High-temperature thermal expansion and elasticity of calcium-rich garnets     

Donald G. Isaak  Orson L. Anderson  Hitoshi Oda 《Physics and Chemistry of Minerals》1992,19(2):106-120

We present new high temperature elasticity data on two grossular garnet specimens. One specimen is single-crystal, of nearly endmember grossular, the other is polycrystalline with about 22% molar andradite. Our data extend the high temperature regime for which any garnet elasticity data are available from 1000 to 1350 K and the compositional range of temperature data to near endmember grossular. We also present new data on the thermal expansivity of calcium-rich garnet. We find virtually no discernable differences in the temperatureT derivatives at ambient conditions of the isotropic bulkK _S and shearμ moduli when comparing our results between these two specimens. These calcium-rich garnets have the lowest values of ¦(?K _S /?T) _P ¦ = (1.47,1.49) x 10^-2GPa/K, and among the highest values of ¦(?μ/?T) _P ¦ = 1.25 x 10^-2GPa/K, when compared with other garnets. Small, but measurable, nonlinear temperature dependences of most of the elastic moduli are observed. Several dimensionless parameters are computed with the new data and used to illustrate the effects of different assumptions on elastic equations of state extra-polated to high temperatures. We discuss how dimensionless parameters and other systematic considerations can be useful in estimating the temperature dependence of some properties of garnet phases for which temperature data are not yet available. While we believe it is premature to quantitatively predict the temperature variation ofK _S andμ for majorite garnets, our results have bearing on the amount of diopside required to explain the shear velocity gradients in Earth's transition zone.  相似文献   

Acetylene reducing activity at a tropical seagrass bed in Papua New Guinea     

Hitoshi Iizumi 《Journal of Oceanography》1992,48(4):377-384

Acetylene reduction activity at a tropical seagrass bed in Papua New Guinea was studied. Blades of every species of seagrass studied (Enhalus acoroides, Thalassia hemprichii, Halodule uninervis, Syringodium isoetifolium) at the bed showed active acetylene reduction in the rage of 0.025–0.050 mol cm^–2d^–1. It is suggested that epiphytic blue-green algae would be responsible for active acetylene reduction. Acetylene reducing activity was observed also at rhizosphere of seagrasses, microbial communities on the detritus and periphyton on snail shells. It is estimated that total nitrogen fixed at the seagrass bed will be equivalent to 6.7% of that required for the growth of seagrasses.  相似文献   

Spatial and temporal variations in free polyamine distributions in Uranouchi Inlet, Japan   总被引：1，自引：0，他引：1  

Naoyoshi Nishibori  Yukihiko Matuyama  Takushi Uchida  Takamitu Moriyama  Yoshihiko Ogita  Masumi Oda  Hitoshi Hirota 《Marine Chemistry》2003,82(3-4):307-314

Polyamines are an essential component of living organisms that influence normal cell growth and development. Despite the possible importance of polyamines for marine microbial ecology, concentrations of polyamines in seawater are not well known.Using HPLC analysis with a cation exchange column and OPA reagent, we determined polyamine concentrations in seawater without carrying out desalting, concentration or derivatization steps prior to chromatography.In seawater collected from Uranouchi Inlet, putrescine and spermidine were the predominant polyamines, ranging from undetectable (N.D.) to 4.4 nM and N.D. to 2.8 nM, respectively. Though other polyamines were detected, the frequency of detection was much lower than that of putrescine and spermidine; concentrations ranged from N.D. to 0.9 nM for cadaverine, and N.D. to 3.2 nM for norspermidine. Norspermine and spermine were detected in only a few samples; their concentrations varied from N.D. to 3.2 nM and N.D. to 0.5 nM, respectively. These concentrations were higher in the summer.  相似文献   

Tributyltin and triphenyltin induce spermatogenesis in ovary of female abalone,Haliotis gigantea   总被引：1，自引：0，他引：1  

Horiguchi T  Kojima M  Kaya M  Matsuo T  Shiraishi H  Morita M  Adachi Y 《Marine environmental research》2002,54(3-5):679-684

Two-month flow-through exposure experiments of tributyltin (TBT) and triphenyltin (TPhT) were conducted with abalone, Haliotis gigantea. Nominal concentrations of 100 ng TBT/l and 100 ng TPhT/l caused significant spermatogenesis in ovaries of exposed females. There were also significantly more contracted primary oocytes observed in females exposed to either TBT or TPhT than controls. The incidence of two types of unknown cells was also significant in females exposed to TPhT. No significant histological changes were observed in testis of exposed males. This ovarian spermatogenesis caused by TBT and/or TPhT resembles gastropod imposex. Remarkably high concentrations of TBT and TPhT were observed in the head (including central nervous system ganglia), compared to muscles concentrations. Accumulation of TBT and TPhT in the head may disturb reproductive hormonal regulators through neuropeptides released from ganglia. This, as well as possible aromatase inhibition, may be one of the inducers for spermatogenesis in the abalone ovaries.  相似文献   

Accelerated continental-scale snowmelt and ecohydrological impacts in the four largest Siberian river basins in response to spring warming     

Kazuyoshi Suzuki  Tetsuya Hiyama  Koji Matsuo  Kazuhito Ichii  Yoshihiro Iijima  Dai Yamazaki 《水文研究》2020,34(19):3867-3881

River runoff from the four largest Siberian river basins (the Ob, Yenisei, Lena, and Kolyma) considerably contributes to freshwater flux into the Arctic Ocean from the Eurasian continent. However, the effects of variation in snow cover fraction on the ecohydrological variations in these basins are not well understood. In this study, we analysed the spatiotemporal variability of the maximum snow cover fraction (SCF_max) in the four Siberian river basins. We compared the SCF_max from 2000 to 2016 with data in terms of monthly temperature and precipitation, night-time surface temperatures, the terrestrial water storage anomaly (TWSA), the normalised difference vegetation index (NDVI), and river runoff. Our results exhibit a decreasing trend in the April SCF_max values since 2000, largely in response to warming air temperatures in April. We identified snowmelt water as the dominant control on the observed increase in the runoff contribution in May across all four Siberian river basins. In addition, we detected that the interannual river runoff was predominantly controlled by interannual variations in the TWSA. The NDVI in June was strongly controlled by the timing of the snowmelt along with the surface air temperature and TWSA in June. The rate of increase in the freshwater flux from the four Siberian rivers decreased from 2000 to 2016, exhibiting large interannual variations corresponding to interannual variations in the TWSA. However, we identified a clear increase trend in the freshwater flux of ~4 km³/year when analysing the long-term 39-year historical record (1978–2016). Our results suggest that continued global warming will accelerate the transition towards the earlier timing of snowmelt and spring freshwater flux into the Arctic Ocean. Our findings also highlight the effects of earlier snowmelt on ecohydrological changes in the Northern Hemisphere.  相似文献   

Seasonal and inter-annual changes of volume density of martian CO₂ snow from time-variable elevation and gravity     

Koji Matsuo 《Icarus》2009,202(1):90-578

The martian atmosphere seasonally exchanges CO₂ with the surface by repeating condensation and sublimation, causing seasonal growth and decay of the polar CO₂ snowcaps. These processes leave two kinds of geodetic signatures, i.e. seasonal changes of the martian gravity field and of surface elevation of the snow-covered regions. Here we study gradual increase of the volume density of the martian snow due to compaction, by combining these two data sets during 1999-2001 covering three martian winters. We found that light fresh snow of slowly becomes denser reaching or more immediately before it thaws. The maximum snow density varies slightly from year to year, and between hemispheres. In the second southern winter, the density became as high as . This might have been caused by a dust storm activity, e.g. increased mixing of silicate particles and/or enhancement of sintering.  相似文献   

AFM study on surface nanotopography of matrix olivines in Allende carbonaceous chondrite     

Jun Nozawa  Junya Yamada  Ken Nagashima  Hitoshi Miura 《Icarus》2009,204(2):681-654

By means of nanoscale surface observation, we have proposed a new approach for investigating fine crystals of cosmic materials to reveal their origin and growth conditions. Several different morphologies of polyhedral fine olivines with faceted faces have been found in Allende carbonaceous chondrite (4.5 byr in geochronological age). In the present work, molecular level topography of the faceted matrix olivine by Atomic Force Microscopy (AFM) has successfully been performed. The matrix olivine found to have preserved growth step pattern on its surface even though quite long time has passed since they formed in the early Solar System. The surface pattern suggests that the faceted matrix olivine could have been condensed from the gas phase, and possibly that these olivine crystals had continued to grow under a rapid cooling condition (0.1-1 K s⁻¹). The estimated cooling rate agrees well with predictions based on hypothetical rapid heating and cooling events such as shock wave heating.  相似文献   

Thermochronology for the Granitic Pluton Related to Lead-Zinc Mineralization in Tsushima, Japan     

Hiroaki IKEMI  Nobutaka SHIMADA  Hitoshi CHIBA 《Resource Geology》2001,51(3):229-238

Abstract: K–Ar datings and oxygen isotope analyses revealed a cooling history of the Uchiyama granitic pluton, which is genetically related to the Pb-Zn deposits (Taishu mine) in the Tsushima Islands, Japan. The pluton intrudes into the Paleogene Taishu Group to form the biotite-hornfels zone, while the Taishu vein-type Pb–Zn deposits occur in fissures developed in the non-hornfels zone about 1 to 3 km westward from the contact. Amphibole and biotite K-Ar ages of the pluton have a wide range from 19 to 13 Ma. Oxygen isotopes of the biotite and coexisting quartz grains indicate that isotopic exchange reactions have occurred under subsolidus conditions, and that the K-Ar ages are affected by various cooling rates in the pluton. The mineralization age of the Taishu ore deposits is obtained for the first time to be 15.40.8 Ma by a K-Ar age of 2 M ₁–muscovite in a calcite–quartz–muscovite–chlorite veinlet of the Shintomi orebody. Whole rock K-Ar ages of biotite-hornfels near the pluton represent similar ages to the ore deposits. Using blocking temperature calculated from reported diffusivity for argon, the pluton was cooled from 560 to 350C in the period of 17 to 14 Ma. The vein formation took place after the time when temperature in wall rocks of the pluton had dropped below the brittle-plastic transition (about 400C). These results imply that the cooling of the pluton has caused injection of magmatic fluids into meteoric hydrothermal systems, and the Pb-Zn mineralization has occurred due to this mixing at the age of about 15 Ma.  相似文献   

THREE NEW GSJ ROCK REFERENCE SAMPLES: RHYOLITE JR-3, GABBRO JGB-2 AND HORNBLENDITE JH-1     

Shigeru TERASHIMA  Shiro ITOH  Masumi UJIIE  Hikari KAMIOKA  Tsuyoshi TANAKA  Hitoshi HATTORI 《Geostandards and Geoanalytical Research》1993,17(1):1-4

Three new rock reference samples, Rhyolite JR-3, Gabbro JGb-2 and Hornblendite JH-1 have been prepared by the Geological Survey of Japan for collaborative studies on their chemical composition. Twenty-eight major, minor and trace elements were determined and presented. The results of homogeneity tests showed that all elements are considered to be distributed homogeneously in each reference sample. Geological and mineralogical characteristics are also described.  相似文献   

A thermodynamic theory of the Grüneisen ratio at extreme conditions: MgO as an example     

Orson L. Anderson  Hitoshi Oda  Anastasia Chopelas  Donald G. Isaak 《Physics and Chemistry of Minerals》1993,19(6):369-380

The Grüneisen ratio, γ, is defined as γy=αK _TV/C_v. The volume dependence of γ(V) is solved for a wide range in temperature. The volume dependence of αK _T is solved from the identity (? ln(αK _T)/? ln V)T ≡ δ _T-K′. α is the thermal expansivity; K _T is the bulk modulus; C _V is specific heat; and δ _Tand K′ are dimensionless thermoelastic constants. The approach is to find values of δ _T and K′, each as functions of T and V. We also solve for q=(? ln γ/? ln V) where q=δ _T -K′+ 1-(? ln C _V/? ln V)T. Calculations are taken down to a compression of 0.6, thus covering all possible values pertaining to the earth's mantle, q=? ln γ/? ln V; δ _T=? ln α/? ln V; and K′= (?K _T/?P)T. New experimental information related to the volume dependence of δ _T, q, K′ and C _V was used. For MgO, as the compression, η=V/V ₀, drops from 1.0 to 0.7 at 2000 K, the results show that q drops from 1.2 to about 0.8; δ _T drops from 5.0 to 3.2; δ _T becomes slightly less than K′; ? ln C _V/? In V→0; and γ drops from 1.5 to about 1. These observations are all in accord with recent laboratory data, seismic observations, and theoretical results.  相似文献