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201.
The impacts of forest conversion on runoff generation in the tropics have received much interest, but scientific progress is still hampered by challenging fieldwork conditions and limited knowledge about runoff mechanisms. Here, we assessed the runoff generation, flow paths and water source dynamics of a pristine rainforest catchment in Costa Rica using end member mixing analysis (EMMA) and a Bayesian mixing model (MixSIAR). Geochemical tracer data collected over a 4-week field campaign were combined with tritium data used to assess potential deeper groundwater flow pathways to the perennial stream. The streamflow composition was best captured using three end-members, namely throughfall, shallow (5–15 cm) and deeper (15–50 cm) soil water. We estimated the end-member contributions to the main stream and two tributaries using the two mixing approaches and found good agreement between results obtained from EMMA and MixSIAR. The system was overwhelmingly dominated by near-surface sources, with little evidence for deeper and older groundwater as tritium-derived baseflow mean transit time was between 2.0 and 4.4 years. The shallow soil flow pathway dominated streamflow contributions in the main stream (median 39% and 49% based on EMMA and MixSIAR, respectively), followed by the deeper soil (32% and 31%) and throughfall (25% and 19%). The two tributaries had even greater shallow soil water contributions relative to the main stream (83% and 74% for tributary A and 42% and 63% for tributary B). Tributary B had no detectable deep soil water contribution, reflecting the morphology of the hillslope (steeper slopes, shallower soils and lower vegetation density compared to hillslope A). Despite the short sampling campaign and associated uncertainties, this study allowed to thoroughly assess runoff generation mechanisms in a humid tropical catchment. Our results also provide a first comparison of two increasingly used mixing models and suggest that EMMA and MixSIAR yield comparable estimates of water source partitioning in this tropical, volcanic rainforest environment.  相似文献   
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The Tastil batholith (Eastern Cordillera, NW Argentina) holds relevant keys for interpreting the tectonic evolution of the Central Andes basement since it has always been interpreted as the subcrop of the Cambrian and Lower Ordovician basins in the Eastern Cordillera. However, in the Angosto de la Quesera section, the batholith intrudes sandstones underlying a fossiliferous Lower Tremadocian conglomerate containing Tastil granite pebbles. The precise assignation of the sandstones intruded by the granite to Cambrian Mesón Group or to the Uppermost Cambrian–Lower Tremadocian Santa Victoria Group is a key for refining the relationships between magmatic and sedimentary units. The ages of 526 Ma and 517 Ma (U/Pb, zircons) obtained from two facies of the batholith are coherent with the proposal of including these sandstones in the Mesón Group. However, the lithologic features and fossil content point to an affinity with the basal units of the Santa Victoria Group according to sedimentologic and stratigraphic studies ruled out by other authors. The intrusive relationships between the Tastil batholith and the Lower Paleozoic sandstones indicates the batholith is coeval with the Mesón and/or Santa Victoria groups basins instead of being its subcrop, which strongly contradicts previous proposals about basement evolution along the Lower Paleozoic margin of Gondwana. Therefore, the genesis and emplacement of the Tastil batholith must be related to the development of the Lower Paleozoic shelf basins rather than with the final stages of Puncoviscana-type basin evolution. The basement of central and northern Argentina records a wide spectrum of sedimentary, deformational, magmatic and metamorphic processes at a variety of crust levels during the Early Paleozoic. Tastil batholith emplacement and exhumation in the Eastern Cordillera represent shallower crustal expressions of the plutonic and high-T–low-P metamorphic events at deeper levels in the basement now exposed mainly in eastern Puna and Pampean Ranges.  相似文献   
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We investigated the relative distribution of allochthonous (i.e., terrigenous) organic matter in the complex, continuous, river–fjord–sound–channel–gulf system of Chile’s North Patagonia (41.5–46.5°S) in order to establish whether this organic matter can reach the open ocean or whether it is largely retained near its fluvial sources. Grain size distribution, total organic carbon and total nitrogen contents, and carbon stable isotope contents (δ13C) were quantified in 53 surface sediment samples collected during the CIMAR Fiordos cruises 1, 4, 8, and 10, as were salinity and silicic acid concentrations in the surface waters. A principal component analysis segregated the Chiloé and Aysén interior seas into two zones: (i) the continental fjords, with sediment enriched in allochthonous organic matter, having higher C:N molar ratios (10–14) and lower δ13C composition (?23‰ to ?27‰); and (ii) the channels and gulfs, with a prevalent autochthonous marine source, having lower C:N values (6–10) and higher δ13C composition (?20‰ to ?23‰). Estuarine waters with low salinity (2–30) and high silicic acid (10–90 μM) were associated with high C:N ratios and low δ13C in surface sediments, meaning that terrestrial organic matter was transported up to the mouth of the continental fjords. A two-source mixing model confirmed that allochthonous (terrestrial) organic matter contents (50–90%) associated with local river discharges were present within the continental fjords. On the contrary, autochthonous (marine) organic matter was prevalent (50–90%) at the sites in the marine influenced channels, sounds, and gulfs.  相似文献   
208.
Detailed investigation of an intermediate member of the reddingite–phosphoferrite series, using infrared and Raman spectroscopy, scanning electron microcopy and electron microprobe analysis, has been carried out on a homogeneous sample from a lithium-bearing pegmatite named Cigana mine, near Conselheiro Pena, Minas Gerais, Brazil. The determined formula is $ ({\text{Mn}}_{1.60} {\text{Fe}}_{1.21} {\text{Ca}}_{0.01} {\text{Mg}}_{0.01} )_{\sum 2.83} ({\text{PO}}_{4} )_{2.12} \cdot ({\text{H}}_{2} {\text{O}}_{2.85} {\text{F}}_{0.01} )_{\sum 2.86} $ , indicating predominance in the reddingite member. Raman spectroscopy coupled with infrared spectroscopy supports the concept of phosphate, hydrogen phosphate and dihydrogen phosphate units in the structure of reddingite-phosphoferrite. Infrared and Raman bands attributed to water and hydroxyl stretching modes are identified. Vibrational spectroscopy adds useful information to the molecular structure of reddingite–phosphoferrite.  相似文献   
209.
At present, approximately 1500 asteroids are known to evolve inside or sticked to the exterior 1:2 resonance with Mars at a ? 2.418 AU, being (142) Polana the largest member of this group. The effect of the forced secular modes superposed to the resonance gives rise to a complex dynamical evolution. Chaotic diffusion, collisions, close encounters with massive asteroids and mainly orbital migration due to the Yarkovsky effect generate continuous captures to and losses from the resonance, with a fraction of asteroids remaining captured over long time scales and generating a concentration in the semimajor axis distribution that exceeds by 20% the population of background asteroids. The Yarkovsky effect induces different dynamics according to the asteroid size, producing an excess of small asteroids inside the resonance. The evolution in the resonance generates a signature on the orbits, mainly in eccentricity, that depends on the time the asteroid remains captured inside the resonance and on the magnitude of the Yarkovsky effect. The greater the asteroids, the larger the time they remain captured in the resonance, allowing greater diffusion in eccentricity and inclination. The resonance generates a discontinuity and mixing in the space of proper elements producing misidentification of dynamical family members, mainly for Vesta and Nysa-Polana families. The half-life of resonant asteroids large enough for not being affected by the Yarkovsky effect is about 1 Gyr. From the point of view of taxonomic classes, the resonant population does not differ from the background population and the excess of small asteroids is confirmed.  相似文献   
210.
<正>El Soplao outcrop,an Early Cretaceous amber deposit recently discovered in northern Spain (Cantabria),has been shown to be the largest site of amber with arthropod inclusions that has been found in Spain so far.Relevant data provided herein for biogeochemistry of the amber,palynology,taphonomy and arthropod bioinclusions complement those previously published.This set of data suggests at least two botanical sources for the amber of El Soplao deposit.The first(type A amber)strongly supports a source related to Cheirolepidiaceae,and the second(type B amber)shows non-specific conifer biomarkers.Comparison of molecular composition of type A amber with Frenelopsis leaves(Cheirolepidiaceae)strongly suggests a biochemical affinity and a common botanical origin.A preliminary palynological study indicates a regional high taxonomical diversity,mainly of pteridophyte spores and gymnosperm pollen grains.According to the preliminary palynological data,the region was inhabited by conifer forests adapted to a dry season under a subtropical climate.The abundant charcoalified wood associated with the amber in the same beds is evidence of paleofires that most likely promoted both the resin production and an intensive erosion of the litter,and subsequent great accumulation of amber plus plant cuticles.In addition,for the first time in the fossil record, charcoalified plant fibers as bioinclusions in amber are reported.Other relevant taphonomic data are the exceptional presence of serpulids and bryozoans on the surfaces of some amber pieces indicating both a long exposure on marine or brackish-water and a mixed assemblage of amber.Lastly,new findings of insect bioinclusions,some of them uncommon in the fossil record or showing remarkable adaptations,are reported.In conclusion,a documented scenario for the origin of the El Soplao amber outcrop is provided.  相似文献   
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