Chemical Mechanism Development: Laboratory Studies and Model Applications     

Harald Geiger  Ian Barnes  Karl H. Becker  Birger Bohn  Theo Brauers  Birgit Donner  Hans-Peter Dorn  Manfred Elend  Carlos M. Freitas Dinis  Dirk Grossmann  Heinz Hass  Holger Hein  Axel Hoffmann  Lars Hoppe  Frank Hülsemann  Dieter Kley  Björn Klotz  Hans G. Libuda  Tobias Maurer  Djuro Mihelcic  Geert K. Moortgat  Romeo Olariu  Peter Neeb  Dirk Poppe  Lars Ruppert  Claudia G. Sauer  Oleg Shestakov  Holger Somnitz  William R. Stockwell  Lars P. Thüner  Andreas Wahner  Peter Wiesen  Friedhelm Zabel  Reinhard Zellner  Cornelius Zetzsch 《Journal of Atmospheric Chemistry》2002,42(1):323-357

Within the German Tropospheric Research Programme (TFS) numerous kinetic and mechanistic studies on the tropospheric reaction/degradation of the following reactants were carried out: oxygenated VOC, aromatic VOC, biogenic VOC, short-lived intermediates, such as alkoxy and alkylperoxy radicals.At the conception of the projects these selected groups were classes of VOC or intermediates for which the atmospheric oxidation mechanisms were either poorly characterised or totally unknown. The motivation for these studies was the attainment of significant improvements in our understanding of the atmospheric chemical oxidation processes of these compounds, particularly with respect to their involvement in photooxidant formation in the troposphere. In the present paper the types of experimental investigations performed and the results obtained within the various projects are briefly summarised. The major achievements are highlighted and discussed in terms of their contribution to improving our understanding of the chemical processes controlling photosmog formation in the troposphere.  相似文献   

Lumbering operations,lake humification and consequences for the structure of the lake foodweb: A case study using the LakeWeb-model for Lake Stora Kröntjärn,Sweden     

Lars Håkanson 《Aquatic Sciences - Research Across Boundaries》2002,64(2):185-197

This work presents a scenario to demonstrate how a given lake (Lake Stora Kröntjärn, Sweden) would respond to changes in colour related to lumbering operations in its watershed. The questions posed are: How would lake colour values increase, for how long would such increases last and how would this influence the production and biomasses of key functional organisms in the lake? The work is based on a comprehensive lake ecosystem model, LakeWeb, which accounts for production, biomasses, predation, abiotic/biotic interactions of nine key functional groups of organisms, phytoplankton, bacterioplankton, two types of zooplankton (herbivorous and predatory), two types of fish (prey and predatory), as well as zoobenthos, macrophytes and benthic algae. The LakeWeb-model has been calibrated and critically tested using empirical data and regressions for many lakes and it can capture typical functional and structural patterns in lakes. To obtain results like these by traditional field-work in one or more lakes would be very demanding (in terms of money, persons and time). It has been shown that single tributary peaks in colour concentrations are often "drowned" in weekly mean lake values. The lumbering operations must be extensive and continue for a long time to cause significant increases in tributary colour values in order to significantly influence fundamental lake foodweb structures. This means that it is often realistic to assume that lumbering activities do not strongly influence lake foodweb structures. The LakeWeb-model with the given mass-balance model for lake colour can be a useful tool to assess situations when this might not be valid.  相似文献   

Quantification of carbon flow from stable isotope fractionation in rice field soils with different organic matter content   总被引：1，自引：0，他引：1  

Holger Penning  Ralf Conrad   《Organic Geochemistry》2007,38(12):2058-2069

Rice fields are an important source for the greenhouse gas methane produced by acetoclastic and hydrogenotrophic methanogenesis. Fractionation of ¹³C/¹²C can in principle be used to quantify the relative contribution of these pathways, but our knowledge of isotopic fractionation during reduction of CO₂ and turnover of acetate in different methanogenic environments is still scarce. We therefore measured δ¹³C signatures in two types of anoxic Italian rice field soils, one with high and one with low degradable organic matter (OM) content. Both soils were incubated in the presence and absence of methyl fluoride, a specific inhibitor of acetoclastic methanogenesis. Optimization of methyl fluoride concentration resulted in complete inhibition of acetoclastic methanogenesis. CH₄ was then exclusively produced by hydrogenotrophic methanogenesis, allowing determination of the isotopic signatures and fractionation factors specific for this methanogenic pathway. Acetate, which was then no longer consumed, accumulated and was used for determination of the isotopic signature of the fermentatively produced acetate (both total acetate and methyl carbon of acetate). Hence, all isotopic signatures, including fractionation factors were determined for the methanogenic soil. These data, were then used for computation of the relative contribution of the two methanogenic pathways. In the high OM soil, the contribution of acetoclastic methanogenesis to total CH₄ production increased simultaneously with decreasing acetate concentration. In the low OM soil, methanogenesis from H₂/CO₂ was clearly greater than theoretically expected. Furthermore, isotope fractionation of hydrogenotrophic methanogenesis indicated that the in situ energy status of methanogens strongly depended on the availability of organic carbon in the rice field soil system. Collectively, our data show that the study of isotopic fractionation in methanogenic environments allows a deeper insight into the ongoing processes, which may be quite different in the same ecosystem with different content of degradable OM.  相似文献   

The Visible Solar Spectral Irradiance from 350 to 850 nm As Measured by the SOLSPEC Spectrometer During the ATLAS I Mission     

Gérard Thuillier  Michel Hersé  Paul C. Simon  Dietrich Labs  Holger Mandel  Didier Gillotay  Thomas Foujols 《Solar physics》1998,177(1-2):41-61

The SOLSPEC instrument has been built to carry out solar spectral irradiance measurements from 200 to 3000 nm. It consists of three spectrometers designed to measure the solar spectral irradiance in ultraviolet, visible, and infrared domains. It flew with the ATLAS I mission in March 1992. This paper is dedicated to the visible part of the solar spectrum. Comparisons with recent data are shown and differences below 450 nm are discussed.  相似文献   

Alkaline ultramafic lamprophyres and associated carbonatite dykes from the Kalix area,northern Sweden     

Peter Kresten  Erik åhman  Arild O. Brunfelt 《International Journal of Earth Sciences》1981,70(3):1215-1231

Alkahne ultramafic lamprophyres and associated carbonatite dykes form north-south trending dyke swarms. The lamprophyres are sub-divided into micaceous, picritic and breccia varieties. Carbonatites sensu stricto (beforsites) occur very subordinate.The dykes of the Kalix area show great similarities to petrographically related rocks from other Scandinavian occurrences (Sokli, Alnö and Fen). Major differences are found in their tectonic setting (regularly striking dyke swarms) and the REE-pattern (distinctly negative cerium anomalies).The following petrogenetic model is advanced for the Kalix dykes: (1) partial melting of upper mantle material, (2) Intrusion into a crustal magma chamber, fractional crystallization, (3) Interactions between crystallized material and the volatile phase (light REE depletion, oxidation of cerium), (4) Intrusion in fracture zones under horizontal tension.

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Zusammenfassung Alkalin-ultrabasiscbe Lamprophyre und begleitende KarbonatitgÄnge bilden nordsüdlidi streichende GangschwÄrme. Die Lamprophyre zeigen gewisse Ähnlichkeiten zu alnöitischen und kimberlitischen Gesteinen; sie wurden unterteilt in glimmerreiche und pikritische Lamprophyre sowie Brekzien. Karbonatite im engeren Sinn treten nur sehr untergeordnet auf; sie sind als Beforsite charakterisiert.Die Ganggesteine des Kalix-Gebiets weisen gro\e Ähnlichkeiten mit petrographiscb verwandten Gesteinen von anderen skandinavischen Vorkommen (Sokli, Alnö und Fen) auf. GrundsÄtzliche Unterschiede finden sich vor allem im tektonischen Auftreten (ziemlich konstant streichende GangschwÄrme) und im Verteilungsmuster der seltenen Erden (deutlich negative Cer-Anomalien).Die Bildung der Kalix-GÄnge wird folgenderweise erklÄrt: (1) Partielle Aufschmelzung des oberen Mantels, (2) Intrusion der Schmelze in eine krustale Magmakammer, gefolgt von fraktionierter Kristallisation, (3) Reaktion zwischen vorzugsweise kristallisiertem Material und der volatilen Phase (Entarmung an leichten seltenen Erden, Oxidation des Cers), (4) Intrusion in Bruchzonen, die horizonteller Dehnung ausgesetzt sind.

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Résumé Des lamprophyres alcalins ultrabasiques accompagnés de carbonatites forment des essaims de dykes de direction nord-sud. Les lamprophyres se subdivisent en variétés micacée, picritique ainsi que brÊchique. Les carbonatites sensu stricto sont rares et sont plutÔ des beforsites.Les dykes de la région de Kalix présentent de grandes similitudes avec des roches pétrographiquement apparentées d'autres localités Scandinaves (Sokli, Alnö et Fen). Les différences essentielles sont dues à leur situation tectonique (essaims de dykes de direction régulière) ainsi qu'à la distribution des Terres Rares (anomalie négative distincte de cérium).Le modèle pétrogénétique suivant est proposé pour les dykes de Kalix: (1) fusion partielle de matériau du manteau supérieur, (2) intrusion dans une chambre magmatique de l'écorce et cristallisation fractionnée, (3) interaction entre le material déjà cristallisé et la phase volatile (appauvrissement des éléments légers des Terres Rares, oxydation du cérium), (4) intrusion le long de zones de fracture dans des conditions d'extension horizontale.

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Mineral zoning as a record of P,T history of Precambrian eclogites and schists in western Tasmania     

Arne Råheim 《Lithos》1975,8(3):221-236

Ferromagnesian minerals, particularly garnet but also phengite, omphacite and talc, from eclogites and surrounding schists from the Lyell Highway-Collingwood river area, western Tasmania are compositionally zoned.In rocks which have suffered little secondary alteration the Mg-value ($\text{100 Mg}\text{Mg+Fe}{}^{\mathrm{++}}$) of granets increases from core to rim, while the Mg-value of the most important coexisting ferromagnesian phases (clinopyroxene, phengite and talc in different assemblages) decreases from core to rim. CaO decreases from core to rim in garnet. MnO may show little or no variation in garnet, or decrease from core to rim.When compared with experimental data, the zoning of these minerals can be uniquely explained by growth during changing P,T conditions. The eclogites and the surrounding schists have the same prograde P,T history.When determining the K_D-values of garnet and its coexisting ferromagnesian phases it is important to consider secondary rim alterations as well as the prograde zoning of the mineral.  相似文献   

Danish marine oil pollution policy     

Hans Ulrik Riisgård 《Marine pollution bulletin》1979,10(9):250-253

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Investigations on coastal upwelling off Northwest Africa and Portugal with empirical orthogonal functions     

Dipl.-Math. Holger Detlefsen  Prof. Dr. Peter Speth 《Ocean Dynamics》1980,33(5):210-221

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Temperature and pressure dependence of Fe-Mg partitioning between garnet and phengite,with particular reference to eclogites     

Erling J. Krogh  Arne Råheim 《Contributions to Mineralogy and Petrology》1978,66(1):75-80

Experimental data combined with data from natural rocks have been used to calibrate a geothermometer based on the distribution of Fe²⁺ and Mg between coexisting garnets and phengites. The pressure effect on the K _D -value appears to be considerable. The calculated thermometer is expressed as $$T(K) = \frac{{3685 + 77.1P(kb)}}{{InK_D + 3.52}}.$$ The use of this \(K_{D_{(FeO/MgO)} }^{ga + ph}\) geothermometer on eclogites with low Fe₂O₃ content, gives P-T values which are in good accordance with those obtained by other methods. The problems that arise when Fe³⁺ is present in larger amounts, are discussed.  相似文献   

Talc-garnet-kyanite-quartz schist from an eclogite-bearing terrane,Western Tasmania     

Arne Råheim  D. H. Green 《Contributions to Mineralogy and Petrology》1974,43(3):223-231

Talc-garnet-kyanite-quartz schist occurs in an eclogite-bearing terrane in the Precambrian of Western Tasmania. It is argued that this rock was formed at a pressure of ? 10 kb and a temperature of 600°±20° C. Chemical zoning in the garnet and talc preserves evidence of increasing temperature during growth of the major minerals.  相似文献