The shoshonite porphyry Cu-Au association in the Goonumbla District,N.S.W., Australia     

Dipl.-Geol. D. Müller  D. I. Groves  P. S. Heithersay 《Mineralogy and Petrology》1994,51(2-4):299-321

Summary The Goonumbla porphyry copper-gold deposit in N.S.W., Australia, is hosted by late Ordovician (439.2 ± 1.2 Ma)shoshonitic igneous rocks. In terms of their petrography, the rocks vary from andesitic to dacitic lavas and tuffs which are partly intruded by monzonite stocks; they are characterized by high and variable Al₂O₃ (13.4–19.9 wt%), very high K₂O values (up to 6.8 wt%), and high K₂O/Na₂O ratios (0.58–1.48), which are typical for the shoshonite association. The rocks also have enriched LILE concentrations (Ba up to 1200 ppm, Sr up to 1350 ppm), low HFSE (TiO₂ < 0.67 wt%, Zr < 125 ppm, Nb < 10 ppm, Hf < 3.4 ppm), and very low LREE (La < 22.4 ppm, Ce < 31 ppm), which are typical for potassic volcanic rocks formed in alate oceanic-arc setting.Mineral chemistry of selected magmatic mica and apatite phenocrysts from host rocks reveals relatively high SrO and BaO contents (micas: 0.15 wt% and up to 0.28 wt%, respectively; apatites: up to 0.28 wt% and 0.19 wt%, respectively) and very high halogen concentrations. Micas are characterized by up to 3.9 wt% F and 0.14 wt% Cl, whereas apatites have up to 3.6 wt% F and 0.68 wt% Cl. These very high halogen contents compared to those from barren intrusions imply that the shoshonitic magmatism was the source of mineralization.Copper-gold mineralization consists mainly of bornite, chalcopyrite, chalcocite and minor pyrite and tetrahedrite. Native gold occurs mainly as minute grains within silicates of the host rocks, and more rarely as fine inclusions in the sulphides. Mineralization is accompanied by wallrock alteration comprising a spatially restricted potassic type and a regional propylitic alteration type.Thus, the porphyry copper-gold deposit in the Goonumbla district can be viewed as an additional example of a worldwide association between potassic/shoshonitic magmatism and base- and precious-metal mineralization. More specifically, it appears to be the oldest recorded example of a shoshontie-associated porphyry Cu-Au deposit from a late oceanic-arc setting, a possible modern analogue being Ladolam at Lihir Island, Papua New Guinea

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Die Shoshonit Porphyry Cu-Au Assoziation im Goonumbla Distrikt, N.S.W., Australien

Zusammenfassung Die Porphyry Cu-Au Vererzung im Goonumbla Distrikt in New South Wales, Australien, sitzt in oberordovizischen (ca. 439.2 ± 1.2 Ma) Shoshoniten auf. Das petrographische Spektrum dieser Gesteine reicht von andesitischen bis dazitischen Laven und Tuffen, die lokal von Monzonit-Stöcken intrudiert werden; die Gesteine besitzen hohe, aber variable Al₂O₃ Gehalte (13.4–19.9 Gew%), sehr hohe K₂O Gehalte (bis zu 6.8 Gew%) und hohe K₂O/Na₂O Verhältnisse (0.58–1.48), die typisch sind für Shoshonite. Außerdem weisen sie hohe Konzentrationen an LILE Elementen (Ba bis 1200 ppm, Sr bis 1350 ppm) auf und geringe Konzentrationen an HFSE (TiO₂ < 0.67 Gew%, Zr < 125 ppm, Nb < 10 ppm, Hf < 3.4 ppm) sowie an LREE (La < 22.4 ppm, Ce < 31 ppm), die als typisch gelten für potassische Vulkanite von ozeanischen Plattengrenzen.Die Mineralchemie von repräsentativen Glimmer- und Apatit-Phänokristallen ist charakterisiert durch hohe SrO und BaO Gehalte (Glimmer: 0.15 Gew%, bzw. bis 0.28 Gew%; Apatite: bis 0.28 Gew%, bzw. 0.19 Gew%). Sie enthalten ferner sehr hohe Halogen-Konzentrationen. Die Glimmer enthalten beispielsweise bis zu 3.9 Gew% F und 0.14 Gew% Cl, während Apatite bis zu 3.6 Gew% F und 0.68 Gew% Ci aufweisen. Dies erscheint nicht ungewöhnlich, weil Glimmer und Apatite von vererzten Mag matiten zumeist deutlich höhere Halogengehalte besitzen, als solche von unvererzten Magmatiten. Die hohen Halogen-Gehalte in Phänokristallen aus den Shoshoniten legen nahe, die Vulkanite als den Ursprung der Vererzung zu interpretieren.Die Cu-Au Vererzung besteht überwiegend aus den Sulfiden Bornit, Kupferkies, Kupferglanz und vereinzelt auftretendem Pyrit und Tetrahedrit. Gediegen Gold wird in der Regel nur als kleine Partikel innerhalb von Silikaten der shoshonitischen Wirtsgesteine und seltener als feine Einschlüsse in Sulfiden gefunden.Die Vererzung wird von hydrothermaler Alteration der Wirtsgesteine begleitet und zwei Alterationsarten lassen sich unterscheiden: eine potassische sowie eine regional zu beobachtende propylitische Alteration.Die Porphyry Cu-Au Lagerstätte im Goonumbla Gebiet ist ein Beispiel für die weltweit beobachtete Assoziation von Bunt- und Edelmetallvererzungen und potassisch/shoshonitischem Magmatismus. Der Goonumbla Distrikt stellt die älteste bisher bekannte Porphyry Cu-Au Lagerstätte aus einerspätgenetischen ozeanischen Plattengrenze dar. Einmodernes Beispiel für eine Cu-Au Lagerstätte vergleichbaren Typs ist Ladolam auf Lihir Island, Papua New Guinea.

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Early Cretaceous volcaniclastic and quartzose sandstones from north central Nepal: composition,sedimentology and geotectonic significance     

Sören B. Dürr  Martin R. Gibling 《International Journal of Earth Sciences》1994,83(1):62-75

Early Cretaceous sandstones and shales from the Thakkhola region (Chukh and Tangbe Formations) were deposited on the subsiding northern (Tethyan) margin of Gondwana; current directions indicate a source area to the south. Whereas the Berriasian Chukh Formation is dominated by quartz arenites, volcaniclastic sandstones and minor conglomerates dominate the Tangbe Formation of Valanginian to Aptian age. Upsection, the composition of the volcaniclastic components changes from mainly basaltic to dominantly dacitic/rhyolitic. Magmatism was preceded and accompanied by strong uplift in the source area of the Chukh and Tangbe clastics, resulting in the erosion of probably more than several hundred meters of pre-Cretaceous sedimentary, metamorphic and plutonic rocks. A geochemical whole rock analysis of basaltic pebble fragments shows their alkaline character and suggests a within-plate geotectonic setting for the volcanic source. This volcanotectonic event is probably related to rifting between Australia and Greater India, where seafloor spreading began in late Valanginian/Hauterivian times.  相似文献   

Upper Silesia,a forgotten region in Central Europe     

Adolf Kühnemann 《GeoJournal》1993,30(3):259-272

On the map of Europe, forming the south-western border region of Poland, is to be found the name Silesia, with in many cases its southern part emphasized — Upper Silesia. Any search for statistics as to its exact surface area and population size will be in vain. At the end of World War I, Upper Silesia found itself squeezed between two nationalistically-obsessed peoples, and economically too attractive to both to be allowed to play an idependent political role, as it had for centuries. Upper Silesia was in 1921 divided. After World War II, under the communist centralised power system, a completely colonial robber economy was pursued. Because of the coal production there is now here one of the greatest agglomeration areas in Europe, with an ageing heavy industry and a catastropihcally damaged environment.  相似文献   

Ozone production due to emissions from vegetation burning     

Günter Helas  Jürgen Lobert  Dieter Scharffe  Luise Schäfer  Johann Goldammer  Jean Baudet  Brou Ahoua  Ayité-Lô Ajavon  Jean-Pierre Lacaux  Robert Delmas  Meinrat O. Andreae 《Journal of Atmospheric Chemistry》1995,22(1-2):163-174

Ozone has been observed in elevated concentrations by satellites over areas previously believed to be background. There is meteorological evidence, that these ozone plumes found over the Atlantic Ocean originate from vegetation fires on the African continent.In a previous study (DECAFE-88), we have investigated ozone and assumed precursor compounds over African tropical forest regions. Our measurements revealed large photosmog layers at altitudes from 1.5 to 4 km. Both chemical and meteorological evidence point to savanna fires up to several thousand km upwind as sources.Here we describe ozone mixing ratios observed over western Africa and compare ozone production ratios from different field measurement campaigns related to vegetation burning. We find that air masses containing photosmog ingredients require several days to develop their oxidation potential, similar to what is known from air polluted by emissions from fossil fuel burning. Finally, we estimate the global ozone production due to vegetation fires and conclude that this source is comparable in strength to the stratospheric input.  相似文献   

A model of the origin of the Jovian ring     

E. Grün  G. Morfill  G. Schwehm  T.V. Johnson 《Icarus》1980,44(2):326-338

Starting with the assumption that the micron-sized particles which make up the bright Jovian ring are fragments of erosive collisions between micrometeoroid projectiles and large parent bodies, a physical model of the ring is calculated. The physics of high-velocity impacts leads to a well-defined size distribution for the ejecta, the optical properties of which can be compared with observation. This gives information on the ejecta material (very likely silicates) and on the maximum size of the projectiles, which turns out to be about 0.1 μm. The origin of these projectiles is discussed, and it is concluded that dust particles ejected in volcanic activity from Io are the most likely source. The impact model leads quite naturally to a distribution in ejecta sizes, which in turn determines the structure of the ring. The largest ejecta form the bright ring, medium-sized ejecta form a disk extending all the way to the Jovian atmosphere, and the small ejecta form a faint halo, the structure of which is dominated by electromagnetic forces. In addition to the Io particles, interaction with interplanetary micrometeoroids is also considered. It is concluded that μm-sized ejecta from this source have ejection velocities which are several orders of magnitude too large, and thus cannot contribute significantly to the observed bright ring. However, the total mass ejection rate is significant. Destruction of these ejecta by the Io particles may provide additional particles for the halo.  相似文献   

Spectral investigation of the chromosphere     

U. Grossmann-Doerth  Marina Von Uexküll 《Solar physics》1977,55(2):321-333

Several hundred H spectrograms from areas close to the solar limb were taken with the 35 cm Coudé refractor at Anacapri. The 41 spectra with the greatest spatial resolution were selected and analysed. At the supergranular boundaries a considerable fraction of the line profiles were found to correspond to Beckers Cloud Model (BCM). Moreover, the BCM parameters of the dark mottles at the limb appear to be approximately equal to those from the center of the disk. On the other hand, we also obtained evidence in disagreement with the general applicability of the BCM to all features of the chromospheric fine structure.We attempted to present the large set of observational data in a fashion that permits their interpretation by alternative theoretical models.Mitteilungen aus dem Fraunhofer Institut Nr. 151.  相似文献   

The ion-composition of the plasma produced by impacts of fast dust particles     

B.-K. Dalmann  E. Grün  J. Kissel  H. Dietzel 《Planetary and Space Science》1977,25(2):135-147

The composition of the impact plasma produced by fast dust particles (v > 1 km/sec) hitting an Au or W target was measured both with a model of the HELIOS micrometeoroid experiment (low electric field at the target) and a high field detector. The plasma composition and the total plasma charge depend strongly on the impact velocity and the electric field strength at the target. Spectra of 9 different projectile-target combinations were analysed. Two types of spectra could be observed, depending on the projectile material. (1) Spectra of metals and hard dielectrics (Mohs' hardness ? 5). Particle constituents of low ionisation energy (e · u ? 7eV, e.g. Na, K, Al) dominate the spectra of these materials at impact velocities below 10 km/sec. At higher speed the relative intensities change and new ions with higher ionisation energies appear. (2) Spectra of soft dielectrics (Mohs' hardness < 3). Below 9 km/sec these materials produced less total charge than did the others. The highest masses were detected at 74 amu. The relative abundance of ions with low ionization energies such as Li, Na, K, etc. is comparatively small. Negative ions were also observed in the impact plasma. Their total number was found to be approximately 3–6% of that of the positive ions at 6 km/sec particle speed.  相似文献   

Measurements of peroxyacetylnitrate in the marine boundary layer over the Atlantic     

K. P. Müller  J. Rudolph 《Journal of Atmospheric Chemistry》1992,15(3-4):361-367

The atmospheric concentration of peroxyacetylnitrate (PAN) was measured during a cruise of the R.S. Polarstern from Bremerhaven (Germany) to Rio Grande do Sul (Brazil) in September/ October 1988. The measurements were made in-situ by a combination of electron capture gaschromatography with a cryogenic preconcentration step. The theoretical lower limit of detection (3) was 0.4 ppt. The mixing ratios of PAN varied by more than three orders of magnitude from 2000 ppt in the English Channel to less than 0.4 ppt south of the Azores (38° N). South of 35° N, PAN levels were below the detection limit, except at 30–31° S off the eastern coast of South America. Here, PAN mixing ratios of 10 to 100 ppt were detected in continentally influenced air masses. Detectable levels of PAN were mostly observed in air masses of continental or high northern origin. Changes in the wind directions were usually associated with substantial changes in the PAN mixing ratios.  相似文献   

Theory of the local scale parameter method for EDM     

F. K. Brunner  J. M. Rüeger 《Journal of Geodesy》1992,66(4):355-364

The determination of a representative refractive index for the wave path is the main limitation of the attainable accuracy in electronic distance measurement. To overcome this limitation the length ratio method was initially proposed and later developed into the local scale parameter (LSP) method. In this paper, the mathematical model of the LSP method is derived for electro-optical distance measurement from first principles based on the physics of the atmospheric boundary layer. The model does not rely on standard atmospheres. It is shown that atmospheric temperatures and pressures must be observed at instrument stations but not at reflector stations. Appropriate LSP field procedures and the results of some field experiments are summarized. The method consistently produces accuracies of better than ±1 ppm. Use of the method is recommended for high precision (trilateration) networks, which need to be measured repeatedly and where absolute scale is not relevant.  相似文献   

Nd-, Sr-, O-isotopic and chemical evidence for a two-stage contamination history of mantle magma in the Central-Alpine Bergell intrusion     

Friedhelm von Blanckenburg  Gretchen Früh-Green  Karlheinz Diethelm  Peter Stille 《Contributions to Mineralogy and Petrology》1992,110(1):33-45

Two different contamination processes have been identified as having been operative in the genesis of a plutonic suite: initial contamination of a mantle source, and subsequent crustal contamination of uprising partial melts from the mantle. These processes are indicated by a detailed analyses of Nd, Sr, and oxygen isotopes together with major-and trace-elements of the 32–30 Ma calc-alkaline Bergell intrusion. This intrusion is located at the suture of the Alpine continental collision zone and contains rock types capable of discriminating between mantle and intracrustal processes. A range from basaltic-andesitic dykes in the surrounding country rocks, cumulitic hornblendites, gabbros, tonalite, granodiorite and lamprophyres, to pegmatites and aplites, is exposed in this single intrusion. The results of REE modelling and isotopic compositions of the basic members suggest that the cumulates were fractionated from a picrobasaltic liquid originating by partial melting of enriched subcontinental mantle (_Nd=+4). Increases in ⁸⁷Sr/⁸⁶Sr (0.7055) and ¹⁸O(+6.7) in these samples relative to the mantle array and compositions of other Periadriatic intrusions are most likely the result of an initial contamination of the mantle source by dehydration or partial melting of altered subducted oceanic crust. Slight differentiation of such a picrobasaltic liquid produced the basaltic-andesitic dykes. Simultaneous fractional crystallization and contamination of the uprising magma by continental crust produced crustal isotopic signatures which increase with acidity to values of (_Nd=-7.6), ⁸⁷Sr/⁸⁶Sr=0.716 and ¹⁸O=+10. The crustal imprint and LREE enrichment in the dominating tonalite increase with decreasing crystallization depth which indicates that the tonalites were emplaced in several distinct batches with different degrees of contamination. Shoshonitic lamprophyres, which intruded into the partly solidified granodiorite, were generated in a deep, strongly contaminated mantle source. The posttectonic 26 Ma Novate leucogranite is not cogenetic with the main Bergell body, but rather formed from a predominantly crustal source. If the described features are indeed due to mantle source contamination processes, which are well known for volcanic arcs, it must be concluded that these may also play a significant role in the genesis of calcalkaline plutonic suites.  相似文献