Possibility of recent changes in vertical distribution and size composition of chlorophyll-a in the western North Pacific region     

Hiroshi Ishida  Yutaka W. Watanabe  Joji Ishizaka  Toshiya Nakano  Naoki Nagai  Yuji Watanabe  Akifumi Shimamoto  Nobuhiro Maeda  Michimasa Magi 《Journal of Oceanography》2009,65(2):179-186

Our analysis of the last three decades of retrospective data of vertical distributions and size composition of chlorophyll-a (Chl-a) over the western North Pacific has revealed significant changes of three indices related to Chl-a during summer season, as follows: (1) decreasing linear trend of the proportion of Chl-a in surface layer to that of the whole water column by 0.4 and 2.3% year⁻¹ in the subtropical area along 137°E (STA₁₃₇) during 1972 to 1997 and in the Kuroshio Extension area along 175°E (KEA₁₇₅) during 1990 to 2001; (2) increasing linear trend of the depth of subsurface Chl-a maximum (DCM) by 0.4 and 2.6 m year⁻¹ in STA₁₃₇ and KEA₁₇₅; and (3) decreasing linear trend of larger-size Chl-a (>3 μm) by 0.1 and 2.5% year⁻¹ in STA₁₃₇ and KEA₁₇₅, respectively. Water density (σ _θ ) at 75 m depth had also decreased by 0.006 and 0.05 year⁻¹ in STA₁₃₇ and KEA₁₇₅, respectively. The ratio of biogenic opal to biogenic CaCO₃ in the sinking flux decreased by 0.015 year⁻¹ in the subtropical region from 1997 to 2005. These findings may indicate that the subsurface chlorophyll maximum is deepening and larger phytoplankton such as diatoms has been decreasing during the past decade, associated with the decreasing density of surface water caused by warming in the western North Pacific, especially in the summer.  相似文献   

Nd and Sr isotopic variations in acidic rocks formed under a peculiar tectonic environment in Miocene Southwest Japan     

Yasutaka Terakado  Hiroshi Shimizu  Akimasa Masuda 《Contributions to Mineralogy and Petrology》1988,99(1):1-10

Initial Nd and Sr isotopic ratios were obtained for middle Miocene igneous rocks as well as for related rocks from the Outer Zone of Southwest Japan to investigate the petrogenesis of acidic magmas and their relation to a peculiar tectonic environment bearing on the back-arc spreading of the Japan Sea. On the _Nd- _Sr diagram, data points for the acidic rocks fall in the – _Nd, + _Sr quadrant occupying different positions from those for sedimentary and old crustal rocks, and seem to define several subparallel lines which extend towards the lower-righthand sedimentary field. The S-type acidic rocks occupy an intermediate position between I-type rocks and sedimentary ones, a fact suggesting mixing of an igneous component and a sedimentary one. The linear mixing trend observed on the _Nd- _Sr diagram can be attained in the restricted case that the igneous component has similar Sr/Nd concentration ratios to that of the sedimentary one, which implies an intermediate to acidic composition for the igneous component. Inconsistency between the elemental and isotopic variations observed may be reconciled by considering that mixing, probably in the relatively deep part of the crust, might have occured prior to chemical differentiation processes. The episodic igneous activity and the high heat energy required to melt such materials involving sedimentary rocks may be explained by a model in which a hot mantle region probably corresponding to the rising part of the mantle convection supplied the heating energy to the Outer Zone of Southwest Japan when passing beneath Southwest Japan in the course of movement of the hot rising part from the Shikoku basin areas to the Japan Sea area.  相似文献   

Pressure and temperature dependence of cation distribution in Mg-Mn olivine     

Tadashi Akamatsu  Kiyoshi Fujino  Mineo Kumazawa  Akio Fujimura  Manabu Kato  Hiroshi Sawamoto  Takamitsu Yamanaka 《Physics and Chemistry of Minerals》1988,16(2):105-113

Synthetic (Mg_0.51, Mn_0.49)₂SiO₄ olivine samples are heat-treated at three different pressures; 0, 8 and 12 GPa, all at the same temperature (～500° C). X-ray structure analyses on these single crystals are made in order to see the pressure effect on cation distribution. The intersite distribution coefficient of Mg and Mn in M1 and M2 sites, K _D = (Mn/Mg) _M1/(Mn/Mg) _M2, of these samples are 0.192 (0 GPa), 0.246 (8 GPa) and 0.281 (12 GPa), indicating cationic disordering with pressure. The small differences of cell dimensions between these samples are determined by powder X-ray diffraction. Cell dimensions b and c decrease, whereas a increases with pressure of equilibration. Cell volume decreases with pressure as a result of a large contraction of the b cell dimension. The effect of pressure on the free energy of the cation exchange reaction is evaluated by the observed relation between the cell volume and the site occupancy numbers. The magnitude of the pressure effect on cation distribution is only a fifth of that predicted from the observed change in volume combined with thermodynamic theory. This phenomenon is attributed to nonideality in this solid solution, and nonideal parameters are required to describe cation distribution determined in the present and previous experiments. We use a five-parameter equation to specify the cationic equilibrium on the basic of thermodynamic theory. It includes one energy parameter of ideal mixing, two parameters for nonideal effects, one volume parameter, and one thermal parameter originated from the lattice vibrational energy. The present data combined with some of the existing data are used to determine the five parameters, and the cation distribution in Mg-Mn olivine is described as a function of temperature, pressure, and composition. The basic framework of describing the cationic behavior in olivine-type mineral is worked out, although the result is preliminary: each of the determined parameters is not accurate enough to enable us to make a reliable prediction.  相似文献   

Nuclide analyses of rare earth elements of the Oklo uranium ore samples: a new method to estimate the neutron fluence     

Hiroshi Hidaka  Akimasa Masuda 《Earth and Planetary Science Letters》1988,88(3-4)

Isotopic ratios and abundances of all REE in two Oklo ore samples have been measured. We have succeeded in developing a new method to estimate the neutron fluence, the conversion factor of uranium and the average neutron energy (or temperature) based on Gd and U isotopic ratios. This new calculation is found to be useful in evaluating those parameters for the natural nuclear reactors at Oklo. Comparison is made between the neutron fluence values evaluated by our new method employing Gd isotopes and a previous one [11] employing Sm and Nd isotopes. The relative agreement becomes better with the increase of fluence. A relationship between the abundances of fissiongenic nuclides of La, Ce, Nd, Sm, and Gd and their mass numbers is also presented.  相似文献   

Mineral composition variation in Alpine Schist, Southern Alps, New Zealand: Implications for recrystallization and exhumation   总被引：1，自引：0，他引：1  

RodneyH.  Grapes Teruo  Watanabe 《Island Arc》1994,3(3):163-181

Abstract Compositional variation of silicates (plagioclase, K-feldspar, epidote, titanite, garnet, white mica, biotite, chlorite), ilmenite, carbonates (calcite, ankerite) and apatite, in quartzofeldspathic lithologies of the Alpine Schist, New Zealand, is discussed in terms of increasing metamorphic grade and possible isograd-producing reactions. The mineral data, in conjunction with geological considerations, are used to determine polychronous P-T arrays of an early high P/T event (c. 16°C/kb; 5°C/km) overprinted by a lower P/T event (c. 50°C/kb; 15°C/km) that provides an estimation of Mesozoic and Cenozoic exhumation of schist of 11 to 13 km and 19 to 22 km respectively. The effects of possible shear heating and recrystallization to form K-feldspar zone schist near the Alpine Fault is consistent with movement along a mid to lower crustal detachment surface during Cenozoic shortening, and near isothermal exhumation of the schists to form the Southern Alps.  相似文献   

Classification and distribution of Oligocene Aetiocetidae (Mammalia; Cetacea; Mysticeti) from western North America and Japan     

Lawrence G.  Barnes  Masaichi  Kimura Hitoshi  Furusawa Hiroshi  Sawamura 《Island Arc》1994,3(4):392-431

Abstract Fossil whales in the very rare, primitive, extinct cetacean family Aetiocetidae are small, relict, toothed mysticetes that persisted into Late Oligocene time after more highly derived baleen-bearing mysticetes had already evolved. No known aetiocetid could be ancestral to baleen-bearing mysticetes, but aetiocetid morphology is in many ways intermediate between archaeocetes and baleen-bearing mysticetes, demonstrating the probable transitional steps passed through in the evolution of baleen-bearing mysticetes. Their discovery indicates that mysticetes evolved from Archaeocetes, and supports theories of the monophyly of Cetacea. Late Oligocene aetiocetids have been found on both sides of the North Pacific Ocean: on Vancouver Island, British Columbia, Canada; in Oregon and Washington, USA; in Baja California Sur, México; and the islands of Kyushu and Hokkaido, Japan. The most primitive North American aetiocetid, Chonecetus sookensis Russell, 1968, is from the early Late Oligocene Hesquiat Formation on Vancouver Island, British Columbia, Canada. A more derived, Late Oligocene species, Chonecetus goedertorum Barnes and Furusawa, new species, from the Late Oligocene Pysht Formation, Olympic Peninsula, Washington, has the primitive placental mammalian tooth count of 11/11. The type genus of the family, Aetiocetus Emlong, 1966, has as its type species, A. cotylalveus Emlong, 1966, known only from the Late Oligocene Yaquina Formation on the coast of Oregon. It has 11 upper teeth on each side of the rostrum. A more derived species, Aetiocetus weltoni Barnes and Kimura, new species, from a higher stratigraphic level in the Yaquina Formation, has a more posteriorly positioned cranial vertex and a tooth count of 11/12. We describe four new species of aetiocetids in three genera from the Late Oligocene Morawan Formation near Ashoro, Hokkaido, Japan. The most primitive, Ashorocetus eguchii Barnes and Kimura, new genus and species, has a primitive stage of cranial telescoping, and is closely related to Chonecetus Russell, 1968. Another, Morawanocetus yabukii Kimura and Barnes, new genus and species, in some ways intermediate between Chonecetus and Aetiocetus, has a suite of unique derived characters, including a much foreshortened brain case. The third, Aetiocetus tomitai Kimura and Barnes, new species, is the most primitive species of Aetiocetus yet discovered. The fourth, Aetiocetus polydentatus Sawamura, new species, the most derived species of Aetiocetus known, has a highly telescoped cranium, homodonty, polydonty and a dental count of 13–14/14–15. The fossil record now indicates considerable diversity in the family, with several different contemporaneous lineages in three new subfamilies: Chonecetinae, Morawanocetinae and Aetiocetinae. Aetiocetids are not known outside the North Pacific. Many Recent mysticetes are essentially cosmopolitan, and aetiocetids might have also been relatively widely dispersed. We suspect that with time their remains will be found around other ocean basins also. If so, then they may be potentially useful in trans-oceanic geological correlations.  相似文献   

Numerical study of the oxidation process of dimethylsulfide in the marine atmosphere   总被引：1，自引：0，他引：1  

Seizi Koga  Hiroshi Tanaka 《Journal of Atmospheric Chemistry》1993,17(3):201-228

A box model, involving simple heterogeneous reaction processes associated with the production of non-sea-salt sulfate (nss-SO ₄ ^2– ) particles, is used to investigate the oxidation processes of dimethylsulfide (DMS or CH₃SCH₃) in the marine atmosphere. The model is applied to chemical reactions in the atmospheric surface mixing layer, at intervals of 15 degrees latitude between 60° N and 60° S. Given that the addition reaction of the hydroxyl radical (OH) to the sulfur atom in the DMS molecule is faster at lower temperature than at higher temperature and that it is the predominant pathway for the production of methanesulfonic acid (MSA or CH₃SO₃H), the results can well explain both the increasing tendency of the molar ratio of MSA to nss-SO ₄ ^2– toward higher latitudes and the uniform distribution with latitude of sulfur dioxide (SO₂). The predicted production rate of MSA increases with increasing latitude due to the elevated rate constant of the addition reaction at lower temperature. Since latitudinal distributions of OH concentration and DMS reaction rate with OH are opposite, a uniform production rate of SO₂ is realized over the globe. The primary sink of DMS in unpolluted air is caused by the reaction with OH. Reaction of DMS with the nitrate radical (NO₃) also reduces DMS concentration but it is less important compared with that of OH. Concentrations of SO₂, MSA, and nss-SO ₄ ^2– are almost independent of NO _x concentration and radiation field. If dimethylsulfoxide (DMSO or CH₃S(O)CH₃) is produced by the addition reaction and further converted to sulfuric acid (H₂SO₄) in an aqueous solution of cloud droplets, the oxidation process of DMSO might be important for the production of aerosol particles containing nss-SO ₄ ^2– at high latitudes.  相似文献   

Seasonal variations of spectra of wind speed and air temperature in the mesoscale frequency range     

Hiroshi Ishida 《Boundary-Layer Meteorology》1990,52(4):335-348

Seasonal variations of the spectra of wind speed and air temperature in the mesoscale frequency range from 1.3 × 10^-4 to 1.5 × 10^-3 Hz (10 min to 2 h periods) have been studied through observations over land for one year. Spectrographs [time series of isopleths of spectral densities, f · S(f) vs f] of wind speed and air temperature contain occasional peaks that are attributed to short-lived mesoscale atmospheric activity with narrow frequency bands. Significant spectral peaks of wind speed were found in 19% of the total observations in winter, and in 15–16% in the other seasons; for air temperature, they occured in 12% of observations in autumn, and in 16–19% in the other seasons. The peaks most often occurred in the period range from 30 min to 1 h; most had durations less than 24 h. Mesoscale fluctuations of wind speed and air temperature were highly correlated, and in most cases, phase differences were 90–180 ° with air temperature leading wind speed. Significant spectral peaks of wind speed often occurred during northerly seasonal cold winds in winter, and accompanied tropical and/or mid-latitude cyclones in the other seasons. When the peaks occurred, wind speed was usually relatively high and the atmospheric surface layer was unstable.  相似文献   

Symmetrical fft technique and its applications to earthquake engineering     

Hiroshi Katukura  Susumu Ohno  Masanori Izumi 《地震工程与结构动力学》1989,18(5):717-725

The objective of this paper is to propose an FFT technique symmetrical for time and frequency, in which the symmetrization is done by introducing generating functions. By the symmetrical treatment, it becomes possible to derive several complementary relations in the time and frequency domains. Based on the idea of the symmetrical FFT technique, the phase problem of seismic waves is discussed not only in the frequency domain but also in the time domain. Furthermore, the deconvolution technique to evaluate the minimum-phase-shift and all-pass functions of seismic waves, which is not discussed sufficiently in earthquake engineering, is developed in the two domains. Numerical examples to present these basic ideas are also illustrated in the symmetrical framework.  相似文献   

On the chondrite—achondrite transition: mineralogy and chemistry of Yamato 74160 (LL7)     

Hiroshi Takeda  Ted J. Huston  Michael E. Lipschutz 《Earth and Planetary Science Letters》1984,71(2):329-339

We report on the petrology, mineralogic properties and contents of major elements and trace elements Ag, Au, Bi, Cd, Co, Cs, Ga, In, Rb, Se, Te, Tl, U and Zn (determined by radiochemical neutron activation analysis) in Yamato 74160, interpreted as an LL7 chondrite. All properties are consistent with this meteorite having been recrystallized and partially melted locally once at temperatures well above 1090°C under conditions such that some minerals (e.g. plagioclase, euhedral pyroxene, tetrataenite) grew from melt pockets and siderophilic and chalcophilic elements were lost by extraction into eutectic melt that drained away. Inhomogeneous plagioclase compositions and mobile element loss suggest shock as the most likely heat source. Yamato 74160, while inferentially chondritic, is a larval achondrite: even higher temperatures and longer times would have been required to cause the separations necessary to transform it to an identifiable achondrite type.  相似文献