Al-related centers in relation to γ-irradiation     

Pedro L. Guzzo  Fumiko Iwasaki  Hideo Iwasaki 《Physics and Chemistry of Minerals》1997,24(4):254-263

 The charge compensation problem for Si−Al substitution in Brazilian natural quartz is investigated in relation to γ-irradiation darkening response and impurity contents evaluated by atomic absorption spectrometry and infrared absorption spectroscopy. Al⁺³ in as-grown natural quartz is compensated by Li⁺ and H⁺ to form Al−Li and Al−OH centers. The content ratios (Al−Li)/(Al−OH) and Li/(broad OH band) depend on the environmental conditions of crystal growth and influence the formation of Al-hole centers due to γ-irradiation. Al−OH centers are the dominant Al-related centers in quartz from hydrothermal origin while Al−Li centers are dominant for that of pegmatitic origin. The formation of Al-hole centers is little in quartz with a high content of broad OH band which is from low temperature hydrothermal origin. Received May 23, 1995 / Revised, accepted May 8, 1996  相似文献   

Development of composite planar fabric in mylonites along the Median Tectonic Line, southwest Japan     

Hideo  Takagi 《Island Arc》1992,1(1):92-102

Abstract Mylonites along the Median Tectonic Line, southwest Japan commonly contain shear bands comprising S(-C)-Ss fabrics. This paper stresses the lithologic control on the orientation, dimension and development of shear bands by comparing the microstructure of the shear bands in different rock types (P mylonites, F mylonites, micaceous phyllonite and quartzose phyllonite). There is no significant change of the α angles (average 21–24°) between Ss and S toward the centre of the shear zone (viz. increasing the intensity of mylonitization) and it is different from the S-C relationship in a narrow sense.
The generation of the composite planar fabric can be classified into four different strain partitioning models: S only type without any slip surface (model A); S-C type (model B); S-Ss type with Ss-slip precedence (model C), and S-Ss type with S-slip precedence (model D). Model C is proposed in this paper and is similar to the model for the generation of Riedel shears in brittle shear zones. An unstable slip between porphyroclasts and the matrix during ductile flow can easily initiate shear bands. Formation of a composite planar fabric is initiated according to model A, followed by model C in conditions of increasing strain, and then model D when the angle between S and the shear zone boundary becomes small enough (α/2 = 10°) to produce S-slip. Thus the generation of the shear bands probably begins in the early stages of shear deformation and continues until the latest stages.  相似文献   

Sound velocity and elastic properties of Fe–Ni and Fe–Ni–C liquids at high pressure     

Soma Kuwabara  Hidenori Terasaki  Keisuke Nishida  Yuta Shimoyama  Yusaku Takubo  Yuji Higo  Yuki Shibazaki  Satoru Urakawa  Kentaro Uesugi  Akihisa Takeuchi  Tadashi Kondo 《Physics and Chemistry of Minerals》2016,43(3):229-236

The sound velocity (V _P) of liquid Fe–10 wt% Ni and Fe–10 wt% Ni–4 wt% C up to 6.6 GPa was studied using the ultrasonic pulse-echo method combined with synchrotron X-ray techniques. The obtained V _P of liquid Fe–Ni is insensitive to temperature, whereas that of liquid Fe–Ni–C tends to decrease with increasing temperature. The V _P values of both liquid Fe–Ni and Fe–Ni–C increase with pressure. Alloying with 10 wt% of Ni slightly reduces the V _P of liquid Fe, whereas alloying with C is likely to increase the V _P. However, a difference in V _P between liquid Fe–Ni and Fe–Ni–C becomes to be smaller at higher temperature. By fitting the measured V _P data with the Murnaghan equation of state, the adiabatic bulk modulus (K _S0) and its pressure derivative (K _S ^′ ) were obtained to be K _S0 = 103 GPa and K _S ^′  = 5.7 for liquid Fe–Ni and K _S0 = 110 GPa and K _S ^′  = 7.6 for liquid Fe–Ni–C. The calculated density of liquid Fe–Ni–C using the obtained elastic parameters was consistent with the density values measured directly using the X-ray computed tomography technique. In the relation between the density (ρ) and sound velocity (V _P) at 5 GPa (the lunar core condition), it was found that the effect of alloying Fe with Ni was that ρ increased mildly and V _P decreased, whereas the effect of C dissolution was to decrease ρ but increase V _P. In contrast, alloying with S significantly reduces both ρ and V _P. Therefore, the effects of light elements (C and S) and Ni on the ρ and V _P of liquid Fe are quite different under the lunar core conditions, providing a clue to constrain the light element in the lunar core by comparing with lunar seismic data.  相似文献   

Distribution of Scyllarid Phyllosoma Larvae (Crustacea: Decapoda: Scyllaridae) in the Kuroshio Subgyre     

Nariaki?Inoue  Hideo?SekiguchiEmail author 《Journal of Oceanography》2005,61(3):389-398

Using ichthyoplankton samples collected in the Kuroshio Subgyre during early summer cruises, we examined spatial distributions of scyllarid phyllosoma larvae in the Subgyre, particularly of the genus Scyllarus. The present study has two objectives: (1) to reveal species composition of Scyllarus phyllosoma larvae in the Kuroshio Subgyre, and (2) to examine larval recruitment of Scyllarus species as contrasted with that of Panulirus, particularly P. japonicus, the larval recruitment of which has been examined in detail. A total of 218 phyllosoma larvae collected in the present study belonged to two families (Palinuridae and Scyllaridae) representing 5 genera and 11 species. Phyllosoma larvae of two Scyllarus species (S. cultrifer and Scyllarus sp. c) were abundant among the collected larvae, and were found mainly in the following three regions located within the Kuroshio-Counter Current region south of Kuroshio Current: the water east of Okinawa Is., the water far east of Okinawa Is. (or far south of Shikoku Is.), and the water around Hachijojima Is. Larvae of each of the above two Scyllarus species collected in the three regions may belong to different populations: larvae collected in the water around Hachijojima Is. may come from their benthic populations along the Pacific coast of Honshu and Shikoku Is., central Japan, while larvae collected in the other two regions may come from their benthic populations of the Ryukyu Archipelago and Taiwan. Judging from their shorter larval period and current systems within the Kuroshio Subgyre, these Scyllarus larvae may be destined for death. An erratum to this article is available at .  相似文献   

Inertial Instability of Arbitrarily Meandering Currents Governed by the Eccentrically Cyclogeostrophic Equation     

Hideo Kawai 《Journal of Oceanography》2003,59(2):163-172

Using natural coordinates, we have derived a criterion for the inertial instability of arbitrarily meandering currents. Such currents, governed by the eccentrically cyclogeostrophic equation, are adopted as the basic current field for the parcel method. We assume that any virtual displacement which is given to a water parcel moving in the basic field has no influence on this field. From the conservation of mechanical energy for a virtual displacement we derive an inertial instability frequency ω _m = [(f + 2u/r)Z]^0.5 for the eccentrically cyclogeostrophic current, where f is the Coriolis parameter, u the velocity (always positive), r the radius of curvature of a streamline (negative for an anticyclonic meander), and Z the vertical component of absolute vorticity. If ω _m ² is negative, the eccentrically cyclogeostrophic current becomes unstable. Although the conventional, centrifugal instability criterion, derived from the conservation of angular momentum in a circularly symmetric current field, has a certain meaning for a monopolar vortex, it contains a radial shear vorticity that is difficult to use in arbitrarily meandering currents. The new criterion ω _m ² contains a lateral shear vorticity that is applicable to arbitrarily meandering currents. Examining instabilities of concentric rings with radii of 50–100 km, we consider reasons why the anticyclonic supersolid rotation has been very much less frequently observed than the cyclonic supersolid rotation, despite a prediction of some common stability and a rapid change in radial velocity gradient for the former. Classifying eccentric streamlines into the large and small curvature-gradient types, we point out that the large-gradient curvature in anticyclonic rings is apt to be unstable. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

A cross-correlation analysis of tidal current,water temperature and salinity records     

Hideo Nakajima  Norio Hayakawa 《Journal of Oceanography》1982,38(2):52-56

Fifteen day records of current velocity, water temperature and salinity were obtained at a coastal station in the Seto Inland Sea. It was observed that water movement was characterized by an exchange of two distinctive water masses east and west of the station. Cross-correlation analysis shows that, at the semi-diurnal period, the motion of these characteristic waters causes temperature and salinity variations. At frequencies higher than 2 cycles per day where power spectra of current velocity have a slope of ?5/3, coherence between current velocity and both water temperature and salinity decreases rapidly.  相似文献   

Algal Growth Potential and the limiting nutrient in Mikawa Bay     

Masao Kondo  Tsutomu Sakai  Hajime Yamamoto  Yukio Arakawa 《Journal of Oceanography》1984,40(5):391-396

The Algal Growth Potential (AGP) of water samples collected off Gamagori in Mikawa Bay was measured from May 1978 through February 1979, and the limiting nutrient was determined using regression analysis and enrichment bioassays. The surface and bottom water samples had AGP that produced increments of chemical oxygen demand (COD) of 2.1 mg l^–1 and 3.1 mg l^–1, respectively, on average. These values ofCOD correspond to 46% and 97% of the average COD values of the raw water samples at the surface and bottom, respectively. Seasonal changes of AGP showed a close correlation with those of dissolved inorganic nitrogen (DIN) concentration. Enrichment bioassays showed that DIN was the most deficient nutrient. The DIN:phosphate-phosphorus (PO₄ ^3–-P) ratios and DIN: dissolved phosphorus (DP) ratios in the water samples were below the cellular N:P ratios of the natural algal populations. These results suggest that AGP was mainly limited by DIN concentration.  相似文献   

Simultaneous Measurement of Hydrogen Peroxide and Fe Species (Fe(II) and Fe<Subscript>(tot)</Subscript>) in Okinawa Island Seawater: Impacts of Red Soil Pollution     

Takemitsu?ArakakiEmail author  Hiroyuki?Fujimura  Asha?Mansour?Hamdun  Kouichirou?Okada  Hiroaki?Kondo  Tamotsu?Oomori  Akira?Tanahara  Hatsuo?Taira 《Journal of Oceanography》2005,61(3):561-568

The northern part of Okinawa Island suffers from red soil pollution—runoff of red soil into coastal seawater—which damages coastal ecosystems and scenery. To elucidate the impacts of red soil pollution on the oxidizing power of seawater, hydrogen peroxide (HOOH) and iron species including Fe(II) and total iron (Fe_(tot), defined as the sum of Fe(II) and Fe(III)) were measured simultaneously in seawater from Taira Bay (red-soil-polluted sea) and Sesoko Island (unpolluted sea), off the northern part of Okinawa Island, Japan. We performed simultaneous measurements of HOOH and Fe(II) because the reaction between HOOH and Fe(II) forms hydroxyl radical (•OH), the most potent environmental oxidant. Gas-phase HOOH concentrations were also measured to better understand the sources of HOOH in seawater. Both HOOH and Fe(II) in seawater showed a clear diurnal variation, i.e. higher in the daytime and lower at night, while Fe_(tot) concentrations were relatively constant throughout the sampling period. Fe(II) and Fe_(tot) concentrations were approximately 58% and 19% higher in red-soil-polluted seawater than in unpolluted seawater. Gas-phase HOOH and seawater HOOH concentrations were comparable at both sampling sites, ranging from 1.4 to 5.4 ppbv in air and 30 to 160 nM in seawater. Since Fe(II) concentrations were higher in red-soil-polluted seawater while concentrations of HOOH were similar, •OH would form faster in red-soil-polluted seawater than in unpolluted seawater. Since the major scavenger of •OH, Br⁻, is expected to have similar concentrations at both sites, red-soil-polluted seawater is expected to have higher steady-state •OH concentrations.  相似文献   

Global distribution and atmospheric transport of chlorinated hydrocarbons: HCH (BHC) isomers and DDT compounds in the Western Pacific,Eastern Indian and Antarctic Oceans     

Shinsuke Tanabe  Ryo Tatsukawa  Masahide Kawano  Hideo Hidaka 《Journal of Oceanography》1982,38(3):137-148

Concentrations of chlorinated hydrocarbons such as HCH isomers and DDT compounds were determined in air and surface water samples taken from the Western Pacific, Eastern Indian and Antarctic Oceans. The most interesting finding was their presence in measurable concentrations in the Antarctic Ocean. Chlorinated hydrocarbon pesticides are widely distributed in the open ocean environment over both the northern and southern hemispheres, and some characteristic distribution patterns of pesticide species in different oceanic regions were observed both in air and water samples. HCH residues found in the northern hemisphere were much higher in concentration than those in the southern hemisphere. On the other hand, higher concentrations of DDT residues were found in the tropical regions, but their levels were not so different between both the northern and southern hemispheres. HCH isomers found in the northern hemisphere had the following order of concentrations:-HCH> HCH>-HCH, while in the southern hemisphere-HCH was apparently dominant. DDT compound compositions were rather uniform in all the oceans surveyed, and more than 50% wasp,p-DDT. These facts can be explained by the world wide situation regarding pesticide use and the physicochemical properties of the pesticides such as their vapor pressures and water solubilities. In addition, the meridional circulation of the atmosphere, particularly the mass flows of the Hadley and Ferrel cells in the troposphere, also contributes to the atmospheric transport and global distribution of these pesticides.  相似文献   

On the Concentrations of the Dissolved Chemical Elements in the Estuary Water of the Chikugogawa River     

Iwao Hosokawa  Fumio Ohshima  Norihiko Kondo 《Journal of Oceanography》1970,26(1):1-5

When river water mixes with sea water in estuary area, the concentrations of the dissolved element in river water may be changed by either a simple physical mixing process or some complex chemical processes. It has been clarified in the Chikugogawa River estuary area that the change in concentrations of SO ₄ ²⁻ , BO ₃ ³⁻ , Mg²⁺, Ca²⁺ and F⁻ is only due to the mixing process but the change in concentrations of SiO ₃ ²⁻ and Al³⁺ is due to the chemical process in addition to the mixing process.   相似文献