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91.
92.
Ajay Jasra David A. Stephens Kerry Gallagher Christopher C. Holmes 《Mathematical Geology》2006,38(3):269-300
In this paper we develop a generalized statistical methodology for characterizing geochronological data, represented by a distribution of single mineral ages. The main characteristics of such data are the heterogeneity and error associated with its collection. The former property means that mixture models are often appropriate for their analysis, in order to identify discrete age components in the overall distribution. We demonstrate that current methods (e.g., Sambridge and Compston, 1994) for analyzing such problems are not always suitable due to the restriction of the class of component densities that may be fitted to the data. This is of importance, when modelling geochronological data, as it is often the case that skewed and heavy tailed distributions will fit the data well. We concentrate on developing (Bayesian) mixture models with flexibility in the class of component densities, using Markov chain Monte Carlo (MCMC) methods to fit the models. Our method allows us to use any component density to fit the data, as well as returning a probability distribution for the number of components. Furthermore, rather than dealing with the observed ages, as in previous approaches, we make the inferences of components from the “true” ages, i.e., the ages had we been able to observe them without measurement error. We demonstrate our approach on two data sets: uranium-lead (U-Pb) zircon ages from the Khorat basin of northern Thailand and the Carrickalinga Head formation of southern Australia. 相似文献
93.
A synthetic Earth Gravity Model Designed Specifically for Testing Regional Gravimetric Geoid Determination Algorithms 总被引:1,自引:0,他引:1
I. Baran M. Kuhn S. J. Claessens W. E. Featherstone S. A. Holmes P. Vaníček 《Journal of Geodesy》2006,80(1):1-16
A synthetic [simulated] Earth gravity model (SEGM) of the geoid, gravity and topography has been constructed over Australia specifically for validating regional gravimetric geoid determination theories, techniques and computer software. This regional high-resolution (1-arc-min by 1-arc-min) Australian SEGM (AusSEGM) is a combined source and effect model. The long-wavelength effect part (up to and including spherical harmonic degree and order 360) is taken from an assumed errorless EGM96 global geopotential model. Using forward modelling via numerical Newtonian integration, the short-wavelength source part is computed from a high-resolution (3-arc-sec by 3-arc-sec) synthetic digital elevation model (SDEM), which is a fractal surface based on the GLOBE v1 DEM. All topographic masses are modelled with a constant mass-density of 2,670 kg/m3. Based on these input data, gravity values on the synthetic topography (on a grid and at arbitrarily distributed discrete points) and consistent geoidal heights at regular 1-arc-min geographical grid nodes have been computed. The precision of the synthetic gravity and geoid data (after a first iteration) is estimated to be better than 30 μ Gal and 3 mm, respectively, which reduces to 1 μ Gal and 1 mm after a second iteration. The second iteration accounts for the changes in the geoid due to the superposed synthetic topographic mass distribution. The first iteration of AusSEGM is compared with Australian gravity and GPS-levelling data to verify that it gives a realistic representation of the Earth’s gravity field. As a by-product of this comparison, AusSEGM gives further evidence of the north–south-trending error in the Australian Height Datum. The freely available AusSEGM-derived gravity and SDEM data, included as Electronic Supplementary Material (ESM) with this paper, can be used to compute a geoid model that, if correct, will agree to in 3 mm with the AusSEGM geoidal heights, thus offering independent verification of theories and numerical techniques used for regional geoid modelling.Electronic Supplementary Material Supplementary material is available in the online version of this article at http://dx.doi.org/10.1007/s00190-005-0002-z 相似文献
94.
Richard R. Goulet Jonathan Holmes Laurier Poissant David R.S. Lean Marc Amyot 《Geochimica et cosmochimica acta》2007,71(14):3393-3406
Porewater samples were obtained on five occasions during spring, summer and fall by in situ dialysis from three sites of a large freshwater wetland situated along the St. Lawrence River. These samples were analysed for total dissolved mercury ([Hg]T) and methylmercury ([MeHg]) concentrations and for complementary variables including dissolved sulfate, sulfide and elemental sulfur concentrations. Sediment cores were obtained on three occasions from one of these sites for the determination of total mercury ({Hg}T) and methylmercury ({MeHg}) concentration as well as mercury methyltransferase (HgMT) activity profiles. {MeHg} and HgMT activity varied with time and sediment depth. The porewater [Hg]T and [MeHg] depth profiles varied with time and among sites. Modeling the porewater [MeHg] profiles with a one-dimensional reaction-transport equation allowed identification of the sediment depths where MeHg is produced or consumed, as well as an estimate of the net in situ MeHg production rates in the sediments. The model-predicted depths of MeHg production, as well as the sulfate concentration and the HgMT activity depth distributions are all consistent with the involvement of sulfate reducing bacteria in the production of MeHg. 相似文献
95.
K. John Holmes 《Climatic change》2015,129(1-2):351-361
96.
Philippa Holmes James Rose Jonathan R. Lee Rene Barendregt Ian Candy James B. Riding Mark Lewis 《Proceedings of the Geologists' Association. Geologists' Association》2018,129(1):70-88
Although substantial work has been done on the pre-glacial terraces of East Anglia, very little systematic work has been done to understand the origin of river terraces in East Anglia that have formed since ice last covered the region. This paper records the results of studies of exposures and borehole records in ‘classical’ Quaternary terrace landforms that are considered to have formed since the Anglian (MIS 12) Glaciation, in the middle Waveney Valley. These features have been examined in terms of their morphological and sedimentological properties, in order to provide a detailed record of their form and composition, understand their processes of formation, and identify their stratigraphical status. The results show that the main body of the highest terrace (Homersfield Terrace, Terrace 3) is not composed of river sediments, but of shallow marine sediments, and is a remnant of early Middle Pleistocene Wroxham Crag. River sediments, in the form of Anglian age (MIS 12) glaciofluvial Aldeby Sands and Gravels also exist in the area as a channel fill, cut through the Wroxham Crag, and reflect outwash erosion and sedimentation from a relatively proximal ice margin to the west. The results mean that the interpretations previously presented for the terrace landforms of the middle Waveney valley are not applicable. The issue of why the terrace stratigraphy, hitherto identified in East Anglia cannot be related to that for the River Thames to the south and the rivers of Midland England to the west, still requires further research. 相似文献
97.
Gorm Heron Ken Parker Jim Galligan Thomas C. Holmes 《Ground Water Monitoring & Remediation》2009,29(3):56-65
In situ thermal desorption (ISTD) was used for the treatment of eight separate source zones containing chlorinated solvents in a tight loess (silt/clay) above the water table. The source areas were as much as 365 m (1200 feet) apart. A target volume of 38,200 m3 (49,950 cubic yards) of subsurface material to a depth of 9.1 m (30 feet) was treated in a period of 177 days. Energy was delivered through 367 thermal conduction heater borings, and vapors were extracted from 68 vertical vacuum wells. A vapor extraction and capture system, including a surface cover and vertical vacuum wells next to heater borings, provided for effective pneumatic control and capture of the chlorinated volatile organic compound (CVOC) vapors. A central treatment system, based on condensation and granular activated carbon filtration, was used to treat the vapors. Approximately 5675 kg (12,500 pounds) of contaminants was recovered in the extracted vapors. Forty-seven soil samples were used to document remedial performance. Based on these, the concentrations of the target contaminants were reduced to below the target remedial goals in all eight areas, typically with concentrations below 0.01 mg/kg in locations that had had CVOC concentrations higher than 1000 mg/kg. Turn-key costs for the thermal remediation were $3.9 million, and the unit treatment cost, including all utilities, was $103 per cubic meter treated ($79 per cubic yard). 相似文献
98.
Bulk δ15N values in surface sediment samples off the southwestern coast of Africa were measured to investigate the biogeochemical
processes occurring in the water column. Nitrate concentrations and the degree of utilization of the nitrate pool are the
predominant controls on sedimentary δ15N in the Benguela Current region. Denitrification does not appear to have had an important effect on the δ15N signal of these sediments and, based on δ15N and δ13C, there is little terrestrial input.
Received: 9 May 1996 / Revision received: 27 May 1997 相似文献
99.
Cross-shore hydrodynamics within an unsaturated surf zone 总被引:1,自引:0,他引:1
This paper concerns the hydrodynamics induced by random waves incident on a steep beach. New experimental results are presented on surface elevation and kinematic probability density functions, cross-shore variation in wave heights, the fraction of broken waves and velocity moments. The surf zone is found to be unsaturated at incident wave frequencies, with a significant proportion of the incident wave energy remaining at the shoreline in the form of bores. Wave heights in both the outer and inner surf zones are best described by a full Rayleigh distribution [Thornton, E.B., Guza, R.T., 1983. Transformation of wave height distribution. J. Geophys. Res. 88, 5925–5938], rather than a truncated Rayleigh distribution as used by Battjes and Janssen (1978) [Battjes, J.A, Janssen, J.P., 1978. Energy loss and setup due to breaking of random waves. Proc. 16th Int. Conf. Coastal Eng. ASCE, New York, pp. 569–588]. A new parametric wave transformation model is outlined which provides explicit expressions for the fraction of broken waves and the energy dissipation rate within the surf zone. On steep beaches, the model appears to offer improved predictive capabilities over the original Battjes and Janssen model. Cross-shore variations in the velocity variance and velocity moments are best described using Linear Gaussian wave theory, with less than 20% of the velocity variance in the inner surf zone due to low frequency energy. 相似文献
100.
Reactions of levoglucosan with produced from Fenton chemistry were studied in solution serving as a proxy for biomass burning aerosols. Two modes of oligomerization
(≤2000 u) were observed for reaction times between 1 and 7 days using matrix-assisted laser desorption time-of-flight mass
spectrometry (MALDI-TOF-MS) and laser desorption ionization time-of-flight mass spectrometry (LDI-TOF-MS). Single-mass unit
continuum mass distributions with dominant −2 u patterns were measured and superimposed by a +176/+162 u oligomer series.
This latter oligomer pattern was attributed to a Criegee rearrangement (+14 u) of levoglucosan, initiated by , forming a lactone (176 u). The acid-catalyzed reaction of any ROH from levoglucosan (+162 u) forms an ester through transesterification
of the lactone functionality, whereupon propagation forms polyesters. Proposed products and chemical mechanisms are suggested
as sources and precursors of humic-like substances (HULIS), which are known to possess a large saccharic component and are
possibly formed from biomass burning aerosols (Andreae, Global Biomass Burning, MIT Press, Cambridge, Massachusetts, 3–21,
1991). 相似文献