larger of the two inclusions.  相似文献   

Chloride loading in the South Fork of the Shenandoah River,Virginia, U.S.A.     

W. Cullen Sherwood 《Environmental Geology》1989,14(2):99-106

Loading trends and sources of CI^– in the South Fork of the Shenandoah River, Virginia were analyzed for the period 1929–1982. CI^– has increased from approximately 2 mg/L (2,776 tons/yr) to over 10 mg/L (14,256 tons/yr). Natural CI^– is estimated to be 1.01 mg/L (1,388 tons/yr) with precipitation providing 0.99 mg/L and rocks 0.02 mg/L. From 1929 to 1949 CI^– concentrations were relatively constant and independent of discharge, conforming to the Type II curve of Davis and Zobrist (1978), indicative of natural or relatively uncontaminated streams. Since 1952 CI^– concentrations increased exponentially as river discharge decreases conforming to the Type I curve of Davis and Zobrist for polluted streams. Since 1965 anthropogenic CI^– loading at 12,868 tons/yr has remained relatively constant. Four major sources contribute 92.2 percent (11,871 tons/yr) of the anthropogenic CI^–: (1) deicing salts—4,149 tons/yr, (2) domestic sewage—3,015 tons/yr, (3) livestock and poultry wastes—2,458 tons/yr, and (4) commercial fertilizers—2,249 tons/yr.  相似文献   

Future trends in transport and fate of diffuse contaminants in catchments,with special emphasis on stable isotope applications     

Jeffrey Turner  Hans‐Jrgen Albrechtsen  Mike Bonell  Jean‐Pierre Duguet  Bob Harris  Rainer Meckenstock  Kevin McGuire  Roger Moussa  Norman Peters  Hans H. Richnow  Barbara Sherwood‐Lollar  Stefan Uhlenbrook  Henny van Lanen 《水文研究》2006,20(1):205-213

A summary is provided of the first of a series of proposed Integrated Science Initiative workshops supported by the UNESCO International Hydrological Programme. The workshop brought together hydrologists, environmental chemists, microbiologists, stable isotope specialists and natural resource managers with the purpose of communicating new ideas on ways to assess microbial degradation processes and reactive transport at catchment scales. The focus was on diffuse contamination at catchment scales and the application of compound‐specific isotope analysis (CSIA) in the assessment of biological degradation processes of agrochemicals. Major outcomes were identifying the linkage between water residence time distribution and rates of contaminant degradation, identifying the need for better information on compound specific microbial degradation isotope fractionation factors and the potential of CSIA in identifying key degradative processes. In the natural resource management context, a framework was developed where CSIA techniques were identified as practically unique in their capacity to serve as distributed integrating indicators of process across a range of scales (micro to diffuse) of relevance to the problem of diffuse pollution assessment. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

Anthropogenic CO₂ in the oceans estimated using transit time distributions     

D. W. WAUGH  T. M. HALL  B. I. McNEIL  R. KEY  R. J. MATEAR 《Tellus. Series B, Chemical and physical meteorology》2006,58(5):376-389

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Extreme precipitation in WRF during the Newcastle East Coast Low of 2007     

James B. Gilmore  Jason P. Evans  Steven C. Sherwood  Marie Ekström  Fei Ji 《Theoretical and Applied Climatology》2016,125(3-4):809-827

In the context of regional downscaling, we study the representation of extreme precipitation in the Weather Research and Forecasting (WRF) model, focusing on a major event that occurred on the 8^th of June 2007 along the coast of eastern Australia (abbreviated “Newy”). This was one of the strongest extra-tropical low-pressure systems off eastern Australia in the last 30 years and was one of several storms comprising a test bed for the WRF ensemble that underpins the regional climate change projections for eastern Australia (New South Wales/Australian Capital Territory Regional Climate Modelling Project, NARCliM). Newy provides an informative case study for examining precipitation extremes as simulated by WRF set up for regional downscaling. Here, simulations from the NARCliM physics ensemble of Newy available at ～10 km grid spacing are used. Extremes and spatio-temporal characteristics are examined using land-based daily and hourly precipitation totals, with a particular focus on hourly accumulations. Of the different physics schemes assessed, the cumulus and the boundary layer schemes cause the largest differences. Although the Betts-Miller-Janjic cumulus scheme produces better rainfall totals over the entire storm, the Kain-Fritsch cumulus scheme promotes higher and more realistic hourly extreme precipitation totals. Analysis indicates the Kain-Fritsch runs are correlated with larger resolved grid-scale vertical moisture fluxes, which are produced through the influence of parameterized convection on the larger-scale circulation and the subsequent convergence and ascent of moisture. Results show that WRF qualitatively reproduces spatial precipitation patterns during the storm, albeit with some errors in timing. This case study indicates that whilst regional climate simulations of an extreme event such as Newy in WRF may be well represented at daily scales irrespective of the physics scheme used, the representation at hourly scales is likely to be physics scheme dependent.  相似文献   

Geology and jungle fieldwork in eastern Indonesia     

SIMON BAKER  ROBERT HALL  EMILY FORDE 《Geology Today》1994,10(1):18-23

Collecting geological information from the jungles and islands of eastern Indonesia depends largely on traditional fieldwork methods involving much footwork and messing about in boats. Coupled with modern laboratory and computing techniques, information gained on the ground is being used to interpret the tectonic development of east Indonesia, the Philippine Sea and the western Pacific.  相似文献   

Colloidally separated samples from Allende residues: Noble gases,carbon and an ESCA-study     

Ulrich Ott  Johann Kronenbitter  Jose Flores  Sherwood Chang 《Geochimica et cosmochimica acta》1984,48(2):267-280

A non-colloidal fraction separated by physical means from an $\text{HF}\text{HCl}$-resistant residue of the Allende carbonaceous meteorite exhibits a ratio of isotopically “normal” (Q-type) xenon to “anomalous” xenon (X-type) that is ~4 times larger than usually observed. Coincidentally this fraction contains carbon that is isotopically heavier by ~10%. than bulk Allende residue samples. ESCA analyses of companion colloidal separates show that the major portion of the S contained in our $\text{HF}\text{HCl}$-residues is elemental rather than a sulfide. They also confirm earlier observations that no elementally distinct surface coating is present, in accord with the absence of a surface-sited sulfur-bearing gas carrier, and that the oxygen content is increased after etching with nitric acid. For these separates noble gas data coupled with the ESCA data for nitrogen and the isotopic data for carbon point to the existence of heterogeneities among the noble gas-, carbon- and nitrogen-bearing phases and, thus, preservation of discrete components from the variety of source regions (or production mechanisms, or both) sampled by the Allende parent body. In sharp contrast to the success of physical and chemical methods in yielding samples in which one of the major noble gas components predominates to an extraordinary degree over the other, carbon isotopic compositions that have been inferred for the respective carrier phases in these same samples are strongly contradictory. Mass and isotope balance considerations lead us to conclude that a major fraction of the carbonaceous matter in Allende is noble-gas-poor, a result that could be confirmed by direct isolation of a sample, the carbon in which is dominated by this variety; and for that reason no simple relationship is discernable yet between observed isotopic compositions and either major noble gas component. Similar ambiguities may exist for nitrogen. The possible relationship between carbon-rich phases in ureilites and carbonaceous chondrites is considered.  相似文献   

World-wide increase in tropospheric methane, 1978–1983     

Donald R. Blake  F. Sherwood Rowland 《Journal of Atmospheric Chemistry》1986,4(1):43-62

Tropospheric concentrations of methane in remote locations have averaged a yearly world-wide increase of 0.018±0.002 parts per million by volume (ppmv) during the period from January 1978 to December 1983. The concentrations in the north temperate zone are always greater than those in the south temperate zone by 7±1% because the major methane sources are all predominantly located in the northern hemisphere. The average world-wide tropospheric concentration of methane in dry air was 1.625 ppmv at the end of 1983, measured against an NBS standard certified as 0.97 ppmv (but with an accuracy of only ±1%). The world-wide concentration increases are described by a linear equation with a standard deviation of 0.003 ppmv for ten different collection periods during 1978–1983. The precision of measurement of the methane concentration in the atmospheric samples and in the standard was measured to be ±0.4% for each. Repetitive measurements of an air sample collected in November 1977 have shown the same concentration for six years with a standard deviation for these data of ±0.003 ppmv.The causes for the steady increase in methane concentration in the troposphere cannot be fixed with certainty from present data. Contributing causes can include increases in the source strengths from cattle and rice fields. The atmospheric concentrations of CO, CH₄ and HO are all closely coupled with one another, and increased concentrations of CO and/or CH₄ should cause reduced concentrations of HO, which in turn should lengthen the atmospheric lifetimes of CO and CH₄.Among other physical and chemical effects, a increase of 0.18 ppmv per decade should contribute a greenhouse warming of about 0.04°C per decade. Other secondary contributions to the greenhouse effect from increases in CH₄ may arise from methane-induced increases in stratospheric H₂O, in tropospheric O₃, and in numerous other trace species whose concentration is controlled by reaction with HO radicals.An increased CH₄ source strength may result from the effect of increasing atmospheric temperatures on the known aqueous biological CH₄ sources, such as swamps, and may be an added consequence of the greenhouse effect.  相似文献