Ba isotopic signature for early differentiation between Cs and Ba in natural fission reactors     

Hiroshi Hidaka  François Gauthier-Lafaye 《Geochimica et cosmochimica acta》2008,72(16):4123-4135

Ba isotopic studies of the Oklo and Bangombé natural fission reactors in east Gabon provide information on the geochemical behavior of radioactive Cs (¹³⁵Cs and ¹³⁷Cs) in a geological medium. Large isotopic deviations derived from fissiogenic Ba were found in chemical leachates of the reactor uraninites. The fissiogenic Ba isotopic patterns calculated by subtracting the non-fissiogenic component are classified into three types that show different magnifications of chemical fractionation between Cs and Ba. In addition, the isotopic signatures of fissiogenic ¹³⁵Ba, ¹³⁷Ba and ¹³⁸Ba suggest an early differentiation between Cs and Ba of less than 20 years after the production of fissiogenic Cs and Ba. On the other hand, only small excesses of ¹³⁵Ba (ε < +1.8) and/or ¹³⁷Ba (ε < +1.3) were identified in some clay samples, which might have resulted from selective adsorption of ¹³⁵Cs and ¹³⁷Cs that migrated from the reactors by differentiation.  相似文献   

Hydrological and geochemical constraints on the mechanism of formation of arsenic contaminated groundwater in Sonargaon,Bangladesh     

Takaaki Itai  Harue Masuda  Ashraf A. Seddique  Muneki Mitamura  Teruyuki Maruoka  Xiaodong Li  Minoru Kusakabe  Biswas K. Dipak  Abida Farooqi  Toshiro Yamanaka  Shinji Nakaya  Jun-ichi Matsuda  Kazi Matin Ahmed 《Applied Geochemistry》2008

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An Actively Controlled Wind Tunnel And Its Application To The Reproduction Of The Atmospheric Boundary Layer     

Cao Shuyang  Akira Nishi  Kimitaka Hirano  Shigehira Ozono  Hiromori Miyagi  Hiromori Kikugawa  Yuji Matsuda  Yasuo Wakasugi 《Boundary-Layer Meteorology》2001,101(1):61-76

An actively controlled wind tunnel equipped with multiple fansand airfoils has been developed, mainly for the purpose of reproducing the atmospheric boundary layer (ABL) for wind engineering applications. Various fluctuating flows can be achieved in this wind tunnel by altering the input data of the fans and airfoils through computer control. In this study, the ABL is physically simulated in this wind tunnel, and particular attention ispaid to the simulation of the profile of Reynolds stress. The method of generating the fluctuating flow and the experimental results of reproducing the ABL are presented. As the results show, the spatial distribution of Reynolds stress is satisfactorily simulated, and the profiles of other statisticalturbulent parameters, such as mean velocity, turbulent intensity, integral scale and power spectrum are successfully reproduced simultaneously.  相似文献   

Crystal-field theory calculations for Fe2+ Ions in bronzite,augite, and olivine     

Takahiro Hiroi  Hiroshi Takeda 《Physics and Chemistry of Minerals》1992,19(4):229-235

Crystal-field theory was applied to Fe²⁺ ions in three types of silicates in an attempt to assign all the major absorption bands with only one parameter to adjust. Coulomb potential energy field were calculated by Fourier method based on all the actual atomic coordinates refined by X-ray diffraction studies. Perturbed d-electron splitting energies of the central Fe²⁺ ion were calculated by introducing Configuration Interaction (CI) method for the lowest energy spectral states. All the major absorption bands observed in powdered bronzite, augite, and olivine, were assigned to the transitions between those calculated energy levels by optimizing only one parameter that expresses expansion or contraction of d-electron cloud. The result of the calculations gives almost the same assignments as the other previous works for bronzites, different assignments for augites, and a possibility of the existence of the fourth band hidden in the composite 1-μm band of olivines.  相似文献   

Revisit of event-based rainfall characteristics at Shapotou area in northern China     

XinPing Wang  YaFeng Zhang  Rui Hu  YanXia Pan  HaoJie Xu  Wei Shi  YanXia Jin  Hiroshi Yasuda 《寒旱区科学》2016,8(6):477-484

Distribution of rainfall event sizes and interval lengths between events are important characteristics of arid and semi-arid climates. Understanding their importance will contribute to our ability to understand ecosystem dynamics in these regions. Rainfall event timing and magnitude are important drivers of ecosystem processes and are instrumental in creating landscape heterogeneity in arid and semi-arid regions. Rainfall event characteristics were analyzed using an automatic tipping-bucket rain-gauge record across the entire summer monsoon season from 2008 to 2015 at the arid desert area of Shapotou in the Tengger Desert, China. Changing the minimum inter-event time (MIT) from 30 min to 24 h alters the number of rainfall events from 64 to 25 for the event depth larger than 0.1 mm. The mean rainfall intensity declined from 0.95 mm/h to 0.53 mm/h, and the geometric mean event duration rose from 0.55 h to 4.4 h. The number of rainfall events, mean rainfall intensity, and geometric mean event duration differed under different criteria of individual rainfall depths, except that for an individual rainfall depth of 0.5, 1.0, and 5.0 mm. The aforementioned features differed only at the lowest range of the mean rainfall intensity and depth for MIT=3 and 6 h. These findings suggest that identification of event-based rainfall in this specific arid region can be better achieved by setting the MIT at six hours. The wide variation in rainfall event properties indicate the need for paying more attention to the proper selection and reporting of event criteria in studies that adopt event-based data analysis. This is especially true in quantifying effective rainfall for soil water replenishment in terms of rainfall depth and intensity with infrequent rainfall events.  相似文献   

Relationships between textural and photoluminescence spectral features of carbonado (natural polycrystalline diamond) and implications for its origin     

Hidemi Ishibashi  Hiroyuki Kagi  Shoko Odake  Hiroyuki Ohfuji  Hiroshi Kitawaki 《Geochemistry International》2016,54(10):882-889

Field Emission SEM (FESEM) textural observations, crystal size distribution (CSD) analyses, UV-excited luminescence imaging, and photoluminescence (PL) microspectroscopy excited by 488 nm laser were conducted on two texturally contrasting samples of carbonado, a kind of natural polycrystalline diamond from the Central African Republic (CAR). The investigated carbonado samples A and B show extremely different textures: sample A is made up of faceted crystals accompanied by abundant, small rectangular pores, whereas sample B has a granular texture with coarser crystals and scarce, large pores. Diamond crystals smaller than 2–3 µm are enriched in sample A but depleted in sample B. These textural features indicate that sample B diamonds were annealed under thermodynamically stable P–T conditions. The pore characteristics indicate that fluid permeability was higher for sample A than sample B. Photoluminescence (PL) spectra indicate that samples A and B correspond to Group A and B carbonados in the classification of Kagi et al. (1994), respectively, so that sample A reveals emissions from the H3 center without any N–V⁰ derived emission at 575 nm, whereas sample B shows emissions from the 3H center and the N–V⁰ defect. In addition, UV-excited luminescence images and photoluminescence spectra for sample B indicate that the rims of diamond crystals within several microns of a pore show luminescence features similar to those of Group AB carbonados (Kagi et al., 1994), indicating that this Group AB material was formed from Group B by irradiation from pore-filling, radioactive-element-bearing materials at a low temperature. The extent of the low-temperature irradiation is considered to depend on fluid permeability, and the Group A material was strongly irradiated due to its permeable texture whereas the Group B material was not significantly irradiated due to its less permeable granular texture. These results indicate that Group B carbonados have retained their original PL spectral features produced under high pressures and temperatures at mantle depths.  相似文献   

Seasonal variations of dissolved organic matter and nutrients in sediment pore water in the inner part of Tokyo Bay     

Saori Yasui  Jota Kanda  Toshihiro Usui  Hiroshi Ogawa 《Journal of Oceanography》2016,72(6):851-866

At four stations in Tokyo Bay, pore water profiles of dissolved organic carbon (DOC), nitrogen (DON), phosphorus (DOP), and inorganic nutrients were determined at 3-month intervals over 6 years. Concentrations of dissolved organic matter (DOM) and nutrients were significantly higher in pore waters than in the overlying waters. Pore water DOC, DON, and DOP concentrations in the upper most sediment layer (0–1 cm) ranged from 246 to 888 μM, from 14.6 to 75.9 μM, and from 0.02 to 9.83 μM, respectively. Concentrations of DOM and nutrients in pore waters occasionally showed clear seasonal trends and were highest in the summer and lowest in the winter. The seasonal trends in the pore water DOM concentrations were coupled with trends in the overlying water temperature and dissolved oxygen concentration. Benthic effluxes of DON and DOP were low compared with those of inorganic nutrients, accounting for only 1.0 and 1.5 % of the total benthic effluxes of nitrogen and phosphorus, respectively; thus benthic DOM fluxes were quantitatively insignificant to the inorganic nutrient fluxes in Tokyo Bay. The DOM fluxes represented about 7, 3, and 10 % of the riverine discharge of DOC, DON, and DOP to Tokyo Bay, respectively.  相似文献   

Numerical study for specifying the major origin of low salinity water associated with <Emphasis Type="Italic">Chattonella</Emphasis> (Raphidophyceae) blooms in Tachibana Bay,Japan     

Kazuhiro?AokiEmail author  Manabu?Shimizu  Hiroshi?Kuroda  Toshifumi?Yamatogi  Naoya?Ishida  Shigeru?Kitahara  Keiji?Hirano 《Journal of Oceanography》2016,72(5):811-816

In both 2009 and 2010, massive Chattonella blooms occurred in Tachibana Bay. Observation results show that high cell densities of Chattonella were distributed in the central area of Tachibana Bay with low salinity water. Model results indicate that the low salinity water originated from the Ariake Sea and intruded into Tachibana Bay during the northerly or weak winds. It is suggested that low salinity water was mainly discharged from the northern area of the Ariake Sea. Northerly wind enhanced the horizontal advection of the low salinity water intruding into Tachibana Bay originating from the northern area of the Ariake Sea.  相似文献   

Effects of temperature elevation and glucose addition on prokaryotic production and respiration in the mesopelagic layer of the western North Pacific     

Mario Uchimiya  Hiroshi Ogawa  Toshi Nagata 《Journal of Oceanography》2016,72(3):419-426

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Effect of Fetch on a Mechanism for Pollutant Removal from a Two-Dimensional Street Canyon     

Takenobu Michioka  Hiroshi Takimoto  Hiroki Ono  Ayumu Sato 《Boundary-Layer Meteorology》2016,160(1):185-199

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