Late Holocene hydrologic changes in northern New Zealand inferred from stable isotope values of aquatic cellulose in sediments from Lake Pupuke     

Alexander M. Heyng  Christoph Mayr  Andreas Lücke  Holger Wissel  Bernd Striewski 《Journal of Paleolimnology》2014,51(4):485-497

Isotopic records of aquatic cellulose are becoming increasingly important for palaeohydrological reconstructions, but widespread application of this climate proxy is hampered by minerogenic contamination that affects oxygen isotope measures in cellulose. Few records of isotopes in aquatic cellulose are available from palaeoclimate archives in the Southern Hemisphere. In this study, we used a new bulk cellulose extraction method and determined the oxygen (δ¹⁸O) and carbon (δ¹³C) isotope values in cellulose from a Holocene lake sediment core segment (7.2–1.1 cal ka BP) from Lake Pupuke, Auckland, New Zealand. Isotope values from modern, potential sources of sedimentary cellulose revealed the aquatic origin of the cellulose extracted from the core, and hence enabled inference of past lake water δ¹⁸O values from the δ¹⁸O of measured cellulose in the core. A shift to a more positive water balance in the lake was identified around 2.8 cal ka BP by a decrease in inferred lake water δ¹⁸O values. At that time, greater epilimnetic primary productivity is indicated by the higher δ¹³C values of sedimentary cellulose. Greater divergence between the δ¹³C values of cellulose and bulk organic matter suggests stronger stratification of the lake, likely caused by greater freshwater input. We discuss a possible link to a solar minimum that occurred at that time.  相似文献   

Ecological aspects of fin whale and humpback whale distribution during summer in the Norwegian Sea     

Leif Nøttestad  Lise D. Sivle  Bjørn A. Krafft  Lise Langård  Valantine Anthonypillai  Matteo Bernasconi  Herdis Langøy  Bjørn E. Axelsen 《Marine Ecology》2014,35(2):221-232

The Norwegian Sea is a migration and feeding ground for fin whales (Balaenoptera physalus) and humpback whales (Megaptera novaeangliae) in summer. During the last decade, significant structural changes in the prey community, including northerly expansion and movement in the distribution of pelagic fish species, have been reported from this ecosystem. However, little information on whale feeding ecology exists in the Norwegian Sea and surrounding waters. A total of 59 fin whales and 48 humpback whales were sighted during 864 h of observation over an observation distance of about 8200 nmi (15,200 km) in the Norwegian Sea from 15 July to 6 August 2006 and 2007. The fin whale group size, as mean (±SD), varied between one and five individuals (2.1 ± 1.2 ind.) and humpback whale group size varied between one and six individuals (2.5 ± 1.7 ind.). Fin‐ and humpback whales were observed mainly in the northern part of the study area, and were only found correlated with the presence of macro‐zooplankton in cold Arctic water. Humpback whales were not correlated with the occurrence of adult Norwegian spring‐spawning herring (Clupea harengus) except for the northernmost areas. Despite changes in the whale prey communities in the Norwegian Sea, no apparent changes in fin‐ or humpback whale distribution pattern could be found in our study compared to their observed summer distribution 10–15 years ago.  相似文献   

Open-source MATLAB implementation of consistent discretisations on complex grids   总被引：1，自引：0，他引：1  

Knut–Andreas Lie  Stein Krogstad  Ingeborg Skjelkv?le Ligaarden  Jostein Roald Natvig  Halvor M?ll Nilsen  B?rd Skaflestad 《Computational Geosciences》2012,16(2):297-322

Accurate geological modelling of features such as faults, fractures or erosion requires grids that are flexible with respect to geometry. Such grids generally contain polyhedral cells and complex grid-cell connectivities. The grid representation for polyhedral grids in turn affects the efficient implementation of numerical methods for subsurface flow simulations. It is well known that conventional two-point flux-approximation methods are only consistent for K-orthogonal grids and will, therefore, not converge in the general case. In recent years, there has been significant research into consistent and convergent methods, including mixed, multipoint and mimetic discretisation methods. Likewise, the so-called multiscale methods based upon hierarchically coarsened grids have received a lot of attention. The paper does not propose novel mathematical methods but instead presents an open-source Matlab? toolkit that can be used as an efficient test platform for (new) discretisation and solution methods in reservoir simulation. The aim of the toolkit is to support reproducible research and simplify the development, verification and validation and testing and comparison of new discretisation and solution methods on general unstructured grids, including in particular corner point and 2.5D PEBI grids. The toolkit consists of a set of data structures and routines for creating, manipulating and visualising petrophysical data, fluid models and (unstructured) grids, including support for industry standard input formats, as well as routines for computing single and multiphase (incompressible) flow. We review key features of the toolkit and discuss a generic mimetic formulation that includes many known discretisation methods, including both the standard two-point method as well as consistent and convergent multipoint and mimetic methods. Apart from the core routines and data structures, the toolkit contains add-on modules that implement more advanced solvers and functionality. Herein, we show examples of multiscale methods and adjoint methods for use in optimisation of rates and placement of wells.  相似文献   

An EELS study of near edge structures of the oxygen K-edge in spinels     

Susanne Nyquist  Ulf Hålenius 《Physics and Chemistry of Minerals》2014,41(4):255-265

Spectra of seven aluminate, ferrite and chromate spinels were collected at the oxygen K-edge in order to examine the effect of octahedral ion composition on the near edge structures and explore whether these may shed some light on previously reported major variations in the optical absorption coefficient (ε) for the spin-allowed d–d band transitions due to tetrahedrally coordinated Fe²⁺ in optical spectra of oxide spinels. Interpretation of the energy loss near edge structure (ELNES) spectra was aided using the multiple scattering code FEFF8.40. For the chromate samples spin polarised calculations were included. Gold’s iterative deconvolution method was utilized to improve on energy resolution, resulting in spectra equal in merit to those recorded by technically superior instruments. Results include absolute energy positions and interpretation of ELNES features in terms of transitions to available states. We conclude that the major causes of differences in the optical absorption coefficient mentioned above are hybridization between oxygen p- and octahedral metal orbitals. Our study does not support the idea presented by other authors that there exists a local antiferromagnetic ordering in MgCr₂O₄ at room temperature.  相似文献   

A 10Be‐based reconstruction of the last deglaciation in southern Sweden     

Johanna Anjar  Nicolaj K. Larsen  Lena Håkansson  Per Möller  Henriette Linge  Derek Fabel  Sheng Xu 《Boreas: An International Journal of Quaternary Research》2014,43(1):132-148

We present 23 cosmogenic surface exposure ages from 10 localities in southern Sweden. The new ¹⁰Be ages allow a direct correlation between the east and west coasts of southern Sweden, based on the same dating technique, and provide new information about the deglaciation of the Fennoscandian Ice Sheet in the circum‐Baltic area. In western Skåne, southernmost Sweden, a single cosmogenic surface exposure sample gave an age of 16.8±1.0 ka, whereas two samples from the central part of Skåne gave ages of 17.0±0.9 and 14.1±0.8 ka. Further northeast, in southern Småland, two localities gave ages ranging from 15.2±0.8 to 16.9±0.9 ka (n=5) indicating a somewhat earlier deglaciation of the area than has previously been suggested. Our third locality, in S Småland, gave ages ranging from 10.2±0.5 to 18.4±1.6 ka (n=3), which are probably not representative of the timing of deglaciation. In central Småland one locality was dated to 14.5±0.8 ka (n=3), whereas our northernmost locality, situated in northern Småland, was dated to 13.8±0.8 ka (n=3). Samples from the island of Gotland suggest deglaciation before 13 ka ago. We combined the new ¹⁰Be ages with previously published deglaciation ages to constrain the deglaciation chronology of southern Sweden. The combined deglaciation chronology suggests a rather steady deglaciation in southern Sweden starting at c. 17.9 cal. ka BP in NW Skåne and reaching northern Småland, ～200 km further north, c. 13.8 ka ago. Overall the new deglaciation ages agree reasonably well with existing deglaciation chronologies, but suggest a somewhat earlier deglaciation in Småland.  相似文献   

High-resolution aquifer analog of fluvial–aeolian sediments of the Guarani aquifer system     

Dominik Höyng  Fernando Mazo D’Affonseca  Peter Bayer  Edson Gomes de Oliveira  José Alexandre J. Perinotto  Fábio Reis  Holger Weiß  Peter Grathwohl 《Environmental Earth Sciences》2014,71(7):3081-3094

The Guarani aquifer system (GAS) represents one of the biggest aquifers in the world and is the most relevant groundwater resource in South America. For the first time, by combining field and laboratory measurements, a high-resolution aquifer analog model of fluvial–aeolian sediments of the GAS in São Paulo State (Brazil) is constructed. Three parallel sections of frontal outcrops, 28 m × 5.8 m, and two parallel sections of lateral outcrops, 7 m × 5.8 m, are recorded during open-pit mining of sandy sediments and describe in detail the three-dimensional distribution of the local lithofacies and hydrofacies. Variations of hydraulic conductivity, K, and porosity, n, are resolved on the centimeter scale, and the most permeable units of the fluvial–aeolian facies association are identified. The constructed aquifer analog model shows moderate hydraulic heterogeneity and a mean K value of 1.36 × 10^?4 m/s, which is greater than the reported range of K values for the entire GAS in São Paulo State. The results suggest that the examined sedimentary unit constitutes a relevant portion of the GAS in São Paulo State in the context of groundwater extraction and pollution. Moreover, the constructed aquifer analog is considered an ideal basis for future numerical model experiments, aiming at in-depth understanding of the groundwater flow and contaminant transport patterns at this GAS portion or at comparable fluvial–aeolian facies associations.  相似文献   

The pseudometeorite Angara     

Holger Pedersen 《Meteoritics & planetary science》2013,48(6):1091-1095

Several pallasites are known to have formed strewn fields with multiple fragments. Therefore, it seems possible that the famous Krasnojarsk pallasite—the Pallas Iron of 687 kg—could have been accompanied by one or more additional fragments that had not been recovered due to incomplete observations from the overgrown and remote place of fall. During a survey for literature accounts of distant fragments in such a hypothetical strewn field, a report of native iron was found, dating to 1847. The fragments of nickel‐free iron—amounting to at least a few kg—had been recovered 1836–1843 during placer gold mining north of the Angara River. The position of these finds is coincident with Burovaya, Murozhna, and Uderei, the three known fragments of the pseudometeorite Angara, all collected in 1885.  相似文献