Recharge sources and hydrogeochemical evolution of groundwater in semiarid and karstic environments: A field study in the Granada Basin (Southern Spain)     

Claus Kohfahl  Christoph Sprenger  Jose Benavente Herrera  Hanno Meyer  Franzisca Fernández Chacón  Asaf Pekdeger 《Applied Geochemistry》2008

The objective of this study is to refine the understanding of recharge processes in watersheds representative for karstic semiarid areas by means of stable isotope analysis and hydrogeochemistry. The study focuses on the Granada aquifer system which is located in an intramontane basin bounded by high mountain ranges providing elevation differences of almost 2900 m. These altitude gradients lead to important temperature and precipitation gradients and provide excellent conditions for the application of stable isotopes of water whose composition depends mainly on temperature. Samples of rain, snow, surface water and groundwater were collected at 154 locations for stable isotope studies (δ¹⁸O, D) and, in the case of ground- and surface waters, also for major and minor ion analysis. Thirty-seven springs were sampled between 2 and 5 times from October 2004 to March 2005 along an altitudinal gradient from 552 masl in the Granada basin to 2156 masl in Sierra Nevada. Nine groundwater samples were taken from the discharge of operating wells in the Granada basin which are all located between 540 and 728 masl. The two main rivers were monitored every 2–3 weeks at three different altitudes. Rainfall being scarce during the sampling period, precipitation could only be sampled during four rainfall events. Calculated recharge altitudes of springs showed that source areas of mainly snowmelt recharge are generally located between 1600 and 2000 masl. The isotope compositions of spring water indicate water sources from the western Mediterranean as well as from the Atlantic without indicating a seasonal trend. The isotope pattern of the Quaternary aquifer reflects the spatial separation of different sources of recharge which occur mainly by bankfiltration of the main rivers. Isotopic signatures in the southeastern part of the aquifer indicate a considerable recharge contribution by subsurface flow discharged from the adjacent carbonate aquifer. No evaporation effects due to agricultural irrigation were detected.  相似文献   

STUDIES OF BRAZILIAN METEORITES XIV. MINERALOGY,PETROLOGY, AND CHEMISTRY OF THE CONQUISTA,MINAS GERAIS,CHONDRITE     

K. Keil  E. Kirchner  C.B. Gomes  E. Jarosewich  R.L.L. Murta 《Meteoritics & planetary science》1978,13(2):177-187

The Conquista chondrite consists of major olivine, low-Ca pyroxene (both ortho- and twinned clino-), troilite and metallic nickel-iron; minor glassy to microcrystalline material and pigeonite; and accessory chromite, high-Ca clinopyroxene and hydrous ferric oxides that formed by terrestrial weathering of metallic nickel-iron. Results of microscopic, electron microprobe, and bulk chemical studies, particularly the compositions of olivine (Fa_17.2) and low-Ca pyroxene (Fs_15.4); the contents of metallic nickel-iron (18.5%) and total iron (25.83%); and the ratios of Fe°/Fe_total (0.64), Fe°/Ni° (9.59) and Fe_total/SiO₂ (0.69) indicate H-group classification. The pronounced, well-developed chondritic texture; the slight compositional variations in constituent phases; the high Ca contents of pyroxene and the presence of pigeonite, glassy to microcrystalline interstitial material rich in alkalis and SiO₂, and of twinned low-Ca clinopyroxene suggest that Conquista is of petrologic type 4.  相似文献   

Formation of feldspathic and metallic melts by shock in enstatite chondrite Reckling Peak A80259     

Timothy j. Fagan  Edward r. d. Scott  Klaus Keil  Thomas f. Cooney  Shiv k. Sharma 《Meteoritics & planetary science》2000,35(2):319-329

Abstract— The enstatite chondrite reckling peak (rkp) a80259 contains feldspathic glass, kamacite, troilite, and unusual sets of parallel fine‐grained enstatite prisms that formed by rapid cooling of shock melts. Metallic Fe,Ni and troilite occur as spherical inclusions in feldspathic glass, reflecting the immiscible Fe‐Ni‐S and feldspathic melts generated during the impact. The Fe‐Ni‐S and feldspathic liquids were injected into fractures in coarse‐grained enstatite and cooled rapidly, resulting in thin (≤ 10 μm) semicontinuous to discontinuous veins and inclusion trails in host enstatite. Whole‐rock melt veins characteristic of heavily shocked ordinary chondrites are conspicuously absent. Raman spectroscopy shows that the feldspathic material is a glass. Elevated MgO and SiO₂ contents of the glass indicate that some enstatite and silica were incorporated in the feldspathic melt. Metallic Fe,Ni globules are enclosed by sulfide and exhibit Nienrichment along their margins characteristic of rapid crystallization from a Fe‐Ni‐S liquid. Metal enclosed by sulfide is higher in Si and P than metal in feldspathic glass and enstatite, possibly indicating lower O fugacities in metal/sulfide than in silicate domains. Fine‐grained, elongate enstatite prisms in troilite or feldspathic glass crystallized from local pyroxene melts that formed along precursor grain boundaries, but most of the enstatite in the target rock remained solid during the impact and occurs as deformed, coarsegrained crystals with lower CaO, Al₂O₃, and FeO than the fine‐grained enstatite. Reckling Peak A80259 represents an intermediate stage of shock melting between unmelted E chondrites and whole‐rock shock melts and melt breccias documented by previous workers. The shock petrogenesis of RKPA80259 reflects the extensive impact processing of the enstatite chondrite parent bodies relative to those of other chondrite types.  相似文献   

Design and development of the Advanced Technology Solar Telescope     

S. Keil  T. Rimmele  C. Keller  The ATST Team 《Astronomische Nachrichten》2003,324(4):303-304

Led by the National Solar Observatory, plans have been made to design and to develop the Advanced Technology Solar Telescope (ATST). The ATST will be a 4‐m general‐purpose solar telescope equipped with adaptive optics and versatile post‐focus instrumentation. Its main aim will be to achieve an angular resolution of 0.03 arcsec (20 km on the solar surface). The project and the telescope design are briefly described.  相似文献   

Insight into the Last Glacial Maximum climate and environments of the Baikal region     

Pavel E. Tarasov  Boris P. Ilyashuk  Christian Leipe  Stefanie Müller  Birgit Plessen  Philipp Hoelzmann  Svetlana S. Kostrova  Elena V. Bezrukova  Hanno Meyer 《Boreas: An International Journal of Quaternary Research》2019,48(2):488-506

This study presents a multi‐proxy record from Lake Kotokel in the Baikal region at decadal‐to‐multidecadal resolution and provides a reconstruction of terrestrial and aquatic environments in the area during a 2000‐year interval of globally harsh climate often referred to as the Last Glacial Maximum (LGM). The studied lake is situated near the eastern shoreline of Lake Baikal, in a climatically sensitive zone that hosts boreal taiga and cold deciduous forests, cold steppe associations typical for northern Mongolia, and mountain tundra vegetation. The results provide a detailed picture of the period in focus, indicating (i) a driest phase (c. 24.0–23.4 cal. ka BP) with low precipitation, high summer evaporation, and low lake levels, (ii) a transitional interval of unstable conditions (c. 23.4–22.6 cal. ka BP), and (iii) a phase (c. 22.6–22.0 cal. ka BP) of relatively high precipitation (and moisture availability) and relatively high lake levels. One hotly debated issue in late Quaternary research is regional summer thermal conditions during the LGM. Our chironomid‐based reconstruction suggests at least 3.5 °C higher than present summer temperatures between c. 22.6 and 22.0 cal. ka BP, which are well in line with warmer and wetter conditions in the North Atlantic region inferred from Greenland ice‐cores. Overall, it appears that environments in central Eurasia during the LGM were affected by much colder than present winter temperatures and higher than present summer temperatures, although the effects of temperature oscillations were strongly influenced by changes in humidity.  相似文献   

Differential presence of anthropogenic compounds dissolved in the marine waters of Puget Sound, WA and Barkley Sound, BC   总被引：1，自引：0，他引：1  

Keil R  Salemme K  Forrest B  Neibauer J  Logsdon M 《Marine pollution bulletin》2011,62(11):2404-2411

Organic compounds were evaluated in March 2010 at 22 stations in Barkley Sound, Vancouver Island Canada and at 66 locations in Puget Sound. Of 37 compounds, 15 were xenobiotics, 8 were determined to have an anthropogenic imprint over natural sources, and 13 were presumed to be of natural or mixed origin. The three most frequently detected compounds were salicyclic acid, vanillin and thymol. The three most abundant compounds were diethylhexyl phthalate (DEHP), ethyl vanillin and benzaldehyde (∼600 ng L⁻¹ on average). Concentrations of xenobiotics were 10-100 times higher in Puget Sound relative to Barkley Sound. Three compound couplets are used to illustrate the influence of human activity on marine waters; vanillin and ethyl vanillin, salicylic acid and acetylsalicylic acid, and cinnamaldehyde and cinnamic acid. Ratios indicate that anthropogenic activities are the predominant source of these chemicals in Puget Sound.  相似文献   

Kurt Fredriksson (1926–2001)     

Edward J. Olsen  Klaus Keil  Gero Kurat 《Meteoritics & planetary science》2002,37(2):301-302

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Dark clasts in the Khor Temiki aubrite: Not basalts     

Horton E. Newsom  Theo Ntaflos  Klaus Keil 《Meteoritics & planetary science》1996,31(1):146-151

Abstract— The enstatite achondrite meteorites (aubrites) are ultramafic assemblages with highly variable bulk rare earth element (REE) compositions. An enrichment of REE in a dark clast from the Khor Temiki aubrite led Wolf et al. (1983) to suggest that such dark clasts could be the basaltic (i.e., enstatite-plagioclase) complements to the ultramafic aubrites, with the relatively high REE contents resulting from the presence of plagioclase, which is a common carrier of the REEs. We have studied several dark clasts from the Khor Temiki aubrite and find no evidence for a basaltic character for such material. The microscopic character of the dark clasts is not significantly different from the main portions of Khor Temiki and consists either of highly brecciated material, containing a fine-grained matrix, or of enstatite grains with abundant inclusions. We suggest that the dark clasts are shock-darkened, heterogeneous Khor Temiki material that, by chance, contained variable trace contents of oldhamite (CaS), which has been shown to be a major carrier of REE in aubrites. We find that the REE contents of the clasts range from 0.1 to ～20× CI. Most have negative Eu anomalies, but one has a small positive anomaly. Extensive searches have failed to identify basaltic material in Khor Temiki and other aubrites. The absence of basaltic material is consistent with, but does not prove, the model of Wilson and Keil (1991). They calculate that, on an asteroidal parent body < ～100 km in radius, a volatile-rich basaltic partial melt erupted with a velocity greater than the escape velocity of the asteroid and, thus, was lost into space ～ 4.55 Ga ago.  相似文献   

Oxygen isotopic alteration in Ca‐Al‐rich inclusions from Efremovka: Nebular or parent body setting?     

T. J. Fagan  A. N. Krot  K. Keil  H. Yurimoto 《Meteoritics & planetary science》2004,39(8):1257-1272

Abstract— In situ SIMS oxygen isotope data were collected from a coarse‐grained type B1 Ca‐Al‐rich inclusion (CAI) and an adjacent fine‐grained CAI in the reduced CV3 Efremovka to evaluate the timing of isotopic alteration of these two objects. The coarse‐grained CAI (CGI‐10) is a sub‐spherical object composed of elongate, euhedral, normally‐zoned melilite crystals ranging up to several hundreds of Pm in length, coarse‐grained anorthite and Al, Ti‐diopside (fassaite), all with finegrained (～10 μm across) inclusions of spinel. Similar to many previously examined coarse‐grained CAIs from CV chondrites, spinel and fassaite are ¹⁶O‐rich and melilite is ¹⁶O‐poor, but in contrast to many previous results, anorthite is ¹⁶O‐rich. Isotopic composition does not vary with textural setting in the CAI: analyses of melilite from the core and mantle and analyses from a variety of major element compositions yield consistent ¹⁶O‐poor compositions. CGI‐10 originated in an ¹⁶O‐rich environment, and subsequent alteration resulted in complete isotopic exchange in melilite. The fine‐grained CAI (FGI‐12) also preserves evidence of a 1st‐generation origin in an ¹⁶O‐rich setting but underwent less severe isotopic alteration. FGI‐12 is composed of spinel ± melilite nodules linked by a mass of Al‐diopside and minor forsterite along the CAI rim. All minerals are very fine‐grained (<5 μm) with no apparent igneous textures or zoning. Spinel, Al‐diopside, and forsterite are ¹⁶O‐rich, while melilite is variably depleted in ¹⁶O (δ^17,18O from ～‐40‰ to ?5‰). The contrast in isotopic distributions in CGI‐10 and FGI‐12 is opposite to the pattern that would result from simultaneous alteration: the object with finer‐grained melilite and a greater surface area/ volume has undergone less isotopic exchange than the coarser‐grained object. Thus, the two CAIs were altered in different settings. As the CAIs are adjacent to each other in the meteorite, isotopic exchange in CGI‐10 must have preceded incorporation of this CAI in the Efremovka parent body. This supports a nebular setting for isotopic alteration of the commonly observed ¹⁶O‐poor melilite in coarse‐grained CAIs from CV chondrites.  相似文献   

The Vicência meteorite fall: A new unshocked (S1) weakly metamorphosed (3.2) LL chondrite          下载免费PDF全文

Klaus Keil  Maria E. Zucolotto  Alexander N. Krot  Patricia M. Doyle  Myriam Telus  Tatiana V. Krot  Richard C. Greenwood  Ian A. Franchi  John T. Wasson  Kees C. Welten  Marc W. Caffee  Derek W. G. Sears  My Riebe  Rainer Wieler  Edivaldo dos Santos  Rosa B. Scorzelli  Jerome Gattacceca  France Lagroix  Matthias Laubenstein  Julio C. Mendes  Philippe Schmitt‐Kopplin  Mourad Harir  Andre L. R. Moutinho 《Meteoritics & planetary science》2015,50(6):1089-1111

The Vicência meteorite, a stone of 1.547 kg, fell on September 21, 2013, at the village Borracha, near the city of Vicência, Pernambuco, Brazil. It was recovered immediately after the fall, and our consortium study showed it to be an unshocked (S1) LL3.2 ordinary chondrite. The LL group classification is based on the bulk density (3.13 g cm^?3); the chondrule mean apparent diameter (0.9 mm); the bulk oxygen isotopic composition (δ¹⁷O = 3.768 ± 0.042‰, δ¹⁸O = 5.359 ± 0.042‰, Δ¹⁷O = 0.981 ± 0.020‰); the content of metallic Fe,Ni (1.8 vol%); the Co content of kamacite (1.73 wt%); the bulk contents of the siderophile elements Ir and Co versus Au; and the ratios of metallic Fe⁰/total iron (0.105) versus total Fe/Mg (1.164), and of Ni/Mg (0.057) versus total Fe/Mg. The petrologic type 3.2 classification is indicated by the beautifully developed chondritic texture, the standard deviation (~0.09) versus mean Cr₂O₃ content (~0.14 wt%) of ferroan olivine, the TL sensitivity and the peak temperature and peak width at half maximum, the cathodoluminescence properties of chondrules, the content of trapped ¹³²Xe_tr (0.317 × 10^?8cm³STP g^?1), and the Raman spectra for organic material in the matrix. The cosmic ray exposure age is ~72 Ma, which is at the upper end of the age distribution of LL group chondrites. The meteorite is unusual in that it contains relatively large, up to nearly 100 μm in size, secondary fayalite grains, defined as olivine with Fa_>75, large enough to allow in situ measurement of oxygen and Mn‐Cr isotope systematics with SIMS. Its oxygen isotopes plot along a mass‐dependent fractionation line with a slope of ~0.5 and Δ¹⁷O of 4.0 ± 0.3‰, and are similar to those of secondary fayalite and magnetite in the unequilibrated chondrites EET 90161, MET 96503, and Ngawi. These data suggest that secondary fayalite in Vicência was in equilibrium with a fluid with a Δ¹⁷O of ~4‰, consistent with the composition of the fluid in equilibrium with secondary magnetite and fayalite in other unequilibrated ordinary chondrites. Secondary fayalite and the chondrule olivine phenocrysts in Vicência are not in isotopic equilibrium, consistent with low‐temperature formation of fayalite during aqueous alteration on the LL parent body. That alteration, as dated by the ⁵³Mn‐⁵³Cr chronology age of secondary fayalite, took place $4.0{}_{?1.1}^{+1.4}$ Ma after formation of CV CAIs when anchored to the quenched angrite D'Orbigny.  相似文献