Interaction of atmospheric chemistry and climate and its impact on stratospheric ozone     

C. Schnadt  M. Dameris  M. Ponater  R. Hein  V. Grewe  B. Steil 《Climate Dynamics》2002,18(6):501-517

The interactively coupled chemistry-climate model ECHAM4.L39(DLR)/CHEM is employed in sensitivity calculations to investigate feedback mechanisms of dynamic, chemical, and radiative processes. Two multi-year model simulations are carried out, which represent recent atmospheric conditions. It is shown that the model is able to reproduce observed features and trends with respect to dynamics and chemistry of the troposphere and lower stratosphere. In polar regions it is demonstrated that an increased persistence of the winter vortices is mainly due to enhanced greenhouse gas mixing ratios and to reduced ozone concentration in the lower stratosphere. An additional sensitivity simulation is investigated, concerning a possible future development of the chemical composition of the atmosphere and climate. The model results in the Southern Hemisphere indicate that the adopted further increase of greenhouse gas mixing ratios leads to an intensified radiative cooling in the lower stratosphere. Therefore, Antarctic ozone depletion slightly increases due to a larger PSC activity, although stratospheric chlorine is reduced. Interestingly, the behavior in the Northern Hemisphere is different. During winter, an enhanced activity of planetary waves yields a more disturbed stratospheric vortex. This "dynamical heating" compensates the additional radiative cooling due to enhanced greenhouse gas concentrations in the polar region. In connection with reduced stratospheric chlorine loading, the ozone layer clearly recovers.  相似文献   

Anomalies in rare earth distributions in seawater: Gd and Tb     

Hein J.W. De Baar  Peter G. Brewer  Michael P. Bacon 《Geochimica et cosmochimica acta》1985,49(9):1961-1969

We have measured profiles of the rare earth elements (REE) in Atlantic and Pacific Ocean waters. The data, normalized versus shales, exhibit a pronounced anomaly in Gd relative to its neighbors Eu and Tb in the REE series such that the Gd concentrations are high by 30–50%. Closer inspection reveals that the anomaly is made up of both elevated Gd and depressed Tb concentrations, likely associated with solution chemistry shifts in the transition from an exactly half filled 4f electron shell. Anomalies in Gd and Tb solution complexation are also indicated by the Turner-Whitfield-Dickson speciation model. The overall trend of heavy REE(III) enrichment in seawater and the $\text{Gd}\text{Tb}$ anomaly described here tend to support scavenging as an important removal mechanism for the REE from seawater.  相似文献   

Geology of the Ranger Uranium Mine, Northern Territory, Australia: structural constraints on the timing of uranium emplacement   总被引：1，自引：0，他引：1  

K. A. A. Hein   《Ore Geology Reviews》2002,20(3-4)

The geology of the No 1 and 3 pits at the Ranger Mine in the Pine Creek Inlier (PCI) of Australia is dominated by Palaeoproterozoic volcanic, carbonate and sedimentary sequences that unconformably overlie Archaean granitic gneiss of the Nanambu Complex (2470±50 Ma). These sequences are folded, faulted and sheared, and crosscut by east-trending granite (sensu stricto) dykes and pegmatite veins, and gently dipping N–NE trending mafic dykes of the Oenpelli Dolerite (1690 Ma). Regional metamorphism is to greenschist facies and contact metamorphism is to hornblende-hornfels facies.The rocks of the Ranger Mine have been subjected to at least two phases of ductile–brittle deformation (D2–D3) and one phase of brittle deformation (D4). These events were preceded by regional diastathermal or extension-related metamorphism (D1) and the development of an ubiquitous bedding-parallel cleavage (S1).D2 resulted in the development of NNE–NNW trending mesoscopic folds (F2) and a network of thrusts and dextral reverse shears. The modelled palaeo-stress directions for the emplacement of pegmatite veins suggests that they formed early in D2. D3 resulted in the development of WNW–NW trending mesoscopic folds (F3), a weakly defined axial planar cleavage (S3) and sinistral reactivation of D2 shears. D2–D3 are correlated with deformation during the Maud Creek Event of the Top End Orogeny (1870–1780 Ma), while the emplacement of granite dykes and pegmatite veins is correlated with emplacement of regional granites at 1870–1860 Ma.D4 is associated with brittle deformation and resulted in the development of normal faults and fault breccias during a period of east–west extension. This event is correlated with regional east–west extension during deposition of Palaeo- to Mesoproterozoic platform sequences.The sequence of tectonic events established in this study indicates that uranium-bearing ore shoots in the Ranger No 1 and 3 pits formed during extension in D4, and after emplacement of the Oenpelli Dolerite at 1690 Ma. However, the currently accepted 1737±20 U–Pb Ma age places the mineralising event at time of regional post-orogenic erosion, after the Top End Orogeny and before emplacement of the Oenpelli Dolerite and extension in D4. The U–Pb age is not consistent with Sm–Nd ages for primary uranium mineralisation at Nabarlek and Jabiluka at 1650 Ma [Econ. Geol. 84 (1989) 64] and does not concur with currently accepted regional tectonic data of Johnston [Johnston, J.D., 1984. Structural evolution of the Pine Creek Inlier and mineralisation therein, Northern Territory, Australia. Unpublished PhD Thesis, Monash University, Australia], Needham et al. [Precambrian Res. 40/41 (1988) 543] and others. Consequently, the absolute age of uranium mineralisation at the Ranger Mine is open.  相似文献   

Gravity Spectra from the Density Distribution of Earth’s Uppermost 435 km     

Josef Sebera  Roger Haagmans  Rune Floberghagen  Jörg Ebbing 《Surveys in Geophysics》2018,39(2):227-244

The Earth masses reside in a near-hydrostatic equilibrium, while the deviations are, for example, manifested in the geoid, which is nowadays well determined by satellite gravimetry. Recent progress in estimating the density distribution of the Earth allows us to examine individual Earth layers and to directly see how the sum approaches the observed anomalous gravitational field. This study evaluates contributions from the crust and the upper mantle taken from the LITHO1.0 model and quantifies the gravitational spectra of the density structure to the depth of 435 km. This is done without isostatic adjustments to see what can be revealed with models like LITHO1.0 alone. At the resolution of 290 km (spherical harmonic degree 70), the crustal contribution starts to dominate over the upper mantle and at about 150 km (degree 130) the upper mantle contribution is nearly negligible. At the spatial resolution \(<150\,\hbox {km},\) the spectra behavior is driven by the crust, the mantle lid and the asthenosphere. The LITHO1.0 model was furthermore referenced by adding deeper Earth layers from ak135, and the gravity signal of the merged model was then compared with the observed satellite-only model GOCO05s. The largest differences are found over the tectonothermal cold and old (such as cratonic), and over warm and young areas (such as oceanic ridges). The misfit encountered comes from the mantle lid where a velocity–density relation helped to reduce the RMS error by 40%. Global residuals are also provided in terms of the gravitational gradients as they provide better spatial localization than gravity, and there is strong observational support from ESA’s satellite gradiometry mission GOCE down to the spatial resolution of 80–90 km.  相似文献   

An integrated approach for assessing the relative significance of human pressures and environmental forcing on the status of Large Marine Ecosystems     

Andrew J. Kenny  Hein Rune Skjoldal  Georg H. Engelhard  Peter J. Kershaw  James B. Reid 《Progress in Oceanography》2009,81(1-4):132

An ecosystem approach to the management of the marine environment has received considerable attention over recent years. However, there are few examples which demonstrate its practical implementation. Much of this relates to the history of existing marine monitoring and assessment programmes which (for many countries) are sectoral, making it difficult to integrate monitoring data and knowledge across programmes at the operational level.To address this, a scientific expert group, under the auspices of the International Council for the Exploration of the Sea (ICES), prepared a plan for how ICES could contribute to the development of an Integrated Ecosystem Assessment (IEA) for the North Sea by undertaking a pilot study utilising marine monitoring data. This paper presents the main findings arising from the expert group and in particular it sets out one possible integrated approach for assessing the relative significance of environmental forcing and fishing pressure on the ecological status of the North Sea, it then compares the findings with assessments made of other Large Marine Ecosystems (LMEs).We define the North Sea ecosystem on the basis of 114 state and pressure variables resolved as annual averages between 1983 and 2003 and at the spatial scale of ICES rectangles. The paper presents results of integrated time-series and spatial analysis which identifies and explains significant spatial and temporal gradients in the data. For example, a significant shift in the status of the North Sea ecosystem (based upon 114 state-pressure variables) is identified to have occurred around 1993. This corresponds to previously documented shifts in the environmental conditions (particularly sea surface temperature) and changes in the distribution of key species of plankton (Calanus sp.), both reported to have occurred in 1989. The difference in specific timing between reported regime shifts for the North Sea may be explained, in part, by time-lag dependencies in the trophic structure of the ecosystem with shifts in higher trophic levels occurring later than 1989.By examining the connection (or relatedness) between ecosystem components (e.g. environment, plankton, fish, fishery and seabirds) for the identified regime states (1983–1993; 1993–2003) we conclude that both the North Sea pelagic and benthic parts of the ecosystem were predominantly top-down (fishery) controlled between 1983 and 1993, whereas between 1993 and 2003 the pelagic stocks shifted to a state responding mainly to bottom-up (environment) influences. However, for the demersal fish stocks between 1993 and 2003 top-down (fishery) pressure dominated even though over this period significant reductions in fishing pressure occurred. The present analysis, therefore, provides further evidence in support of the need for precautionary management measures taken in relation to setting fishery quotas.  相似文献   

Measuring coastal cliff retreat in the Kongsfjorden area, Svalbard, using terrestrial photogrammetry     

Bjørn Wangensteen  Trond Eiken  Rune S. Ødegård  & Johan Ludvig Sollid 《Polar research》2007,26(1):14-21

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CO₂ in the Weddell Gyre and Antarctic Circumpolar Current: austral autumn and early winter     

Mario Hoppema  Michel H. C. Stoll  Hein J. W. de Baar   《Marine Chemistry》2000,72(2-4)

Quasi-continuous fugacity of CO₂ (fCO₂) data were collected in the eastern Weddell Gyre and southern Antarctic Circumpolar Current (ACC) of the Southern Ocean during austral autumn 1996. Full depth Total CO₂ (TCO₂) sections are presented for austral autumn and winter (1992) cruises. Pronounced fCO₂ gradients were observed at the Southern Ocean fronts. In the Weddell Gyre, fCO₂ regimes appeared to coincide with surface and subsurface hydrographic regimes. The southern ACC was supersaturated with respect to CO₂, as was part of the northern Weddell Gyre. The southern Weddell Gyre was markedly undersaturated. The great potential of autumn cooling for generating undersaturation and CO₂ uptake from the atmosphere was demonstrated. In the northeastern Weddell Gyre, upwelling of CO₂- and salt-rich deep water was shown to play a role as the horizontal fCO₂ distribution closely resembled that of the surface salinity. The total uptake of atmospheric CO₂ by the Weddell Gyre in autumn (45 days) was calculated to be 7·10¹² g C. The deep TCO₂ distribution noticeably reflected the different water masses in the region. A new deep TCO₂ maximum was detected in the ACC, which apparently characterizes the boundary between the equatorward flowing Antarctic Bottom Water (AABW) and the Circumpolar Deep Water (CDW). East of the Weddell Gyre, the AABW stratum is much thicker (>2000 m) than more to the west, on the prime meridian (<300 m).  相似文献   

Temporal and life history related trends of perfluorochemicals in harbor porpoises from the Danish North Sea     

Galatius A  Dietz R  Rigét FF  Sonne C  Kinze CC  Lockyer C  Bossi R 《Marine pollution bulletin》2011,62(7):1476-1483

Eighty-five stranded or bycaught harbor porpoises collected from the Danish North Sea between 1980 and 2005 were analyzed for perfluorochemicals in the liver. PFOS was the predominant compound, making up on average 88.9% of the ∑PFC, followed by PFOSA (7.8%). PFUnA (1.9%) and PFDA (1.2%) were detected in most samples. PFHxS, PFNA and PFOA were only found in a minority of the samples. We found substantial differences in PFC concentrations among life history stages, the highest concentrations were found in neonates, suckling juveniles and lactating females. Such differences should be considered when PFC levels in wildlife are evaluated. The high concentrations found in young porpoises are of concern as PFCs have known toxic effects on the development of the central nervous system and reproductive organs. Despite efforts to reduce PFC emissions, a decreasing temporal trend of concentrations was not detected for any compound. PFCA concentrations were found to be increasing.  相似文献   

Arctic climate change in 21st century CMIP5 simulations with EC-Earth   总被引：4，自引：2，他引：2  

Torben Koenigk  Laurent Brodeau  Rune Grand Graversen  Johannes Karlsson  Gunilla Svensson  Michael Tjernström  Ulrika Willén  Klaus Wyser 《Climate Dynamics》2013,40(11-12):2719-2743

The Arctic climate change is analyzed in an ensemble of future projection simulations performed with the global coupled climate model EC-Earth2.3. EC-Earth simulates the twentieth century Arctic climate relatively well but the Arctic is about 2 K too cold and the sea ice thickness and extent are overestimated. In the twenty-first century, the results show a continuation and strengthening of the Arctic trends observed over the recent decades, which leads to a dramatically changed Arctic climate, especially in the high emission scenario RCP8.5. The annually averaged Arctic mean near-surface temperature increases by 12 K in RCP8.5, with largest warming in the Barents Sea region. The warming is most pronounced in winter and autumn and in the lower atmosphere. The Arctic winter temperature inversion is reduced in all scenarios and disappears in RCP8.5. The Arctic becomes ice free in September in all RCP8.5 simulations after a rapid reduction event without recovery around year 2060. Taking into account the overestimation of ice in the twentieth century, our model results indicate a likely ice-free Arctic in September around 2040. Sea ice reductions are most pronounced in the Barents Sea in all RCPs, which lead to the most dramatic changes in this region. Here, surface heat fluxes are strongly enhanced and the cloudiness is substantially decreased. The meridional heat flux into the Arctic is reduced in the atmosphere but increases in the ocean. This oceanic increase is dominated by an enhanced heat flux into the Barents Sea, which strongly contributes to the large sea ice reduction and surface-air warming in this region. Increased precipitation and river runoff lead to more freshwater input into the Arctic Ocean. However, most of the additional freshwater is stored in the Arctic Ocean while the total Arctic freshwater export only slightly increases.  相似文献   

Discrete element simulation of geogrid-stabilised soil     

Michael Stahl  Heinz Konietzky  Lothar te Kamp  Hein Jas 《Acta Geotechnica》2014,9(6):1073-1084

A particle-based numerical simulation procedure is presented for the generation and calibration of geogrid-stabilised soil on the basis of experimental data. The paper describes how to simulate a biaxial geogrid depending on a specific particle and parallel bond model. Numerical and experimental pull-out tests have been performed to reproduce the pull-out force–strain behaviour of a biaxial geogrid specimen embedded in granular material under special consideration of the grain-size distribution, initial relative density, normal stress state as well as sample installation. Model analysis of soil mobilisation and geogrid deformation is presented to understand the significance of the interlocking effect as key mechanism for soil stabilisation. The procedure can be used for further investigations of the influence and effects of soil stabilisation depending on the significant properties of the interacting components (soils and geogrids).  相似文献